scholarly journals Effect of quasi-stationary electric field on charge transfer in poly(phenylene oxide) based composites

2020 ◽  
Vol 1 (2) ◽  
pp. 52-55
Author(s):  
Alexey A. Kononov ◽  
Rene Alejandro Castro Arata ◽  
Natalia A. Nikonorova
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Phenylene Oxide ◽  
Stationary Electric Field

scholarly journals An In-Situ Reaction Route to Molecular Level Dispersed Bisimide and ZnO Nanorod Hybrids with Efficient Photo-Induced Charge Transfer

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Chunzheng Lv ◽  
Lirong He ◽  
Jiahong Tang ◽  
Feng Yang ◽  
Chuhong Zhang
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Self Assembly ◽  
Molecular Level ◽  
Surface Photovoltage ◽  
Zno Nanorod ◽  
In Situ Reaction ◽  
Perylene Bisimide ◽  
Induced Charge

AbstractAs an important photoconductive hybrid material, perylene/ZnO has attracted tremendous attention for photovoltaic-related applications, but generally faces a great challenge to design molecular level dispersed perylenes/ZnO nanohybrids due to easy phase separation between perylenes and ZnO nanocrystals. In this work, we reported an in-situ reaction method to prepare molecular level dispersed H-aggregates of perylene bisimide/ZnO nanorod hybrids. Surface photovoltage and electric field-induced surface photovoltage spectrum show that the photovoltage intensities of nanorod hybrids increased dramatically for 100 times compared with that of pristine perylene bisimide. The enhancement of photovoltage intensities resulting from two aspects: (1) the photo-generated electrons transfer from perylene bisimide to ZnO nanorod due to the electric field formed on the interface of perylene bisimide/ZnO; (2) the H-aggregates of perylene bisimide in ZnO nanorod composites, which is beneficial for photo-generated charge separation and transportation. The introduction of ordered self-assembly thiol-functionalized perylene-3,4,9,10-tetracarboxylic diimide (T-PTCDI)/ ZnO nanorod composites induces a significant improvement in incident photo-to-electron conversion efficiency. This work provides a novel mentality to boost photo-induced charge transfer efficiency, which brings new inspiration for the preparation of the highly efficient solar cell.

scholarly journals Interfacial chemical bond and internal electric field modulated Z-scheme Sv-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xuehua Wang ◽  
Xianghu Wang ◽  
Jianfeng Huang ◽  
Shaoxiang Li ◽  
Alan Meng ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Hydrogen Evolution ◽  
Density Functional ◽  
Monochromatic Light ◽  
Density Functional Theory Calculations ◽  
Internal Electric Field ◽  
Apparent Quantum Yield ◽  
Paramagnetic Resonance ◽  
High Hydrogen

AbstractConstruction of Z-scheme heterostructure is of great significance for realizing efficient photocatalytic water splitting. However, the conscious modulation of Z-scheme charge transfer is still a great challenge. Herein, interfacial Mo-S bond and internal electric field modulated Z-scheme heterostructure composed by sulfur vacancies-rich ZnIn2S4 and MoSe2 was rationally fabricated for efficient photocatalytic hydrogen evolution. Systematic investigations reveal that Mo-S bond and internal electric field induce the Z-scheme charge transfer mechanism as confirmed by the surface photovoltage spectra, DMPO spin-trapping electron paramagnetic resonance spectra and density functional theory calculations. Under the intense synergy among the Mo-S bond, internal electric field and S-vacancies, the optimized photocatalyst exhibits high hydrogen evolution rate of 63.21 mmol∙g−1·h−1 with an apparent quantum yield of 76.48% at 420 nm monochromatic light, which is about 18.8-fold of the pristine ZIS. This work affords a useful inspiration on consciously modulating Z-scheme charge transfer by atomic-level interface control and internal electric field to signally promote the photocatalytic performance.

scholarly journals Restraining Surface Charge Accumulation and Enhancing Surface Flashover Voltage through Dielectric Coating

Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 750
Author(s):  
Jixing Sun ◽  
Sibo Song ◽  
Xiyu Li ◽  
Yunlong Lv ◽  
Jiayi Ren ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Electric Fields ◽  
Transition Process ◽  
Metallic Particle ◽  
Particle Charging ◽  
Insulating Surfaces ◽  
Surface Flashover ◽  
Charging Time ◽  
The Impact

A conductive metallic particle in a gas-insulated metal-enclosed system can charge through conduction or induction and move between electrodes or on insulating surfaces, which may lead to breakdown and flashover. The charge on the metallic particle and the charging time vary depending on the spatial electric field intensity, the particle shape, and the electrode surface coating. The charged metallic particle can move between the electrodes under the influence of the spatial electric field, and it can discharge and become electrically conductive when colliding with the electrodes, thus changing its charge. This process and its factors are mainly affected by the coating condition of the colliding electrode. In addition, the interface characteristics affect the particle when it is near the insulator. The charge transition process also changes due to the electric field strength and the particle charging state. This paper explores the impact of the coating material on particle charging characteristics, movement, and discharge. Particle charging, movement, and charge transfer in DC, AC, and superimposed electric fields are summarized. Furthermore, the effects of conductive particles on discharge characteristics are compared between coated and bare electrodes. The reviewed studies demonstrate that the coating can effectively reduce particle charge and thus the probability of discharge. The presented research results can provide theoretical support and data for studying charge transfer theory and design optimization in a gas-insulated system.

MEASUREMENT OF LEAKAGE CURRENTS AND QUASI-STATIONARY ELECTRIC FIELD IN THE SURFACE AREA OF THE ISS RS IN THE EARTH'S IONOSPHERE

2021 ◽  
pp. 5-21
Author(s):  
Yury V. LISAKOV ◽  
Olga V. LAPSHINOVA ◽  
Nikolay M. PUSHKIN ◽  
Viktor P. KONOSHENKO ◽  
Nikolay V. MATVEEV ◽  
...  
Keyword(s):  
Electric Field ◽  
Spatial Configuration ◽  
Flow Direction ◽  
Electrical Measurements ◽  
Leakage Currents ◽  
Current Leakage ◽  
Stationary Electric Field ◽  
Charged Component ◽  
Stage 1 ◽  
Orbital Data

The paper presents the results of analysis of electrical measurements performed in the space experiment "Impulse (stage 1)" on the Service module of the ISS RS. This experiment investigated the effects of the interaction of the charged component of the ionosphere to the surface of large KA, which is the ISS. This paper analyses the measurement of quasi-stationary electric field and current leakage, was, respectively, sensors of the vibration type and flat probes from the Complex control electrophysical parameters (CCEP), developed by SPJ MT. To study the dependence of measurements from the ionosphere flow direction to the surface of the ISS RS was installed two sets of sensors with the direction of the angle of "visibility" in the Nadir (towards the Earth) and to "satellite footprint " (against the velocity vector of the ISS). Carried out analysis of common regularities measurements depending on the sun-shadow environment on orbit ISS motions and depending on current geophysical dynamics of the ionosphere. Massive the measurements including more than 170 telemetric sessions were analyzed. More than 11000 hours of measurements current of leakage (or runoff current) and measurements of quasi-stationary electric field with discretization 1s and UT binding to each point were analysed. The data measurements, geophysical and orbital data were collected in an electronic album. It is shown that experimental data correlate with the crossing time of the ISS boundaries known geophysical structures: the noon Meridian, the Main ionospheric failure (MIF), the boundaries diffuse intrusion (BDI), the Equatorial Geomagnetic anomaly (EA). In this regard, despite the specificity of the ISS (the spacecraft super big sizes, the most complex spatial configuration) similar measurements, nevertheless, are quite suitable for monitoring researches of some features of an ionosphere at the level of F2 layer with a temporary scale from 1s and can be used for more detailed study of the geophysical structures and related effects in the ionosphere. In addition, the results obtained can be used for the analysis of disturbances of electromagnetic conditions near the surface of the ISS RS, for monitoring potential and currents of leakage on the surface of the ISS. Keywords: electrophysical measurements, sensors of the vibration type, flat probes, electric field, current leakage, geophysical structure, ionosphere

The dependence of the rate of electrochemical charge transfer on the electric field at the metal-electrolyte interface

1972 ◽  
Vol 25 (2) ◽  
pp. 231 ◽  
Author(s):  
DB Matthews
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Potential Energy ◽  
Electric Field ◽  
Electric Fields ◽  
Potential Energy Curves ◽  
Energy Curve ◽  
Electrolyte Interface ◽  
Activated State ◽  
Wide Range

Electric fields at the metal-electrolyte interface are very high (of the order of 107 V/cm) and one intuitively expects that these fields should have a profound influence on the movement of charged species such as ions and electrons at the interface. Qualitatively, such field effects manifest themselves as deviations from linearity of Tafel plots or as a dependence of the symmetry factor on electrode potential. It is shown that Gurney's potential energy curve representation of charge transfer reactions yields only small changes in β over a wide range of potential, with the anharmonic (Morse) curves showing smaller changes than the harmonic (parabolic) curves. Superposition of the double layer electric field on these potential energy curves increases the curvature of the Tafel plots, but the effect is still not very large, being within the limits of uncertainty in determining the correct form of the potential energy curves. The effect of electric field on electron transfer is considered both from the viewpoint of change in electron transfer distance arising from a dependence of coordinates of the activated state on potential and from the viewpoint of a direct effect on the electron transfer barrier (analogous to field electron emission). The field emission effects are found to be even less than the effects of the field on the proton transfer potential energy barrier.

scholarly journals Hydrocarbon flame in non-stationary electric field

2018 ◽  
Author(s):  
V. S. Venediktov ◽  
P. K. Tretyakov ◽  
A. V. Tupikin
Keyword(s):  
Electric Field ◽  
Hydrocarbon Flame ◽  
Stationary Electric Field
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