A Novel NiCl2-CuCl2/HMOR Catalyst for Direct Vapor-Phase Carbonylation of Methanol
2013 ◽
Vol 316-317
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pp. 983-986
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Keyword(s):
Direct vapor-phase methanol carbonylation, without any methyl iodide in the feed as a promoter, was carried out over NiCl2-CuCl2/HMOR catalysts. The results showed that NiCl2-CuCl2/HMOR catalysts exhibited high activity for methanol carbonylation. The optimum component of the composite catalyst was 5wt% NiCl2 and 15wt% CuCl2. In addition, the effects of reaction pressure and temperature on catalytic performance of 5%NiCl2-15%CuCl2/HMOR catalyst were investigated. It was revealed that methanol conversion of 84.2% and carbonylation selectivity of 73.5% could be obtained under the optimum reaction conditions of P=1.5MPa and T=623K.
1999 ◽
Vol 150
(1-2)
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pp. 205-212
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2011 ◽
Vol 396-398
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pp. 1769-1772
1978 ◽
Vol 51
(1)
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pp. 96-100
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Keyword(s):
2011 ◽
Vol 396-398
◽
pp. 2411-2415
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