Fracture Toughness and Hardness of Ti(C0.7N0.3)-19Mo2C-xNbC-24Ni

2015 ◽  
Vol 1088 ◽  
pp. 255-259 ◽  
Author(s):  
Hiroyuki Hosokawa ◽  
Kiyotaka Katou ◽  
Koji Shimojima ◽  
Ryoichi Furushima ◽  
Akihiro Matsumoto

The fracture toughness and hardness of Ti (C0.7N0.3)-19Mo2C-xNbC-24Ni cermets (x= 0, 5, 20) were studied. Fracture toughness of 5 NbC was the largest, and it of 20 NbC was the lowest. The microstructures of all the cermets consisted of Ti (C,N) and solid soluted Ti (C,N) hard phase, and Ni binder phase. The solid soluted Ti (C,N) surrounded Ti (C,N), namely, core-rim structures were observed in 0NbC and 5NbC. On the other hand, the isolated Ti (C,N) and solid soluted Ti (C,N) were observed in 20NbC, as a result of the phase separation between Ti (C,N) core and solid soluted Ti (C,N).

2020 ◽  
Vol 837 ◽  
pp. 139-145
Author(s):  
Ai Jun Liu ◽  
Gang Li ◽  
Ning Liu ◽  
Ke Bei Chen ◽  
Hai Dong Yang

Effect of Ti (C,N) based cermets granule on the microstructure, mechanical properties, sintering and fracture behavior of Ti (C,N) based cermets was investigated. Results show that the Ti (C,N) based cermets granules distribute in the matrix homogeneously. A nanoindentation study was performed on hard phase and binder phase in the matrix and granule. With the increase of granules content, sintering properties is worse. With the increase of granules content, transverse rupture strength (TRS) and relative density decrease gradually, while the hardness has an opposite trend. The fracture toughness increases firstly with increasing granule, and then decreases with the further increase of granules. Higher fracture toughness of the cermets is mainly owing to the crack branch and higher fracture energy of coarse granule.


2006 ◽  
Vol 306-308 ◽  
pp. 857-862 ◽  
Author(s):  
Taisuke Sasaki ◽  
Tokuteru Uesugi ◽  
Yorinobu Takigawa ◽  
Kenji Higashi

The effect of manganese on strength and fracture toughness was investigated using five kinds of Mg-6Al-1Zn alloys. From the experimental results, the yield strength increased with increasing in manganese content until manganese content reached 0.14 wt. %. On the other hand, further increase in yield strength was not observed in case larger than 0.14 % of manganese was added. In addition, fracture toughness decreases with increasing manganese content. Fracture of magnesium alloy was ductile fracture by void coalescence. Adding excessive amount of manganese caused the increase in the presence of inclusions. This kind of particle easily became the nucleus of microvoid. As a conclusion, manganese should be added so that coarse manganese-bearing particle is not formed. Thus, 0.14 wt. % of manganese should be added to Mg-6Al-1Zn alloy in order to develop the alloy with well-balanced relationship between strength and fracture toughness.


1995 ◽  
Vol 395 ◽  
Author(s):  
R. Singh ◽  
T.D. Moustakas

ABSTRACTWe report the growth of InGaN alloys over practically the entire composition range at the growth temperature of GaN (700–800 °C) by MBE. We found that when the grown films are thick (> 0.3 μm), incorporation of more than about 30% indium results in phase separation of InN, which is consistent with spinodal decomposition. On the other hand we discovered that such phase separation is absent in thin InGaN films ( < 600Å) grown as GaN/InGaN/GaN heterostructures. In such configurations we were able to incorporate up to 81% In, which is the highest yet reported.


1995 ◽  
Vol 397 ◽  
Author(s):  
B. Dam ◽  
J.H. Rector ◽  
J. Johansson ◽  
DG. DE Groot ◽  
R. Griessen

ABSTRACTWe provide evidence that non-stoichiometric ablation of YBa2Cu3O7δ at low fluences is due to a phase separation of the target surface. On the other hand, in SrTiO3 we find at low fluences evidence for preferential ablation which is assisted by volume-diffusion. As a result, the Sr/Ti ratio of the ablated films can be tuned by choosing the appropriate fluence.


1990 ◽  
Vol 181 ◽  
Author(s):  
Q. Z. Hong ◽  
J. W. Mayer

ABSTRACTMetal-GeSi reactions have been investigated in the Pt-GeSi and Cr-GeSi systems. Pt started to diffuse into and react with the alloys at 250 °C. The reacted region consisted of a uniform mixture of Pt2Si and Pt2Ge, with the same ratios of Ge to Si as those in the unreacted region. On the other hand, the Cr-GeSi reaction was induced by Ge motion at 375 °C. As a result a two-layer phase separation was observed. A Si-rich ternary layer was sandwiched between a germanide layer and the unreacted alloy


Author(s):  
Hideo Kawamura

In order to develop a ceramics engine with heat insulated combustion chambers, the strength of engine parts made of ceramics materials, design methods of the parts and triborogical features were studied for producing ceramics engine. In order to use the ceramics materials mainly Si3N4 with a suitable strength and fracture toughness, the correlation of strength and pore or flaw size or microstructures were investigated. On the other hand, designing methods were studied by using the calculation results of F. E. M on the practical engine and the strength of ceramics. Also, we investigated the characteristics of triborogical factors on the test pieces made of ceramics materials. In the result, we have achieved to produce the ceramics engine with a satisfactory durability and a lower friction through very severe tests.


2006 ◽  
Vol 45 ◽  
pp. 759-768
Author(s):  
Kazuki Nakanishi ◽  
Kazuyoshi Kanamori

Organic-inorganic hybrid monoliths with well-defined macropores and/or mesopores have been synthesized by a sol-gel process accompanied by polymerization-induced phase separation. Using aklyltrialkoxysilanes and alkylene-bridged alkoxysilanes, two different categories of organo-siloxane networks have been characterized in view of macroporoisity based on phase separation as well as mesoporosity based on supramolecular templating by surfactants. The alkyl-terminated polysiloxane network exhibited substantial surface hydrophobicity together with the mechanical flexibility. On the other hand, the alkylene-bridged network behaved much more similarly to those prepared from tetraalkoxysilanes with regard to surface hydrophilicity, mechanical rigidness and mesopore-forming ability. Supramolecular templating of mesopores embedded in the gel skeletons comprising well-defined macroporous network has proven to give wide variety of hierarchically designed macro-mesoporous organic-inorganic hybrid materials.


1999 ◽  
Vol 173 ◽  
pp. 249-254
Author(s):  
A.M. Silva ◽  
R.D. Miró

AbstractWe have developed a model for theH2OandOHevolution in a comet outburst, assuming that together with the gas, a distribution of icy grains is ejected. With an initial mass of icy grains of 108kg released, theH2OandOHproductions are increased up to a factor two, and the growth curves change drastically in the first two days. The model is applied to eruptions detected in theOHradio monitorings and fits well with the slow variations in the flux. On the other hand, several events of short duration appear, consisting of a sudden rise ofOHflux, followed by a sudden decay on the second day. These apparent short bursts are frequently found as precursors of a more durable eruption. We suggest that both of them are part of a unique eruption, and that the sudden decay is due to collisions that de-excite theOHmaser, when it reaches the Cometopause region located at 1.35 × 105kmfrom the nucleus.


Author(s):  
A. V. Crewe

We have become accustomed to differentiating between the scanning microscope and the conventional transmission microscope according to the resolving power which the two instruments offer. The conventional microscope is capable of a point resolution of a few angstroms and line resolutions of periodic objects of about 1Å. On the other hand, the scanning microscope, in its normal form, is not ordinarily capable of a point resolution better than 100Å. Upon examining reasons for the 100Å limitation, it becomes clear that this is based more on tradition than reason, and in particular, it is a condition imposed upon the microscope by adherence to thermal sources of electrons.


Author(s):  
J. Tong ◽  
L. Eyring

There is increasing interest in composites containing zirconia because of their high strength, fracture toughness, and its great influence on the chemical durability in glass. For the zirconia-silica system, monolithic glasses, fibers and coatings have been obtained. There is currently a great interest in designing zirconia-toughened alumina including exploration of the processing methods and the toughening mechanism.The possibility of forming nanocrystal composites by a phase separation method has been investigated in three systems: zirconia-alumina, zirconia-silica and zirconia-titania using HREM. The morphological observations initially suggest that the formation of nanocrystal composites by a phase separation method is possible in the zirconia-alumina and zirconia-silica systems, but impossible in the zirconia-titania system. The separation-produced grain size in silica-zirconia system is around 5 nm and is more uniform than that in the alumina-zirconia system in which the sizes of the small polyhedron grains are around 10 nm. In the titania-zirconia system, there is no obvious separation as was observed in die alumina-zirconia and silica-zirconia system.


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