Electrical Properties of Y2NiMnO6 Ceramics Sintered at High Temperature

2015 ◽  
Vol 804 ◽  
pp. 55-58 ◽  
Author(s):  
Thanapong Sareein ◽  
Panakamon Deeyai ◽  
Bundit Putasaeng ◽  
Naphat Chathirat

In this work, impedance spectroscopy technique was used in order to investigate the electric properties of double perovskites of the Y2NiMnO6 ceramics, which were prepared by thermal decomposition technique at 800°C for 6 hours and then sintered at a high temperature of 1400°C for 6, 12, 18, and 24 hours. Consequently, the electric characterization of the Y2NiMnO6 ceramics was performed at 30°C °C in the frequency range from 102 Hz to 108 Hz. The results in the Rg with 10,000, 9,990, 6,400, and 1,700 (Ω) at sintering time, respectively. Dispersion was observed in the variation of impedance values with frequency. Possible reason for all the above observation was discussed.

1991 ◽  
Vol 6 (10) ◽  
pp. 2054-2058 ◽  
Author(s):  
B-S. Hong ◽  
T.O. Mason

Via in situ electrical property measurements (conductivity, Seebeck coefficient) over the temperature range 500–800 °C and oxygen partial pressure range 10−4-1 atm, the equilibrium transport properties and stability range of YBa2Cu4O8 were determined. YBa2Cu4O8 behaves like the intrinsically mixed-valent compound, magnetite (Fe3O4), with small variations in electrical properties with changes in oxygen partial pressure. The decomposition boundary to YBa2Cu3O6+y (or YBa2Cu3.5O7.5±z) and CuO occurs at log(po2, atm) = −1.24 × 104/T(K) + 11.01(773 ⋚ T(K) ⋚ 1073).


MRS Advances ◽  
2017 ◽  
Vol 2 (54) ◽  
pp. 3329-3334 ◽  
Author(s):  
Bo Dong ◽  
Kazi Ahmed ◽  
Yige Li ◽  
Cengiz Sinan Ozkan ◽  
Mihrimah Ozkan

ABSTRACTTo better understand the condition of commercial batteries used in Tesla EVs and stationary applications under real performing situations, this article focuses on tracking the temperature of commercial batteries during varying cycling conditions. We have found evidence of significant impact of cycling methods on batteries in ionic conductivity, inner impedance development, and structural change in both cathode and anode electrodes, which will be further analyzed by electrochemical impedance spectroscopy technique in the following research.


RSC Advances ◽  
2015 ◽  
Vol 5 (66) ◽  
pp. 53504-53513 ◽  
Author(s):  
Juntao Xing ◽  
Donghui Chen ◽  
Wei Zhao ◽  
Xiaoling Peng ◽  
Zilong Bai ◽  
...  

Porous Ti/SnO2–Sb2O3–CNT/PbO2 electrodes were successfully fabricated using a thermal decomposition technique and electro-deposition technologies.


2020 ◽  
Vol 10 (18) ◽  
pp. 6576
Author(s):  
Manuel Vázquez-Nambo ◽  
José-Antonio Gutiérrez-Gnecchi ◽  
Enrique Reyes-Archundia ◽  
Wuqiang Yang ◽  
Marco-A. Rodriguez-Frias ◽  
...  

The physicochemical characterization of pharmaceutical materials is essential for drug discovery, development and evaluation, and for understanding and predicting their interaction with physiological systems. Amongst many measurement techniques for spectroscopic characterization of pharmaceutical materials, Electrical Impedance Spectroscopy (EIS) is powerful as it can be used to model the electrical properties of pure substances and compounds in correlation with specific chemical composition. In particular, the accurate measurement of specific properties of drugs is important for evaluating physiological interaction. The electrochemical modelling of compounds is usually carried out using spectral impedance data over a wide frequency range, to fit a predetermined model of an equivalent electrochemical cell. This paper presents experimental results by EIS analysis of four drug formulations (trimethoprim/sulfamethoxazole C14H18N4O3-C10H11N3O3, ambroxol C13H18Br2N2O.HCl, metamizole sodium C13H16N3NaO4S, and ranitidine C13H22N4O3S.HCl). A wide frequency range from 20 Hz to 30 MHz is used to evaluate system identification techniques using EIS data and to obtain process models. The results suggest that arrays of linear R-C models derived using system identification techniques in the frequency domain can be used to identify different compounds.


Biosensors ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 108 ◽  
Author(s):  
Arthur Luiz Alves de Araujo ◽  
Julien Claudel ◽  
Djilali Kourtiche ◽  
Mustapha Nadi

New technologies, such as biosensors and lab-on-a-chip, are reducing time consumption and costs for the detection and characterization of biological cells. One challenge is to detect and characterize cells and bacteria one by one or at a very low concentration. In this case, measurements have very low variations that can be difficult to detect. In this article, the use of an insulation layer on the connection tracks of a biosensor with coplanar electrodes is proposed to improve a biosensor previously developed. The impedance spectroscopy technique was used to analyze the influence of the insulation layer on the cutoff frequencies and on the normalized impedance variation. This solution does not induce changes in the cutoff frequencies, though it permits improving the normalized impedance variations, compared to the same biosensor without the insulation layer.


2018 ◽  
Vol 879 ◽  
pp. 47-50
Author(s):  
Naphat Albutt ◽  
Suejit Pechprasarn ◽  
Sangwoei Sawekwiharee ◽  
Anchana Kuttiyawong ◽  
Panakamon Thonglor ◽  
...  

Determining the structure of ceramic materials is essential in order to fully characterize the electrical properties and improve existing materials. YMNO ceramics (Y2NiMnO6) prepared by compression and sintering were doped with TiO2 and analyzed using XRD and SEM. The calcined sample prior to sintering contained phases of the YMNO double perovskite and TiO2. Following sintering at 1400°C, the perovskite structure was replaced by Y2Ti2O7 fcc structure, and the grain size was found to increase with sintering time up to 18 hours. This sets a limit to the amount of TiO2 which can be used to successfully dope the YMNO ceramic.


RSC Advances ◽  
2014 ◽  
Vol 4 (92) ◽  
pp. 50435-50442 ◽  
Author(s):  
J. N. Behera ◽  
Joydeep Bhattacharjee ◽  
Satoshi Horike ◽  
Subba R. Marri ◽  
Prem P. Dahiya

Chiral three-dimensional Mg(ii) and Mn(ii) sulfates have been synthesized, well characterized and studied from first-principles calculations. High temperature X-ray diffraction, thermogravimetric analysis and DFT calculations reveal that the structures of both the compounds remain intact even after the thermal decomposition of the ammonium ion.


1992 ◽  
Vol 269 ◽  
Author(s):  
Octavio M. Andrade ◽  
Magdy F. Iskander ◽  
Shane Bringhurst

ABSTRACTThis paper discusses theoretical and practical aspects of the development and implementation of various measurement techniques for high-temperature broadband microwave characterization of materials at the University of Utah. Objectives include materials measurements in the frequency range from 45 MHz to 12 GHz and for temperatures as high as 1000°C.


1984 ◽  
Vol 56 (8) ◽  
pp. 2323-2329 ◽  
Author(s):  
Bouzid Boudjema ◽  
Gérard Guillaud ◽  
Maxime Gamoudi ◽  
Monique Maitrot ◽  
Jean‐Jacques André ◽  
...  

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