scholarly journals Low-cost natural carbon dioxide sorbents available in the Czech Republic

Paliva ◽  
2021 ◽  
pp. 86-95
Author(s):  
Marek Staf ◽  
Barbora Votavová
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Gas Flow ◽  
Initial Conditions ◽  
Low Cost ◽  
Reference Sample ◽  
Gaseous Mixture ◽  
Total Pore Volume ◽  
Absolute Pressure ◽  
Adsorption Capacities

The article deals with the issue of carbon dioxide adsorption on mineral samples, two of which are rich in montmorillonite and one in kaolinite. The last comparative sample is clinoptilolite, which is widely used as a sorbent in agriculture, water treatment, etc. The theoretical part summarizes several current researches on the use of bentonites as adsorbents, both in their raw form and after various chemical treatments. The study presented here does not suggest any modification procedure, but tests untreated samples and samples subjected to calcinations at temperatures of 250-750 ° C. The calcination of units of grams was carried out by means of a carousel TGA, which made it possible to record curves of mass changes and to obtain a sufficient amount of calcinates for further analyses at the same time. From the point of view of achieving the highest specific surface area and the total pore volume, the optimal calcination temperature for the phyllosilicate samples ranged from 250 to 450 °C. Natural zeolite, on the other hand, showed a deterioration of both of these parameters at any temperature exceeding 150 °C. The same temperature dependence was found in the case of adsorption capacities determined by an automatic analyser Autosorb IQ using pure CO2. Measurements on this instrument also confirmed that selected inexpensive natural materials provide comparable adsorption capacities as the commercially available 13X molecular sieve used as a reference sample. Based on the performed analyses, the initial conditions of sample preparation for the upcoming measurement of adsorption properties on a larger apparatus operating in the PSA/TSA mode were determined. The primary aim of the tests using the selfdesigned high-pressure adsorption unit will be to determine the adsorption capacities that will take into account the temperature and pressure conditions in a real postcombustion carbon dioxide capture system. Unlike the automatic analyser described above, it will be possible to quantify the influence of important factors such as: flue gas humidity, the presence of other permanent gases (especially SO2) and last but not least various CO2 partial pressures and absolute pressure during adsorption and desorption. The experiments will verify the extent to which the presence of noncondensing moisture in the gaseous mixture is problematic. In the case of phyllosilicates, it is not just the parallel adsorption of H2O that affects the adsorption capacity available for CO2 capture. It will be empirically determined to what extent the swelling of the sorbent occurs in the wet gas, changing the gas flow through the layer and especially the pressure loss. The results of measurements on high-pressure apparatus will be the basis for the design and construction of a larger pilot scale unit.

scholarly journals Defining a performance map of porous carbon sorbents for high-pressure carbon dioxide uptake and carbon dioxide–methane selectivity

2016 ◽  
Vol 4 (38) ◽  
pp. 14739-14751 ◽  
Author(s):  
Saunab Ghosh ◽  
Marta Sevilla ◽  
Antonio B. Fuertes ◽  
Enrico Andreoli ◽  
Jason Ho ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Pore Volume ◽  
Carbon Materials ◽  
Total Pore Volume ◽  
Uptake Capacity ◽  
Heteroatom Doping ◽  
Carbon Dioxide Uptake ◽  
Performance Map ◽  
Methane Selectivity

The relative influence of heteroatom doping, surface area, and total pore volume of highly microporous carbon materials on CO2 uptake capacity, and the CO2/CH4 selectivity, at high pressure (≤30 bar) is presented.

scholarly journals Preparation of Active Carbon by Additional Activation with Potassium Hydroxide and Characterization of Their Properties

2016 ◽  
Vol 2016 ◽  
pp. 1-4 ◽  
Author(s):  
Bronislaw Buczek
Keyword(s):  
Carbon Dioxide ◽  
Particle Size ◽  
High Pressure ◽  
Active Carbon ◽  
Potassium Hydroxide ◽  
Pressure Swing Adsorption ◽  
Total Pore Volume ◽  
Micropore Volume ◽  
Pressure Swing

A commercially available activated carbon was used to prepare active carbonviareactivation with KOH at 750°C. Active carbon was obtained with 60.5% yield. The resulting active carbon showed a well-developed porous structure with specific surface area 2939 m2/g, total pore volume 1.488 cm3/g, and micropore volume 1.001 cm3/g. Process reactivation of carbon changes its particle size as well as density properties and increases by nearly twice the amounts of methane and carbon dioxide adsorbed under high pressure conditions. Such active carbon may be used to enrich methane or carbon dioxide by pressure swing adsorption technique. Other possible applications of reactivated carbon are storage of hydrogen and methane and sequestration of carbon dioxide.

Analysis of the Behavior of a Metallic Filter in Particle Removal under High Pressure Conditions

2012 ◽  
Vol 727-728 ◽  
pp. 1648-1653
Author(s):  
Eduardo Hiromitsu Tanabe ◽  
Murilo Daniel de Mello Innocentini ◽  
Priscila Martins de Barros ◽  
Mônica Lopes Aguiar ◽  
José Renato Coury
Keyword(s):  
High Pressure ◽  
Gas Flow ◽  
Operating Conditions ◽  
Absolute Pressure ◽  
Particle Removal ◽  
Gas Velocity ◽  
Gas Filtration ◽  
Powder Mass ◽  
Fractional Efficiency ◽  
Phosphate Concentrate

This study aimed to examine the behavior of different filter media used in gas filtration at high pressure. Trials were carried out having phosphate concentrate as the particulate matter and compressed air as fluid. Operating conditions were evaluated at the following absolute pressures of the system: 193, 393 and 693 kPa, and the gas velocity was kept constant at 0.05 m/s. The results indicated that, for a given pressure drop at the filter, the highest absolute pressure applied to the system (693 kPa) yielded the highest powder mass deposited on the filter medium. An analysis of the porosity of dust cakes revealed that the increase in pressure resulted in cakes which were more porous and less resistant to gas flow. It was also verified that the increase in the pressure of the system provided an increase in the fractional efficiency of the filters for particles smaller than 5 μm.

INVESTIGATION OF THE TIME OF GAS FLOW THROUGH A HOLE IN LONG PIPELINES UNDER HIGH PRESSURE

2020 ◽  
Vol 58 (1) ◽  
pp. 30-43
Author(s):  
N.D. Yakimov ◽  
◽  
A.I. Khafizova ◽  
N.D. Chichirova ◽  
O.S. Dmitrieva ◽  
...  
Keyword(s):  
High Pressure ◽  
Gas Flow ◽  
Flow Through

Application of Disk Aerators to Recarbonation of Alkaline Wastewater from Wet Gasification of Carbide

1991 ◽  
Vol 24 (7) ◽  
pp. 277-284 ◽  
Author(s):  
E. Gomólka ◽  
B. Gomólka
Keyword(s):  
Carbon Dioxide ◽  
Liquid Phase ◽  
Gas Phase ◽  
Flue Gas ◽  
Carbonic Acid ◽  
Low Cost ◽  
Flue Gases ◽  
Carbon Dioxide Content ◽  
Patent Claim ◽  
Phase Dispersion

Whenever possible, neutralization of alkaline wastewater should involve low-cost acid. It is conventional to make use of carbonic acid produced via the reaction of carbon dioxide (contained in flue gases) with water according to the following equation: Carbon dioxide content in the flue gas stream varies from 10% to 15%. The flue gas stream may either be passed to the wastewater contained in the recarbonizers, or. enter the scrubbers (which are continually sprayed with wastewater) from the bottom in oountercurrent. The reactors, in which recarbonation occurs, have the ability to expand the contact surface between gaseous and liquid phase. This can be achieved by gas phase dispersion in the liquid phase (bubbling), by liquid phase dispersion in the gas phase (spraying), or by bubbling and spraying, and mixing. These concurrent operations are carried out during motion of the disk aerator (which is a patent claim). The authors describe the functioning of the disk aerator, the composition of the wastewater produced during wet gasification of carbide, the chemistry of recarbonation and decarbonation, and the concept of applying the disk aerator so as to make the wastewater fit for reuse (after suitable neutralization) as feeding water in acetylene generators.

Characterization of a Polymeric Membrane for the Separation of Hydrogen in a Mixture with CO2

2016 ◽  
Vol 9 (1) ◽  
pp. 126-136 ◽  
Author(s):  
Dionisio H. Malagón-Romero ◽  
Alexander Ladino ◽  
Nataly Ortiz ◽  
Liliana P. Green
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Production ◽  
Test Performance ◽  
Low Cost ◽  
Time Lag ◽  
Polymeric Membrane ◽  
Biological Processes ◽  
Scanning Calorimetry ◽  
Environmentally Sustainable ◽  
Production Of Hydrogen

Hydrogen is expected to play an important role as a clean, reliable and renewable energy source. A key challenge is the production of hydrogen in an economically and environmentally sustainable way on an industrial scale. One promising method of hydrogen production is via biological processes using agricultural resources, where the hydrogen is found to be mixed with other gases, such as carbon dioxide. Thus, to separate hydrogen from the mixture, it is challenging to implement and evaluate a simple, low cost, reliable and efficient separation process. So, the aim of this work was to develop a polymeric membrane for hydrogen separation. The developed membranes were made of polysulfone via phase inversion by a controlled evaporation method with 5 wt % and 10 wt % of polysulfone resulting in thicknesses of 132 and 239 micrometers, respectively. Membrane characterization was performed using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), atomic force microscopy (AFM), and ASTM D882 tensile test. Performance was characterized using a 23 factorial experiment using the time lag method, comparing the results with those from gas chromatography (GC). As a result, developed membranes exhibited dense microstructures, low values of RMS roughness, and glass transition temperatures of approximately 191.75 °C and 190.43 °C for the 5 wt % and 10 wt % membranes, respectively. Performance results for the given membranes showed a hydrogen selectivity of 8.20 for an evaluated gas mixture 54% hydrogen and 46% carbon dioxide. According to selectivity achieved, H2 separation from carbon dioxide is feasible with possibilities of scalability. These results are important for consolidating hydrogen production from biological processes.

scholarly journals The degradation of cellulose in ionic mixture solutions under the high pressure of carbon dioxide

RSC Advances ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 3484-3494
Author(s):  
Sumarno ◽  
Prida Novarita Trisanti ◽  
Bramantyo Airlangga ◽  
Novi Eka Mayangsari ◽  
Agus Haryono
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Hydrothermal Process ◽  
Reducing Sugar

Cellulose processing by a hydrothermal process as well as in combination with a sonication pretreatment under a CO2 pressurization that affects the morphology and reducing sugar products.

scholarly journals Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater

2020 ◽  
Author(s):  
T. G. Ambaye ◽  
M. Vaccari ◽  
E. D. van Hullebusch ◽  
A. Amrane ◽  
S. Rtimi
Keyword(s):  
Organic Contaminants ◽  
Pyrolysis Temperature ◽  
Low Cost ◽  
Industrial Effluents ◽  
Economic Benefits ◽  
Inorganic Pollutants ◽  
Solution Ph ◽  
Adsorption Mechanisms ◽  
Adsorption Capacities ◽  
Temperature Solution

AbstractCurrently, due to the rapid growth of urbanization and industrialization in developing countries, a large volume of wastewater is produced from industries that contain chemicals generating high environmental risks affecting human health and the economy if not treated properly. Consequently, the development of a sustainable low-cost wastewater treatment approach has attracted more attention of policymakers and scientists. The present review highlights the recent applications of biochar in removing organic and inorganic pollutants present in industrial effluents. The recent modes of preparation, physicochemical properties and adsorption mechanisms of biochar in removing organic and inorganic industrial pollutants are also reviewed comprehensively. Biochar showed high adsorption of industrial dyes up to 80%. It also discusses the recent application and mechanism of biochar-supported photocatalytic materials for the degradation of organic contaminants in wastewater. We reviewed also the possible optimizations (such as the pyrolysis temperature, solution pH) allowing the increase of the adsorption capabilities of biochar leading to organic contaminants removal. Besides, increasing the pyrolysis temperature of the biochar was seen to lead to an increase in its surface area, while it decreases their amount of oxygen-containing functional groups, consequently leading to a decrease in the adsorption of metal (loid) ions present in the medium. Finally, the review suggests that more research should be carried out to optimize the main parameters involved in biochar production and its regeneration methods. Future efforts should be also carried out towards process engineering to improve its adsorption capacity to increase the economic benefits of its implementation.

Sign in / Sign up

Export Citation Format

Share Document