scholarly journals NGHIÊN CỨU BIỂU HIỆN TỚI HẠN TRONG CÁC BĂNG HỢP KIM Fe88Co2Zr7B2Cu1

Author(s):  
Nguyen Hai Yen ◽  
Nguyen Hoang Ha ◽  
Pham Thi Thanh ◽  
Kieu Xuan Hau ◽  
Tran Dang Thanh ◽  
...  

In this work, we investigated the critical behavior of Fe88Co2Zr7B2Cu1 alloy ribbons prepared using a single-roller melt-spinning method. X-ray diffraction analysis shows that the alloy is almost amorphous. This alloy undergoes a second-order ferromagnetic-paramagnetic (FM-PM) phase transition at room temperature (Curie temperature TC = 296 K). To investigate the nature of the FM-PM phase transition near the TC for the alloy, we performed a critical-exponent study. Based on modified Arrott plots, the Kouvel-Fisher method, and Widom’s scaling relation, a set of critical parameters were determined. The critical parameters are β = 0.545 ± 0.041 and γ = 1.109 ± 0.018 obtained from the modified Arrott plots; β = 0.547 ± 0.005 and γ = 1.105 ± 0.016 from the Kouvel-Fisher method, and d = 3.035 ± 0.059 from Widom’s scaling relation. These values are close to those expected for the mean-field model, revealing long-range FM interactions.

2017 ◽  
Vol 31 (09) ◽  
pp. 1750092 ◽  
Author(s):  
H. Yurtseven ◽  
U. Ipekoğlu ◽  
S. Ateş

Tilt angle (order parameter) and the susceptibility are calculated as a function of temperature for the [Formula: see text]–[Formula: see text] transition in quartz using a Landau phenomenological model. The tilt angle as obtained from the model is fitted to the experimental data from the literature and the temperature dependence of the tilt angle susceptibility is predicted close to the [Formula: see text]–[Formula: see text] transition in quartz. Our results show that the mean field model explains the observed behavior of the [Formula: see text]–[Formula: see text] phase transition in quartz adequately and it can be applied to some related materials.


2018 ◽  
Vol 185 ◽  
pp. 05001
Author(s):  
Yen Nguyen ◽  
Mai Nguyen ◽  
Quang Vu ◽  
Thanh Pham ◽  
Victor Koledov ◽  
...  

Magnetic phase transition, magnetocaloric effect and critical parameters of Ni50-xCoxMn50-yAly (x = 5 and 10; y = 17, 18 and 19) rapidly quenched ribbons have been studied. X-ray diffraction patterns exhibit a coexistence of the L21 and 10M crystalline phases of the ribbons. Magnetization measurements show that all the samples behave as soft magnetic materials with a low coercive force less than 60 Oe. The shape of thermomagnetization curves considerably depends on Co and Al concentrations. The Curie temperature (TC) of the alloy ribbons strongly increases with increasing the Co concentration and slightly decreases with increasing the Al concentration. The Ni45Co5Mn31Al19 and Ni40Co10Mn33Al17 ribbons reveal both the positive and negative magnetocaloric effects. Under magnetic field change (ΔGH) of 13.5 kOe, the maximum magnetic entropy change (|ΔSm|max) of the Ni45Co5Mn31Al19 ribbon is about 2 and -1 J·kg−1·K−1 for negative and positive magnetocaloric effects, respectively. Basing on Arrott - Noakes and Kouvel - Fisher methods, critical parameters of the Ni45Co5Mn31Al19 ribbon were determined to be TC ≈ 290 K, β ≈ 0.58, γ ≈ 0.92 and δ ≈ 2.59. The obtained values of the critical exponents indicate that the magnetic order of the alloy ribbon is close to the mean-field model.


Author(s):  
Natalia Lindner ◽  
Zbigniew Śniadecki ◽  
Mieszko Kołodziej ◽  
Jean-Marc Grenèche ◽  
Jozef Marcin ◽  
...  

AbstractA magnetocaloric effect with wide tunability was observed in melt-spun amorphous Gd65Fe15-xCo5+xAl10Si5 (x = 0, 5, 10) alloys of different Fe/Co ratios. Their magnetic properties were compared with those of the previously investigated parent alloy Gd65Fe10Co10Al15. The glassy structure of the melt-spun samples was confirmed by X-ray diffraction (XRD) and 57Fe Mössbauer spectrometry. Their Curie temperatures (TC) were between 155 and 195 K and increased significantly with decreasing Co content. The highest value of the magnetic entropy change ΔSM = − 6.8 J/kg K was obtained for Gd65Fe5Co15Al10Si5, when the magnetic field was increased from 0 to 5 T. Refrigerant capacity (RC) takes values close to 700 J/kg for the whole series of the alloys. The occurrence of the second-order phase transition and the conformity of the magnetic behavior with the mean field model were concluded on the basis of the analysis of the universal curves and the values of the exponent n (ΔSM ∝ Hn). Graphical abstract


1998 ◽  
Vol 66 (1-4) ◽  
pp. 259-270 ◽  
Author(s):  
S. SalihoĞLu ◽  
H. Yurtseven ◽  
A. Giz ◽  
D. Kayişoğlu ◽  
A. Konu

2020 ◽  
Vol 28 (2) ◽  
pp. 3-18
Author(s):  
D. Anchishkin ◽  
V. Gnatovskyy ◽  
D. Zhuravel ◽  
V. Karpenko

Thermodynamic properties of a system of an interacting boson particles and antiparticles at high tem­peratures are studied within the framework of the thermodynamically consistent Skyrme-­like mean-­field model. The mean field contains both attractive and repulsive terms. Self­-consistency relations between the mean field and thermodynamic functions are derived. We assume a conservation of the isospin density for all temperatures. It is shown that, independently of the strength of the attractive mean field, at the critical tem­perature Tc the system undergoes the phase transition of second order to the Bose­-Einstein condensate, which exists in the temperature interval 0 ≤ T ≤ Tc . It is obtained that the condensation represents a discontinuity of the derivative of the specific heat at T = Tc .


2019 ◽  
Vol 61 (2) ◽  
pp. 339
Author(s):  
H. Yurtseven ◽  
S.B. Isik ◽  
E. Kilit Dogan

AbstractThe T – P phase diagrams of the halogenomethane compounds (CCl_4 – _ n Br_ n , n = 0, 1, 2, 4) are calculated using a mean field model. By expanding the free energy in terms of the order parameters for the transitions of the liquid (L), rhombohedral (R), face-centered cubic (FCC) and monoclinic (M) phases in those compounds, the phase line equations are derived and they are fitted to the experimental data from the literature. This method of calculating the T – P phase diagram is satisfactory to explain the T – P measurements for the halogenomethane compounds and it can also be applied to two-component systems.


2021 ◽  
Vol 29 (1) ◽  
pp. 5-14
Author(s):  
D. Anchishkin ◽  
V. Gnatovskyy ◽  
D. Zhuravel ◽  
V. Karpenko

A system of interacting relativistic bosons at finite temperatures and isospin densities is studied within the framework of the Skyrme­like mean­field model. The mean field contains both attractive and repulsive terms. The consideration is taken within the framework of the Canonical Ensemble and the isospin­density dependencies of thermodynamic quantities is obtained, in particular as the phase diagrams. It is shown that in such a system, in addition to the formation of a Bose­Einstein condensate, a liquid­gas phase transition is possible. We prove that the multi­boson system develops the Bose condensate for particles of high­density component only.


1992 ◽  
Vol 45 (11) ◽  
pp. 1899 ◽  
Author(s):  
PA Reynolds ◽  
CD Delfs ◽  
BN Figgis ◽  
B Moubaraki ◽  
KS Murray

The magnetic susceptibilities along and perpendicular to the c axis (hexagonal setting) between 2.0 and 300 K at a magnetic field of 1.00 T, and the magnetizations at field strengths up to 5.00 T, are presented for single crystals of [Co(NH3)5(OH2)] [Cr(CN)6]. The results are interpreted in terms of zero-field splitting (2D) of the ground 4A2g term by spin-orbit coupling and of magnetic exchange interaction between the chromium atoms. The magnetic exchange is modelled as one of Ising or mean-field in type. The exchange is found to be quite small: J = -0.18(6) cm-1 if the Ising model is employed, and -0.03(1) cm-1 for the mean-field model. The model adopted for the exchange has a strong influence on the value of the parameter D obtained. When the Ising model is used D is deduced to be -0.28(9) cm-l; when the mean-field model is used D is -0.14(4) cm-l. The g-values deduced are in agreement with those from e.s.r. measurements at higher temperatures and do not depend on the exchange model. In any case, D is found to be sufficiently large that it must be considered in a polarized neutron diffraction experiment on the compound.


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