Centimeter-Sized Single Crystal of a One-Dimensional Lead-Free Mixed-Cation Perovskite Ferroelectric for Highly Polarization Sensitive Photodetection

2021 ◽  
Vol 143 (40) ◽  
pp. 16758-16767
Author(s):  
Weichuan Zhang ◽  
Maochun Hong ◽  
Junhua Luo
Keyword(s):  
Single Crystal ◽  
Lead Free ◽  
One Dimensional ◽  
Mixed Cation

scholarly journals Dark Self-Healing-Mediated Negative Photoconductivity of a Lead-Free Cs3Bi2Cl9 Perovskite Single Crystal

2021 ◽  
pp. 2286-2292
Author(s):  
Naveen Kumar Tailor ◽  
Partha Maity ◽  
Makhsud I. Saidaminov ◽  
Narayan Pradhan ◽  
Soumitra Satapathi
Keyword(s):  
Single Crystal ◽  
Lead Free ◽  
Self Healing ◽  
Negative Photoconductivity

The Characteristic of the La3Ga5SiO14 Single Crystal Grown by Vertical Bridgman Method in Ar Atmosphere

2006 ◽  
Vol 510-511 ◽  
pp. 842-845 ◽  
Author(s):  
Noriko Bamba ◽  
Kentaro Kato ◽  
Toshinori Taishi ◽  
Takayuki Hayashi ◽  
Keigo Hoshikawa ◽  
...  
Keyword(s):  
Melting Point ◽  
Single Crystal ◽  
Single Crystals ◽  
Room Temperature ◽  
Color Change ◽  
Piezoelectric Materials ◽  
Lead Free ◽  
Piezoelectric Constant ◽  
Interstitial Oxygen ◽  
Vertical Bridgman

Langasite (La3Ga5SiO14: denoted by LGS) single crystal is one of the lead free piezoelectric materials with high piezoelectricity that is maintained up to its melting point (1470°C). Although LGS single crystals have usually been grown by Czochralski (CZ) method in oxygen contained atmosphere to prevent evaporation of Ga, they were grown by the vertical Bridgman (VB) method in Ar atmosphere without oxygen, and their properties were evaluated in this work. Transparent and colorless LGS single crystals were successfully obtained without Ga evaporation by the VB method in Ar atmosphere, and their resistivity at room temperature was much higher than that grown by conventional CZ method. Piezoelectric constant d11 of the crystal grown by the VB method was 6 x 10-12 C/N, which was close to that of the crystal grown by CZ method. The colorless transparent LGS single crystal turned to orange and its resistivity decreased by annealing in air. Since an orange-colored transparent LGS single crystal has been grown by conventional CZ method, this indicates that color change and the resistivity decrease of LGS crystal is caused by extra interstitial oxygen atoms in the crystal.

Synthesis, IR spectrum, thermal behaviour and crystal structure of a novel one-dimensional cyano-bridged zinc(II)/nickel(II) complex

2005 ◽  
Vol 220 (1) ◽  
Author(s):  
Ahmet Karadag ◽  
Hümeyra Pasaoglu ◽  
Gökhan Kastas ◽  
Orhan Büyükgüngör
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Ir Spectrum ◽  
Polymeric Chain ◽  
X Ray Diffraction ◽  
Bimetallic Complex ◽  
One Dimensional ◽  
X Ray

AbstractThe cyano-bridged heteronuclear coordination polymer of zinc(II)/nickel(II) has been prepared by N-(2-hydroxyethyl)-ethylendiamine (hydet-en), alternatively named 2-(2-aminoethylamino)-ethanol and characterised by IR and thermal analysis. In the bimetallic complex, the decomposition of hydet-en ligands is seen to be endothermic whereas that of the cyano ligands is found to be exothermic. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. The crystal structure of the zinc(II)-nickel(II) complex consists of a one-dimensional polymeric chain –Zn(hydet-en)

scholarly journals Record-Low and Anisotropic Thermal Conductivity of a Quasi-One-Dimensional Bulk ZrTe5 Single Crystal

2018 ◽  
Vol 10 (47) ◽  
pp. 40740-40747 ◽  
Author(s):  
Jie Zhu ◽  
Tianli Feng ◽  
Scott Mills ◽  
Peipei Wang ◽  
Xuewang Wu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Single Crystal ◽  
One Dimensional ◽  
Anisotropic Thermal Conductivity

scholarly journals The Synthesis and Characterization of a Novel One-Dimensional Bismuth (III) Coordination Polymer as a Precursor for the Production of Bismuth (III) Oxide Nanorods

Crystals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 113
Author(s):  
Younes Hanifehpour ◽  
Babak Mirtamizdoust ◽  
Jaber Dadashi ◽  
Ruiyao Wang ◽  
Mahboube Rezaei ◽  
...  
Keyword(s):  
Single Crystal ◽  
Coordination Compound ◽  
Organic Ligand ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography ◽  
Oxide Nanorods ◽  
Pure Phase ◽  
3D Framework

A novel Bi (III) coordination compound, [Bi(HQ)(Cl)4]n ((Q = pyridine-4-carbaldehyde thiosemicarbazone), was prepared in this research using a sonochemical technique. SEM, infrared spectroscopy (IR), XRD, and single-crystal X-ray analysis were utilized to analyze the Bi(III) coordination compound. The structure determined using single-crystal X-ray crystallography indicates that the coordination compound is a 1D polymer in solid state and that the coordination number of bismuth (III) ions is six, (BiSCl5), with one S donor from the organic ligand and five Cl donors from anions. It is equipped with a hemidirectional coordination sphere. It is interesting that the ligand has been protonated in the course of the reaction with a Cl- ion balancing the charge. This compound’s supramolecular properties are directed and regulated by weak directional intermolecular interactions. Through π–π stacking interactions, the chains interact with one another, forming a 3D framework. Thermolysis of the compound at 170 °C with oleic acid resulted in the formation of pure phase nanosized Bi (III) oxide. SEM technique was used to examine the morphology and size of the bismuth (III) oxide product produced.

scholarly journals SIMULATION OF SINGLE CRYSTAL ONE DIMENSIONAL ZnO RODS ARRAY GROWTH PROCESS

2021 ◽  
Author(s):  
Andrey Sharapov ◽  
Igor Matyushkin
Keyword(s):  
Zinc Oxide ◽  
Single Crystal ◽  
Gas Phase ◽  
Growth Process ◽  
Silicon Oxide ◽  
Phase Growth ◽  
One Dimensional ◽  
Zno Rods

In this work, the formation of zinc oxide arrows by gas-phase growth on the surface of silicon oxide is simulated.

scholarly journals Comparative study on the performance of piezo-active 1–3-type composites with lead-free components

2021 ◽  
pp. 2160003
Author(s):  
Ashura N. Isaeva ◽  
Vitaly Yu. Topolov
Keyword(s):  
Single Crystal ◽  
Piezoelectric Coefficient ◽  
Piezoelectric Properties ◽  
Volume Fraction ◽  
Lead Free ◽  
Figures Of Merit ◽  
Piezoelectric Energy ◽  
Harvesting Systems ◽  
Porous Matrices ◽  
Large Anisotropy

Piezoelectric properties and related figures of merit are studied in novel 1–3-type composites based on ferroelectric domain-engineered lead-free single crystal with the relatively large longitudinal piezoelectric coefficient [Formula: see text]. Relationships between the piezoelectric properties and the set of figures of merit are analyzed for the 1–3 and 1–3–0 composites that contain the same single-crystal and polymer components. For a composite characterized by 1–3–0 connectivity, an influence of a porous piezo-passive matrix on the figures of merit and their volume-fraction behavior is considered additionally. A large anisotropy of figures of merit is observed in the 1–3–0 composite with specific porous matrices. A diagram is put forward to show volume-fraction regions of the large anisotropy of figures of merit of the studied 1–3–0 composite. Due to large figures of merit and their considerable anisotropy, the studied lead-free composites can be applied in piezoelectric energy-harvesting systems, sensors, transducers, and so on.

scholarly journals Mixed Ca/Sr salt forms of salicylic acid: tuning structure and aqueous solubility

2018 ◽  
Vol 74 (2) ◽  
pp. 131-138 ◽  
Author(s):  
Pamela Allan ◽  
Jean-Baptiste Arlin ◽  
Alan R. Kennedy ◽  
Aiden Walls
Keyword(s):  
Salicylic Acid ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Feature ◽  
Structural Changes ◽  
Aqueous Solubility ◽  
Single Crystal Diffraction ◽  
One Dimensional ◽  
The One ◽  
Salt Forms

Ten isostructural single-crystal diffraction studies of mixed cation Ca/Sr salt forms of the salicylate anion are presented, namely catena-poly[[diaquacalcium(II)/strontium(II)]-bis(μ2-2-hydroxybenzoato)], [Ca1–x Sr x (C7H5O3)2(H2O)2] n , where x = 0, 0.041, 0.083, 0.165, 0.306, 0.529, 0.632, 0.789, 0.835 and 1. The structure of an isostructural Sr/Ba species, namely catena-poly[[diaquastrontium(II)/barium(II)]-bis(μ2-2-hydroxybenzoato)], [Sr0.729Ba0.271(C7H5O3)2(H2O)2], is also described. The Ca/Sr structures form a series where, with increasing Sr content, the unit cell expands in both the crystallographic a and c directions (by 1.80 and 3.18%, respectively), but contracts slightly in the b direction (−0.31%). The largest percentage structural expansion lies parallel to the direction of propagation of the one-dimensional coordination polymer that is the primary structural feature. This structural expansion is thus associated with increased M—O distances. Aqueous solubility measurements show that solubility generally increases with increasing Sr content. Thus, tuning the composition of these mixed counter-ion salt forms leads to systematic structural changes and allows solubility to be tuned to values between those for the pure Ca and Sr species.

Enhanced fatigue resistance and lattice dynamics induced by the strong local strain in Fe-doped KTa1-xNbxO3 single crystal

2021 ◽  
Author(s):  
Xiaolin Huang ◽  
Peng Tan ◽  
Yu Wang ◽  
Yao Zhang ◽  
Xiangda Meng ◽  
...  
Keyword(s):  
Single Crystal ◽  
Fatigue Resistance ◽  
Lattice Dynamics ◽  
Piezoelectric Materials ◽  
Local Strain ◽  
Lead Free ◽  
Fatigue Properties ◽  
Practical Applications ◽  
Local Structures ◽  
The Impact

Improvement of durability is greatly important for the practical applications of lead-free-doped piezoelectric materials. However, the promotional mechanism of anti-fatigue properties and the impact on local structures from ion dopants...

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