Study on Re-Using Media from Iron and Manganese Biological Removal Filter for Defluoridation

2010 ◽  
Vol 113-116 ◽  
pp. 1472-1475
Author(s):  
Xing Guan Ma ◽  
Tie Shan Ming ◽  
Wei Cui ◽  
Jin Xiang Fu ◽  
Zhi Xiao Ma ◽  
...  

The filter media from iron and manganese biological removal filter which w- as replaced by new termly can be re-used. The sand filter media was characterized u- sing the SEM and owns developed interspaces. Drying the sand filter media at 110°C, then inspect and analyse its character and mode of defluoridation。The results show as follows. Under the test condition ,the adsorption balance can come out in about 3 hou-rs , the fluoride sorption on the re-used matured filter media followed pseudo-second kinetics. The effect of defluoridation by the matured filter media will be better within the range of pH 3~7, and best at about pH 4.58. The primary mode of fluoride sorpti- on is chemism, but physical sorption is also in existence , and the adsorption isother- ms could be described by Langmuir equation. Contact-time is a vary important factor in the continuous-flow column experiment. The effect of fluoride removal is long,as the height of filter column is controlled as 40cm.The filter media from iron and manga- nese biological removal filter possess potential of perfect sorbent, space for deeply study and foreground of practical application.

2021 ◽  
Vol 288 ◽  
pp. 112412
Author(s):  
Bárbara Luíza Souza Freitas ◽  
Ulisses Costa Terin ◽  
Natália de Melo Nasser Fava ◽  
Lyda Patricia Sabogal-Paz

2016 ◽  
Vol Volume 112 (Number 11/12) ◽  
Author(s):  
Rabelani Mudzielwana ◽  
Mugera W. Gitari ◽  
Titus A.M. Msagati ◽  
◽  
◽  
...  

Abstract Groundwater is a widely used and affordable source of drinking water in most of the rural areas of South Africa. Several studies have indicated that groundwater in some boreholes in South Africa has a fluoride concentration above the level recommended by the World Health Organization (1.5 mg/L). Fluoride concentrations above the permissible limit (>1.5 mg/L) lead to dental fluorosis, with even higher concentrations leading to skeletal fluorosis. In the present work, we evaluate the application of smectite-rich clay soil from Mukondeni (Limpopo Province, South Africa) in defluoridation of groundwater. The clay soil was characterised by mineralogy using X-ray diffraction, by elemental composition using X-ray fluorescence and by morphology using scanning electron microscopy. Surface area and pore volume was determined by the Brunauer–Emmett–Teller surface analysis method. Cation exchange capacity and pHpzc of the soil were also evaluated using standard laboratory methods. Batch experiments were conducted to evaluate and optimise various operational parameters such as contact time, adsorbent dose, pH and initial adsorbate concentration. It was observed that 0.8 g/100 mL of smectite-rich clay soil removed up to 92% of fluoride from the initial concentration of 3 mg/L at a pH of 2 with a contact time of 30 min. The experimental data fitted well to a Langmuir adsorption isotherm and followed pseudo second order reaction kinetics. Smectite-rich clay soil showed 52% fluoride removal from field groundwater with an initial fluoride concentration of 5.4 mg/L at an initial pH of 2 and 44% removal at a natural pH of 7.8. Therefore smectite-rich clay soil from Mukondeni has potential for application in defluoridation of groundwater. Chemical modification is recommended to improve the defluoridation capacity.


2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Temesgen Abeto Amibo ◽  
Surafel Mustafa Beyan ◽  
Tsegaye Markos Damite

The problem extent of the large concentration of fluoride ions in drinking water is still a central health issue. In the present study, lanthanum doped magnetic Teff straw biochar (LDMTSB) was developed as a novel adsorbent for removing fluoride ions in the groundwater in Rift-Valley regions, especially Hawassa city, Ethiopia. The synthesized LDMTBC was characterized via FTIR, XRD, SEM, and BET. And, this analysis proposed that multiadsorption techniques such as ligand exchange, precipitations, and electrostatic interaction could be evinced throughout the fluoride ions adsorption process by LDMTSB. The constraints that influence the adsorption efficacy, namely, a dosage of LDMTSB, contact time, pH of the solution, and rotational speed, were analyzed and optimized using the response surface methodology approach. Under the optimum situations, LDMTSB dosage: 3.97 g, contact time: 56.36 min, rotational speed: 591.19 rpm, and pH: 3.968 demonstrate high efficacy of LDMTSB with 98.89% fluoride removal capacity. Further, the quadratic model (R2 = 0.9841) was designated for governing the mathematical process. The LDMTSB was successful in the removal of fluoride ions in the groundwater. This study provides a valuable economical solution for the application of Teff straw.


2013 ◽  
Vol 316-317 ◽  
pp. 653-656
Author(s):  
Bai Jie Niu ◽  
Wen Ming Ding ◽  
Dan Dang

As an effective adsorbent, granular activated alumina (GAA) has been widely used in defluoridation. In order to reduce cost and operate environment-friendly, the adsorbent should be regenerated. In this paper, column experiment was done to characterize the fluoride removal properties and to develop an optimal method to regenerate fluoride-rich modified activated alumina (MGAA). The MGAA can be regenerated by utilizing sodium hydroxide solution desorption, deionized water washing and ferric sulfate reactivation and then used for futher defluoride operation. The influence of the concentration of desorption agent (NaOH solution) and desorbing time on desorption rate and the adsorption capacity of regenerated MGAA were studied. The optimal desorption condition was: 1% NaOH solution for desorption agent, desorbing time in 1.5h.In addition, when the regenerated MGAA was used again for column adsorption test, its adsorption capacity reached 94% of that of original sorbent in 1mg/L outlet fluoride concentration.


Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1160 ◽  
Author(s):  
Tadele Haile ◽  
Maria Fuerhacker

Stormwater runoff from roadways often contains a variety of contaminants such as heavy metals, which can adversely impact receiving waters. The filter media in stormwater filtration/infiltration systems play a significant role in the simultaneous removal of multiple pollutants. In this study, the capacity of five filter media—natural quartz sand (QS), sandy soil (SS) and three mineral-based technical filter media (TF-I, TF-II and TF-III)—to adsorb heavy metals (Cu, Pb and Zn) frequently detected in stormwater, as well as remobilization due to de-icing salt (NaCl), were evaluated in column experiments. The column breakthrough data were used to predict lifespan of the filter media. Column experiment operated under high hydraulic load showed that all technical filters and sandy soil achieved >97%, 94% and >80% of Pb, Cu and Zn load removals, respectively, while natural quartz sand (QS) showed very poor performance. Furthermore, treatment of synthetic stormwater by the soil and technical filter media met the requirements of the Austrian regulation regarding maximum effluent concentrations and minimum removal efficiencies for groundwater protection. The results showed that application of NaCl had only a minor impact on the remobilization of heavy metals from the soil and technical filter media, while the largest release of metals was observed from the QS column. Breakthrough analysis indicated that load removal efficiencies at column exhaustion (SS, TF-I, TF-II and TF-III) were >95% for Cu and Pb and 80–97% for Zn. Based on the adsorption capacities, filtration systems could be sized to 0.4 to 1% (TF-I, TF-II and TF-III) and 3.5% (SS) of their impervious catchment area and predicated lifespan of each filter media was at least 35, 36, 41 and 29 years for SS, TF-I, TF-II and TF-III, respectively. The findings of this study demonstrate that soil—based and technical filter media are effective in removing heavy metals and can be utilized in full-stormwater filtration systems.


2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
Tesfaye Akafu ◽  
Achalu Chimdi ◽  
Kefyalew Gomoro

Exposure to fluoride beyond the recommended level for longer duration causes both dental and skeletal fluorosis. Thus, the development of cost-effective, locally available, and environmentally benign adsorbents for fluoride removal from contaminated water sources is absolutely required. In the present study, diatomaceous earth (diatomite) locally available in Ethiopia, modified by treating it with an aluminum hydroxide solution, was used as an adsorbent for fluoride removal from aqueous solutions. Adsorption experiments were carried out by using batch contact method. The adsorbent was characterized using FT-IR spectroscopy. Effects of different parameters affecting efficiency of fluoride removal such as adsorbent dose, contact time, initial fluoride concentration, and pH were investigated and optimized. The optimum adsorbent dose, contact time, initial fluoride concentration, and pH values were 25 g/L, 180 min, 10 mg/L, and 6.7, respectively. The performance of the adsorbent was also tested under optimum conditions using groundwater samples taken from Hawassa and Ziway. Langmuir and Freundlich isotherm models were applied to describe the equilibrium data. Compared to Langmuir isotherm (R2 = 0.888), the Freundlich isotherm (R2 = 0.985) model was better fitted to describe the adsorption characteristics of fluoride on Al-diatomite. The Langmuir maximum adsorption capacity was 1.67 mg/g. The pseudosecond-order model was found to be more suitable than the pseudofirst-order to describe the adsorption kinetics. The low correlation coefficient value of R2 = 0.596 for the intraparticle diffusion model indicates that the intraparticle diffusion model does not apply to the present studied adsorption system. The maximum fluoride removal was observed to be 89.4% under the optimum conditions which indicated that aluminum hydroxide-modified diatomite can be used as efficient, cheap, and ecofriendly adsorbents for the removal of fluoride from contaminated water.


2021 ◽  
Vol 189 ◽  
pp. 116581 ◽  
Author(s):  
F.H. de Souza ◽  
P.B. Roecker ◽  
D.D. Silveira ◽  
M.L. Sens ◽  
L.C. Campos

2016 ◽  
Vol 857 ◽  
pp. 509-513
Author(s):  
Azrin Mohd Sanusi ◽  
Mohd Nordin Adlan ◽  
M.A.Z. Mohd Remy Rozainy ◽  
Rhahimi Jamil

Combination between oxidation and filtration can be used for removing iron and manganese from groundwater especially when the concentrations of these metals were high. This study focused on the effectiveness of the cascade aerator and the size of the limestone filter media to remove iron and manganese from groundwater. Water samples used for this study were collected from orphanage home, Rumah Nur Kasih, Taiping. Universiti Sains Malaysia (USM) has provided a tube well of 15 m depth and 150 mm diameter for the orphanage home. However, the water cannot be used for domestic consumption due to high amount of iron and manganese at 6.48 and 1.9 mg/L which exceeded the drinking water standard of 0.3 and 0.1 mg/L respectively. Using laboratory physical model, the study has shown that the removals of iron and manganese have reduce the concentration until 0.17 and 0.2 mg/L respectively. Thus, the results from this study which utilize cascade aerator and limestone roughing filter could be implemented on site for the community to use the ground water for domestic purposes.


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