Synthesis and Characterization of SnSe Nanowires by Solvothermal Method

2015 ◽  
Vol 713-715 ◽  
pp. 2924-2927 ◽  
Author(s):  
Jian Li ◽  
Long Yan ◽  
Hui Jin Liu
Keyword(s):  
Thin Film ◽  
Band Gap ◽  
Solvothermal Method ◽  
Thin Film Solar Cells ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structure Morphology ◽  
Uv Visible

A simple solvothermal route has been used to prepare SnSe nanowires using SnCl4·4H2O and Selenium powder. The phase, structure, morphology, and optical properties of the as-synthesized products were characterized by powder X-ray diffraction (XRD), scan electron microscopy (SEM), Raman spectroscope (RS) and UV-visible spectrophotometer (UV-vis). The results showed that SnSe nanowires were prepared at 200°C for 24 h and in the length of 150-200μm, and width of 1-1.5μm. The band gap of SnSe nanowires was about 1.67 eV, which was close to the optimum band gap of thin film solar cells.

Synthesis and Electrochemistry of Aluminum Porphycenes: Crystal and Molecular Structure of Methyl-σ-Bonded Aluminum Etioporphycene

1997 ◽  
Vol 01 (02) ◽  
pp. 109-119 ◽  
Author(s):  
ROGER GUILARD ◽  
VIRGINIE PICHON-PESME ◽  
HASSANE LACHEKAR ◽  
CLAUDE LECOMTE ◽  
ALLY M. AUKAULOO ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Structural Data ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
H Nmr ◽  
Axial Ligands ◽  
Uv Visible

The synthesis and characterization of three monomeric aluminum porphycenes with anionic or σ-bonded axial ligands is reported. The investigated compounds are represented as ( EtioPc ) Al ( CH 3) and ( EtioPc ) AlX where EtioPc represents the dianion of etioporphycene and X = Cl − or OH −. Each synthesized complex was characterized by mass spectrometry. 1 H NMR, IR and UV-visible spectroscopies as well as by electrochemistry. Comparisons are made between the properties of complexes in the aluminum etioporphycene series and related chloro- or methyl σ-bonded Al ( III ) porphyrins containing octaethylporphyrin ( OEP ) or tetraphenylporphyrin ( TPP ) macrocycles. Comparisons are also made between the currently investigated compounds and a previously reported Al ( III ) μ-oxo dimer, [( EtioPc ) Al ]2 O . In addition, the crystal and molecular structure of ( EtioPc ) Al ( CH 3) was determined by X-ray diffraction. The molecular structure of this methyl-σ-bonded aluminum etioporphycene provides the first structural data for an aluminum porphycene compound. The aluminum(III) atom in ( EtioPc ) Al ( CH 3) is pentacoordinated and is located 0.54 Å from the plane of the four N -nitrogens.

Synthesis and Characterization of NiFeCo3O4 Ternary Thin Film Electrodes for Supercapacitors Applications by Galvanostatic Method

2020 ◽  
Vol 12 (2) ◽  
pp. 254-262
Author(s):  
Kalyani Muninathan ◽  
Emerson Rajamony Navaneetha
Keyword(s):  
Thin Film ◽  
Synthesis And Characterization ◽  
Film Electrode ◽  
X Ray Diffraction ◽  
X Ray ◽  
Galvanostatic Method ◽  
Electrodes For Supercapacitors ◽  
Charge Discharge ◽  
Scanning Electron

At this present task, an attempt done in order to synthesize NiFeCo3O4 ternary thin film electrode by Electrodeposition method. Microstructure of the films studied using X-ray diffraction, energy dispersive X-ray spectroscopy (EDAX) and Field emission (FESEM) scanning electron microscopy. Films Electrochemical property were studied and confirmed with the help of charge discharge techniques using cyclic voltammetry, which confirms that the prepared electrode has excellent electrochemical capacitive behaviour with 757 F g–1 specific capacitance value of at the density in current about 1 mA g–1.

Microwave-Hydrothermal Synthesis and Characterization of Graphene

2012 ◽  
Vol 602-604 ◽  
pp. 917-920 ◽  
Author(s):  
Zhen Hui Xiao ◽  
Shui Sheng Wu ◽  
Yan Lin Sun ◽  
Yu Lin Zhao ◽  
Ya Ming Wang
Keyword(s):  
Chemical Reduction ◽  
Visible Spectrum ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microwave Hydrothermal ◽  
Ft Ir ◽  
Uv Visible ◽  
Scanning Electron

Graphene was synthesized by microwave-hydrothermal chemical reduction of graphite oxide using hydrazine hydrate as the reducing agent. Graphene was characterized using X-ray diffraction, UV-visible spectrum, FT-IR spectrum and scanning electron microscopy. Results indicated that the as-prepared graphene was wrinkled and comprised fewer graphenes with a highly crystalline structure.

scholarly journals Synthesis and characterization of novel coumarin-based terpyridine ligands and their Zn(II) complexes

2020 ◽  
Vol 44 (11-12) ◽  
pp. 721-726
Author(s):  
Xiaolong Wang ◽  
Xian Yue ◽  
Long Deng
Keyword(s):  
Solvothermal Method ◽  
Emission Spectra ◽  
Synthesis And Characterization ◽  
Spectroscopic Methods ◽  
X Ray Diffraction ◽  
X Ray ◽  
Trigonal Bipyramidal ◽  
Terpyridine Ligands ◽  
Distorted Trigonal Bipyramidal

Two novel mononuclear Zn(II) complexes, [ZnL1Cl2] (1) (L1=( E)-3-(4-(2,2′:6′,2″-tripyridyl)-4′-styryl)-7-diethylaminocoumarin) and [ZnL2Cl2] (2) (L2=3-(4-(2,2′:6′,2″-tripyridyl)-4′-phenylimine)-7-diethylaminocoumarin), were obtained by the solvothermal method from ZnCl2 and coumarin-based terpyridine ligands. The complexes were characterized by spectroscopic methods and single-crystal X-ray diffraction. The Zn2+ in the complexes is coordinated by three nitrogen atoms of the terpyridine ligand and two chloride anions, forming a distorted trigonal bipyramidal environment. Moreover, the UV–Vis absorption and emission spectra of the ligands and complexes in diluted dichloromethane solutions were measured.

Synthesis and Characterization of New Functional Material (C6H5CNH2nNH3)2PbI4(where n=0,1,2)

2011 ◽  
Vol 311-313 ◽  
pp. 2099-2105 ◽  
Author(s):  
Li Ling Guo ◽  
Xing Li ◽  
Han Xing Liu
Keyword(s):  
Electron Microscopy ◽  
Band Gap ◽  
Synthesis And Characterization ◽  
Molecular Formula ◽  
Reactant Ratio ◽  
Functional Material ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

The new functional material, the hybrids with molecular formula (C6H5CNH2nNH3)2PbI4(where N=0,1,2) were synthesized by reactions in solution. The influences of the reactant ratio and the reaction time on the structures of the products were investigated. The structures and the properties of the hybrids were characterized using X-ray diffraction(XRD), scanning electron microscopy (SEM) and ultraviolet&visible (UV) adsorption spectra . The effect of number of methylene, n, on the structure forming and the band gap magnitude has been studied. The results demenstrate that the number of methylene has effect both on the forming of the layered structure and on the magnitude of the band gap.

scholarly journals Synthesis and characterization of erbium trioxide nanoparticles as photocatalyzers for degradation of methyl orange dye

2019 ◽  
Vol 12 (1) ◽  
pp. 15-21 ◽  
Author(s):  
Rifat Mohammed Dakhil ◽  
Tayser Sumer Gaaz ◽  
Ahmed Al-Amiery ◽  
Mohd S. Takriff ◽  
Abdul Amir H. Kadhum
Keyword(s):  
Methyl Orange ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
Visible Spectroscopy ◽  
X Ray ◽  
Uv Visible ◽  
Methyl Orange Dye ◽  
Microscopy Techniques ◽  
Degradation Of Methyl Orange

Abstract. The present work focuses on the photocatalytic degradation of methyl orange (MO) on erbium trioxide nanoparticles (Er2O3 NPs). In this study, Er2O3 nanoparticles were synthesized and fully characterized via various techniques, including X-ray diffraction, UV–visible spectroscopy and scanning electron microscopy techniques. The results revealed that the photocatalytic activity of the prepared Er2O3 NPs was manifested in MO photodegradation. The optimum efficiency obtained was 16 %.

Synthesis and characterization of 1,4-diazophenylenebridged Cu-phthalocyanine polymer

e-Polymers ◽  
2004 ◽  
Vol 4 (1) ◽  
Author(s):  
Cemil Alkan ◽  
Leyla Aras ◽  
Güngör Gündüz
Keyword(s):  
Electrical Conductivity ◽  
Diazonium Salt ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
Visible Spectroscopy ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Uv Visible ◽  
Soluble Part

Abstract A novel type of phthalocyanine polymer, 1,4-diazophenylene-bridged Cuphthalocyanine, was prepared from the diazonium salt of diaminobenzene and Cu(II) 1,8,15,22-tetraaminophthalocyanine. The polymer is partially soluble in tetrahydrofuran, dichloromethane, and dimethylformamide. Characterization of the polymer was performed by IR and UV-visible spectroscopy, X-ray diffraction, ash analysis, viscometry, differential scanning calorimetry and thermogravimetric analysis. The molecular weight of the soluble part of the polymer was determined by ebullioscopy. Electrical conductivity of the polymer and its doped samples were determined by the 4-probe technique. It was found that the electrical conductivity increased up to 10-4 S/cm after doping. The redox behaviour of the polymer was investigated utilizing cyclic voltammetry.

Characterization of Crystalline Cu2SnS3 Synthesized via Low Temperature Solvothermal Method

2018 ◽  
Vol 780 ◽  
pp. 62-66 ◽  
Author(s):  
Mohamed S. Abdel Latif ◽  
N.M. Shaalan ◽  
Ahmed A. El-Moneim
Keyword(s):  
Band Gap ◽  
Solvothermal Method ◽  
Average Crystallite Size ◽  
Annealing Process ◽  
Secondary Phases ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Scanning Electron

Cu2SnS3flower-like nanoparticles consisted of nanoflakes were successfully produced using solvothermal technique at 120°C for 12 h. The precursors used in this process were CuCl2.2H2O, SnCl2.2H2O, and thiourea with dimethyl sulfoxide (DMSO) as a solvent. The results showed that the as-obtained product was triclinic Cu2SnS3with secondary phases CuS and SnS, and after annealing process, a pure triclinic was obtained. The crystal structure of the obtained samples was investigated by X-ray diffraction which assured the obtained data and the average crystallite size of as-prepared and annealed CTS was found to be 18.42 and 31.6 nm, respectively. Scanning electron microscopy (SEM) showed that the surface morphology has the shape of flower like consisted of nanoflakes. The transmission electron microscope (TEM) displayed the formation of sheets. The band gap was measured using UV-Vis absorption spectroscopy and found that the as-prepared sample has 1.97 eV band gap, which obtained for various phases CuS and SnS. However, this band was changed to 1.26 eV upon the heat treatment at 500°C for 10 minutes. This value of Egis comparable with the value reported by other literatures.

scholarly journals Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor

2015 ◽  
Vol 11 ◽  
pp. 951-956 ◽  
Author(s):  
Sandrina Oliveira ◽  
Dulce Belo ◽  
Isabel Cordeiro Santos ◽  
Sandra Rabaça ◽  
Manuel Almeida
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Triethyl Phosphite ◽  
High Yield ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cross Coupling Reaction ◽  
Uv Visible

A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new donor was characterized namely by single crystal X-ray diffraction, cyclic voltammetry, NMR, UV-visible and IR spectroscopy.

scholarly journals Synthesis and Characterization of a Nano (CdO)0.94:(In2O3) 0.06 / Si gas Sensor

2021 ◽  
pp. 3858-3870
Author(s):  
M. F. A. Alias ◽  
H. A. Abdulrahman
Keyword(s):  
Thin Film ◽  
Gas Sensor ◽  
Morphological Properties ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Atomic Force ◽  
Q Switching ◽  
Sensor Properties

In this work, a (CdO)0.94:(In2O3)0.06 film was developed on a glass substrate using Q- switching pulse laser beam (Nd:YAG; wavelength 1064 nm). The quantitative elemental analysis of the (CdO)0.94:(In2O3)0.06 thin film was achieved using energy dispersive X- ray diffraction (EDX). The topological and morphological properties of the deposited thin film were investigated using atomic force microscope (AFM) and field emission scan electron microscopy (FESEM). The I-V characteristic and Hall effect of (CdO)0.94 :(In2O3)0.06 thin films were used  to  study the electrical properties. The gas sensor properties of the film prepared on n-Si were investigated for oxidization and reduction gases.

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