scholarly journals SPE-LC/MS/MS Method for Detection of Antidiabetic Contaminants in Municipal and Rural Wastewater

2020 ◽  
Vol 70 (12) ◽  
pp. 4617-4623
Keyword(s):  
Waste Water ◽  
Collision Energy ◽  
Multiple Reaction Monitoring ◽  
Treatment Plant ◽  
High Sensitivity ◽  
Liquid Chromatography Mass Spectrometry ◽  
Limit Values ◽  
Ionization Mode ◽  
Good Determination ◽  
Linear Regressions

Antidiabetic drugs are among the most prescribed and consumed pharmaceuticals worldwide. Their occurrence in environment was little investigated due of lack of analytcial methods for their detection in waters. In this work has been developed a selective SPE-UHPLC/MS/MS method for isolation, identification and quantification of some antidiabetic compounds. The 3 selected analytes (glyburide, glimepiride and repaglinide) were separated on Eclipse C18 LC column at 300C using isocrat elution with mobile phase of acetonitrile: 0.04% acetic acid (60/40, v/v %). The optimal flow rate was 0.2 mL/min and the injected volum was 10 µL. The contaminants were detected in negative electropray ionization mode (ESI-) by Multiple Reaction Monitoring (MRM). Collision energy, fragmentor voltages were optimized to obtain high sensitivity. Optimization of SPE-LC-MS/MS parameters gave low quantification limit values between 0.27 and 11.1 ng/L. The organic pollutants were isolated from waste water samples on Strata C18 cartridges. The linear regressions were drawn in the interval of 1-100ng/L with good determination coefficients. Spike recovery rates were between 74.5 and 88.2% for waste water, with satisfactory precisions (RSD<15). the method was applied to analyze real influent and effluent of wastewater treatment plant (WWTP) samples. Keywords: antidiabetic contaminants, liquid chromatography-mass spectrometry, wastewater

scholarly journals Preliminary studies on the use of Fenton reagent to reduce pollution from wastewater from the production of household chemicals

2018 ◽  
Vol 50 (4) ◽  
pp. 301-312
Author(s):  
Maciej Malarski ◽  
Justyna Czajkowska ◽  
Piotr Nowak
Keyword(s):  
Waste Water ◽  
Industrial Wastewater ◽  
Treatment Plant ◽  
Pollution Reduction ◽  
Fenton Reagent ◽  
Chemistry Industry ◽  
Limit Values ◽  
Phenol Solution ◽  
Household Chemicals ◽  
Industrial Sewage

Abstract Industrial sewage from the production of household chemicals contain large amounts of impurities in the form of ionic and non-ionic surfactants, detergents, active extenders, enzymes. The mixture of these components means that the reduction of pollutants from this type of waste-water is very burdensome. The article presents the results of preliminary laboratory tests of the possibility of using Fenton reaction in the reduction of pollution in wastewater from the household chemistry industry. The reduction of impurities was determined by the concentration of COD. The tests were carried out on samples of wastewater taken from an industrial wastewater treatment plant from the production of household chemistry. A pollution reduction of 24.7–32.3% was achieved. On the basis of the preliminary tests carried out, the need to better match the doses of reagents to carry out pollution reduction was determined. Despite obtaining values exceeding the limit values for introducing this type of sewage into the sewage system and into the environment, the conducted tests can be considered as prognostic. To compare the process carried out on industrial waste-water, a reduction of impurities was carried out using the Fenton reagent in the standard phenol solution.

Atomic absorption determination of Hg (II), Cd (II), and As (III) in natural and waste water after preliminary group preconcentration

2019 ◽  
Vol 85 (2) ◽  
pp. 12-16
Author(s):  
I. V. Saunina ◽  
E. N. Gribanov ◽  
E. R. Oskotskaya
Keyword(s):  
Waste Water ◽  
Atomic Absorption ◽  
High Sensitivity ◽  
Distribution Coefficients ◽  
Neutral Medium ◽  
Atomic Absorption Determination ◽  
Absorption Determination ◽  
Relative Standard ◽  
Preliminary Group

The sorption of Hg (II), Cd (II), and As (III) by natural aluminosilicate is studied. It is shown that the mineral absorbs those toxicants in a rather wide pH range, quantitative extraction of analytes being achieved in a neutral or close to neutral medium (pH values range within 7.0 - 8.0; 6.3 - 7.5; 7.4 - 8.5 for Hg (II), As (III), and Cd (II), respectively). The effect of the time of phase contact on the degree of extraction of elements is shown. The sorption capacity of the mineral in optimal conditions of the medium acidity (0.06 mmol/g for mercury, 0.31 mmol/g for cadmium, and 0.52 mmol/g for arsenic) is determined. The distribution coefficients attain values of aboutnX 103-nX 104. A new combined method for determination of Hg (II), Cd (II), and As (III) in natural and waste water is developed and tested. The method consists in a preliminary group sorption concentration of the analytes by aluminosilicate, desorption of the analytes from the surface of the mineral and their subsequent atomic absorption determination. The correctness of the method is verified in analysis of spiked samples. The method is easy to use and exhibits high sensitivity, reproducibility and accuracy of analyte determination. The relative standard deviation does not exceed 0.13. Economic availability and possibility of using domestic sorption materials are the important advantages of the proposed procedure which can be used in the practice of laboratories monitoring the quality and safety of environmental objects.

DESIGN PLANNING WASTEWATER TREATMENT PLANT OF NATA DE COCO INDUSTRY WITH THE ACTIVATED SLUDGE PROCESS

2016 ◽  
Vol 9 (2) ◽  
Author(s):  
Dinda Rita K. Hartaja ◽  
Imam Setiadi
Keyword(s):  
Waste Water ◽  
Wastewater Treatment ◽  
Activated Sludge ◽  
Waste Water Treatment ◽  
Treatment Plant ◽  
Water Treatment Plant ◽  
Appropriate Technology ◽  
Waste Water Treatment Plant ◽  
Activated Sludge Process ◽  
High Level

Generally, wastewater of nata de coco industry contains suspended solids and COD were high, ranging from 90,000 mg / l. The high level of of the wastewater pollutants, resulting in nata de coco industry can not be directly disposed of its wastewater into the environment agency. Appropriate technology required in order to process the waste water so that the treated water can meet the environmental quality standards that are allowed. Designing the waste water treatment plant that is suitable and efficient for treating industrial wastewater nata de coco is the activated sludge process. Wastewater treatment using activated sludge process of conventional (standard) generally consists of initial sedimentation, aeration and final sedimentation.Keywords : Activated Sludge, Design, IPAL

The Design and Construction of the “Houtrust” Waste Water Treatment Plant in the Hague

1991 ◽  
Vol 24 (10) ◽  
pp. 161-170 ◽  
Author(s):  
M. D. Sinke
Keyword(s):  
Waste Water ◽  
Water Treatment ◽  
North Sea ◽  
Waste Water Treatment ◽  
Treatment Plant ◽  
Water Treatment Plant ◽  
Waste Water Treatment Plant ◽  
The North ◽  
The North Sea ◽  
The Hague

Until a century ago, The Hague's waste water was discharged directly into the city's canals. However, the obnoxious smell and resultant pollution of local waters and beaches then necessitated the implementation of a policy of collecting and transferring waste water by means of a system of sewers. By 1937, it was being discharged, via a 400 metre-long sea outfall, directly into the North Sea. By 1967, however, the increasing volume of waste water being generated by The Hague and the surrounding conurbations called for the construction of a primary sedimentation plant. This had two sea outfalls, one 2.5 km long and the other 10 km long, the former for discharging pre-settled waste water and the latter for discharging sludge directly into the North Sea. This “separation plant” was enlarged during the period 1986-1990. On account of the little available area - only 4.1 ha - the plant had to be enlarged in two stages by constructing a biological treatment section and a sludge treatment section with a capacity of 1,700,000 p.e. (at 136 gr O2/p.e./day). In order to gain additional space, a number of special measures were introduced, including aerating gas containing 90% oxygen and stacked final clarifiers. Following completion of the sludge treatment section, it has become possible, since 1st May 1990, to dump digested sludge into a large reservoir (“The Slufter”), specially constructed to accommodate polluted mud dredged from the Rotterdam harbours and waterways. As a result of these measures, there has been a reduction of between 70% and 95% in North Sea pollution arising from the “Houtrust” waste water treatment plant. Related investment totalled Dfl. 200 million and annual operating and maintenance costs (including investment charges) will amount to Dfl. 30 million. Further measures will have to be taken in the future to reduce the discharge of phosphorus and nitrogen. So this enlargement is not the end. There will be continued extension of the purification operations of the “Houtrust” waste water treatment plant.

Solids Concentrations in a Treatment Plant Effluent

1992 ◽  
Vol 26 (9-11) ◽  
pp. 2543-2546
Author(s):  
M. Defrain ◽  
F. Schmidt
Keyword(s):  
Waste Water ◽  
Activated Sludge ◽  
Federal Republic ◽  
Treatment Plant ◽  
Analysis Procedure ◽  
Process Water ◽  
Federal Republic Of Germany ◽  
Output Variable ◽  
Sludge Treatment ◽  
Sewerage Network

In the calculations customarily used to dimension nitrification and denitrification plants in the Federal Republic of Germany, solids in the influent of the biological stage represent a significant output variable. Numerous modified methods based on nationally and internationally standardized analysis procedures are available to determine solids concentrations in waste-water. Tests showed that different values are measured depending on the method of analysis employed. Harmonization of the analysis procedure is advisable to ensure comparable conditions for the calculation of activated sludge tank volumes. The solids reaching a treatment plant originate from two main sources. Filterable materials are passed to the treatment plant via the preceding sewerage network with its industrial and commercial users, but are also carried by process water from sludge treatment. The influence of process water on wastewater composition is illustrated by reference to the Wuppertal-Buchenhofen treatment plant.

Design, Operating Results and Experiences of Two Large-Scale Treatment Plants with Biological Nitrogen and Phosphate Elimination

1992 ◽  
Vol 25 (4-5) ◽  
pp. 225-232
Author(s):  
C. F. Seyfried ◽  
P. Hartwig
Keyword(s):  
Waste Water ◽  
Water Treatment ◽  
Large Scale ◽  
Waste Water Treatment ◽  
Treatment Plant ◽  
Water Treatment Plant ◽  
Waste Water Treatment Plant ◽  
Main Stream ◽  
Side Stream ◽  
Biological Nitrogen

This is a report on the design and operating results of two waste water treatment plants which make use of biological nitrogen and phosphate elimination. Both plants are characterized by load situations that are unfavourable for biological P elimination. The influent of the HILDESHEIM WASTE WATER TREATMENT PLANT contains nitrates and little BOD5. Use of the ISAH process ensures the optimum exploitation of the easily degradable substrate for the redissolution of phosphates. Over 70 % phosphate elimination and effluent concentrations of 1.3 mg PO4-P/I have been achieved. Due to severe seasonal fluctuations in loading the activated sludge plant of the HUSUM WASTE WATER TREATMENT PLANT has to be operated in the stabilization range (F/M ≤ 0.05 kg/(kg·d)) in order not to infringe the required effluent values of 3.9 mg NH4-N/l (2-h-average). The production of surplus sludge is at times too small to allow biological phosphate elimination to be effected in the main stream process. The CISAH (Combined ISAH) process is a combination of the fullstream with the side stream process. It is used in order to achieve the optimum exploitation of biological phosphate elimination by the precipitation of a stripped side stream with a high phosphate content when necessary.

Semi-technical investigations into the removal of nitrogen and phosphorus at the kleve-salmorth waste water treatment plant

1996 ◽  
Vol 33 (12) ◽  
pp. 251-254
Author(s):  
Karl Arno Bäumer ◽  
Angela Baumann
Keyword(s):  
Waste Water ◽  
Water Treatment ◽  
Waste Water Treatment ◽  
Treatment Plant ◽  
Water Treatment Plant ◽  
Waste Water Treatment Plant ◽  
Biological Phosphorus Removal ◽  
Nitrogen And Phosphorus ◽  
University Of Technology ◽  
Biological Phosphorus

The Institute for Water and Waste Management (ISA) at the Aachen University of Technology (RWTH) verified, through semi-technical analysis, the efficiency of the planned upgrade of the Kleve-Salmorth waste water treatment plant. Additionally the allowable biological phosphorus removal limit and the scheduled simultaneous precipitation were also ascertained.

Analysis and design of suitable model structures for activated sludge tanks with circulating flow

1999 ◽  
Vol 39 (4) ◽  
pp. 55-60 ◽  
Author(s):  
J. Alex ◽  
R. Tschepetzki ◽  
U. Jumar ◽  
F. Obenaus ◽  
K.-H. Rosenwinkel
Keyword(s):  
Activated Sludge ◽  
Large Scale ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
High Sensitivity ◽  
Suitable Model ◽  
Model Structure ◽  
Analysis And Design ◽  
Hydraulic Behaviour ◽  
Model Structures

Activated sludge models are widely used for planning and optimisation of wastewater treatment plants and on line applications are under development to support the operation of complex treatment plants. A proper model is crucial for all of these applications. The task of parameter calibration is focused in several papers and applications. An essential precondition for this task is an appropriately defined model structure, which is often given much less attention. Different model structures for a large scale treatment plant with circulation flow are discussed in this paper. A more systematic method to derive a suitable model structure is applied to this case. Results of a numerical hydraulic model are used for this purpose. The importance of these efforts are proven by a high sensitivity of the simulation results with respect to the selection of the model structure and the hydraulic conditions. Finally it is shown, that model calibration was possible only by adjusting to the hydraulic behaviour and without any changes of biological parameters.

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