Heating ability of elongated magnetic nanoparticles

Low-frequency hysteresis loops and specific absorption rate (SAR) of various assemblies of elongated spheroidal magnetite nanoparticles have been calculated for a range of particle semiaxis ratios a/b = 1.0–3.0. The SAR of a dilute randomly oriented assembly of magnetite nanoparticles in an alternating magnetic field of moderate frequency, f = 300 kHz, and amplitude H0 = 100–200 Oe is shown to decrease significantly with an increase in the aspect ratio of nanoparticles. In addition, there is a narrowing and shift of the intervals of optimal particle diameters towards smaller particle sizes. However, the orientation of a dilute assembly of elongated nanoparticles in a magnetic field leads to an almost twofold increase in SAR at the same frequency and amplitude of the alternating magnetic field, the range of optimal particle diameters remaining unchanged. The effect of the magneto-dipole interaction on the SAR of a dilute assembly of oriented clusters of elongated magnetite nanoparticles has also been investigated depending on the volume fraction of nanoparticles in a cluster. It has been found that the SAR of the assembly of oriented clusters decreases by approximately an order of magnitude with an increase in the volume fraction of nanoparticles in a cluster in the range of 0.04–0.2.

Heating ability of elongated magnetic nanoparticles

Low-frequency hysteresis loops and specific absorption rate (SAR) of various assemblies of elongated spheroidal magnetite nanoparticles have been calculated for a range of particle semiaxis ratios a/b = 1.0 – 3.0. The SAR of a dilute randomly oriented assembly of magnetite nanoparticles in an alternating magnetic field of moderate frequency, f = 300 kHz, and amplitude H0 = 100 - 200 Oe is shown to decrease significantly with an increase in the aspect ratio of nanoparticles. In addition, there is a narrowing and shift of the intervals of optimal particle diameters towards smaller particle sizes. However, the orientation of a dilute assembly of elongated nanoparticles in a magnetic field leads to an almost twofold increase in SAR at the same frequency and amplitude of the alternating magnetic field, the range of optimal particle diameters remaining unchanged. The effect of the magneto-dipole interaction on the SAR of an assembly of oriented clusters of elongated magnetite nanoparticles has also been investigated depending on the volume fraction of nanoparticles in a cluster. It has been found that the SAR of the assembly of oriented clusters decreases by approximately an order of magnitude with an increase in the volume fraction of nanoparticles in a cluster in the range 0.04 - 0.2.

Terahertz Radiation Generation Process In The Medium Based On The Array of The Elongated Nanoparticles

We conduct a theoretical study and numerical simulations of terahertz radiation generation in the medium based on armchair-edge nanoribbons and zigzag nanotubes with metallic conductivity. The multicascade mechanism of radiation generation is considered in the task of terahertz radiation generation. The level of the injection current in nanoparticle arrays has been estimated. The task expands to the similar medium where radiation current is generated with the use of infrared radiation stimulated absorption, for example, radiation of a CO2 laser. Numerical results for the effective dielectric function have been obtained with the use of the effective medium-approximation, the Maxwell-Garnett’s theory and the Maxwell-Garnett model with the Clausius-Mossotti correction (geometrical model arrays).

Characterization and antibacterial properties of Eriobotrya japonica extract loaded silver-nanoparticles

Background:: Currently, developing methods for the formation of nanoparticles with antimicrobial properties based on green chemistry are the research hotspots. In this research green biosynthesis of Eriobotrya japonica extract loaded silver nanoparticles and their characterization were the main objectives to achieve. Methods:: Green synthesis of E. japonica leaves extract-loaded silver nanoparticles (AgNPs) was carried out and its effect on bacterial growth was examined. The reduction of silver ions in solution was observed using UV-Vis spectrophotometer. The properties of AgNPs were assessed using Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). Also, their antibacterial effects were checked against Staphylococcus aureus and Escherichia coli. Results:: It was revealed that 5-50 nm sized spherical to elongated nanoparticles were synthesized that possessed comparatively better antibacterial potential against E. coli and S. aureus than conventional extract of the E. japonica leaves. Conclusions:: Green synthesis and effective utilization of Eriobotrya japonica extract loaded silver nanoparticles is a promising approach for nanoparticle production avoiding negative environmental impacts.

Machine learning approach for elucidating and predicting the role of synthesis parameters on the shape and size of TiO2 nanoparticles

In the present work a series of design rules are developed in order to tune the morphology of TiO2 nanoparticles through hydrothermal process. Through a careful experimental design, the influence of relevant process parameters on the synthesis outcome are studied, reaching to the develop predictive models by using Machine Learning methods. The models, after the validation and training, are able to predict with high accuracy the synthesis outcome in terms of nanoparticle size, polydispersity and aspect ratio. Furthermore, they are implemented by reverse engineering approach to do the inverse process, i.e. obtain the optimal synthesis parameters given a specific product characteristic. For the first time, it is presented a synthesis method that allows continuous and precise control of NPs morphology with the possibility to tune the aspect ratio over a large range from 1.4 (perfect truncated bipyramids) to 6 (elongated nanoparticles) and the length from 20 to 140 nm.

Bio-fabricated ZnO nanoparticles: direct sunlight-driven selective photodegradation, antibacterial activity, and thermoluminescence-emission characteristics

Zinc oxide (ZnO) nanoparticles were prepared via a Gliricidia sepium leaf extract-assisted green synthetic route. Near-spherical and elongated nanoparticles were obtained according to morphology analysis.

Orientation Distributions of Cellulose Nanofibrils and Nanocrystals in Confined Flow

The pursuit of sustainable and environmentally friendly materials has been driving a tremendous interest in biobased alternatives in the last decade. Nanocellulose has been widely seen as a prime contender due to its impressive properties as well as being abundant and biodegradable. Recently, it has been demonstrated how nanocellulosic materials can be hydrodynamically aligned in flows and assembled continuously into materials with tunable macroscopic properties. However, the aligning mechanisms of the highly entangled system of elongated nanoparticles in different flow situations still remain largely unknown. Here, we investigate the orientation distributions of cellulose nanofibrils and nanocrystals (CNF and CNC) in a straight quadratic channel at various flow rates using small-angle X-ray scattering (SAXS), where CNF and CNC are aligned by strong shear flow close to the walls. In dilute systems, CNC behave as Brownian ellipsoids, while at semi-dilute concentrations there seems to be a limit to how high alignment of CNF and CNC can be achieved in a shear dominated flow even though particle interactions clearly aid in aligning the system at low flow rates. Furthermore, we show how some essential parameters in the orientational distribution can be obtained with polarized optical microscopy.

Orientation Distributions of Cellulose Nanofibrils and Nanocrystals in Confined Flow

The pursuit of sustainable and environmentally friendly materials has been driving a tremendous interest in biobased alternatives in the last decade. Nanocellulose has been widely seen as a prime contender due to its impressive properties as well as being abundant and biodegradable. Recently, it has been demonstrated how nanocellulosic materials can be hydrodynamically aligned in flows and assembled continuously into materials with tunable macroscopic properties. However, the aligning mechanisms of the highly entangled system of elongated nanoparticles in different flow situations still remain largely unknown. Here, we investigate the orientation distributions of cellulose nanofibrils and nanocrystals (CNF and CNC) in a straight quadratic channel at various flow rates using small-angle X-ray scattering (SAXS), where CNF and CNC are aligned by strong shear flow close to the walls. In dilute systems, CNC behave as Brownian ellipsoids, while at semi-dilute concentrations there seems to be a limit to how high alignment of CNF and CNC can be achieved in a shear dominated flow even though particle interactions clearly aid in aligning the system at low flow rates. Furthermore, we show how some essential parameters in the orientational distribution can be obtained with polarized optical microscopy.

The Design of Optical Circuit-Analog Absorbers through Electrically Small Nanoparticles

In the last few years, the perfect absorption of light has become an important research topic due to its dramatic impact in photovoltaics, photodetectors, color filters and thermal emitters. While broadband optical absorption is relatively easy to achieve using bulky devices, today there is a strong need and interest in achieving the same effects by employing nanometric structures that are compatible with modern nanophotonic components. In this paper, we propose a general procedure to design broadband nanometer-scale absorbers working in the optical spectrum. The proposed devices, which can be considered an extension to optics of microwave circuit-analog absorbers, consist of several layers containing arrays of elongated nanoparticles, whose dimensions are engineered to control both the absorption level and the operational bandwidth. By combining a surface-impedance homogenization and an equivalent transmission-line formalism, we define a general analytical procedure that can be employed to achieve a final working design. As a relevant example, we show that the proposed approach allows designing an optical absorber exhibiting a 20% fractional bandwidth on a thickness of λ/4 at the central frequency of operation. Full-wave results confirming the effectiveness of the analytical findings, as well as some considerations about the experimental realization of the proposed devices are provided.