Study on the Influence of Air-Entraining Agent on the Impermeability of Cement-Based Composites Based on its Pore Structure by Fractal Theory

2010 ◽  
Vol 168-170 ◽  
pp. 615-618
Author(s):  
Zhi Qin Du ◽  
Wei Sun
Keyword(s):  
Fractal Dimension ◽  
Pore Structure ◽  
Mercury Intrusion Porosimetry ◽  
Fractal Theory ◽  
Mercury Intrusion ◽  
Pore Structures ◽  
Cement Based Materials

The effect of different quantity of air-entraining agent on the impermeability of cement-based materials are studied in this paper. Impermeability test and mercury intrusion porosimetry (MIP) method were used to characterize the impermeability and pore structures. The fractal dimension is used to describe the characteristic of pore structure and calculated by the data of MIP experiment. The result shows that owing to the improvement of pore structure, the impermeability performance of the cement-based composites is noticeably enhanced when air-entraining agent is added with appropriate quantity.

A Comparison of the Pore Structure of Cement and Fly Ash/Cement Mortars Made with Sea Water and Fresh Water

1986 ◽  
Vol 85 ◽  
Author(s):  
B. K. Marsh ◽  
R. C. Joshi ◽  
A. Balasundaram
Keyword(s):  
Fly Ash ◽  
Pore Structure ◽  
Fresh Water ◽  
Mercury Intrusion Porosimetry ◽  
Sea Water ◽  
Blended Cement ◽  
Fly Ashes ◽  
Mercury Intrusion ◽  
Pore Structures ◽  
Cement Mortars

ABSTRACTPore structures of portland and blended cement mortars prepared with sea water were assessed by mercury intrusion porosimetry. Comparison is made with similar mortars made with fresh water. Mortars were made using cement containing 0%, 25% or 50% (by volume) of one of two Alberta fly ashes. They were tested after 90 days of continuous immersion in sea water at 5°C or 20° C. Results show that the mortars made with sea water generally contained a much higher volume of fine pores although the porosity was, in some cases, greater than that of mortars made with fresh water. Nevertheless, the volume of larger pores was lower in the mortars made with sea water. The pore structure of the various mortars is discussed in relation to potential durability.

scholarly journals Influence of Different Alkali Sulfates on the Shrinkage, Hydration, Pore Structure, Fractal Dimension and Microstructure of Low-Heat Portland Cement, Medium-Heat Portland Cement and Ordinary Portland Cement

2021 ◽  
Vol 5 (3) ◽  
pp. 79
Author(s):  
Yang Li ◽  
Hui Zhang ◽  
Minghui Huang ◽  
Haibo Yin ◽  
Ke Jiang ◽  
...  
Keyword(s):  
Fractal Dimension ◽  
Portland Cement ◽  
Pore Structure ◽  
Ordinary Portland Cement ◽  
Autogenous Shrinkage ◽  
Drying Shrinkage ◽  
Crystal Forms ◽  
Pore Structures ◽  
Cement Based Materials ◽  
Mineral Compositions

In cement-based materials, alkalis mainly exist in the form of different alkali sulfates. In this study, the impacts of different alkali sulfates on the shrinkage, hydration, pore structure, fractal dimension and microstructure of low-heat Portland cement (LHPC), medium-heat Portland cement (MHPC) and ordinary Portland cement (OPC) are investigated. The results indicate that alkali sulfates magnify the autogenous shrinkage and drying shrinkage of cement-based materials with different mineral compositions, which are mainly related to different pore structures and hydration processes. LHPC has the lowest shrinkage. Otherwise, the effect of alkali sulfates on the autogenous shrinkage is more profound than that of drying shrinkage. Compared with the pore size distribution, the fractal dimension can better characterize the shrinkage properties of cement-based materials. It is noted that the contribution of K2SO4 (K alkali) to the promotion effect of shrinkage on cement-based materials is more significant than that of Na2SO4 (Na alkali), which cannot be ignored. The microstructure investigation of different cement-based materials by means of nuclear magnetic resonance (NMR), mercury intrusion porosimetry (MIP) and scanning electron microscope (SEM) shows that this effect may be related to the different pore structures, crystal forms and morphologies of hydration products of cement-based materials.

scholarly journals Full‐Scale Pore Structure and Fractal Dimension of the Longmaxi Shale from the Southern Sichuan Basin: Investigations Using FE‐SEM, Gas Adsorption and Mercury Intrusion Porosimetry

Minerals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 543 ◽  
Author(s):  
Wang ◽  
Jiang ◽  
Jiang ◽  
Chang ◽  
Zhu ◽  
...  
Keyword(s):  
Organic Matter ◽  
Fractal Dimension ◽  
Pore Structure ◽  
Clay Minerals ◽  
Sichuan Basin ◽  
Mercury Intrusion Porosimetry ◽  
Fractal Dimensions ◽  
Full Scale ◽  
Mercury Intrusion ◽  
Longmaxi Shale

Pore structure determines the gas occurrence and storage properties of gas shale and is a vital element for reservoir evaluation and shale gas resources assessment. Field emission scanning electron microscopy (FE‐SEM), high‐pressure mercury intrusion porosimetry (HMIP), and low‐pressure N2/CO2 adsorption were used to qualitatively and quantitatively characterize full‐scale pore structure of Longmaxi (LM) shale from the southern Sichuan Basin. Fractal dimension and its controlling factors were also discussed in our study. Longmaxi shale mainly developed organic matter (OM) pores, interparticle pores, intraparticle pores, and microfracture, of which the OM pores dominated the pore system. The pore diameters are mainly distributed in the ranges of 0.4–0.7 nm, 2–20 nm and 40–200 μm. Micro‐, meso‐ and macropores contribute 24%, 57% and 19% of the total pore volume (PV), respectively, and 64.5%, 34.6%, and 0.9% of the total specific surface area (SSA). Organic matter and clay minerals have a positive contribution to pore development. While high brittle mineral content can inhibit shale pore development. The fractal dimensions D1 and D2 which represents the roughness of the shale surface and irregularity of the space structure, respectively, are calculated based on N2 desorption data. The value of D1 is in the range of 2.6480–2.7334 (average of 2.6857), D2 is in the range of 2.8924–2.9439 (average of 2.9229), which indicates that Longmaxi shales have a rather irregular pore morphology as well as complex pore structure. Both PV and SSA positively correlated with fractal dimensions D1 and D2. The fractal dimension D1 decreases with increasing average pore diameter, while D2 is on the contrary. These results suggest that the small pores have a higher roughness surface, while the larger pores have a more complex spatial structure. The fractal dimensions of shale are jointly controlled by OM, clays and brittle minerals. The TOC content is the key factor which has a positive correlation with the fractal dimension. Clay minerals have a negative influence on fractal dimension D1, and positive influence D2, while brittle minerals show an opposite effect compared with clay minerals.

Influence of Surface Treatment on Pore Structures of Cement-Based Materials

2006 ◽  
Vol 302-303 ◽  
pp. 347-355 ◽  
Author(s):  
Chien Hung Chen ◽  
Ming Chin Ho ◽  
Shaing Hai Yeh ◽  
Ran Huang
Keyword(s):  
Surface Treatment ◽  
Mercury Intrusion Porosimetry ◽  
Total Charge ◽  
Penetration Test ◽  
Mercury Intrusion ◽  
Pore Structures ◽  
Cement Based Materials ◽  
Positive Effect ◽  
Electronic Microscope ◽  
Effect Of Surface

The objective of this investigation is to evaluate the effect of surface treatments on cement-based materials, which include mortar and concrete samples. Penetrated sealers and methyl methacrylate (MMA) were used as surface treatment materials. Two concrete mixes (w/c = 0.35, 0.55) were selected and cubic/cylindrical specimens were prepared according to ASTM specifications. The treated specimens have higher compressive strengths than the control specimens. Also, the absorptions and total charge passed of rapid chloride penetration test (RCPT) are lower in the treated specimens. Scanning electronic microscope (SEM) was utilized to estimate the microstructure of the specimens. Denser pore structures and narrower pore-size distribution were observed in SEM micrographs and mercury intrusion porosimetry (MIP) spectrum for the treated specimens, which are correspondent to the macro-observation. The positive effect is most prominent in polymer treated specimens. For higher w/c ratio mix, large capillary pores were filled by most of treatment materials and compressive strength significantly increased, while, for lower w/c ratio mix, polymer and silicate sealer filled in medium capillary pores as indicated by MIP and RCPT results.

The Fractal Characteristic Analysis of Coal Pore Structure Based on the Mercury Intrusion Porosimetry

2013 ◽  
Vol 353-356 ◽  
pp. 1191-1195 ◽  
Author(s):  
Nai Hao ◽  
Yong Liang Wang ◽  
Ling Tao Mao ◽  
Qing Liu
Keyword(s):  
Fractal Dimension ◽  
Pore Structure ◽  
Pore Volume ◽  
Coalbed Methane ◽  
Mercury Intrusion Porosimetry ◽  
Shanxi Province ◽  
Characteristic Analysis ◽  
Mercury Intrusion ◽  
Specific Pore Volume ◽  
Radius Size

The pore structure of coal rock atYangquan Xinjing mine in Shanxi Province is analyzed with mercury intrusion porosimetry to obtain the specific pore volume data and calculate the fractal dimension of coal pore surface. The pores are divided into macropore, mesopore and micropore according to radius size considering the calculated fractal dimension. The distribution characteristics of pore radius size, specific surface area and specific pore volume of different types are effectively analyzed. The research results show that mesopore surface has significantly fractal characteristics, which features could be discussed quantitatively. The proposed method in this paper has reference significance for studying the sorption and desorption properties, the diffussion and permeation of coalbed methane.

scholarly journals Influence of MgO on the Hydration and Shrinkage Behavior of Low Heat Portland Cement-Based Materials via Pore Structural and Fractal Analysis

2022 ◽  
Vol 6 (1) ◽  
pp. 40
Author(s):  
Lei Wang ◽  
Xiao Lu ◽  
Lisheng Liu ◽  
Jie Xiao ◽  
Ge Zhang ◽  
...  
Keyword(s):  
Fractal Dimension ◽  
Portland Cement ◽  
Pore Structure ◽  
Fractal Analysis ◽  
Concrete Structures ◽  
Mass Concrete ◽  
Pore Structures ◽  
Cement Based Materials ◽  
Induction Stage ◽  
Shrinkage Behavior

Currently, low heat Portland (LHP) cement is widely used in mass concrete structures. The magnesia expansion agent (MgO) can be adopted to reduce the shrinkage of conventional Portland cement-based materials, but very few studies can be found that investigate the influence of MgO on the properties of LHP cement-based materials. In this study, the influences of two types of MgO on the hydration, as well as the shrinkage behavior of LHP cement-based materials, were studied via pore structural and fractal analysis. The results indicate: (1) The addition of reactive MgO (with a reactivity of 50 s and shortened as M50 thereafter) not only extends the induction stage of LHP cement by about 1–2 h, but also slightly increases the hydration heat. In contrast, the addition of weak reactive MgO (with a reactivity of 300 s and shortened as M300 thereafter) could not prolong the induction stage of LHP cement. (2) The addition of 4 wt.%–8 wt.% MgO (by weight of binder) lowers the mechanical property of LHP concrete. Higher dosages of MgO and stronger reactivity lead to a larger reduction in mechanical properties at all of the hydration times studied. M300 favors the strength improvement of LHP concrete at later ages. (3) M50 effectively compensates the shrinkage of LHP concrete at a much earlier time than M300, whereas M300 compensates the long-term shrinkage more effectively than M50. Thus, M300 with an optimal dosage of 8 wt.% is suggested to be applied in mass LHP concrete structures. (4) The addition of M50 obviously refines the pore structures of LHP concrete at 7 days, whereas M300 starts to refine the pore structure at around 60 days. At 360 days, the concretes containing M300 exhibits much finer pore structures than those containing M50. (5) Fractal dimension is closely correlated with the pore structure of LHP concrete. Both pore structure and fractal dimension exhibit weak (or no) correlations with shrinkage of LHP concrete.

Influences of Ground Limestone Fineness on the Properties of Cement-Based Materials

2012 ◽  
Vol 517 ◽  
pp. 403-410
Author(s):  
Jia Xiao ◽  
Bao Guo Ma ◽  
Rong Zhen Dong ◽  
Cai Yun Xu
Keyword(s):  
Pore Structure ◽  
Mercury Intrusion Porosimetry ◽  
Cement Mortar ◽  
Hardened Cement ◽  
Cement Pastes ◽  
Mercury Intrusion ◽  
Setting Times ◽  
Cement Based Materials ◽  
Hardened Cement Pastes ◽  
Ground Limestone

The effect of ground limestone fineness on the properties and mechanism of cement-based composite materials was investigated. The setting times, fluidity and strength of cement mortar were measured. In order to identify the mechanism effect of ground limestone fineness on the microstructure of the hardened cement pastes, microstructure analyses such as calorimetry analysis and Mercury Intrusion Porosimetry (MIP) were also performed. Experimental results indicated that the setting times are shortened, and the fluidity and strength of cement mortar are improved with the ground limestone fineness increases. The increase of the ground limestone fineness can effectively inhibit the pore structure of hardened paste, which due to mortar and paste samples incorporating replacement levels of ground limestone, and improve the pore structure of hardened paste.

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