scholarly journals Investigation of Sorbents for Phosphorus Removal

Author(s):  
Julita Šarko ◽  
Aušra Mažeikienė

Nowadays, the problem of water pollution with phosphorus compounds is especially important. Wastewater treatment plants do not always meet the strict requirements for the residual total phosphorus concentration – 1 mg/l in the treated wastewater. Usually individual wastewater treatment plants have a poorer removal of phosphorus from the wastewater because they are more sensitive to fluctuations in wastewater flow and environmental conditions. Research results in the scientific literature shows that only 30–50% of the phosphorus is removed from the wastewater by conventional methods. Additional wastewater treatment is recommended for higher phosphorus removal efficiency achievement. One of the ways to remove phosphorus from wastewater is filtration through sorbents filter media. The efficiency of three sorbents – Filtralite P, foam-glass and crushed shells to remove phosphorus from biologically treated wastewater is investigated in this article. A phosphate phosphorus concentration was reduced by filtering wastewater through sorbents filter media during the experiment. Concentrations of treated wastewater pollutants, filtration rate, efficiency of sorbents to remove phosphorus from the wastewater were measured and evaluated. Experiment results showed that phosphate phosphorus was effectively removed by Filtralite P sorbent (removal efficiency 97–98%), less effective were foam-glass (removal efficiency 66–95%) and crushed shells sorbents (removal efficiency 39–50%).

Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1650 ◽  
Author(s):  
Krzysztof Czerwionka ◽  
Anna Wilinska ◽  
Agnieszka Tuszynska

Measurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency in the 2-h sedimentation process was 46%, 34%, 8%, 12% for the total suspended solids, organic matter (COD), total nitrogen, and total phosphorus, respectively. The use of organic coagulants contributed to 14–81% increase of pollutant removal efficiency. Substantial discrepancies in biological nutrient removal processes were not discovered in two-phase (anaerobic-anoxic) experiments without and with the addition of the organic coagulants. The increase in organic matter removal efficiency as a result of the CEPT process may contribute to a 65–80% increase in biogas production. The conducted research confirms the possibility of using organic coagulants in the primary precipitation process in wastewater treatment plants (WWTPs) in accordance with the principles of maximum energy recovery, thereby promoting renewable energy sources. Additionally, organic coagulants, as opposed to inorganic ones, do not cause a significant increase of chloride and sulfate ion concentrations, which facilitates the use of treated wastewater in the water reuse systems, such as irrigation of agricultural crops.


2013 ◽  
Vol 781-784 ◽  
pp. 2138-2141
Author(s):  
Hong Jie Sun ◽  
Shao Hua Yang ◽  
Yu Bo Cui

Phosphorus removal from wastewater has always been given serious attention in sewage treatment. Eutrophication can happen if phosphorus wastewater is directly discharged into natural water and high phosphorus-contained irrigation water may lead crops beat down. The research investigated the phosphorus removal efficiency in wastewater by shell powder. The experiment results showed that the best removal effect could meet the Wastewater Treatment Plant Discharge Standard (GB18918-2002) Grade I-A in China, which can be achieved under the conditions of the dosage of shell powder solution 1 ml, pH > 11 and precipitation one to four hours at the initial phosphorus concentration of about 3 mg/L.


2017 ◽  
Vol 76 (4) ◽  
pp. 920-927 ◽  
Author(s):  
I. Mishima ◽  
M. Hama ◽  
Y. Tabata ◽  
J. Nakajima

Small-scale wastewater treatment plants (SWTPs) are widely used as decentralized wastewater treatment systems in sparsely populated areas of Japan. Iron electrolysis, an electrocoagulation technology, is installed in these SWTPs for phosphorus removal. Phosphorus can be removed via the formation of an insoluble compound containing phosphate and iron, such as FePO4; however, it was necessary to determine the conditions under which phosphorus can be effectively and stably removed in actual SWTPs. According to previous studies using iron compounds, improved phosphorus removal was obtained by Ca addition. It is therefore thought that calcium addition may also be effective in improving the phosphorus removal during iron electrolysis in SWTPs. It is also important to determine the chemical state of iron to understand the phosphorus removal mechanism during iron electrolysis. In this study, laboratory-scale batch experiments with the iron electrolysis method were conducted to investigate the effect of phosphorus removal using treated wastewater from actual SWTPs without or with Ca addition. The results indicated that the addition of Ca improved the phosphorus removal performance. Furthermore, phosphorus removal was inhibited in the presence of high dissolved organic carbon (DOC). The X-ray absorption fine structure measurements of the produced particulates in the experiments showed no substantial change in the chemical state of iron without or with Ca addition. The statistical analyses revealed the range of improving or inhibiting effects on phosphorus removal due to the Ca and DOC. Thus, the results of this study provided useful information pertaining to the influence of coexisting substances on phosphorus removal and the chemical state of iron in the produced particulates.


2014 ◽  
Vol 14 (3) ◽  
pp. 63-74 ◽  
Author(s):  
Ewelina Płuciennik-Koropczuk

Abstract Increased production and consumption of drugs influences the pollution pharmaceuticals. Recent years have seen a significant increase in the consumption of non-prescription medicines, among which, are a large group of non-steroidal anti-inflammatory drugs (NSAIDs). Research conducted in Poland and abroad showed the presence of NSAIDs, both in treated wastewater in surface waters and drinking waters. One of the most frequently detected drugs in the environment is diclofenac, belongs to NSAID. Its concentration in surface waters range from 9 to 3363 ng/L. Traditional wastewater treatment plants are not specialized enough in removing the pharmaceuticals and their metabolites, and with purified wastewater are introduced into surface waters. Diclofenac concentrations in treated wastewater range from 0.29 to 2.5 μg/L, the average removal efficiency is about 40%.


2021 ◽  
Vol 937 (4) ◽  
pp. 042054
Author(s):  
Ivan Kulik ◽  
Elena Shuckaya

Abstract The article discusses the basic principles of wastewater treatment from biogenic elements, provides the necessary conditions for the biological removal of phosphorus compounds. The technology of pre-fermentation of the sediment of primary sedimentation tanks, options for its design, the main parameters of the process are described. Specific aspects of the operation of low-capacity wastewater treatment facilities are indicated and the expediency of using the technology of biological phosphorus removal in them is considered.


1994 ◽  
Vol 29 (12) ◽  
pp. 13-21
Author(s):  
P. Schleypen

Full-scale investigations have demonstrated that wastewater lagoons combined with rotating biological contactors can be installed for denitrification without much effort when designed for nitrification. By recirculation of a mixture of nitrified wastewater and biological sludge from the outlet of the high loaded sedimentation tank back to the inlet of the sedimentation pond the removal efficiency was consistently high combined with a high process stability. In addition a considerable amount of enhanced biological phosphorus removal could be attained simultaneously.


1990 ◽  
Vol 22 (3-4) ◽  
pp. 211-216
Author(s):  
Niels Skov Olesen

In some areas of Denmark nutrient removal is required even for very small wastewater plants, that is down to 500 pe (pe = person equivalents). The goal for the removal is 80% removal of nitrogen and 90% removal of phosphorus, or in terms of concentrations: 8 mg nitrogen/l and 1.2 mg phosphorus/l. The inlet concentrations are typically 40 mg N/l and 10 mg P/l. The paper presents the results from two such plants with a capacity of 800 pe. Phosphorus removal is made by simultaneous precipitation with ferrous sulphate. Nitrogen removal is carried out using the recirculation method. Both plants were originally rotor aerated oxidation ditches. They have been extended with a denitrification reactor and a recirculation pumping station. At present both plants have been in activity for about 3 years and with satisfactory results. Average concentrations of nitrogen (summer) and phosphorus is 7 mg/l and 0.9 mg/l respectively. Nitrogen removal seems to be a practical solution on these small plants. It is,though, sensitive to temperature and highly oxidized rain water. Phosphorus removal seems to be an easily run and relatively non-sensitive technique at least when using simultaneous precipitation.


Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 221
Author(s):  
Rafał Tytus Bray ◽  
Katarzyna Jankowska ◽  
Eliza Kulbat ◽  
Aneta Łuczkiewicz ◽  
Aleksandra Sokołowska

The paper presents the results of research on the use of ultrafiltration, using membranes of 200 and 400 kDa separation, for disinfection of municipal treated wastewater. The research was conducted on a fractional technical scale using real municipal treated wastewater from two large wastewater treatment plants treating most of the wastewater over the one-million polycentric Gdańsk agglomeration (1.2 million inhabitants). UF 200 kDa and UF 400 kDa processes enabled further improvement of the physical and chemical parameters of treated wastewater. Total phosphorus (to below 0.2 mg/L–UF 200 kDa, 0.13 mg/L–UF 400 kDa) and turbid substances (to below 0.2 mg/L, both membranes) were removed in the highest degree. COD was reduced efficiently (to below 25.6 mgO2/L–UF 200 kDa, 26.8 mgO2/L–UF 400 kDa), while total nitrogen was removed to a small extent (to 7.12 mg/L–UF 200 kDa and 5.7 mg/L–UF 400 kDa. Based on the reduction of indicator bacteria; fecal coliforms including E. coli (FC) and fecal enterococci (FE) it was found that the ultrafiltration is an effective method of disinfection. Not much indicator bacterial were observed in the permeate after processes (UF 200 kDa; FC—5 CFU/L; FE—1 CFU/L and UF 400 kDa; FC—70 CFU/L; FE—10 CFU/L. However, microscopic analysis of prokaryotic cells and virus particles showed their presence after the application of both membrane types; TCN 3.0 × 102 cells/mL–UF 200 kDa, 5.0 × 103 cells/mL–UF 400 kDa, VP 1.0 × 105/mL. The presence of potentially pathogenic, highly infectious virus particles means that ultrafiltration cannot be considered a sufficient disinfection method for treated wastewater diverted for reuse or discharged from high load wastewater treatment plants to recreational areas. For full microbiological safety it would be advisable to apply an additional disinfection method (e.g., ozonation).


2021 ◽  
Vol 3 (7) ◽  
Author(s):  
T. S. C. Quintão ◽  
F. G. Silva ◽  
A. L. Pereira ◽  
W. N. Araújo ◽  
P. M. Oliveira ◽  
...  

AbstractHuman enteric viruses, such as enteric adenoviruses (HAdV), are known to be involved with gastrointestinal disorders, especially acute gastroenteritis. Several studies have used HAdV as an indicator of water quality, since they are considered highly stable and widely distributed viruses in water matrices. The aim of this study was to detect and genotype HAdVs in water matrices impacted by discharges of treated effluents from wastewater treatment plants (WWTPs). Wastewater treatment plants from the sanitary system of the Brazilian Federal District were assessed in 2018 and 2019. Samples were collected upstream and downstream from discharge points for each WWTP. Viral concentration based on adsorption-elution and conventional PCR was used for molecular detection, and positive samples were sequenced for phylogenetic analysis. Pluviosity data for the period in which the samples were collected were obtained. Our results demonstrated the presence of HAdVs in 27.2% (61/224) of the samples. The positivity was significantly higher in downstream samples compared to upstream. Moreover, the HAdV positivity was higher in downstream samples collected from receiving water bodies impacted by secondary-level WWTPs in comparison with those impacted by tertiary-level WWTPs. Phylogenetic analysis demonstrated the presence of genotypes 40 and 41, with prevalence of HAdV genotype 41. Despite the predominance of HAdV-41, an increasing frequency of the HAdV-40 was associated with higher pluviosity. In conclusion, this study is the first documentation in the Brazilian Federal District dealing with the prevalence and diversity of HAdVs in several WWTP, along with their correlation with rainfall index.


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