Study on Catalytic Wet Oxidation of H-Acid Containing Water over Fe/SiO2 Catalyst

2013 ◽  
Vol 641-642 ◽  
pp. 281-284
Author(s):  
Hong Ya Li ◽  
Bin Xia Zhao ◽  
Wei Li Bai ◽  
Xiao Li Zhang

This study has investigated the degradation of H-acid (1-amino-8-naphthol-3, 6-disulfonic acid) containing water by catalytic wet hydrogen peroxide oxidation method, in which the catalyst of Fe/SiO2 was prepared by impregnation technology. The effect of catalyst dosage, initial pH value, amount of hydrogen peroxide and reaction temperature on the degradation process have been discussed, and the results indicated that wet hydrogen peroxide oxidation is an effective method for treating the wastewater containing H-acid, under the conditions that: catalyst dosage was 2 g, initial pH value was 7, amount of hydrogen peroxide was 10 mL (0.83 time of theoretical required amount) and reaction temperature was 80 °C, the COD and color removal rate can reach 87.3% and 96.5%, respectively.

2014 ◽  
Vol 884-885 ◽  
pp. 29-32
Author(s):  
Hong Ya Li ◽  
Biao Yan ◽  
Bin Xia Zhao ◽  
Xiao Li Zhang

Fe2O3-CeO2/γ-Al2O3 was used as catalyst for treating the dye wastewater by catalytic wet peroxide oxidation method, the effect of reaction temperature, initial pH value of the wastewater, dosage of catalyst and hydrogen peroxide on the COD removal were studied. Results showed that 90.3% of COD removal rate can be obtained under the condition of 90°C, pH=7, 0.8g catalyst/100 mL wasterwater, and 6mL H2O2 /100 mL wasterwater.


2013 ◽  
Vol 726-731 ◽  
pp. 2515-2520 ◽  
Author(s):  
De Min Yang ◽  
Jian Mei Yuan

Advanced treatment of biochemical treated coking wastewater was studied experimentally with ozonation process. The effects of initial pH value, ozone concentration, reaction temperature, and reaction time on the COD and color removal rate were investigated. The results showed that ozonation was an effective method for advanced treatment of biochemical treated coking wastewater. The increasing of initial pH value, ozone concentration, reaction temperature, and reaction time has enhanced the removal rate of COD and color. Meanwhile, the results also revealed that the maximal COD and color removal rate of 69.65% and 92.27% could be reached under the optimal conditions of the initial pH value is 10.5, ozone concentration is 150 mg/L, reaction temperature is 298 K, and reaction time is 30 min.


2012 ◽  
Vol 433-440 ◽  
pp. 147-152
Author(s):  
Ying Chun Yang ◽  
Yuan Gang Lu ◽  
Zhi Xiang Ye ◽  
Li Ping He ◽  
Jing Yu

A catalyst based on Fe/active carbon (Fe/AC) and H2O2 as oxidant for the catalytic wet hydrogen peroxide oxidation of phenol in aqueous solution was investigated. The results indicate that the degradation rate of phenol(20mg/L) reach 90.5% in the presence of Fe/AC(2g/L) and hydrogen peroxide (0.5 %) at pH value 7 after 5 hours under normal temperature and atmospheric pressure. Kinetic studies of the degradation reaction show that the degradation rate of phenol nearly follows the first-order reaction. The reaction rate constant and activity energy are 0.4162 min-1 and 23.64 kJ/mol at 25°C, respectively.


1989 ◽  
Vol 54 (12) ◽  
pp. 3253-3259
Author(s):  
Jaroslav Podlaha ◽  
Miloš Buděšínský ◽  
Jana Podlahová ◽  
Jindřich Hašek

The unusual product of the reaction of 2-chloroacrylonitrile with ethane thiol and following hydrogen peroxide oxidation was found to be (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile by means of X-ray crystallography. 1H and 13C NMR study of this compound has proven the same conformation of the molecule in solution.


1973 ◽  
Vol 51 (24) ◽  
pp. 4152-4158 ◽  
Author(s):  
Albert Richard Norris ◽  
James William Lennox Wilson

The hydrogen peroxide oxidation of thiocyanate ion in cis- and trans-[Coen2NH3NCS]2+ leads to the formation of the corresponding cis- and trans-cyanoammine- and diamminebis(ethylenediamine)cobalt-(III) complexes. The spectral properties of the previously unreported trans-[Coe2NH3CN]2+ are reported and compared to the spectral properties of the cis-isomer.Observations are made concerning the reaction conditions which favor a high percent conversion of trans-[Coen2NH3NCS]2+ to trans-[Coen2NH3CN]2+.


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