The Treatment of H-GL Dye Wastewater by Fenton Oxidation

2012 ◽  
Vol 518-523 ◽  
pp. 2274-2277
Author(s):  
Wen Yao Yan ◽  
Yu Hong Chai
Keyword(s):  
Reaction Time ◽  
Fenton Oxidation ◽  
Dye Wastewater ◽  
Reaction Conditions ◽  
Decolorization Rate ◽  
Initial Ph ◽  
Simulated Wastewater ◽  
Dark Blue

Abstract. Investigation on the degradation of dye simulated wastewater containing disperse H-GL dark blue was conducted under Fenton oxidation scheme. Reaction conditions such as the dosage of H2O2 and Fe2+, initial pH, initial dye concentration and reaction time were studied in terms of decolorization efficiencies. Up to 94.5% decolorization rate was attained after 30 min using H2O2 36 mg L-1 and Fe2+ 75mg L-1 at a pH of 3.

Study on Pretreatment of Dye Wastewater by Fenton Oxidation Process

2012 ◽  
Vol 627 ◽  
pp. 378-381
Author(s):  
Bi Rong Wang
Keyword(s):  
Reaction Time ◽  
Oxidation Process ◽  
Removal Rate ◽  
Fenton Oxidation ◽  
Dye Wastewater ◽  
Dyeing Wastewater ◽  
Reaction Conditions ◽  
Fenton Oxidation Process

Fenton pretreatment has been used for treating dye wastewater. The effects of the dos of H2O2 and FeSO4, reaction time and pH on the removal COD were investigated. It was found that, when the reaction conditions are as follows: COD 2850 mg/L dyeing wastewater, the dosage of H2O2 is 140mmol/L, FeSO4 17.02 mmol/L, pH 7.6, and reaction time 1.0 h, the CODcr of dye wastewater removal rate of up to 70%. Fenton pretreatment process of dye wastewater has a broad prospect.

scholarly journals Solar Photocatalytic Degradation of Azo Dye in AqueousTiO2Suspension Assisted by Fresnel Lens

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Wen-Shiuh Kuo ◽  
Wen-Yu Chen
Keyword(s):  
Reaction Time ◽  
Solar Energy ◽  
Photocatalytic Degradation ◽  
Azo Dye ◽  
Fresnel Lens ◽  
Dye Wastewater ◽  
Promoting Effect ◽  
Reaction Conditions ◽  
Initial Ph ◽  
Critical Process Parameters

Solar TiO2photocatalytic process assisted by a Fresnel lens was investigated for treating an azo dye wastewater of Acid Orange 10 (AO10). Response surface methodology (RSM) was employed to assess the effect of critical process parameters (including initial pH of wastewater, concentration of TiO2, and reaction time) on treatment performance in terms of COD and TOC degradation efficiency. Optimized reaction conditions based on the analysis of RSM were established under an initial pH of 6.0, a concentration of TiO2of 1 g/L, and a reaction time of 2 h for reaching a 90% COD and TOC degradation of AO10 wastewater. With the assistance of Fresnel lens, the TOC degradation rate of AO10 wastewater increased significantly from 0.606 h−1and 0.289 h−1to 1.477 h−1and 0.866 h−1in summer (June) season (UV280–400 nm nm: 39.9–44.8 W/m2) and winter (December) season (UV280–400 nm nm: 23.9–26.9 W/m2), respectively. This could be mainly due to the concentrating effect of Fresnel lens for solar energy, resulting in an increase of 2~2.5 times of solar light intensity and a raising heat irradiation in terms of 10~15 °C of wastewater temperature. These results revealed that solar energy could be concentrated effectively by using Fresnel lens and showed a significant promoting effect on the TiO2photocatalytic degradation of dye wastewater.

Decolorization of Methylene Blue Dye Wastewater by Fenton’s Reagent

2011 ◽  
Vol 295-297 ◽  
pp. 1447-1450 ◽  
Author(s):  
Jun Tan Liu ◽  
Huan Gao ◽  
Shi Jing Liu
Keyword(s):  
Methylene Blue ◽  
Reaction Time ◽  
Inorganic Compounds ◽  
Good Effect ◽  
Blue Dye ◽  
Fenton’S Reagent ◽  
Methylene Blue Dye ◽  
Dye Wastewater ◽  
Fenton's Reagent ◽  
Initial Ph

Using ·OH from Fenton’s reagent, the strong oxidation treatment of methylene blue dye wastewater can destruct the chromophore in organic compounds, and yield CO2, H2O and small molecule inorganic compounds by oxidative degradation finally. The influence of Fenton's reagent dosage, initial pH, and reaction time on the degradation effect was studied. The experimental results show that the decolorization rate of 100mL 20mg/L methylene blue dye wastewater can achieve 96% in the conditions of 0.02g FeSO4·7H2O, 1mL 30% H2O2, initial pH at 3.0 ~4.0, reaction time is 30 min, at room temperature. This treatment of dye wastewater is easy to operate and with good effect.

The Study of Phosphorus Removal by Electrocoagulation with Iron-Anodes

2011 ◽  
Vol 183-185 ◽  
pp. 417-421
Author(s):  
Yong Bo Lin ◽  
Yang Yang ◽  
Shuai Wang
Keyword(s):  
Reaction Time ◽  
Total Phosphorus ◽  
Current Density ◽  
Phosphorus Removal ◽  
Removal Rate ◽  
Electrolysis Time ◽  
Optimal Conditions ◽  
Reaction Conditions ◽  
Electrode Distance ◽  
Initial Ph

Determined to adopt iron as anodes, and Ti-base board with coating as cathodes. To optimize the reaction conditions of phosphorus removal by electrocoagulation (EC), testing the effect of current density, electrode distance, initial pH and electrolysis time on the phosphorus removal. According to the results, the optimal conditions for the phosphorus removal in the EC treatment were obtained, i.e., 20 mA/cm2 of current density, 2cm of distance and 10min of reaction time were optimum. Under these conditions, phosphorus removal by electrocoagulation reached to 95.07%, 10min later the change of total phosphorus (TP) removal rate is not obvious. By the end of this test, phosphorus removal by electrocoagulation reached to 99.68%.

Treatment of Sodium Formate Wastewater by Fenton Oxidation Process

2012 ◽  
Vol 573-574 ◽  
pp. 627-630
Author(s):  
Zhi Gang Chen ◽  
Rui Xue Zhang ◽  
Bo Zhang ◽  
An Ping Wei
Keyword(s):  
Reaction Time ◽  
Removal Efficiency ◽  
Oxidation Process ◽  
Ph Value ◽  
Sodium Formate ◽  
Cod Removal ◽  
Fenton Oxidation ◽  
Fenton Process ◽  
Initial Ph ◽  
Fenton Oxidation Process

In this study, in order to reduce the sodium formate concentration thereby reducing toxicity, the treatment of this wastewater by Fenton process was investigated. The effects of initial PH value, reaction time, concentration of FeSO4• 7H2O, and H2O2 dosage on the removal efficiency of COD were studied respectively. The experiment results show that when using Fenton oxidization pretreatment process, with pH 2.0, FeSO4•7H2O concentration 4000mg/L, H2O2(30 % ) portion 4ml/L, and reaction time 20min, COD removal efficiency was more than 50%, oxidization efficiency was good.

Study of Advanced Oxidation Technology on Post Treatment Wastewater of Pulp & Paper Mills

2014 ◽  
Vol 955-959 ◽  
pp. 2697-2700
Author(s):  
Ting Zhi Liu ◽  
Shuai Li ◽  
Fang Chang ◽  
Hao Yu Wang
Keyword(s):  
Fenton Oxidation ◽  
Treated Wastewater ◽  
Treatment Technology ◽  
Reaction Conditions ◽  
Paper Mills ◽  
Initial Ph ◽  
Advanced Oxidation Technology ◽  
Oxidation Technology ◽  
Optimized Conditions

In this article, Fenton oxidation treatment technology was employed to the improving of quality of post treated wastewater from pulp & paper mills in order to increase the recycling ratio of final treated wastewater. The reaction conditions were optimized through single-factor experiments and the removal of color were tested for the optimizing. It was found in this study that the color of Fenton oxidation treated water was variegated with the extending of settling time. The optimized conditions were: Dosage of H2O2 was 682.1mg/L(30% m/m), 1.5 times theoretical consumption, 205mg/L FeSO47H2O (H2O2:FeSO4=15:1), the initial pH and the reaction time were 4.5 and 40min, respectively. The removal of the color and COD were 51.3% and 80% after Fenton treatment. GC-MS analysis shown that the contents of organic extracts and most of organic compounds reduced significantly after the oxidational treatment.

Heterogeneous Fenton System Dynamic Decolorization of Simulated Dye Wastewater

2013 ◽  
Vol 641-642 ◽  
pp. 30-34
Author(s):  
Yan Jie Bi ◽  
Yu Kun Ma ◽  
Sheng Liang Zheng ◽  
Bin Song Wang
Keyword(s):  
Residence Time ◽  
Reaction Temperature ◽  
Ph Value ◽  
System Dynamic ◽  
Dye Wastewater ◽  
Heterogeneous Fenton ◽  
Reaction Conditions ◽  
Simulated Wastewater ◽  
Catalyst Dosage ◽  
Fenton System

Using heterogeneous Fenton system dynamic method, a decolorization test was operated for three kinds of simulated dye wastewater (Reactive Red KE-3B, Reactive Yellow KE-4R and Reactive Blue KN-R). Through the single factor experiments to examine the pH, H2O2 dosage, catalyst dosage, reaction temperature and residence time of simulated dye wastewater effected on the simulated dye wastewater decolorization rate. Determined the best decolorization reaction conditions as pH value of 4, the H2O2 concentration of 800 mg/L, catalyst dosage of 20 g, reaction temperature of 60 °C and reaction residence time of 9 minutes. Under this reaction conditions, in heterogeneous fenton system, degradation rate of the three kinds of simulated wastewater reached 95.01%, 93.86% and 97.74%, respectively.

Color Removal of Reactive Brilliant Blue KN-R Simulated Dye Wastewater by Using Novel Flocculants

2012 ◽  
Vol 610-613 ◽  
pp. 1939-1942
Author(s):  
Ji Zhou Li ◽  
Xu Yin Yuan ◽  
Ming Tian ◽  
Hao Ran Ji ◽  
Wan Jiang
Keyword(s):  
Removal Efficiency ◽  
Color Removal ◽  
Brilliant Blue ◽  
Solution Temperature ◽  
Optimal Dosage ◽  
Dye Wastewater ◽  
Decolorization Efficiency ◽  
Initial Ph ◽  
Simulated Wastewater ◽  
Ph Range

In this study, five novel flocculants, QTRY-02, DC-491, Fennofix K97, BWD-01 and MD-03 were chosen to treat Reactive Brilliant Blue KN-R simulated wastewater by jar tests. The effect of flocculant dosage, initial pH, solution temperature of simulated dye wastewater and sedimentaion time on the color removal was examined respectively. The maximum color removal efficiency of KN-R was over 82% after 20 minutes of sedimentation and the optimal dosage was 150mg/L for all flocculants. In the pH range from 3 to 11, small changes in the color removal efficiency for QTRY-02. While for BWD-01, the efficiency increased from 67.3% to 88.3%. For both QTRY-02 and MD-04, decolorization efficiency increased as the solution temperature increased from 10°C to 50°C and the same result appeared when prolonging the sedimentation time from 1 to 12 hours.

scholarly journals Precipitation Methods Using Calcium-Containing Ores for Fluoride Removal in Wastewater

Minerals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 511 ◽  
Author(s):  
Li Wang ◽  
Ye Zhang ◽  
Ning Sun ◽  
Wei Sun ◽  
Yuehua Hu ◽  
...  
Keyword(s):  
Reaction Time ◽  
Hydrochloric Acid ◽  
Removal Rate ◽  
Ecological Environment ◽  
Fluoride Removal ◽  
Action Mechanism ◽  
Reaction Conditions ◽  
Fluoride Ions ◽  
Simulated Wastewater ◽  
Oscillation Rate

F-containing wastewater does great harm to human health and the ecological environment and thus needs to be treated efficiently. In this paper, the new calcium-containing precipitant calcite and aided precipitant fluorite were adopted to purify F-containing wastewater. Relevant reaction conditions, such as reaction time, oscillation rate, dosage of hydrochloric acid, calcite dosage and the assisting sedimentation performance of fluorite, and action mechanism are analyzed. The experiment showed that the removal rate of fluoride in simulated wastewater reached 96.20%, when the reaction time, the dosage of calcite, the dosage of 5% dilute hydrochloric acid, and the oscillation rate was 30 min, 2 g/L, 21.76 g/L, and 160 r/min, respectively. Moreover, the removal rate of fluoride in the actual F-containing smelting wastewater reaches approximately 95% under the optimum condition of calcite dosage of 12 g/L, reaction time of 30 min, and oscillation rate of 160 r/min. The addition of fluorite significantly improves the sedimentation performance of the reactive precipitates. The experimental results showed that calcite and fluorite can effectively reduce the concentration of fluoride ions in F-containing wastewater and solve the problem of slow sedimentation of reactive precipitates.

scholarly journals Efficient Degradation of Mordant Blue 9 Using the Fenton-Activated Persulfate System

Water ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2532 ◽  
Author(s):  
Md. Nahid Pervez ◽  
Felix Y. Telegin ◽  
Yingjie Cai ◽  
Dongsheng Xia ◽  
Tiziano Zarra ◽  
...  
Keyword(s):  
Butyl Alcohol ◽  
Textile Dye ◽  
Oh Radicals ◽  
Operational Parameters ◽  
Reaction Conditions ◽  
Tert Butyl Alcohol ◽  
Initial Ph ◽  
Fe Complex ◽  
Optimal Reaction ◽  
Activated Persulfate

In this study, a Fenton-activated persulfate (Fe2+/PS) system was introduced for the efficient degradation of Mordant Blue 9 (MB 9) as a textile dye in an aqueous solution. Results showed that the degradation of MB 9 was markedly influenced by operational parameters, such as initial pH, PS concentration, Fe2+ concentration, and initial dye concentration. Optimal reaction conditions were then determined. Inorganic anions, such as Cl− and HCO3−, enhanced the degradation efficiency of MB 9 under optimal conditions. Addition of HCO3− reduced the degradation performance of MB 9, whereas the addition of Cl− increased the degradation percentage of MB 9. In addition, quenching experiments were conducted using methanol and tert-butyl alcohol as scavengers, and methanol was identified as an effective scavenger. Thus, the degradation of MB 9 was attributed to S O 4 • − and •OH radicals. The degradation and mineralization efficiency of MB 9 was significantly reduced using the conventional Fenton process i.e., Fe2+/ hydrogen peroxide (HP) because of the formation of a Fe complex during degradation. Meanwhile, the Fe2+/persulfate (PS) system improved the degradation and mineralization performance.

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