scholarly journals Producción de Hidrógeno mediante digestión anaerobia de residuos de planta de jitomate

Author(s):  
Sarai Camarena-Martínez ◽  
Juan Humberto Martínez-Martínez ◽  
Adriana Saldaña-Robles ◽  
Graciela M.L Ruiz-Aguilar

Hydrogen (H2) is recognized as a promising energy carrier among the alternatives for obtaining clean energy, since it has a high energy efficiency (122 kJ / g) and can be obtained from lignocellulosic waste through a biological process. In the state of Guanajuato, high amounts of plant waste derived from tomato cultivation are generated because this is the crop mostly produced through protected agriculture. So, the objective of the present study was to consider tomato plant residues for the generation of hydrogen through the anaerobic digestion process. Two sources of inoculum, native microflora of the tomato plant and anaerobic sludge pretreated at 100 ° C for 24 h; and four mineral media at an initial pH of 6.5 ± 0.2 in batch experiments, were evaluated. The highest yield was 37.4 mLH2 / g SV using native microflora and mineral media with yeast extract. Hydrogen production was found like those reported in the literature for other type of waste, highlighting the no-need to pretreat the substrate or inoculum. Therefore, the methodology propose is efficient to the hydrogen production from tomato plant residues.

2021 ◽  
Vol 13 (21) ◽  
pp. 11628
Author(s):  
Shuxia Yang ◽  
Shengjiang Peng ◽  
Xianzhang Ling

To improve the utilization rate of the energy industry and reduce high energy consumption and pollution caused by coal chemical industries in northwestern China, a planning scheme of a wind-coal coupling energy system was developed. This scheme involved the analysis method, evaluation criteria, planning method, and optimization operation check for the integration of a comprehensive evaluation framework. A system was established to plan the total cycle revenue to maximize the net present value of the goal programming model and overcome challenges associated with the development of new forms of energy. Subsequently, the proposed scheme is demonstrated using a 500-MW wind farm. The annual capacity of a coal-to-methanol system is 50,000. Results show that the reliability of the wind farm capacity and the investment subject are the main factors affecting the feasibility of the wind-coal coupled system. Wind power hydrogen production generates O2 and H2, which are used for methanol preparation and electricity production in coal chemical systems, respectively. Considering electricity price constraints and environmental benefits, a methanol production plant can construct its own wind farm, matching its output to facilitate a more economical wind-coal coupled system. Owing to the high investment cost of wind power plants, an incentive mechanism for saving energy and reducing emissions should be provided for the wind-coal coupled system to ensure economic feasibility and promote clean energy transformation.


2018 ◽  
Vol 34 ◽  
pp. 02045 ◽  
Author(s):  
C.N.S. Che Zuhar ◽  
N.A. Lutpi ◽  
N. Idris ◽  
Y.S. Wong ◽  
T.N. Tengku Izhar

In this study, mesophilic biohydrogen production by a mixed culture, obtained from a continuous anaerobic reactor treating molasses effluent from sugarcane bagasse, was improved by using granular activated carbon (GAC) as the carrier material. A series of batch fermentation were performed at 37°C by feeding the anaerobic sludge bacteria with molasses to determine the effect of initial pH in the range of 5.5 to 7.5, and the effect of repeated batch cultivation on biohydrogen production. The enrichment of granular activated carbon (GAC) immobilised cells from the repeated batch cultivation were used as immobilised seed culture to obtain the optimal initial pH. The cumulative hydrogen production results from the optimal pH were fitted into modified Gompertz equation in order to obtained the batch profile of biohydrogen production. The optimal hydrogen production was obtained at an initial pH of 5.5 with the maximum hydrogen production (Hm) was found to be 84.14 ml, and maximum hydrogen production rate (Rm) was 3.63 mL/h with hydrogen concentration of 759 ppm. The results showed that the granular activated carbon was successfully enhanced the biohydrogen production by stabilizing the pH and therefore could be used as a carrier material for fermentative hydrogen production using industrial effluent.


2018 ◽  
Vol 192 ◽  
pp. 02020 ◽  
Author(s):  
Vinod Singh Yadav ◽  
Vinoth R ◽  
Dharmesh Yadav

When hydrogen burns in air, it produces nothing but water vapour. It is therefore the cleanest possible, totally non-polluting fuel. This fact has led some people to propose an energy economy based entirely on hydrogen, in which hydrogen would replace gasoline, oil, natural gas, coal, and nuclear power. Hydrogen is a clean energy source. Therefore, in recent years, demand on hydrogen production has increased considerably. Electrolysis of water, steam reforming of hydrocarbons and auto-thermal processes are well-known methods for hydrogen gas production, but not cost-effective due to high energy requirements. As compare to chemical methods, biological production of hydrogen gas has significant advantages such as bio-photolysis of water by algae, dark and photo-fermentation of organic materials, usually carbohydrates by bacteria. New approach for bio-hydrogen production is dark and photo-fermentation process but with some major problems like dark and photo-fermentative hydrogen production is the raw material cost. By using suitable bio-process technologies hydrogen can be produced through carbohydrate rich, nitrogen deficient solid wastes such as cellulose and starch containing agricultural and food industry wastes and some food industry wastewaters such as cheese whey, olive mill and baker's yeast industry wastewaters. Utilization of aforementioned wastes for hydrogen production provides inexpensive energy generation with simultaneous waste treatment. This review article summarizes bio-hydrogen production from some waste materials with recent developments and relative advantages.


2021 ◽  
Author(s):  
Md. Mahmud

Biohydrogen production is most important for simultaneous energy generation. Hydrogen (H2) is considered as a suitable substitute source of energy because of its regenerative, carbon neutral and high energy yielding. However, to optimize key factors affecting hydrogen production from water hyacinth by heat treated anaerobic fermentation process. Biological methods is a potential option to meet the growing clean energy needs for hydrogen production. This paper was discussed about key factors affecting namely substrate concentration.


2014 ◽  
Vol 884-885 ◽  
pp. 433-436 ◽  
Author(s):  
Bo Wang ◽  
Ya Nan Yin ◽  
Rong Cheng ◽  
Qiong Zhang ◽  
Liang Wang ◽  
...  

The effect of SO2-4 concentration ranging from 0 to 10 g/L on fermentative hydrogen production by enriched anaerobic sludge was investigated using glucose as substrate at 35°C and initial pH 7.0. The experimental results showed that the hydrogen yield increased with increasing SO2-4 concentration from 0 to 0.05 g/L. The maximum maximum hydrogen yield of 272.2 mL/g glucose were obtained at the SO2-4 concentration of 0.05 g/L. The average hydrogen production rate increased with increasing SO2-4 concentration from 0 to 0.1 g/L and the maximum average hydrogen production rate of 8.4 mL/h was obtained at the SO2-4 concentration of 0.1 g/L. The Han-Levenspiel model could describe the effect of SO2-4 concentration on average hydrogen production rate successfully.


Adsorption ◽  
2021 ◽  
Author(s):  
Anne Streb ◽  
Marco Mazzotti

Abstract Hydrogen as clean energy carrier is expected to play a key role in future low-carbon energy systems. In this paper, we demonstrate a new technology for coupling fossil-fuel based hydrogen production with carbon capture and storage (CCS): the integration of CO2 capture and H2 purification in a single vacuum pressure swing adsorption (VPSA) cycle. An eight step VPSA cycle is tested in a two-column lab-pilot for a ternary CO2–H2–CH4 stream representative of shifted steam methane reformer (SMR) syngas, while using commercial zeolite 13X as adsorbent. The cycle can co-purify CO2 and H2, thus reaching H2 purities up to 99.96%, CO2 purities up to 98.9%, CO2 recoveries up to 94.3% and H2 recoveries up to 81%. The key decision variables for adjusting the separation performance to reach the required targets are the heavy purge (HP) duration, the feed duration, the evacuation pressure and the flow rate of the light purge (LP). In contrast to that, the separation performance is rather insensitive towards small changes in feed composition and in HP inlet composition. Comparing the experimental results with simulation results shows that the model for describing multi-component adsorption is critical in determining the predictive capabilities of the column model. Here, the real adsorbed solution theory (RAST) is necessary to describe all experiments well, whereas neither extended isotherms nor the ideal adsorbed solution theory (IAST) can reproduce all effects observed experimentally.


Nanoscale ◽  
2021 ◽  
Author(s):  
Xianyun Peng ◽  
Junrong Hou ◽  
Yuying Mi ◽  
Jiaqiang Sun ◽  
Gaocan Qi ◽  
...  

Electrocatalytic hydrogen evolution reaction (HER) for H2 production is essential for future renewable and clean energy technology. Screening energy-saving, low-cost, and highly active catalysts efficiently, however, is still a grand...


2001 ◽  
Vol 676 ◽  
Author(s):  
W. Oelerich ◽  
T. Klassen ◽  
R. Bormann

ABSTRACTHydrogen is the ideal means of energy storage for transportation and conversion of energy in a comprehensive clean-energy concept. However, appropriate storage facilities, both for stationary and for mobile applications, are complicated, because of the very low boiling point of hydrogen (20.4 K at 1 atm) and its low density in the gaseous state (90 g/m3). Furthermore, the storage of hydrogen in liquid or gaseous form imposes safety problems, in particular for mobile applications, e.g. the future zero-emission vehicle. Metal hydrides are a safe alternative for H-storage and, in addition, have a high volumetric energy density that is about 60% higher than that of liquid hydrogen. Mg hydride has a high storage capacity by weight and is therefore favoured for automotive applications. However, so far light metal hydrides have not been considered competitive because of their rather sluggish sorption kinetics. Filling a tank could take several hours. Moreover, the hydrogen desorption temperature of about 300 °C is rather high for most applications. A breakthrough in hydrogen storage technology was achieved by preparing nanocrystalline hydrides using high-energy ball milling. These new materials show very fast aband desorption kinetics within few minutes, thus qualifying lightweight Mg-based hydrides for storage application. In this paper recent detailed results on the sorption behaviour of nanocrystalline Mg and Mg-based alloys are presented. In a following research effort the sorption kinetics of nanocrystalline Mg has been further enhanced by catalyst additions. Furthermore, different transition metals have been added to Mg to achieve a thermodynamic destabilisation of the hydride, thus lowering the desorption temperatures to about 230 °C. The newly developed materials are currently being tested in prototype storage tanks.


2013 ◽  
Vol 14 (2) ◽  
pp. 149-156 ◽  

This work focused on glycerol exploitation for biogas and hydrogen production. Anaerobic digestion of pure glycerol was studied in a continuous stirred tank reactor (CSTR), operated under mesophilic conditions (35oC) at various organic loading rates. The overall operation of the reactor showed that it could not withstand organic loading rates above 0.25 g COD L-1 d-1, where the maximum biogas (0.42 ± 0.05 L (g COD)-1) and methane (0.30 ± 0.04 L (g COD)-1) production were achieved. Fermentative hydrogen production was carried out in batch reactors under mesophilic conditions (35oC), using heat-pretreated anaerobic microbial culture as inoculum. The effects of initial concentration of glycerol and initial pH value on hydrogen production were studied. The highest yield obtained was 22.14 ± 0.46 mL H2 (g COD added)-1 for an initial pH of 6.5 and an initial glycerol concentration of 8.3 g COD L-1. The main metabolic product was 1.3 propanediol (PDO), while butyric and acetic acids as well as ethanol, at lower concentrations, were also determined.


2021 ◽  
Author(s):  
Amit Kumar

Photocatalysis is important in fighting environmental pollution, such as pharmaceutical effluents, dyes, pesticides and endocrine disruptors. It is also used for the production of clean energy, e.g. by way of hydrogen production from watersplitting, or CO2 conversion into fuels. Further, photocatalytic N2 fixation is promising for achieving sustainable ammonia synthesis. The book discusses new materials and reaction engineering techniques, such as heterojunction formations, composites, ion exchangers, photocatalytic membranes, etc.


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