Vehicular Pollution Monitoring Using IOT

The air quality in metropolises is demeaning as a result of a complex commerce between natural and artificial environmental conditions. With the increase in urbanization and industrialization and lack of control on emigrations and use of catalytic transformers, a great quantum of particulate and poisonous feasts is produced. The ideal of this design is to cover air pollution on roads and track vehicles which beget pollution over a specified limit. Increased use of motorcars is a serious problem that has been around for a veritably long time. This paper gives check of different systems used to cover vehicular pollution and proposes use of Internet of Effects (IoT) to address this problem. Then, combination of Poisonous Gas Detectors and Radio Frequency Identification (RFID) trailing system is used to cover vehicular pollution records anytime anywhere. Keywords: loT, WS, Arduino, RFlD, Gas Sensor

A Study to Verify the Practicality of Introducing an Arson Dog (K-9) Unit in Field Investigations

Combustion improvers are often found in acts of arson. Until recently, in fire investigations in Korea, these substances have been identified only by the olfactory sense of the fire inspectors or conventional gas detectors. These methods are neither efficient nor feasible in damaged buildings or large areas. Research on the canine sense of smell has shown that a dog can distinguish the remains of combusted hydrocarbon compounds, even in a large, open area. Field tests confirmed that arson dogs can find combustion improvers at fire sites in about five to 77 s. Therefore, this study verified the practicality of introducing arson dog units in field investigations of fire sites to identify combustion improvers sprayed for committing arson.

Muon detection at FCC-ee

Muons provide a clean experimental signature, typically traversing the whole experimental apparatus without decaying. Muon detection systems are therefore usually located at a rather large distance from the primary interaction vertex after all other sub-detectors. As such, experimental apparatuses at FCC-ee will certainly employ very large muon systems, covering areas of a few thousand square meters. For obvious reasons of cost, the most suitable detectors to realise these large muon systems are gas detectors. In particular, in recent years, micro-pattern gas detectors (MPGDs) have undergone very interesting developments, providing several new types of detectors with very good spatial and time resolution, high efficiency, high rate capability and high radiation tolerance. The good position and time resolution makes a MPGD an excellent particle tracker, reconstructing tracks at 4–5 m from the primary interaction vertex with sub-mm precision. Therefore MPGDs, apart from efficiently detecting muons, can precisely track and help identifying also hypothesized long lived particles (LLP) that would decay outside of the central trackers. MPGDs have the distinct advantage of being, at least for some detectors and some parts of them, mass-producible by industry, since they employ materials and manufacturing procedures that are used extensively for printed circuit boards (PCB) production. A particularly innovative MPGD, the $$\mu $$ μ RWELL, is considered as a possible candidate to build the large muon system of the IDEA detector concept for FCC-ee and is described in some more detail. Other technologies that could be considered for the realisation of muon detection systems are also briefly discussed.

On the Possibility of Reducing the Measurement Error of Spectrometers with Proportional Gas Detectors in the RC-CR Formation of Output Signals

When analyzing the elemental composition of the substance under study, the task is to determine the true intensity of the radiation lines. The error in determining the intensity is caused by errors in the spectrometer. Reducing the error can be achieved by taking into account (correcting) the errors, as well as reducing them. In this paper, we propose a method for reducing the measurement error by reducing the miscalculations with an acceptable deterioration in the energy resolution of the spectrometer. An algorithm for automatically setting the duration of the output signals of the spectrometric amplifier and the width of the differential discriminator window for amplitude analysis is presented.

On Analysis of Topological Properties for Terbium IV Oxide via Enthalpy and Entropy Measurements

A relation between topological indices and thermodynamics properties of terbium IV oxide has been established by using a rational method as it was found the most efficient method based on mean squared error (MSE). Terbium IV oxide has huge application as an insulator in modern technologies such as microelectronics, gas detectors, and luminiferous owing to mechanical and thermal stability, high dielectric constant, radiation resistance, and variable electrical conductivity. The chemical graph and topological indices have attracted the research community due to their potential application in discrete mathematics, biology, and chemistry. Our commitment is to investigate topological indices and thermodynamic properties of terbium IV oxide that depend on an innovative data utilitarian. Moreover, a relationship between topological indices and curve fitting has been established as an application point of view. All curve fittings have been found using MATLAB software.

The Past, Present and Future in Tube- and Paper-Based Colorimetric Gas Detectors

Colorimetric gas detectors have been widely applied in many fields such as environmental sciences, industrial hygiene, process control, forensic science and indoor air quality monitoring. They have a history of about 100 years and include devices such as gas detector tubes and paper-based gas detectors. The sensitivity and selectivity of the colorimetric gas detector are relatively high compared to other types of gas detectors such as semiconductor, catalytic combustion and electrochemical gas detectors. Detection of gas concentration can be performed by the naked eye in some colorimetric gas detectors. These methods do not require an electrical power source and are simple, so they are suitable for field operations. This review introduces the history and provides a general overview of the development in the research of colorimetric gas detectors. Recently, the sensitivity and selectivity of colorimetric gas detectors have improved. New materials such as enzymes or particles with a large surface area have been utilized to improve selectivity and sensitivity. Moreover, new gas detectors without toxic materials have been developed to reduce the environmental load. At present, there is a rapid development of IoT sensors in many industrial fields, which might extend the applications of colorimetric gas detectors in the near future.

The UV Effect on the Chemiresistive Response of ZnO Nanostructures to Isopropanol and Benzene at PPM Concentrations in Mixture with Dry and Wet Air

Towards the development of low-power miniature gas detectors, there is a high interest in the research of light-activated metal oxide gas sensors capable to operate at room temperature (RT). Herein, we study ZnO nanostructures grown by the electrochemical deposition method over Si/SiO2 substrates equipped by multiple Pt electrodes to serve as on-chip gas monitors and thoroughly estimate its chemiresistive performance upon exposing to two model VOCs, isopropanol and benzene, in a wide operating temperature range, from RT to 350 °C, and LED-powered UV illumination, 380 nm wavelength; the dry air and humid-enriched, 50 rel. %, air are employed as a background. We show that the UV activation allows one to get a distinctive chemiresistive signal of the ZnO sensor to isopropanol at RT regardless of the interfering presence of H2O vapors. On the contrary, the benzene vapors do not react with UV-illuminated ZnO at RT under dry air while the humidity’s appearance gives an opportunity to detect this gas. Still, both VOCs are well detected by the ZnO sensor under heating at a 200–350 °C range independently on additional UV exciting. We employ quantum chemical calculations to explain the differences between these two VOCs’ interactions with ZnO surface by a remarkable distinction of the binding energies characterizing single molecules, which is −0.44 eV in the case of isopropanol and −3.67 eV in the case of benzene. The full covering of a ZnO supercell by H2O molecules taken for the effect’s estimation shifts the binding energies to −0.50 eV and −0.72 eV, respectively. This theory insight supports the experimental observation that benzene could not react with ZnO surface at RT under employed LED UV without humidity’s presence, indifference to isopropanol.

Outdoor measurements of thoron progeny in a 232Th-rich area with deposition-based alpha track detectors and corrections for wind bias

Radon and thoron progeny are important contributors to dose from naturally occurring radionuclides, especially in high background areas and with naturally occurring radioactive material (NORM) legacy sites. Due to the short half-life of thoron, measurements of thoron progeny with a longer half-life should be used for risk and dose assessment. Deposition-based alpha track detectors for such progeny are, however, biased by air movement, especially outdoors where winds may be strong but variable. We used deposition detectors for thoron progeny and radon progeny, as well as alpha track gas detectors for 220Rn and 222Rn, outdoors within the Fen complex in Norway, an area with both elevated levels of naturally occurring radionuclides and NORM legacy sites. Different detector types were used and showed different results. We measured airflow along deposition detectors during deployment to assess wind bias and used statistical models to attain location-specific sheltering factors. These models assess how explanatory terms like point measurements with anemometer, predicted airflow along detectors, and levels of 220Rn and 222Rn explained variation in deposition detector measurements of TnP and RnP. For all the detector types, unrealistically, high equilibrium values (F) were found between progenitor noble gas and progeny before correcting for wind bias. Results suggest a magnitude of wind bias on TnP deposition detectors being a fraction of 0.74–0.96 (mean: 0.87) of the total measurement.

Influences of Work Function Changes in NO2 and H2S Adsorption on Pd-Doped ZnGa2O4(111) Thin Films: First-Principles Studies

The work function variations of NO2 and H2S molecules on Pd-adsorbed ZnGa2O4(111) were calculated using first-principle calculations. For the bonding of a nitrogen atom from a single NO2 molecule to a Pd atom, the maximum work function change was +1.37 eV, and for the bonding of two NO2 molecules to a Pd atom, the maximum work function change was +2.37 eV. For H2S adsorption, the maximum work function change was reduced from −0.90 eV to −1.82 eV for bonding sulfur atoms from a single and two H2S molecules to a Pd atom, respectively. Thus, for both NO2 and H2S, the work function change increased with an increase in gas concentration, showing that Pd-decorated ZnGa2O4(111) is a suitable material in NO2/H2S gas detectors.