Polymers and Graphene-Based Materials as Barrier Coatings

2022 ◽  
pp. 129-151
Author(s):  
Shamma Al Hashmi ◽  
Shroq Al Zadjali ◽  
Nitul S. Rajput ◽  
Meriam Mohammedture ◽  
Monserrat Gutierrez ◽  
...  

Currently, a wide range of materials are being used as barrier coatings for different applications. Among them, polymers and graphene have been the focus of many studies. Polymers are used in numerous industries due to their remarkable properties, including resistance to thermal degradation, resistance to chemical permeation, and good mechanical properties. On the other hand, graphene, a one-atom-thick and two-dimensional material, does not allow the permeation of gases or liquid molecules through its plane; thus, it has been considered one of the promising nanomaterials used in gas and liquid barrier applications and corrosion inhibition coatings.

2016 ◽  
Vol 792 ◽  
pp. 50-66 ◽  
Author(s):  
Anirudh Rao ◽  
Mark C. Thompson ◽  
Kerry Hourigan

Linear stability analysis of a wide range of two-dimensional and axisymmetric bluff-body wakes shows that the first three-dimensional mode to became unstable is always mode E. From the studies presented in this paper, it is speculated to be the universal primary 3D instability, irrespective of the flow configuration. However, since it is a transition from a steady two-dimensional flow, whether this mode can be observed in practice does depend on the nature of the flow set-up. For example, the mode E transition of a circular cylinder wake occurs at a Reynolds number of $\mathit{Re}\simeq 96$, which is considerably higher than the steady to unsteady Hopf bifurcation at $\mathit{Re}\simeq 46$ leading to Bénard–von-Kármán shedding. On the other hand, if the absolute instability responsible for the latter transition is suppressed, by rotating the cylinder or moving it towards a wall, then mode E may become the first transition of the steady flow. A well-known example is flow over a backward-facing step, where this instability is the first global instability to be manifested on the otherwise two-dimensional steady flow. Many other examples are considered in this paper. Exploring this further, a structural stability analysis (Pralits et al.J. Fluid Mech., vol. 730, 2013, pp. 5–18) was conducted for the subset of flows past a rotating cylinder as the rotation rate was varied. For the non-rotating or slowly rotating case, this indicated that the growth rate of the instability mode was sensitive to forcing between the recirculation lobes, while for the rapidly rotating case, it confirmed sensitivity near the cylinder and towards the hyperbolic point. For the non-rotating case, the perturbation, adjoint and structural stability fields, together with the wavelength selection, show some similarities with those of a Crow instability of a counter-rotating vortex pair, at least within the recirculation zones. On the other hand, at much higher rotation rates, Pralits et al. (J. Fluid Mech., vol. 730, 2013, pp. 5–18) have suggested that hyperbolic instability may play a role. However, both instabilities lie on the same continuous solution branch in Reynolds number/rotation-rate parameter space. The results suggest that this particular flow transition at least, and probably others, may have a number of different physical mechanisms supporting their development.


1989 ◽  
Vol 67 (8) ◽  
pp. 1354-1358 ◽  
Author(s):  
Jacques Paquet ◽  
Paul Brassard

The behaviour of various types of polar dienes towards halogenated ortho quinones has been investigated in a number of representative cases. As compared to the commonly used para analogues, o-quinones provide a wide range of products that indicate a keener response to the nature, number, and position of substituents on both reactants. 3-Halogenated-o-naphthoquinones 1 and 2 react smoothly with a representative vinologous ketene acetal 3, vinylketene acetals 4 and 5, and a monooxygenated diene 6 to provide variously substituted phenanthrenequinones 7–11. Only monooxygenated dienes on the other hand add to o-benzoquinones 14–16 and give convenient syntheses of the corresponding o-naphthoquinones 18–20. Keywords: cycloaddition, o-naphthoquinones, phenanthrenequinones, regiospecificity.


2002 ◽  
Vol 55 (1) ◽  
pp. 1-37 ◽  
Author(s):  
Craig A. Monson

Abstract Reexamination of a wide range of documents surrounding the twenty-second, twenty-fourth, and twenty-fifth sessions of the Council of Trent reveals that delegates strived officially to say as little as possible about music: only that secular or impure elements should be eliminated and that specific issues should be settled locally, by individual bishops and provincial synods. But, beginning with Gustave Reese, several scholars have misleadingly strung together a preliminary canon, stressing textual intelligibility, which was never approved in the general congregations, and the few lines that actually supplanted it, concerned only with the elimination of lasciviousness. On the other hand, a largely unrecognized or misunderstood attack on church polyphony did occur at the less familiar twenty-fifth session, when Gabriele Paleotti may have attempted to suppress elaborate music in female monasteries. Although this attempt was rejected in the general congregations, its restrictions were subsequently revived by local authorities such as Paleotti and Carlo Borromeo in their own dioceses. In the Council's immediate aftermath, reformers such as Paleotti and Borromeo once again focused on the issue of intelligibility, affording it a quasi-official status that seems to have quickly become widely accepted as “iuxta formam concilii.”


Author(s):  
Shweta Singh ◽  
Sureshbabu Popuri ◽  
Qazi Mohammad Junaid ◽  
Sabiah Shahul Hameed ◽  
Jeyakumar Kandasamy

A wide range of N-tosyl α–ketoamides underwent transamidation with various alkyl amines in the absence of catalyst, base, or additives. On the other hand, transamidation in N-Boc α–ketoamides is achieved...


2019 ◽  
Vol 17 (1) ◽  
pp. 183-194
Author(s):  
Anna Rogacka-Łukasik

ADR (Alternative Dispute Resolution), as a non-judicial resolution of disputes, is a wide range of mechanisms that aim to put an end to a conflict without the need of conducting a trial before the court. On the other hand, the modern form of ADR is ODR (Online Dispute Resolution) – an online dispute resolution system that is the expression of the newest means of communication and technical innovations in order to help in non-judicial dispute resolving. The goal of this publication is to present the ODR platform and, in particular, to describe the process of filing a complaint by the consumer by means of it.


e-Polymers ◽  
2003 ◽  
Vol 3 (1) ◽  
Author(s):  
Koh-hei Nitta ◽  
Yoshikazu Yamamoto

Abstract We examined mechanical and morphological properties of fully transcrystalline polypropylene grown from the surface of poly(tetrafluoroethylene) sheets. Comparison of mechanical properties between transcrystalline and spherulitic polypropylenes demonstrated that Young’s modulus is dependent on the crystallinity and independent of the supermolecular structure. On the other hand, the mechanical yielding process was predominantly affected by the supermolecular structure, and the mechanical energy required for yielding of transcrystalline sheets was greater than that of the spherulitic morphology. In addition, it was found that mechanical necking is required for the alignment of lamellae in the stretching direction. This means that the unfolding process of lamellae orienting in the stretching direction is associated with necking and ductility.


Author(s):  
Ivica Cvrtila ◽  
Vladimir Stilinović

The crystal structures of two polymorphs of a phenazine hexacyanoferrate(II) salt/cocrystal, with the formula (Hphen)3[H2Fe(CN)6][H3Fe(CN)6]·2(phen)·2H2O, are reported. The polymorphs are comprised of (Hphen)2[H2Fe(CN)6] trimers and (Hphen)[(phen)2(H2O)2][H3Fe(CN)6] hexamers connected into two-dimensional (2D) hydrogen-bonded networks through strong hydrogen bonds between the [H2Fe(CN)6]2− and [H3Fe(CN)6]− anions. The layers are further connected by hydrogen bonds, as well as through π–π stacking of phenazine moieties. Aside from the identical 2D hydrogen-bonded networks, the two polymorphs share phenazine stacks comprising both protonated and neutral phenazine molecules. On the other hand, the polymorphs differ in the conformation, placement and orientation of the hydrogen-bonded trimers and hexamers within the hydrogen-bonded networks, which leads to different packing of the hydrogen-bonded layers, as well as to different hydrogen bonding between the layers. Thus, aside from an exceptional number of symmetry-independent units (nine in total), these two polymorphs show how robust structural motifs, such as charge-assisted hydrogen bonding or π-stacking, allow for different arrangements of the supramolecular units, resulting in polymorphism.


2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Ling Liu ◽  
Qiaoxin Yang ◽  
Jingwen Shen

Porous carbon nanotube (CNT) buckypapers (BPs) with various porosities were obtained by using a positive pressure filtration method. The porosity of the BPs fell into a wide range of 11.3–39.3%. Electrical conductivities and tensile mechanical properties of the prepared BPs were then measured and correlated with the porosity of the CNT BPs. Results demonstrated that the conductivities, tensile strength, and elastic modulus of the BPs could decrease by increasing their porosity. The elongation at break of the BPs on the other hand did increase significantly, suggesting improved toughness of the BPs. The obtained electrical conductivity and tensile strength of the porous BPs can reach nearly 0.6 S/m and 26 MPa, respectively, which may be potentially useful in composites reinforcement and conductive materials.


1931 ◽  
Vol 4 (1) ◽  
pp. 54-63
Author(s):  
H. Mark ◽  
E. Valko

Abstract It is only during recent years that it has become possible by the use of new technic to detect molecular phenomena produced in the mechanical deformation of substances. As far as metallic substances are concerned, and crystalline substances in particular, the problem has already been solved for the most part. On the other hand, in spite of considerable progress during recent years the study of the deformation of organic substances and of fibers in particular, in which group rubber is included, has not yet been carried on. The mechanical properties of a crystalline system vary according to whether there is a single crystal or an aggregate of crystals. However, in both cases the extensibility of the products originates in a displacement of parallel layers, i. e., a sliding of the parts of the crystal along definite crystalline planes, this phenomenon of sliding being irreversible in these substances. In fact, in these cases the reversible part of the elongation is very weak, and amounts to only a few thousandths of the entire phenomenon. In brief, the phenomena of hardening brought about by deformation (sometimes observable) are due to disturbances of the regular lattice. In particular, the displacement of the atom and the change from its normal position can cause the appearance of irregularities on the surface of sliding.


1980 ◽  
Vol 102 (2) ◽  
pp. 125-137 ◽  
Author(s):  
Y. T. Tsui ◽  
C. C. Tsui

This paper, which is an extension of [1], treats two-dimensional aeroelastic stability of two coupled conductors. It is found that the wake-induced flutter is symmetric with respect to the horizontal axis of the wake for all cases provided that the sign of the static coupling coefficient, ε = kxy/kxx, is changed. It appears that the spacer coupling ratio, K/kxx = Ω/ωx, is the most important factor in determining stability. For practical purposes, the system is almost always stable for K/kxx = Ω/ωx = 0.8, because the frequency ratio, κ = ωy/ωx, deviates less than ten percent from unity for a typical transmission line. On the other hand, within our range of interest, damping has little or no effect on the stability of coupled conductors. When the windward conductor is fixed, i.e., K = 0, then damping does influence the stability of the leeward conductor.


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