scholarly journals The Effects of Temperature on the Growth of a Lead-Free Perovskite-Like (CH3NH3)3Sb2Br9 Single Crystal for An MSM Photodetector Application

Sensors ◽  
2021 ◽  
Vol 21 (13) ◽  
pp. 4475
Author(s):  
Chien-Min Hun ◽  
Ching-Ho Tien ◽  
Kuan-Lin Lee ◽  
Hong-Ye Lai ◽  
Lung-Chien Chen

We have fabricated a photodetector based on (CH3NH3)3Sb2Br9 (MA3Sb2Br9) lead-free perovskite-like single crystal, which plays an important role in the optoelectronic characteristics of the photodetector as a perovskite-like photosensitive layer. Here, MA3Sb2Br9 single crystals were synthesized by an inverse temperature crystallization process with a precursor solution at three different growth temperatures, 60 °C, 80 °C, and 100 °C. As a result, a MA3Sb2Br9 single crystal with an optimum growth temperature of 60 °C presented a low trap density of 2.63 × 1011 cm−3, a high charge carrier mobility of 0.75 cm2 V−1 s−1, and excellent crystal structure and optical absorption properties. This MA3Sb2Br9 perovskite-like photodetector displayed a low dark current of 8.09 × 10−9 A, high responsivity of 0.113 A W−1, and high detectivity of 4.32 × 1011 Jones.

Author(s):  
Yuanbo Cheng ◽  
Menghua Zhu ◽  
Fangbao Wang ◽  
Ruichen Bai ◽  
Jinshan Yao ◽  
...  

The understanding and tailoring of crystalline defects have been a cornerstone of established semiconductors technological deployment. Here, we report the secondary phase (SP) defects of CsPb2Br5 in CsPbBr3 crystals grown...


Nanoscale ◽  
2021 ◽  
Author(s):  
Thayer Walmsley ◽  
Yaqiong Xu

Group IVB transition metal dichalcogenides (TMDCs) have attracted significant attention due to their predicted high charge carrier mobility, large sheet current density, and enhanced thermoelectric power. Here, we investigate the...


Author(s):  
Naveen Kumar Tailor ◽  
Partha Maity ◽  
Makhsud I. Saidaminov ◽  
Narayan Pradhan ◽  
Soumitra Satapathi

Crystals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 39
Author(s):  
Seunghyun Rhee ◽  
Kunsik An ◽  
Kyung-Tae Kang

Organic-inorganic hybrid perovskite materials have attracted tremendous attention as a key material in various optoelectronic devices. Distinctive optoelectronic properties, such as a tunable energy band position, long carrier diffusion lengths, and high charge carrier mobility, have allowed rapid progress in various perovskite-based optoelectronic devices (solar cells, photodetectors, light emitting diodes (LEDs), and lasers). Interestingly, the developments of each field are based on different characteristics of perovskite materials which are suitable for their own applications. In this review, we provide the fundamental properties of perovskite materials and categorize the usages in various optoelectronic applications. In addition, the prerequisite factors for those applications are suggested to understand the recent progress of perovskite-based optoelectronic devices and the challenges that need to be solved for commercialization.


2009 ◽  
Vol 19 (37) ◽  
pp. 6688 ◽  
Author(s):  
Zesheng An ◽  
Junsheng Yu ◽  
Benoit Domercq ◽  
Simon C. Jones ◽  
Stephen Barlow ◽  
...  

2006 ◽  
Vol 510-511 ◽  
pp. 842-845 ◽  
Author(s):  
Noriko Bamba ◽  
Kentaro Kato ◽  
Toshinori Taishi ◽  
Takayuki Hayashi ◽  
Keigo Hoshikawa ◽  
...  

Langasite (La3Ga5SiO14: denoted by LGS) single crystal is one of the lead free piezoelectric materials with high piezoelectricity that is maintained up to its melting point (1470°C). Although LGS single crystals have usually been grown by Czochralski (CZ) method in oxygen contained atmosphere to prevent evaporation of Ga, they were grown by the vertical Bridgman (VB) method in Ar atmosphere without oxygen, and their properties were evaluated in this work. Transparent and colorless LGS single crystals were successfully obtained without Ga evaporation by the VB method in Ar atmosphere, and their resistivity at room temperature was much higher than that grown by conventional CZ method. Piezoelectric constant d11 of the crystal grown by the VB method was 6 x 10-12 C/N, which was close to that of the crystal grown by CZ method. The colorless transparent LGS single crystal turned to orange and its resistivity decreased by annealing in air. Since an orange-colored transparent LGS single crystal has been grown by conventional CZ method, this indicates that color change and the resistivity decrease of LGS crystal is caused by extra interstitial oxygen atoms in the crystal.


2017 ◽  
Vol 51 (4) ◽  
pp. 488-491 ◽  
Author(s):  
A. V. Emelianov ◽  
A. V. Romashkin ◽  
K. A. Tsarik ◽  
A. G. Nasibulin ◽  
V. K. Nevolin ◽  
...  

2015 ◽  
Vol 51 (38) ◽  
pp. 8120-8122 ◽  
Author(s):  
Kwang Hun Park ◽  
Kwang Hee Cheon ◽  
Yun-Ji Lee ◽  
Dae Sung Chung ◽  
Soon-Ki Kwon ◽  
...  

The selenophene-substitution can lead to a higher crystalline order as well as a high charge carrier mobility in isoindigo-based polymers.


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