scholarly journals Heavy Metals in Bottom Sediments of Reservoirs in the Lowland Area of Western Poland: Concentrations, Distribution, Sources and Ecological Risk

Water ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 56 ◽  
Author(s):  
Mariusz Sojka ◽  
Joanna Jaskuła ◽  
Marcin Siepak
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Ecological Risk ◽  
Bottom Sediments ◽  
Sampling Site ◽  
Point Sources ◽  
Lowland Area ◽  
The Mean ◽  
The Impact ◽  
Geogenic Sources

The paper presents the results of a study of heavy metals (HMs) concentrations in six retention reservoirs located in the lowland area of western Poland. The objectives of this study were to analyze the Cd, Cr, Cu, Ni, Pb and Zn concentrations, assess contamination and ecological risk, analyze the spatial variability of HM concentrations and identify potential sources and factors determining the concentration and spatial distribution. The bottom sediment pollution by HMs was assessed on the basis of the index of geo-accumulation (Igeo), enrichment factor (EF), pollution load index (PLI) and metal pollution index (MPI). To assess the ecological risk associated with multiple HMs, the mean probable effect concentration (PEC) quotient (Qm-PEC) and the toxic risk index (TRI) were used. In order to determine the similarities and differences between sampling sites in regard to the HM concentration, cluster analysis (CA) was applied. Principal component analysis (PCA) was performed to assess the impact of grain size, total organic matter (TOM) content and sampling site location on HM spatial distribution. Additionally, PCA was used to assess the impact of catchment, reservoir characteristics and hydrological conditions. The values of Igeo, EF, MPI and PLI show that Cd, Cr, Cu, Ni and Pb mainly originate from geogenic sources. In contrast, Zn concentrations come from point sources related to agriculture. The mean PEC quotient (Qm-PEC) and TRI value show that the greatest ecological risk occurred at the inlet to the reservoir and near the dam. The analysis showed that the HMs concentration depends on silt and sand content. However, the Pb, Cu, Cd and Zn concentrations are associated with TOM as well. The relationship between individual HMs and silt was stronger than with TOM. The PCA results indicate that HMs with the exception of Zn originate from geogenic sources—weathering of rock material. However, the Ni concentration may additionally depend on road traffic. The results show that a reservoir with more frequent water exchange has higher HMs concentrations, whereas the Zn concentration in bottom sediments is associated with agricultural point sources.

scholarly journals Evaluation of ecological risk, source and spatial distribution of some heavy metals in marine sediments in the Middle and Eastern Black Sea region, Turkey

2021 ◽  
Author(s):  
Aylin Apaydın ◽  
Hatice Kabaoğlu ◽  
Gökhan Apaydın ◽  
Murat Şirin ◽  
Erhan Cengiz ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Black Sea ◽  
Ecological Risk ◽  
Risk Index ◽  
Agricultural Practices ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Black Sea Region ◽  
The Mean

Abstract In the present study, the concentration levels of heavy metals such as Mn, Fe, Ni, Cu, Zn, Cr and Pb in sediment samples collected from 16 sampling locations in the Middle and Eastern Black Sea regions, Turkey was measured using energy dispersive X–ray fluorescence spectroscopy (EDXRF). Various pollution parameters and methods, such as the enrichment factor (EF), geo–accumulation index (Igeo), contamination factor (CF), pollution load index (PLI), ecological risk index (RI), and geo–spatial distribution patterns were used to assess in detail the pollution status, ecological risks and sources of metals in sediment. The mean concentrations of Mn, Fe, Ni, Cu, Zn, Cr and Pb were found to be 565.38, 46,000, 34.38, 104.06, 109.88, 87.31, and 32.31 mg/kg, respectively. Results showed that the mean concentrations of Cu, Zn and Pb exceeded the crustal shale value, with the exception of Mn, Fe, Ni and Cr. According to the calculated pollution parameters, although minimal or moderate pollution was detected in the area investigated, it was determined that there was a very low ecological risk. Multivariate statistical analysis results showed that Cu, Zn, and Pb levels in the investigated region were slightly influenced by anthropogenic inputs such as mining and agricultural practices. In addition, the geo–spatial distributions of Cu, Zn, Fe and Pb were found to be higher in this region due to the mining activities carried out in the Eastern Black Sea region.

scholarly journals Analysis of Spatial Variability of River Bottom Sediment Pollution with Heavy Metals and Assessment of Potential Ecological Hazard for the Warta River, Poland

Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 327
Author(s):  
Joanna Jaskuła ◽  
Mariusz Sojka ◽  
Michał Fiedler ◽  
Rafał Wróżyński
Keyword(s):  
Heavy Metals ◽  
Bottom Sediment ◽  
Bottom Sediments ◽  
Risk Index ◽  
Point Sources ◽  
Sediment Pollution ◽  
Sample Collection ◽  
Effect Concentration ◽  
Ecological Hazard ◽  
River Bottom

Pollution of river bottom sediments with heavy metals (HMs) has emerged as a main environmental issue related to intensive anthropopressure on the water environment. In this context, the risk of harmful effects of the HMs presence in the bottom sediments of the Warta River, the third longest river in Poland, has been assessed. The concentrations of Cr, Ni, Cu, Zn, Cd, and Pb in the river bottom sediments collected at 24 sample collection stations along the whole river length have been measured and analyzed. Moreover, in the GIS environment, a method predicting variation of HMs concentrations along the whole river length, not at particular sites, has been proposed. Analysis of the Warta River bottom sediment pollution with heavy metals in terms of the indices: the Geoaccumulation Index (Igeo), Enrichment Factor (EF), Pollution Load Index (PLI), and Metal Pollution Index (MPI), has proved that, in 2016, the pollution was heavier than in 2017. Assessment of the potential toxic effects of HMs accumulated in bottom sediments, made on the basis of Threshold Effect Concentration (TEC), Midpoint Effect Concentration (MEC), and Probable Effect Concentration (PEC) values, and the Toxic Risk Index (TRI), has shown that the ecological hazard in 2017 was much lower. Cluster analysis revealed two main groups of sample collection stations at which bottom sediments showed similar chemical properties. Changes in classification of particular sample collection stations into the two groups analyzed over a period of two subsequent years indicated that the main impact on the concentrations of HMs could have their point sources in urbanized areas and river fluvial process.

scholarly journals Assessment of heavy metals contamination and associated risks in shallow groundwater sources from three different residential areas within Ibadan metropolis, southwest Nigeria

2021 ◽  
Vol 11 (5) ◽  
Author(s):  
Saheed Adekunle Ganiyu ◽  
Abimbola Temitope Oyadeyi ◽  
Azeem Adedeji Adeyemi
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Urban Area ◽  
Ecological Risk ◽  
Water Samples ◽  
Risk Index ◽  
Shallow Groundwater ◽  
World Health ◽  
Southwest Nigeria ◽  
The Mean

AbstractThis study has been conducted to appraise the concentrations of selected heavy metals and total dissolved solids (TDSs) in the drinking water from shallow wells in parts of Ibadan metropolis, southwest Nigeria. Fifteen (15) water samples were collected from three representative residential locations [traditional core area (TCA), peri-urban area (PUA), and urban area (UA)] for geochemical analysis. Heavy metals and TDS were analyzed with the aid of atomic absorption spectrophotometer and calibrated meter, respectively. The mean concentration (mg/L) of Zn, Pb Mn, Fe, and Cd has been 3.930, 0.658, 0.0304, 1.698, and 0.501, respectively, and as a consequence, the order of abundance of studied metals was Zn > Fe > Pb > Cd > Mn. Concentrations of Zn, Fe, Pb, and Cd were higher than recommended standards in 60%, 86.7%, 100%, and 100% of groundwater samples, respectively. However, at all points tested, the mean concentrations of Mn and TDS in water samples lie within the safe limits set by World Health Organization. The evaluation of geoaccumulation index (Igeo), enrichment factor (EF), and contamination factor suggests that representative water samples were low-to-moderate contamination. The potential ecological risk index advocates low-to-moderate ecological risk in TCA and PUA, while it demonstrated exclusive “moderate” risk in UA. Further, the range of pollution load index (PLI) (0.55–1.32) in both TCA and PUA shows nil-to-moderate pollution status, while PLI values > 1 in UA indicate moderate contaminated state. The degree of contamination in groundwater showed the following trends: UA > TCA > PUA in the study area. Moreover, the results of EF and quantification of contamination of analyzed metals in water samples indicate geogenic and anthropogenic inputs. The contribution of studied metals to the incidence of non-cancer risk via oral intake within the residential sites follows the order: cadmium > lead > zinc > iron > manganese. The hazard index as a result of ingested heavy metals for the three population classes surpasses the acceptable range in the order of infant < child < adult. Cadmium and lead made considerable impact to the estimation of cancer risk in the study area for the three human population categories. Factor analysis extracted only one component that explained 94.64% of the entire variance, while cluster analysis identified three distinct groups based on similar water quality characteristics. Based on the findings of the study, awareness programs toward protecting the shallow groundwater sources should be launched, encouraged, and sustained. Moreover, the study suggests better hygienic practices and pre-treatment of contaminated water before consumption.

scholarly journals Influence of Bottom Sediments Physicochemical Characteristics on Distribution of Microelements in the Crimean Shelf Water Areas

2020 ◽  
Author(s):  
E. A. Kotelyanets ◽  
K. I. Gurov ◽  
◽  
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Spatial Distribution ◽  
Organic Carbon ◽  
Bottom Sediments ◽  
Clay Fraction ◽  
Zinc Content ◽  
Physicochemical Characteristics ◽  
Water Area ◽  
Pollution Level

The paper presents the results of studies of the Kalamitsky Bay bottom sediments pollution level with microelements and heavy metals (Pb, Zn, Cu, Ni, Co, Cr, V, As, Sr, Ti, Fe, Mn) in comparison with the content of these microelements and heavy metals in the Balaklava Bay sediments. The paper analyzes data obtained during expeditions on the R/V Professor Vodyanitsky in the Kalamitsky Gulf in August 2011 (seaward part) and on the R/V Rioni in September 2012 (coastal area) as well as in the Balaklava Bay in October 2018. Content of microelements and heavy metals in bottom sediments of the studied water areas was determined by the X-ray fluorescence method using Spectroscan MAX-G device. For the water area of the Kalamitsky Gulf, the features of the studied trace element spatial distribution are considered, groups of trace elements with different spatial distribution patterns are identified. The correlation analysis determined influence of physicochemical characteristics of the sediments on distribution and accumulation of trace elements. In the water area of the Kalamitsky Gulf, a statistically significant correlation was observed of nickel, iron and zinc content with the clay fraction; dependance of increased concentrations of zinc, nickel and chrome on the content of organic carbon and predominance of lead in highcarbonate sediments. For the Balaklava Bay, the maximum positive values of correlations with the pelitic-silty fraction were noted for iron, manganese, vanadium and chrome; organic carbon correlates with chrome, iron, nickel and copper, whereas carbonates correlate with strontium. Similar patterns were observed earlier in the Sevastopol region bays, Feodosiya Gulf and Kerch Strait.

scholarly journals Distribution, Ecological Risk Assessment, and Bioavailability of Cadmium in Soil from Nansha, Pearl River Delta, China

2019 ◽  
Vol 16 (19) ◽  
pp. 3637 ◽  
Author(s):  
Fangting Wang ◽  
Changsheng Huang ◽  
Zhihua Chen ◽  
Ke Bao
Keyword(s):  
Spatial Distribution ◽  
Human Health ◽  
Ecological Risk ◽  
Risk Index ◽  
Potential Ecological Risk ◽  
Health Examination ◽  
Quaternary Sediments ◽  
Deep Soil ◽  
Accumulation Index ◽  
The Impact

Background: Cadmium (Cd) pollution poses a threat to human health. Examination of the spatial distribution of Cd in soils can be used to assess the risks posed to humans and the environment. Objective: This study determined the enrichment rules and factors influencing Cd pollution in Nansha, and evaluated the pollution characteristics and bioavailability of Cd in quaternary sediments through 7 deep soil profiles (0–200 cm), 4 boreholes, and 348 topsoil (0–20 cm) samples. Methods: The geo-accumulation index (Igeo) and the potential ecological risk index (Er) were used to assess ecological risk, and bioavailability was determined using multivariate, spatial distribution, and correlation matrix analyses. Results: From the Er, 52% of Nansha was classed as being at very high risk of Cd pollution; a further 36% was classed as dangerous. Cadmium was more abundant in clay soils than in sandy soils. Bioavailable Cd in quaternary sediments was significantly affected by the total Cd, and labile Cd accounted for more than half of the total Cd. Changes in pH mainly affected bioavailable Cd rather than total Cd, affecting the overall bioavailability of Cd. Conclusions: Nansha soils are commonly and seriously contaminated with Cd. An appropriate remediation treatment approach should be used to reduce Cd bioavailability. Furthermore, planting structures in farmland should be adjusted to avoid the impact of heavy metals on human health.

scholarly journals ENVIRONMENTAL IMPACT ASSESSMENT OF HEAVY METALS EFFLUIENT (CHROMIUM & NICKEL) RELEASED INTO ROMI RIVER, KADUNA STATE: A CASE STUDY

2020 ◽  
Vol 4 (3) ◽  
pp. 704-707
Author(s):  
Muhammad Mudassir Usman ◽  
Muhammad Nuruddeen Abdulkareem ◽  
Abdullahi Muhammad ◽  
Kabiru Hamza
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Industrial Effluents ◽  
World Health ◽  
Refinery Effluent ◽  
Iron Nickel ◽  
The Mean ◽  
Health Organization ◽  
The Impact

Industrial effluents discharged into the river poses a serious threat to our environment; the research examines the impact of some heavy metals of Kaduna refinery effluent into the Romi River. It asserts the nature of effluent released into the water body and also the impact of effluent on water quality. However the important water quality became relatively slowly as early human could only judge water quality through the physical senses of sight, taste and smell, now a days there is an increase of contamination of natural water bodies by industrial effluents in developing and densely populated countries like Nigeria, because rivers are major means of waste disposal and especially effluents from industries nearby. The data used in this research were generated from direct field measurement of pH, Conductivity, and Turbidity, heavy metal profiles (Chromium & Nickel) from Kaduna Refinery Effluent. The mean concentrations of the metals; chromium, iron, nickel, and zinc with the standard deviation were found to be: < 0.01 ± 0.1 mg/kg, and 0.06 ± 0.1 mg/kg. This study has shown that the mean concentration of chromium and Nickel found to be lower than the World Health Organization (WHO) acceptable limits while the concentration values of nickel 0.06 ± 0.1 mg/kg and iron 0.06 ± 0.1 mg/kg as found to be higher than the WHO, acceptable limits of the metals) obtained at the effluent points and this implicate the industry adjacent to the area as one of the sources of heavy metals in the river.

scholarly journals Heavy metals contamination of the sediments of the south-eastern Baltic Sea: the impact of economic development

Baltica ◽  
2019 ◽  
Vol 32 (1) ◽  
pp. 51-62
Author(s):  
Alexander Krek ◽  
Aleksandr Danchenkov ◽  
Marina Ulyanova ◽  
Darya Ryabchuk
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Baltic Sea ◽  
Metal Concentration ◽  
Bottom Sediments ◽  
Heavy Metal Concentration ◽  
South Eastern ◽  
Heavy Metals Contamination ◽  
The Impact ◽  
Eastern Baltic

The scope of the study was to assess the impact of potential sources of Cu, Zn, Co, Ni, and Cr on bottom sediments of the Russian sector of the south-eastern Baltic Sea. A total of 68 samples were taken and analyzed for grain-size (laser diffraction and sieve method) and heavy metal concentration (atomic absorption spectroscopy method). To avoid the influence of the sorption capacity of the fine-grained sediments to accumulate the pollutants, the normalization of the heavy metal concentration to Fe was applied. The environmental indices (contamination factor and modified degree of contamination) were calculated. The research has shown the contribution of oil platform, pipelines, ports and wastewater treatment facilities on the geochemical composition of bottom sediments. The authors have identified the level of heavy metals contamination of the middle parts of the Curonian and Vistula spits as a result of alongshore transport of pollutants.

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