Effect of Aqueous Milling on the Total Carbon Content of Hard Metal Powders

2021 ◽  
Vol 42 ◽  
pp. 3-8
Author(s):  
Horea Florin Chicinaş ◽  
Darius Ovidiu Jucan ◽  
Glad Contiu ◽  
Cătălin Popa

Materials consisting of a hard phase, usually WC, and a tough binder, traditionally Co, form the most successful class of composite materials, also known as Hard Metals (HM) or Cemented Carbides. Powder metallurgy routes are employed generally for the production of such [1]. The typical processing route of such materials involves mixing the components, kneading and consolidation. Alcohols, alkanes and alkenes are commonly used to limit any excessive heating and oxidation of powders during mixing the components. In this study, we report the results of milling in a more environmentally friendly aqueous milling media. The obtained results are presented comparatively with milling under a traditional media, such as isohexane and acetone. The characterization of the milled samples has been done from the structural, compositional and morphological point of view. Considering our previous results, an important aspect of the milled powder is the carbon content, which dictates the sintering behavior of such parts. The carbon balance investigation performed on a carbon analyzer has revealed no significant differences upon changing the milling media. This work emphasizes the influence of the milling media on the HM powder. HM powders with similar properties have been obtained both by traditional and aqueous milling. The comparative study has revealed that the substitution of the traditional milling media does not influence the carbon content in the HM powder.

1964 ◽  
Vol 44 (2) ◽  
pp. 232-236 ◽  
Author(s):  
J. F. Dormaar

Two orthic profiles, widely separated geographically, of each of four parent materials—lacustrine, alluvial–lacustrine, glacial till, and Aeolian—were selected at undisturbed sites within each of the Brown, Dark Brown, and Thin Black soil zones. Material from the Ah and Bm horizons was subjected to solvent extraction, and for each sample the total organic carbon of seven different fractions was determined.The efficiency of the procedure in extracting humus carbon decreased as the total carbon content of the soil increased. Total organic matter, the first humic acid fraction, and the combined total of the three humic acid fractions showed significant differences between soil zones. The only significant separation between all four parent materials was made by the alcohol-benzene fraction. Other parent material separations were possible only following the summation of data of several fractions, such as the three humic acid fractions or the two fulvic acid fractions. A simplification of the procedure in case of soils of one Order and a modification to overcome the impeding effect of increased carbon content are requisite.


2013 ◽  
Vol 152 ◽  
pp. 74-82 ◽  
Author(s):  
Yasuhiro Tsujimoto ◽  
Yukiyo Yamamoto ◽  
Keiichi Hayashi ◽  
Alhassan I. Zakaria ◽  
Yahaya Inusah ◽  
...  

1972 ◽  
Vol 11 (6) ◽  
pp. 509-511 ◽  
Author(s):  
S. A. Bibinov ◽  
G. T. Dzodziev ◽  
V. K. Vitryanyuk ◽  
V. D. Petrenko

2019 ◽  
Vol 3 (1) ◽  
pp. 40-54
Author(s):  
Ivan Passal ◽  
Gun Mardiatmoko ◽  
Fransina Latumahina

 The study was carried out in the Dusung Community Forest (Agroforestry) area of ​​Toisapu Negeri Hutumuri Hamlet, South Leitimur Sub-District, Ambon City in August - October 2018 to determine the relationship between stand volume and stored biomass for scale plots in dusung agroforestry areas in Toisapu Hamlet. For this reason, it begins with an inventory of potential at seedling, sapling, pole and tree levels so that information and data on the actual potential of carbon content in the dusung system are obtained based on the value of the diversity of stand volume and biomass content. The results of the three measurement plots showed that the highest biomass was seen to be dominated by Durian, Pala and Langsat and Duku and Clove plants. Based on the calculation of the biomass value of the total carbon content in the three plots, it can be seen biomass potential for a total 400 m² plot area or 0.04 ha for the three plots with an area of ​​1,200 m² or 0.12 ha having a total biomass of 50,783.77 Kg / m² multiplied by the assumption of 0.5% of the total amount of tree biomass and poles so that the total carbon content stored in the three plots is 25,391.88 kg / m² or 2,539.19 tons / ha.


2020 ◽  
Vol 9 (2) ◽  
pp. 99-108
Author(s):  
Raka Pramulo Sophianto ◽  
Hadi Endrawati ◽  
Retno Hartati

Padang lamun merupakan ekosistem yang kompleks dan produktif di ekosistem laut dan pesisir serta salah satu peran utama lamun adalah sebagai penyimpan karbon dengan karakteristik uniknya. Penelitian ini bertujuan untuk mengetahui jenis-jenis lamun, mengetahui struktur komunitas lamun,  nilai biomassa dan nilai karbon lamun. Penelitian ini dilakukan pada bulan Oktober dan November 2017 di Teluk Awur dan Pantai Bendengan Jepara. Metode yang digunakan dalam penelitian ini adalah metode deskriptif. Pengambilan sampel dilakukan pada dua tempat masing-masing lima stasiun. Sampel yang diambil adalah lamun, sedimen dan air laut yang ditemukan di lokasi penelitian yang kemudian di identifikasi serta dianalisis di Laboratorium Biologi, Departemen Ilmu Kelautan, dan analisis pengabuan lamun dilakukan pada di Laboratorium Geologi, Departemen Ilmu Kelautan, Fakultas Perikanan dan Ilmu Kelautan, Universitas Diponegoro. Hasil penelitian ini menunjukkan nilai total biomassa lamun yang didapat di kedua lokasi dari sampling pertama yaitu 982,77 gbk/m2 dan sampling kedua yaitu 923,91 gbk/m2. Total kandungan karbon pada sampling pertama berkisar antara 511,76 – 3662,26 gC/m2 dan total karbon pada sampling kedua berkisar antara 141,48 – 3344,2 gC/m2. Perbedaan hasil yang di dapat menunjukkan bahwa perbedaan iklim dapat berpengaruh terhadap hasil yang didapatkan. Seagrass beds are complex and productive ecosystems in marine and coastal ecosystems and one of the main roles of seagrasses is storing carbon with its unique characteristics. This study aims to determine the types of seagrasses, find out the seagrass community structure, biomass values and seagrass carbon values. This research was conducted in October and November 2017 in Teluk Awur and Bendengan Jepara Beach. The method used in this research is descriptive method. Sampling was carried out at two places each of five stations. Samples taken were seagrass, sediments and seawater found at the study site which were then identified and analyzed in the Biology Laboratory, Department of Marine Sciences, and analysis of desertion carried out at the Geology Laboratory, Department of Marine Sciences, Faculty of Fisheries and Marine Sciences, Diponegoro University. The results of this study indicate the total value of seagrass biomass obtained in both locations from the first test was 982.77 gbk/m2 and the second test was 923.91 gbk/m2. The total carbon content in the first sampling ranged from 511.76 - 3662.26 gC/m2 and the total carbon in the second sampling ranged from 141.48-3344.2 gC/m2. The difference in results can show that climate differences can affect the results obtained.


2018 ◽  
Vol 19 (45) ◽  
pp. 5-11 ◽  
Author(s):  
Shurkhuu Tserenpil ◽  
Xing Jung Fan ◽  
Atindra Sapkota ◽  
Enkhmaa Chinzorig ◽  
Jian Zhong Song ◽  
...  

Total carbon content of the atmospheric suspended particulate matters consisted of as high as 89-93% organic carbon (OC) in Ulaanbaatar aerosol without showing seasonal variation. However, limited aerosol measurements have been conducted on these OC rich aerosols particularly for high molecular weight constituents. In order to address the gap above, abundance of high molecular weight humic-like substances (HULIS) in total suspended particulates (TSP) from Ulaanbaatar atmospheric aerosol were determined for the first time. HULIS molecular structure was characterised for different seasons using carbon content and UV absorbance measurements coupled with solid phase extraction methods. Although, HULIS contributions to water soluble organic fraction of the winter and summer aerosols were similar HULIS carbon concentration was higher in winter samples (9-37 mg·L-1) than in summer (2-6 mg·L-1). Consequently quantity of aromatic moieties and degree of aromaticity varied between seasons.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Ning Li ◽  
Ting Meng ◽  
Lai Ma ◽  
Han Zhang ◽  
JiaJia Yao ◽  
...  

AbstractSmart combination of manifold carbonaceous materials with admirable functionalities (like full of pores/functional groups, high specific surface area) is still a mainstream/preferential way to address knotty issues of polysulfides dissolution/shuttling and poor electrical conductivity for S-based cathodes. However, extensive use of conductive carbon fillers in cell designs/technology would induce electrolytic overconsumption and thereby shelve high-energy-density promise of Li–S cells. To cut down carbon usage, we propose the incorporation of multi-functionalized NiFe2O4 quantum dots (QDs) as affordable additive substitutes. The total carbon content can be greatly curtailed from 26% (in traditional S/C cathodes) to a low/commercial mass ratio (~ 5%). Particularly, note that NiFe2O4 QDs additives own superb chemisorption interactions with soluble Li2Sn molecules and proper catalytic features facilitating polysulfide phase conversions and can also strengthen charge-transfer capability/redox kinetics of overall cathode systems. Benefiting from these intrinsic properties, such hybrid cathodes demonstrate prominent rate behaviors (decent capacity retention with ~ 526 mAh g−1 even at 5 A g−1) and stable cyclic performance in LiNO3-free electrolytes (only ~ 0.08% capacity decay per cycle in 500 cycles at 0.2 A g−1). This work may arouse tremendous research interest in seeking other alternative QDs and offer an economical/more applicable methodology to construct low-carbon-content electrodes for practical usage.


2020 ◽  
Vol 6 (4) ◽  
pp. 509-528
Author(s):  
Samuel Gagnon ◽  
Michel Allard

Soils in the northern circumpolar region play a central role in the global carbon cycle because the release of carbon through permafrost thaw and geomorphological disturbances can potentially cause a feedback on climate. However, large uncertainties in estimates of permafrost carbon stocks remain, mainly because of wide gaps in the spatial coverage of soil carbon sampling sites and the large mapping polygons used to upscale data. By combining mapping of landforms and knowledge of surficial geology to upscale soil carbon content measurements, we provide an assessment of soil total carbon content in the region of the Narsajuaq river valley (Nunavik, Canada) to generate the first high-resolution soil carbon estimate confirmed by field measurements in Nunavik. We estimate that the Narsajuaq river valley and the surrounding uplands have a weighted average of 3.4 kg C m−2 (0–100 cm), with 73% of the total carbon content stored in the top 30 cm. The results also indicate that the valley is a carbon hotspot in the region, containing 76% of the total carbon content (0–100 cm) of the study area. Although soil carbon estimates will always require field sampling, the geomorphological mapping approach can significantly improve carbon content estimates and provide better inputs for models.


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