Experimental Advancements of Wastewater Disposal in Coal Chemical Industry by Yeasts

2014 ◽  
Vol 1073-1076 ◽  
pp. 941-948
Author(s):  
Li Li Wang ◽  
Qian Yang
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Chemical Industry ◽  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Good Effect ◽  
Coking Wastewater ◽  
Torula Yeast ◽  
N Removal ◽  
Cod Removal Rate

The research in this paper focuses on improving the COD removal rate of the coking wastewater and the NH3-N removal rate and thus diversifying measures to dispose microbial floras in wastewater from the coal chemical industry. The means of adding nutrients, acid treatment and coagulation sedimentation react synergistically to dispose the organic contaminants in the coking wastewater. We attempted to combine Saccharomyces cerevisiae, Torula yeast, tropical Candida mycoderma, etc. to exploit the respective advantages to the full and improve the disposal effect. According to the COD sample (27000-30000) and NH3-N (2500-3000) offered by the client company, the COD removal rate ranged from 24.2% to 31.8% in the mixed experiment group of Saccharomyces cerevisiae and Torula yeast, with NH3-N removal rate from 63.5% to 69.6%. Obviously, the NH3-N removal rate produced good effect. Meanwhile, the COD removal rate ranged form 35.3% to 41.8% in the experiment group only adjusting PH value and the NH3-N removal rate ranged from 40.2% to 50.2%. It is obvious that NH3-N removal rate is influenced by the amount of bacterial strain.

A Study of Fenton’s Oxidation Pretreatment on Dye Wastewater Containing Acetic Acid

2014 ◽  
Vol 1044-1045 ◽  
pp. 215-218
Author(s):  
Xian Huan Qiu ◽  
Hai Yu ◽  
Peng Fei Deng
Keyword(s):  
Acetic Acid ◽  
Processing Time ◽  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Dye Wastewater ◽  
Fenton’S Oxidation ◽  
Effects Of Ph ◽  
Cod Removal Rate ◽  
Fenton's Oxidation

In the presence of acetic acid, the effects of pH, processing time, addition of Fe2+ and H2O2 on dye wastewater treatment were studied. Experimental results showed that in the presence of acetic acid, when the pH value was 4, the processing time was 30.0min, addition of ferrous sulfate was 4.8g/L, and addition of hydrogen peroxide was 56mL/L, the treatment effect was the best, COD removal rate reached 51.0%. Further studied of the effect of the presence of acetic acid on Fenton’s oxidation of dye wastewater, the results showed that without of acetic acid, the COD removal rate was higher than that with acetic acid. And the effect of Fenton's reagent on oxidation of dye substances was interfered by the presence of acetic acid.

Photocatalytic Oxidation Degradation Behavior on Fracturing Wastewater in Oilfield

2011 ◽  
Vol 396-398 ◽  
pp. 1918-1922 ◽  
Author(s):  
Li Ping Wan ◽  
Ying Feng Meng ◽  
Gao Li ◽  
Hua Zhou
Keyword(s):  
Photocatalytic Oxidation ◽  
Ph Value ◽  
Removal Rate ◽  
Oil Field ◽  
Cod Removal ◽  
Composite Catalyst ◽  
Application Time ◽  
Secondary Pollution ◽  
Cod Removal Rate ◽  
Temperature Activation

Due to great variety additives and disposal difficulty, chemical method, biochemical method and solidification are adopted to treat fracturing wastewater in oil field. These processes easily bring about shortcomings, including high cost and secondary pollution. Studied on the treatment of fracturing wastewater of 4# well in Sichuan Oilfield by modified bentonite loading TiO2-Ag2O composite catalyst, COD removal rate is determined for different condition of pH value of solution, adding content of TiO2, inflating volume and light application time. The optimal condition is obtained as follows: pH value of solution is 3, adding content of TiO2 is 0.4-0.5%, inflating volume is 15L/min and light application time is 3h. Under this condition, COD removal rate of fracturing wastewater is 58.1%. The composite catalyst performance is stable and without secondary pollution. It is reusable by high temperature activation, so it can reduce wastewater treatment cost, and should be widely applied.

Pretreatment of furfural industrial wastewater by Fenton, electro-Fenton and Fe(II)-activated peroxydisulfate processes: a comparative study

2014 ◽  
Vol 70 (3) ◽  
pp. 414-421 ◽  
Author(s):  
C. W. Yang ◽  
D. Wang ◽  
Q. Tang
Keyword(s):  
Comparative Study ◽  
Industrial Wastewater ◽  
Ph Value ◽  
Removal Rate ◽  
Aeration Rate ◽  
Cod Removal ◽  
Optimal Conditions ◽  
Initial Concentration ◽  
Cod Removal Rate ◽  
Pretreatment Technology

The Fenton, electro-Fenton and Fe(II)-activated peroxydisulfate (PDS) processes have been applied for the treatment of actual furfural industrial wastewater in this paper. Through the comparative study of the three processes, a suitable pretreatment technology for actual furfural wastewater treatment was obtained, and the mechanism and dynamics process of this technology is discussed. The experimental results show that Fenton technology has a good and stable effect without adjusting pH of furfural wastewater. At optimal conditions, which were 40 mmol/L H2O2 initial concentration and 10 mmol/L Fe2+ initial concentration, the chemical oxygen demand (COD) removal rate can reach 81.2% after 90 min reaction at 80 °C temperature. The PDS process also has a good performance. The COD removal rate could attain 80.3% when Na2S2O8 initial concentration was 4.2 mmol/L, Fe2+ initial concentration was 0.1 mol/L, the temperature remained at 70 °C, and pH value remained at 2.0. The electro-Fenton process was not competent to deal with the high-temperature furfural industrial wastewater and only 10.2% COD was degraded at 80 °C temperature in the optimal conditions (2.25 mA/cm2 current density, 4 mg/L Na2SO4, 0.3 m3/h aeration rate). For the Fenton, electro-Fenton and PDS processes in pretreatment of furfural wastewater, their kinetic processes follow the pseudo first order kinetics law. The pretreatment pathways of furfural wastewater degradation are also investigated in this study. The results show that furfural and furan formic acid in furfural wastewater were preferentially degraded by Fenton technology. Furfural can be degraded into low-toxicity or nontoxic compounds by Fenton pretreatment technology, which could make furfural wastewater harmless and even reusable.

Study on Treatment of M-Cresol Wastewater Using Potassium Ferrate(VI)

2012 ◽  
Vol 610-613 ◽  
pp. 2367-2371 ◽  
Author(s):  
Ming Zhong Hu ◽  
Zhen He Shi ◽  
Hong Yan Zhao
Keyword(s):  
Reaction Time ◽  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Potassium Ferrate ◽  
Optimum Conditions ◽  
Initial Concentration ◽  
Cod Removal Rate

The effects of the oxidation of potassium ferrate and the flocculation on cresol wastewater water were evaluated. This research aimed at determining the optimum conditions for the COD removal rate duing cresol wastewater water process. The results showed that potassium ferrate dosage of 1.1g/L, the pH value of 5, reaction time 15min, m-cresol initial concentration of 200 mg/L were the optimum conditions. Under the optimum conditions, COD removal rate was over 67%.

Study on Treatment of Polytetrahydrofuran Wastewater by Iron-Carbon Micro Electrolysis

2013 ◽  
Vol 295-298 ◽  
pp. 1307-1310
Author(s):  
Xi Tian ◽  
Ming Xin Huo ◽  
De Jun Bian ◽  
Sheng Shu Ai ◽  
Qing Kai Ren
Keyword(s):  
Reaction Time ◽  
Removal Efficiency ◽  
Contact Time ◽  
Ph Value ◽  
Removal Rate ◽  
Volume Ratio ◽  
Cod Removal ◽  
Electrolysis Process ◽  
Cod Removal Efficiency ◽  
Cod Removal Rate

The wastewater produced from the polytetrahydrofuran (PolyTHF) was treated with iron-carbon micro electrolysis process. This paper had studied the COD removal efficiency influences of primary PH value, reaction time, the quality ratio of the iron-carbon, the quality and volume ratio of Fe-wastewater. The results show that when pH value is 3, the quality ratio of the iron-carbon is 11 and the quality and volume ratio of Fe and wastewater is 17 with contact time of 90 min, the wastewater COD removal rate can reach as high as 95.0%.

Experimental Study on the Treatment of Sewage by Soil

2013 ◽  
Vol 464 ◽  
pp. 179-183
Author(s):  
Xiao Hui Wang ◽  
Yong Zhang ◽  
Chong Hao Huang
Keyword(s):  
Removal Rate ◽  
Soil Column ◽  
Sewage Treatment ◽  
Column Experiment ◽  
Experimental Treatment ◽  
Cod Removal ◽  
Column Experiments ◽  
Soil Thickness ◽  
N Removal ◽  
Cod Removal Rate

The bath static experiments were conducted to study the sewage treatment effects by the typical yellow-brown soil of Xuzhou, the results obtained in this study showed that: The COD removal rate was about 50% or so through experimental treatment. The three days dynamic and intermittent soil column experiments show that: The COD removal rate was more than 80% by the simulated soil column experiments; the dynamic intermittent and soil column experiment both show that soil thickness influence the effect of phosphorus removal, the thicker layers, the better removal rate; the effective depth of NH4-N removal is deeper than 15cm.

Analysis of Degradation by Aerobic Recharge for Concentrated Leachate

2014 ◽  
Vol 675-677 ◽  
pp. 483-488
Author(s):  
Jian Zhang ◽  
Ping Xian ◽  
Long Hui Yang ◽  
Long Hui Zhan ◽  
Guang Hui Bu
Keyword(s):  
Membrane Separation ◽  
Ph Value ◽  
Early Stage ◽  
Removal Rate ◽  
Hydraulic Loading ◽  
Strong Trend ◽  
N Removal ◽  
Cod Removal Rate ◽  
The Impact ◽  
Mean Time

Concentrated leachate obtained from landfill leachate by membrane separation was treated using technique of aerobic recharge. Variation of effluent COD, NH3-N and pH in concentrated leachate during aerobic recharge was studied. The impact of hydraulic loading on the removal rate of COD and NH3-N was investigated. The results indicate that, after passing through the three stages of rapid declining, smooth declining and stabilization, the variation of effluent COD of the concentrated leachate versus time maintains in the range of 900~2000 mg/L, and the corresponding removal rate is 88%~92%. The variation of effluent NH3-N versus time indicates a trend that it climbs up initially and then declines. The effluent NH3-N starts from 700 mg/L. After 35 days, it declines down to 18 mg/L and maintains in the range of 93%~99% with a corresponding removal rate up to 98%. Aerobic recharge reduces the build up of organic acids in the early stage. After 10 days, the pH value of the leachate maintains in the range between 7.5 and 9.0. The COD removal rate decreases from 94.39% down to 75.75% when the hydraulic loading increases from 12.5 mL / (L·d) to 75mL / (L·d), indicating a strong trend. In the mean time, the NH3-N removal rate decreases from 98.14% down to 90.11%, indicating a weak tread.

The Experiment Research of BAF in Treatment on Pharmaceutical Wastewater

2013 ◽  
Vol 295-298 ◽  
pp. 1263-1266
Author(s):  
Peng Wang ◽  
Zeng Zhang Wang
Keyword(s):  
Low Temperature ◽  
Biofilm Formation ◽  
Removal Rate ◽  
Cod Removal ◽  
Pharmaceutical Wastewater ◽  
Experiment Research ◽  
N Removal ◽  
Cod Removal Rate

This research has discussed the biofilm formation on the treatment of pharmaceutical wastewater in BAF. The removal rate of COD and NH3-N and law of the performance on the temperature and height of fillers are studied here. The results show that the BAF can still maintain a higher COD removal rate in the 13°C-25°C, the average removal rate reaches 86.9%. The denitrification is impacted by low temperature that the average removal rate of 74.7%. Experiment shows that, from 0cm to 65cm part, the removal rate of COD reachs 86.3%. The good performance of NH3-N removal rate mainly concentrates in the height of 35cm ~ 95cm.

Catalytic Wet Peroxide Oxidation of Dye Wastewater Using Fe2O3-CeO2/γ-Al2O3 as Catalyst

2014 ◽  
Vol 884-885 ◽  
pp. 29-32
Author(s):  
Hong Ya Li ◽  
Biao Yan ◽  
Bin Xia Zhao ◽  
Xiao Li Zhang
Keyword(s):  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Dye Wastewater ◽  
Peroxide Oxidation ◽  
Oxidation Method ◽  
Wet Peroxide Oxidation ◽  
Initial Ph ◽  
Catalytic Wet Peroxide Oxidation ◽  
Cod Removal Rate

Fe2O3-CeO2/γ-Al2O3 was used as catalyst for treating the dye wastewater by catalytic wet peroxide oxidation method, the effect of reaction temperature, initial pH value of the wastewater, dosage of catalyst and hydrogen peroxide on the COD removal were studied. Results showed that 90.3% of COD removal rate can be obtained under the condition of 90°C, pH=7, 0.8g catalyst/100 mL wasterwater, and 6mL H2O2 /100 mL wasterwater.

Study on Catalyst for Catalytic Ozonation to Leachate and Catalytic Process

2014 ◽  
Vol 989-994 ◽  
pp. 783-788
Author(s):  
Bao Jun Jiang ◽  
Zhu Jun Tian ◽  
Jin Ming Jiang
Keyword(s):  
Nickel Catalyst ◽  
Absorption Rate ◽  
Loading Rate ◽  
Removal Rate ◽  
Copper Catalyst ◽  
Catalytic Ozonation ◽  
Cod Removal ◽  
Ozone Absorption ◽  
N Removal ◽  
Cod Removal Rate

Five kinds of catalyst were prepared with Chromium, cadmium, cobalt, copper, nickel loading on the γ–Al2O3. Catalyst loading rate, effects to the ozone suction rates and water quality change situation of catalytic ozonation to leachate were studied. It can be found that when the mO3/mCOD equaled 0.11, 0.15 and 0.26 separately, and mCatalyst/mCOD fixed at 5, the cobalt has the highest loading rate, the cadmium catalyst could improve the ozone absorption rate, the chromium catalyst makes against the ozone absorption rate, the copper catalyst can increase the COD removal rate and the nickel catalyst has advantages for the NH3–N removal rate. Results indicate that: the leachate COD removal rate increased by 20.2 percent by the copper catalyst adding and the NH3–N removal rate rise 20.7 percent with the nickel catalyst; the best dosage of the ozone in catalytic ozonation is mO3/mCOD at 0.12 to 0.13; the degree of oxidation is exited.

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