Fiber Modification of OCC Pulp with Laccase and Natural Mediator System

2010 ◽  
Vol 113-116 ◽  
pp. 1801-1805 ◽  
Author(s):  
Si Yang Zhang ◽  
Ji Cheng Pei ◽  
Xin Lu Zhang ◽  
Hui Ren Hu ◽  
Yi Mei Hong

Three kinds of phenols, namely gallic acid, syringal alcohol and ferulic acid, were selected as laccase natural mediator to investigate the changes of fiber surfaces, morphological properties of fibers, kappa number and physical properties of OCC (Old Corrugated Containers) pulp with laccase/ natural mediator system treatment. It was illustrated that condensation reaction of phenols could be occured by catalytic oxidation of laccase. The results of fiber quality analysis and SEM observation showed that after treated using laccase/ natural mediator system, the resultantly yielded OCC pulp had much smoother surface, larger fibers coarseness, higher kappa number, and the auto-adhesion of fibers could be observed in the fibers. In additon, the wet strength of handsheets, especially the wet ring crush strength, was improved obviously, compared with control sample.

Biomolecules ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 832
Author(s):  
Monika Vidak ◽  
Boris Lazarević ◽  
Marko Petek ◽  
Jerko Gunjača ◽  
Zlatko Šatović ◽  
...  

Sweet pepper (Capsicum annuum L.) is one of the most important vegetable crops in the world because of the nutritional value of its fruits and its economic importance. Calcium (Ca) improves the quality of sweet pepper fruits, and the application of calcite nanoparticles in agricultural practice has a positive effect on the morphological, physiological, and physicochemical properties of the whole plant. The objectives of this study were to investigate the effect of commercial calcite nanoparticles on yield, chemical, physical, morphological, and multispectral properties of sweet pepper fruits using a combination of conventional and novel image-based nondestructive methods of fruit quality analysis. In the field trial, two sweet pepper cultivars, i.e., Šorokšari and Kurtovska kapija, were treated with commercial calcite nanoparticles (at a concentration of 3% and 5%, calcite-based foliar fertilizer (positive control), and water (negative control) three times during vegetation). Sweet pepper fruits were harvested at the time of technological and physiological maturity. Significant differences were observed between pepper cultivars as well as between harvests times. In general, application of calcite nanoparticles reduced yield and increased fruit firmness. However, different effects of calcite nanoparticles were observed on almost all properties depending on the cultivar. In Šorokšari, calcite nanoparticles and calcite-based foliar fertilizers significantly increased N, P, K, Mg, Fe, Zn, Mn, and Cu at technological maturity, as well as P, Ca, Mg, Fe, Zn, Mn, Cu, and N at physiological maturity. However, in Kurtovska kapija, the treatments increased only Ca at technological maturity and only P at physiological maturity. The effect of treatments on fruit morphological properties was observed only at the second harvest. In Šorokšari, calcite nanoparticles (3% and 5%) increased the fruit length, minimal circle area, and minimal circle radius, and it decreased the fruit width and convex hull compared to the positive and negative controls, respectively. In Kurtovska kapija, calcite nanoparticles increased the fruit width and convex hull compared to the controls. At physiological maturity, lower anthocyanin and chlorophyll indices were found in Kurtovska kapija in both treatments with calcite nanoparticles, while in Šorokšari, the opposite effects were observed.


2019 ◽  
Vol 26 (5) ◽  
pp. 913-920 ◽  
Author(s):  
Alba Blánquez ◽  
Juana Rodríguez ◽  
Vânia Brissos ◽  
Sonia Mendes ◽  
Ligia O. Martins ◽  
...  

TAPPI Journal ◽  
2015 ◽  
Vol 14 (5) ◽  
pp. 305-309
Author(s):  
S. S. LAVRYKOV ◽  
B.V. RAMARAO

It is often necessary to characterize papermaking pulps in order to determine the impact of refining or to predict their drainage properties. The newer methods for pulp quality analysis determine geometrical features of pulp fibers by microimaging techniques. However, features such as fiber length, coarsenes, and their distributions do not yield easily to estimation of their drainage or papermaking properties. In quantifying the impact of refining on fiber quality, it is useful to approach the rheology of pulps as an indicator of their behavior. We determined the hydrodynamic characteristics of a variety of refined pulps along with their permeability characteristics, i.e., the hydrodynamic specific surface area and the specific volume. Our method was to analyze the filtration/drainage curves and fit predictions from models with observed data. This inversion problem is usually complex and requires global minimization techniques. This paper presents data on bleached kraft hardwood pulps and mixtures with fines and how their surface areas and specific volumes change with composition. These data are further used to predict the behavior of the pulps in drainage situations using models of forming.


2012 ◽  
Vol 8 ◽  
pp. 1505-1514 ◽  
Author(s):  
Aurica Farcas ◽  
Ana-Maria Resmerita ◽  
Andreea Stefanache ◽  
Mihaela Balan ◽  
Valeria Harabagiu

The paper reports the preparation of a poly[2,7-(9,9-dioctylfluorene)-alt-5,5'-bithiophene/PS-βCD] (PDOF-BTc) polyrotaxane copolymer, through a Suzuki coupling reaction between the 5,5'-dibromo-2,2'-bithiophene (BT) inclusion complex with persilylated β-cyclodextrin (PS-βCD), and 9,9-dioctylfluorene-2,7-bis(trimethylene borate) (DOF) as the blocking group. The chemical structure and the thermal and morphological properties of the resulting polyrotaxane were investigated by using NMR and FT-IR spectroscopy, TGA, DSC and AFM analysis. The encapsulation of BT inside the PS-βCD cavity results in improvements in the solubility, as well as in different surface morphology and thermal properties of the PDOF-BTc rotaxane copolymer compared to its noncomplexed PDOF-BT homologue. In contrast, the number-average molecular weight (M n) of PDOF-BTc rotaxane copolymer indicated lower values suggesting that the condensation reaction is subjected to steric effects of the bulkier silylated groups, affecting the ability of the diborate groups from the DOF molecule to partially penetrate the PS-βCD cavity.


IAWA Journal ◽  
2010 ◽  
Vol 31 (1) ◽  
pp. 29-38 ◽  
Author(s):  
Balazs Horvath ◽  
Ilona Peszlen ◽  
Perry Peralta ◽  
Bohumil Kasal ◽  
Laigeng Li

The directed modification of specific traits of trees through genetic engineering provides opportunities for making significant genetic improvements to wood properties in matter of years instead of extended time frames required for traditional natural selection. An attractive target of forest- tree engineering is the modification of lignin content and lignin structure. While lower lignin content improves pulping efficiency, a decrease in lignin content could affect wood characteristics that are critical for solid wood use.After one year of growth in a greenhouse, a total of forty transgenic aspen (Populus tremuloides Michx.) with reduced lignin content and increased syringyl to guaiacyl ratio were harvested and diameter growth and cell morphology were investigated using quantitative wood anatomy and fiber quality analysis techniques. Comparing genetic groups to the wild-type as the control, similar radial growth and quantitative anatomical properties were observed for the genetic group with reduced lignin content. The genetic group with increased S/G ratio had lower diameter growth, lower vessel lumen diameter, but more numerous vessels. The combined effect of changes in lignin content and structure on radial growth and cell morphology seems to be more complex and gave inconsistent results.


2013 ◽  
Vol 10 (1) ◽  
pp. 83-97
Author(s):  
Luz Moreno ◽  

The fiber morphological properties of three promising abaca (Musa textilis Nee) cultivars found in the abaca germplasm collection of the National Abaca Research Center were investigated to assess their suitability for pulp and paper production. It was found that Inosa produced the longest fibers (4.58mm) followed by Laylay (3.43mm), while Gomez hybrid had the shortest (2.45mm). The three cultivars did not vary in fiber cell diameter, lumen width and cell wall thickness. Tensile strength of Inosa was highest at 84.68 cN/tex compared to Laylay (69.27 cN/tex) while Gomez hybrid had the lowest at 25.65 cN/tex). The very high tensile strength of Inosa as well as its high slenderness and runkel ratios make it very suitable for the production of high quality pulp and paper. Slenderness and runkel ratios of the Gomez hybrid were the lowest while its flexibility ratio was the highest indicating poop fiber quality. Such properties, however, still make its fibers acceptable for low-grade pulp and paper products such as newsprint paper production.


2011 ◽  
Vol 50 (22) ◽  
pp. 12572-12578 ◽  
Author(s):  
Bin Li ◽  
Rohan Bandekar ◽  
Quanqing Zha ◽  
Ahmed Alsaggaf ◽  
Yonghao Ni

2012 ◽  
Vol 89 (5) ◽  
pp. 230-236 ◽  
Author(s):  
Douglas C. Doehlert ◽  
Senay Simsek ◽  
Michael S. McMullen

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 4323-4336
Author(s):  
Wei Wei ◽  
Zhongjian Tian ◽  
Xingxiang Ji ◽  
Qiang Wang ◽  
Jiachuan Chen ◽  
...  

Prehydrolysis kraft pulping is an effective approach to produce dissolving pulp, which can be used for viscose application. The prehydrolysis process using hot liquid water could remove hemicellulose and loosen the compact cell wall, thus facilitating subsequent pulping and bleaching processes. In this study, the composite severity factor (CSF) was used to reveal the intensity of prehydrolysis treatment and its effect on the pulping and bleaching process by combining the temperature, time, and pH variables. Results showed that the optimum CSF was 6.61, which produced a pulp with α-cellulose of 92.3%, degree of polymerization (DP) of 1081, brightness of 85.1% ISO, and Kappa number of 0.61. In addition, the fiber quality, crystalline structure, and microstructure of pulps were characterized by FQA (fiber quality analysis), XRD (X-ray diffraction), and SEM (scanning electron microscopy).


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