Kinetics of Leaching Vanadium with Sulfuric Acid from Carbonaceous Shale Containing Vanadium

2011 ◽  
Vol 402 ◽  
pp. 7-11
Author(s):  
Yan Liu ◽  
Cong Sun ◽  
Wei Jun Zhong ◽  
Yu Chun Zhai
Keyword(s):  
Sulfuric Acid ◽  
Carbonaceous Shale ◽  
Particle Sizes ◽  
Shrinking Core Model ◽  
Leaching Rate ◽  
Stone Coal ◽  
Rate Of Reaction ◽  
Shrinking Core ◽  
Kinetics Of ◽  
Arrhenius Expression

ηA kinetic study of the leaching of stone coal ore with sulfuric acid has been investigated. The effects of the stirring speed, particle sizes of stone coal, acid concentration, leaching temperature and acid-ore ratio on the leaching rate of vanadium were examined. It was found that the leaching rate of vanadium was significantly influenced by leaching temperature. The shrinking core model was applied to the leaching process and the results showed that the process was based on chemical reaction control. And the rate of reaction was expressed as 1-(1-η)1⁄3=4.98×106·e-55488⁄RT·t. The apparent activation energy for the leaching of vanadium⁄ was calculated to be ¾5⁄5.49 kJ/mol using Arrhenius expression.

The Contrast Study of Microwave Heating and Traditional Heating Leaching Vanadium from Stone Coal with Sulfuric Acid Solution

2013 ◽  
Vol 774-776 ◽  
pp. 660-663
Author(s):  
Hong Zhou Ma ◽  
Yao Ning Wang ◽  
Xin Zhe Lan
Keyword(s):  
Sulfuric Acid ◽  
Acid Solution ◽  
Microwave Heating ◽  
Sulfuric Acid Solution ◽  
Product Layer ◽  
Contrast Study ◽  
Leaching Rate ◽  
Solid Product ◽  
Stone Coal ◽  
Kinetics Of

The aim of this paper is to contrast the effect of the microwave heating and traditional heating leaching vanadium from stone coal with sulfuric acid solution, contrast the leaching rate of vanadium, kinetics of leaching vanadium and the phase change s of slag. The experiment results show that the leaching rate and leaching velocity of vanadium with microwave heating was higher greatly than traditional heating, the kinetics of leaching vanadium with two heating methods was similar and accords with unreacted core contraction model with have solid product layer model, the illite in the stone coal was decomposed with microwave heating, but the traditional heating could not decomposed.

Leaching Kinetics and Seperation of Antimony and Arsenic from Arsenic Alkali Residue

2011 ◽  
Vol 402 ◽  
pp. 57-60 ◽  
Author(s):  
Gui Sheng Zeng ◽  
Hui Li ◽  
Su Hua Chen ◽  
Xin Man Tu ◽  
Wen Bin Wang
Keyword(s):  
Shrinking Core Model ◽  
Leaching Kinetics ◽  
Surface Chemical ◽  
Leaching Rate ◽  
Kinetics Equation ◽  
Surface Chemical Reaction ◽  
Liquid Ratio ◽  
Shrinking Core ◽  
Solid Liquid ◽  
Kinetics Of

The separation of antimony and arsenic and leaching kinetics of arsenic from arsenic alkali residue were investigated. The influencing factors such as solid/liquid ratio, stir speed, temperature and time on leaching of arsenic were studied. The results show that the leaching rate reaches 87.75% at the condition of solid/liquid ratio of 1:4 , stir speed of 600r/min ,temperature of 90°C and time of 60min. The leaching process was controlled by the surface chemical reaction and the kinetics of leaching arsenic followed the model of shrinking core. The activation energy was found to be 666.57kJ/mol. The kinetics equation was expressed as shrinking core model.

Microwave-Assisted Leaching Vanadium from Stone Coal

2011 ◽  
Vol 189-193 ◽  
pp. 3916-3919 ◽  
Author(s):  
Hong Zhou Ma ◽  
Xin Zhe Lan ◽  
Yao Ning Wang ◽  
Yu Hong Tian
Keyword(s):  
Sulfuric Acid ◽  
Microwave Power ◽  
Orthogonal Design ◽  
Chemical Constituents ◽  
Influence Factors ◽  
Sulfate Solution ◽  
Leaching Rate ◽  
Stone Coal ◽  
Microwave Assisted ◽  
Design Experiments

Technological process of microwave-assisted leaching of vanadium with sulfate solution has been defined on the base of phase and chemical constituents of stone coal. The influence factors such as content of sulfuric acid, microwave power, and leaching time were studied on leaching rate of vanadium from the stone coal. One element experiments and orthogonal design experiments are carried out to achieve optimized parameters. The experimental results showed that the leaching rate of vanadium was improved by the change of influence factors at some range. The single leaching rate of vanadium reached 80.9% under the optimal conditions of sulfuric acid content of 12%, microwave power 539w,leaching time of 2h.

scholarly journals Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity

2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Ying Yue Teng ◽  
Yu Zhe Liu ◽  
Quan Sheng Liu ◽  
Chang Qing Li
Keyword(s):  
Activation Energy ◽  
Homogeneous Model ◽  
Optical Microscope ◽  
Core Model ◽  
Shrinking Core Model ◽  
Compact Structure ◽  
Shrinking Core ◽  
Combustion Reactivity ◽  
Combustion Processes ◽  
Kinetics Of

The macerals, including fusinitic coal containing 72.20% inertinite and xyloid coal containing 91.43% huminite, were separated from Shengli lignite using an optical microscope, and their combustion reactivity was examined by thermogravimetric analysis. Several combustion parameters, including ignition and burnout indices, were analyzed, and the combustion kinetics of the samples were calculated by regression. Fusinitic coal presented a porous structure, while xyloid coal presented a compact structure. The specific surface area of fusinitic coal was 2.5 times larger than that of xyloid coal, and the light-off temperature of the former was higher than that of the latter. However, the overall combustion reactivity of fusinitic coal was better than that of xyloid coal. The combustion processes of fusinitic and xyloid coals can be accurately described by both the homogeneous model and the shrinking core model. The features of xyloid coal agree with the shrinking core model when its conversion rate is 10%–90%. The activation energy of fusinitic coal during combustion can be divided into three phases, with the middle phase featuring the highest energy. The activation energy of xyloid coal is lower than that of fusinitic coal in the light-off phase, which may explain the low light-off temperature of this coal.

scholarly journals Kinetics of the dissolution of sand into alkaline solutions: application of a modified shrinking core model

2004 ◽  
Vol 71 (3-4) ◽  
pp. 435-446 ◽  
Author(s):  
A Mgaidi ◽  
F Jendoubi ◽  
D Oulahna ◽  
M El Maaoui ◽  
J.A Dodds
Keyword(s):  
Core Model ◽  
Alkaline Solutions ◽  
Shrinking Core Model ◽  
Shrinking Core ◽  
Kinetics Of

Dissolution kinetics of Amazonian metakaolin in hydrochloric acid

Clay Minerals ◽  
2017 ◽  
Vol 52 (1) ◽  
pp. 75-82 ◽  
Author(s):  
Paula E.A. Lima ◽  
Rômulo S. Angélica ◽  
Roberto F. Neves
Keyword(s):  
Hydrochloric Acid ◽  
Dissolution Kinetics ◽  
Regression Coefficients ◽  
Shrinking Core Model ◽  
First Order ◽  
Constant Size ◽  
Shrinking Core ◽  
Kinetics Of Dissolution ◽  
Leaching Reaction ◽  
Kinetics Of

AbstractThe kinetics of dissolution of Amazonian metakaolin in hydrochloric acid (HCl) was studied using the ‘Shrinking Core Model’ for spherical and ‘flat plate’ particles of constant size. The Amazonian kaolin was calcined at 700°C for 2 h. The calcined samples (metakaolins) were leached in an HCl solution with 5% excess at 70, 80 and 95 ± 3°C for 3 h. Samples were collected every 15 min and subjected to Al analysis by the EDTA titrimetric method. Experimental data showed that the spherical morphology produced a better fit with respect to the regression coefficients. The activation energy of the reaction was 90.6 kJ/mol. The chemical process is a first-order leaching reaction. The results of the present study are consistent with those from previous research on this topic, which used HCl with an excess of >90%.

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