scholarly journals THE INFLUENCE OF THE FE-CR-AL SYSTEM COATINGS CHEMICAL COMPOSITION ON THEIR HEAT RESISTANCE

2021 ◽  
pp. 7-12
Author(s):  
V. G. Shmorgun ◽  
A. I. Bogdanov ◽  
O. V. Slautin ◽  
V. P. Kulevich ◽  
S. A. Kuznecov
Keyword(s):  
Surface Layer ◽  
Chemical Composition ◽  
Corrosion Rate ◽  
Heat Resistance ◽  
Oxidation Rate ◽  
Aluminum Content ◽  
Chromium Content ◽  
Kinetics Of

The influence of the chemical composition of the Fe-Cr-Al system coatings on their heat resistance at 1100 °C was investigated. It is shown that the lowest oxidation rate is possessed by the coating obtained by aluminizing the Cr15Al5 alloy in the silumin melt, for which the depth of corrosion penetration after 500 h at 1100 °C was 2.5 μm. The depth of corrosion penetration in coating with a higher chromium content (23 at.%) reaches 8.9 μm. A decrease in the chromium content (up to 5 at.%) or aluminum (up to 10 at.%) in the surface layer is accompanied by a critical increase in the corrosion rate. Based on the kinetics of changes in the aluminum content in the surface layer, it was established that the coating obtained on the Cr23Al5 alloy has the highest heat resistance.

Evaluation of the Heat Resistance of the Fe-Cr-Al System Coatings

2021 ◽  
Vol 410 ◽  
pp. 525-530
Author(s):  
Vitaliy P. Kulevich ◽  
Oleg V. Slautin ◽  
Valentin O. Kharlamov
Keyword(s):  
Surface Layer ◽  
Chemical Composition ◽  
Corrosion Rate ◽  
Heat Resistance ◽  
Oxidation Rate ◽  
Chromium Content ◽  
Aluminum Melt ◽  
Heat Resistant ◽  
Aluminide Coatings

The influence of the chemical composition of aluminide coatings of the Fe-Cr-Al system on their heat resistance at 1100 °C was investigated. It is shown that the lowest oxidation rate is possessed by the coating obtained by aluminizing the Cr15Al5 alloy in the silumin melt, for which the depth of corrosion penetration after 500 h at 1100 °C did not exceed 2.5 μm. The depth of corrosion penetration after 500 h at 1100 °C in coatings with a higher chromium content (23 at.%) reaches 8.9 μm. A decrease in the content of chromium (up to 5 at.%) or aluminum (up to 10 at.%) in the surface layer is accompanied by a critical increase in the corrosion rate. The longest time of retention of heat-resistant properties at 1100 °C is possessed by the coating obtained by aluminizing the Cr23Al5 alloy in an aluminum melt.

An Explanation of the Removal of Metastability in Some Hydroacid Salts by Water Adsorption

2001 ◽  
Vol 56 (12) ◽  
pp. 869-872
Author(s):  
B. Baranowski ◽  
A. Lundén
Keyword(s):  
Phase Transition ◽  
Surface Layer ◽  
Water Activity ◽  
Induction Time ◽  
Lattice Spacing ◽  
Water Adsorption ◽  
Zeroth Order ◽  
Exponential Functions ◽  
Kinetics Of ◽  
Volume Decrease

Abstract The metastability of some phases of CsHSO4 and RbH2PO4 is due to the volume decrease at an endothermic phase transition which "locks in" the metastability in question. Water adsorption, which removes these metastabilities, probably exerts a "wedge-like" force which expands the lattice spacing in the surface layer, thus facilitating the start of the phase transition. The induction time and the zeroth order kinetics of the transition in RbH2PO4 are exponential functions of the water activity applied.

scholarly journals Mixing state and compositional effects on CCN activity and droplet growth kinetics of size-resolved CCN in an urban environment

2012 ◽  
Vol 12 (21) ◽  
pp. 10239-10255 ◽  
Author(s):  
L. T. Padró ◽  
R. H. Moore ◽  
X. Zhang ◽  
N. Rastogi ◽  
R. J. Weber ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Water Soluble ◽  
Anthropogenic Sources ◽  
Droplet Growth ◽  
Mixing State ◽  
Aerosol Composition ◽  
Activation Kinetics ◽  
Aerosol Mixing State ◽  
Kinetics Of ◽  
Ccn Activity

Abstract. Aerosol composition and mixing state near anthropogenic sources can be highly variable and can challenge predictions of cloud condensation nuclei (CCN). The impacts of chemical composition on CCN activation kinetics is also an important, but largely unknown, aspect of cloud droplet formation. Towards this, we present in-situ size-resolved CCN measurements carried out during the 2008 summertime August Mini Intensive Gas and Aerosol Study (AMIGAS) campaign in Atlanta, GA. Aerosol chemical composition was measured by two particle-into-liquid samplers measuring water-soluble inorganic ions and total water-soluble organic carbon. Size-resolved CCN data were collected using the Scanning Mobility CCN Analysis (SMCA) method and were used to obtain characteristic aerosol hygroscopicity distributions, whose breadth reflects the aerosol compositional variability and mixing state. Knowledge of aerosol mixing state is important for accurate predictions of CCN concentrations and that the influence of an externally-mixed, CCN-active aerosol fraction varies with size from 31% for particle diameters less than 40 nm to 93% for accumulation mode aerosol during the day. Assuming size-dependent aerosol mixing state and size-invariant chemical composition decreases the average CCN concentration overprediction (for all but one mixing state and chemical composition scenario considered) from over 190–240% to less than 20%. CCN activity is parameterized using a single hygroscopicity parameter, κ, which averages to 0.16 ± 0.07 for 80 nm particles and exhibits considerable variability (from 0.03 to 0.48) throughout the study period. Particles in the 60–100 nm range exhibited similar hygroscopicity, with a κ range for 60 nm between 0.06–0.076 (mean of 0.18 ± 0.09). Smaller particles (40 nm) had on average greater κ, with a range of 0.20–0.92 (mean of 0.3 ± 0.12). Analysis of the droplet activation kinetics of the aerosol sampled suggests that most of the CCN activate as rapidly as calibration aerosol, suggesting that aerosol composition exhibits a minor (if any) impact on CCN activation kinetics.

Influence of High-Calcium Ash Composition on the Composite Binders’ Properties

2021 ◽  
Vol 316 ◽  
pp. 1019-1024
Author(s):  
O. A. Ignatova ◽  
A. A. Dyatchina
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Cement Stone ◽  
Normal Density ◽  
Fine Aggregate ◽  
Equivalent Amount ◽  
High Calcium ◽  
Composition Structure ◽  
Kinetics Of ◽  
Positive Effect

The paper presents the studies’ results of chemical composition, structure, and physico-mechanical properties of high-calcium ashes from the Kansk-Achinsk coals (2017-2019 selection). It was found that ash has a complex poly-mineral composition and contains hydraulically active minerals and oxides of СаОfr, β-C2S, CA, C3A, C4AF, C2F, CaSO4. According to the content of CaOfr, MgO does not meet standards’ requirements. The uniformity of the volume change is maintained by the composition with 50% of cement. The structure and hardening kinetics of ash and ash-cement stone compositions, obtained from the test of normal density, were analyzed. It was established that the hardening of compositions with ash from the Kansk-Achinsk coals was largely influenced by ash minerals. An equivalent amount of cement in composite binders cannot be replaced. In order to obtain a positive effect, compositions with ash instead cement of no more than 30% and a part of fine aggregate, without exceeding the ratio of ash: cement = 1: 1, should be used.

Final products and kinetics of biochemical and chemical sulfide oxidation under microaerobic conditions

2018 ◽  
Vol 78 (9) ◽  
pp. 1916-1924 ◽  
Author(s):  
Lucie Pokorna-Krayzelova ◽  
Dana Vejmelková ◽  
Lara Selan ◽  
Pavel Jenicek ◽  
Eveline I. P. Volcke ◽  
...  
Keyword(s):  
Mathematical Model ◽  
Oxidation Rate ◽  
Elemental Sulfur ◽  
Sulfide Oxidation ◽  
Cost Effective ◽  
Anaerobic Treatment ◽  
Batch Experiments ◽  
Cost Effective Method ◽  
Microaerobic Conditions ◽  
Kinetics Of

Abstract Hydrogen sulfide is a toxic and usually undesirable by-product of the anaerobic treatment of sulfate-containing wastewater. It can be removed through microaeration, a simple and cost-effective method involving the application of oxygen-limiting conditions (i.e., dissolved oxygen below 0.1 mg L−1). However, the exact transformation pathways of sulfide under microaerobic conditions are still unclear. In this paper, batch experiments were performed to study biochemical and chemical sulfide oxidation under microaerobic conditions. The biochemical experiments were conducted using a strain of Sulfuricurvum kujiense. Under microaerobic conditions, the biochemical sulfide oxidation rate (in mg S L−1 d−1) was approximately 2.5 times faster than the chemical sulfide oxidation rate. Elemental sulfur was the major end-product of both biochemical and chemical sulfide oxidation. During biochemical sulfide oxidation elemental sulfur was in the form of white flakes, while during chemical sulfide oxidation elemental sulfur created a white suspension. Moreover, a mathematical model describing biochemical and chemical sulfide oxidation was developed and calibrated by the experimental results.

scholarly journals INFLUENCE OF VACUUM ACTIVATED DIFFUSION CHROMING ON MECHANICAL PROPERTIES OF THE SURFACE OF STEEL 25X1MF

2020 ◽  
pp. 132-138
Author(s):  
S.G. Rudenkyi ◽  
V.I. Zmij ◽  
N.F. Kartzev ◽  
A.A. Korneev ◽  
A.V. Kunchenko ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Surface Layer ◽  
Sodium Chloride ◽  
Abrasive Wear ◽  
Steel Surface ◽  
Chromium Content ◽  
Chromium Plating ◽  
Untreated Material

In the work, the surface of samples made of 25X1MF steel was saturated with chromium. For this, the method of vacuum activated diffusion chromium plating was used. In this process, sodium chloride was used as an activator. It was found that vacuum activated diffusion chromium plating of samples made of 25Kh1MF steel leads to the formation of a surface layer containing from 87 to 97 wt.% of this element. It was found that an increase in the temperature of the process and its duration leads to an increase in the chromium content on the surface of the samples. The tests showed that in the case of cavitations-erosion effects on the surface of chrome-plated samples of steel 25X1MF they have higher resistance. With abrasive wear, the resistance of the chrome-plated steel surface is 1.8 to 3 times higher compared to untreated material.

scholarly journals The laboratory tests of hybrid layers combining hardfacing and nitriding dedicated to increase the durability of forging tools in hot forging processes

2019 ◽  
Vol 91 (2) ◽  
Author(s):  
Paweł Widomski ◽  
Zbigniew Gronostajski ◽  
Marcin Kaszuba ◽  
Jagoda Kowalska ◽  
Mariusz Pawełczyk
Keyword(s):  
Surface Layer ◽  
Chemical Composition ◽  
Laboratory Tests ◽  
Hot Forging ◽  
Composition Analysis ◽  
Wear Resistant ◽  
Gas Nitriding ◽  
Use Wear ◽  
Different Types ◽  
Hybrid Layers

In response to the growing need to use wear-resistant layers that increase durability of tools in forging pro-cesses, hybrid layers have been proposed that combine hardfacing with nitriding treatment. This article presents the results of laboratory tests of surface wear-resistant layers made with a new hybrid technology Gas-Shielded Metal Arc surfacing (hardfacing) with ZeroFlow gas nitriding. Specimens made with hardfacing or nitriding were prepared and examined. Analysis covered the thorough microstructure study, EDX chemical composition analysis and microhardness analysis. In experiment, 3 different types of nitrided layers were proposed for alpha, gamma prim and epsilon nitrides in the surface layer. The results of metallographic research in the surface layer was presented. The analysis of chemical composition in the particular overlay welds was performed to determine the content of alloying elements in the particular overlay welds. The susceptibility to nitriding of used weld materials as well as the ability to form particular types of nitrides on selected welded substrates was also tested.

Strain Enhanced Corrosion in the Iron-Caustic System

CORROSION ◽  
1976 ◽  
Vol 32 (9) ◽  
pp. 353-357 ◽  
Author(s):  
RONALD B. DIEGLE ◽  
DAVID A. VERMILYEA
Keyword(s):  
Steady State ◽  
Corrosion Rate ◽  
Strain Rate ◽  
Electrolyte Concentration ◽  
Applied Strain ◽  
Crack Advance ◽  
Film Rupture ◽  
Applied Strain Rate ◽  
Corrosion Of Iron ◽  
Kinetics Of

Abstract Straining electrode experiments were performed to investigate the nature of strain enhanced corrosion of iron in caustic electrolyte. The strain enhanced corrosion rate was generally linearly dependent on applied strain rate, and its potential dependence paralleled that of steady-state polarization behavior on non-straining electrodes. Data was presented as ratios, in which is the corrosion rate in cm/s and is the corresponding strain rate. This ratio, which was shown in a previously published theory to be numerically equal to the crack advance per film rupture event during film rupture SCC, depended on electrochemical variables such as electrolyte concentration and temperature in a manner similar to the kinetics of caustic cracking. Conditions which are known to be marginal in producing caustic cracking resulted in values for of about 10−7 cm, in excellent agreement with a previously developed theory. It was concluded that strain enhanced corrosion in this system results from repetitive film rupture and repair during straining.

Study of corrosion resistance of doped surface layer with CuSn—CrxCy composition after plasma hardening

2021 ◽  
pp. 215-220
Author(s):  
Nguyen Van Trieu ◽  
N.A. Astafeva ◽  
A.E. Balanovsky ◽  
A.N. Baranov
Keyword(s):  
Corrosion Resistance ◽  
Surface Layer ◽  
Chromium Content ◽  
High Hardness ◽  
Plasma Coating ◽  
Corrosion Current ◽  
Ph Values ◽  
Alloyed Surface ◽  
Welding Electrode ◽  
Acidity Parameter

In the process of plasma surface hardening, coatings based on a mixture of CuSn alloy and 10/20 % OK 84.78 additive with high hardness were obtained. The study of the microstructures of the coatings showed that the content of the austenite phase decreases with an increase in the content of chromium carbide in the composition. The influence of the acidity parameter on the corrosion resistance of the alloyed surface layer with the composition of the mixture of alloys CuSn and the coating of the welding electrode OK 84.78 was evaluated. Corrosion control in 3% NaCl solutions with different pH values showed that the plasma coating has high corrosion resistance at pH = 7 and decreases by 2 times at pH = 3. An increase in the chromium content leads to an increase in the corrosion potential, and the presence of cracks leads to an increase in the corrosion current density.

Efficiency of Microstructure Refinement in Ti-Based Alloys

2021 ◽  
Vol 1016 ◽  
pp. 1753-1758
Author(s):  
Sergey Zherebtsov ◽  
Nikita Stepanov ◽  
Gennady Salishchev
Keyword(s):  
Plastic Deformation ◽  
Chemical Composition ◽  
Titanium Alloys ◽  
Microstructure Evolution ◽  
Large Plastic Deformation ◽  
Two Phase ◽  
Microstructure Refinement ◽  
Kinetics Of ◽  
Rate Type ◽  
Lamellar Type

The influence of various factors on the efficiency of microstructure refinement in two-phase titanium alloys with respect to a well-known Ti-6Al-4V alloy was discussed. The kinetics of microstructure evolution in titanium alloys with a lamellar type α/β microstructure during large plastic deformation depends mainly on temperature and strain rate, type of the initial microstructure, thickness of the α lamellae, path of deformation and chemical composition. Each parameter should be controlled to provide the most efficient microstructure refinement during conventional metalforming methods.

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