Treatment of Actual Dyeing Wastewater by Continuous Iron-Carbon Micro-Electrolysis Process

2013 ◽  
Vol 838-841 ◽  
pp. 2395-2399 ◽  
Author(s):  
Yi Bo Wang ◽  
Yong Hong Liu ◽  
Wei Fu ◽  
Li Cheng Chen ◽  
Yao Zhong Li ◽  
...  
Keyword(s):  
Raw Materials ◽  
Removal Rate ◽  
Continuous Operation ◽  
Reflux Ratio ◽  
Dyeing Wastewater ◽  
Electrolysis Process ◽  
Eds Analysis ◽  
Operation Test ◽  
Cod Removal Rate ◽  
Stable Stage

Continuous treating process by iron-carbon micro-electrolytic technology treating actual dyeing wastewater was studied, performance of the micro-electrolysis reactor (MER) assembled homemade iron-carbon micro-electrolysis materials (MEM) and the process of alkaline addition, the properties of iron mud (flocculation precipitation produced from alkaline addition) were also investigated. The results shows that:(1) COD removal rate of MER was stable at around 60%, and the chroma could reached less than 40 times at stable stage of 60 days operation; (2) According to 30 days of continuous operation test, 7.6 kg of iron mud was produced when one ton wastewater was treated in this system; it was also found that iron mud can be recycled as raw materials for the synthesis of MEM by EDS analysis; (3)Effluent reflux (reflux ratio 1~1.5) could effectively reduce the dosage of alkali in practical process.

The pretreatment of acrylonitrile and styrene with the ozonation process

1997 ◽  
Vol 36 (2-3) ◽  
pp. 263-270 ◽  
Author(s):  
Cheng-Nan Chang ◽  
Jih-Gaw Lin ◽  
Allen C. Chao ◽  
Bo-Chuan Cho ◽  
Ruey-Fang Yu
Keyword(s):  
Organic Nitrogen ◽  
Ph Value ◽  
Raw Materials ◽  
Removal Rate ◽  
Acrylonitrile Butadiene Styrene ◽  
Ozone Treatment ◽  
Oxidation Reduction ◽  
Initial Ph ◽  
Cod Removal Rate ◽  
Ozonation Process

Acrylonitrile and styrene are used as the raw materials for manufacturing acrylic fiber, thus they are often found as pollutants in the petrochemical wastewater. This study utilizes ozone to decompose the organic nitrogen contained in acrylonitrile and styrene, and the oxidation process was monitored using on-line measurements of oxidation-reduction potential (ORP) and pH. The efficiency of organic nitrogen decomposition was also estimated based on the COD, organic nitrogen, TOC, ammonia-N, nitrite, and nitrate measurements. Both the initial pH and alkalinity are observed to affect the degradation rate of organic nitrogen. The acrylonitrile sample with the lowest initial pH value (i.e., 4.0) has a shorter t1/2 of 18.9 min and that for samples of the highest initial pH (i.e., 11) was 34 min. The alkalinity of one acrylonitrile sample was boosted by adding 500 mg/l CaCO3, to simulate the field ABS (Acrylonitrile-Butadiene-Styrene) wastewater effluent. It was observed that within a short ozone contact time, the acrylonitrile sample spiked with 500 mg/l CaCO3 had the highest COD decomposition rate of 0.411 min−1, or 1.3 times more than that for samples without addition of CaCO3. Results of the ozonation process can be fitted with a modified Nernst equation for the various pH conditions. Additionally, the ozone treated synthetic ABS sample shows a faster COD removal rate in the subsequent biological process than those samples without ozone treatment.

Effect of Rare Earths on Iron-Carbon Micro Electrolysis in Dyeing Wastewater Treatment

2014 ◽  
Vol 1010-1012 ◽  
pp. 190-194
Author(s):  
Xiao Gang Chen ◽  
Ju Chi Kuang ◽  
Min Hua Chen
Keyword(s):  
Wastewater Treatment ◽  
Removal Rate ◽  
Waste Water Treatment ◽  
Sewage Treatment ◽  
Main Role ◽  
Dyeing Wastewater ◽  
Related Factors ◽  
Orthogonal Experiments ◽  
Cerium Ion ◽  
Cod Removal Rate

In the paper we first discussed the principle of wastewater treatment by iron-carbon micro electrolysis. And the experimental methods were stated clear soon afterwards. Then we designed the micro electrolysis orthogonal experiments. Discussion of influences of related factors on waste water treatment followed. The main factors are cerium ion additive quantity, ratio of La3+/Ce4+ and pH in wastewater. The experimental results show that 1) The sequence of factors influence on wastewater micro-electrolysis treatment is Ce4+ > pH > La3+ > iron/carbon ratio; 2) The lanthanum and cerium ions have a synergistic effect in the wastewater treatment, and cerium ion plays a main role; 3) When pH is 6, COD removal rate arrives at maximum 89%, however when the pH is in the case of too high or too low, the effect of sewage treatment is not good.

Effect of Adding Rare Earths into Iron-Carbon Micro Electrolysis Process on Degradation of Dyeing Wastewater

2014 ◽  
Vol 1021 ◽  
pp. 25-28 ◽  
Author(s):  
Ju Chi Kuang
Keyword(s):  
Iron Powder ◽  
Rare Earths ◽  
Removal Rate ◽  
Waste Water Treatment ◽  
Great Influence ◽  
Powder Particle Size ◽  
Powder Size ◽  
Dyeing Wastewater ◽  
Related Factors ◽  
Electrolysis Process

Nowadays the traditional dyeing wastewater treatments based on flocculation-biochemical technology become more difficult than before. The study in this paper aim was it to probe how adding rare earths (REs) into iron-carbon micro-electrolysis process to advance dyeing wastewater degradation. Firstly, the principle was discussed. Then the experimental methods were stated and it followed by exploring effect of iron powder size on the dye decolorization rate. Next were design of the micro electrolysis orthogonal experiments and discussion of influences of related factors on waste water treatment. The experimental results show that besides common iron powder particle size and the processing time, the factors that have great influence on dyeing wastewater treatment are Ce4+, pH, La3+ and iron/carbon ratio. The sequence of factors influence on wastewater micro-electrolysis treatment is Ce4+ > pH > La3+ > iron/carbon ratio. When pH is 6, COD removal rate arrives at maximum 89%, however when the pH is in the case of too high or too low, the effect of sewage degradation is not good.

Treatment of Printing and Dyeing Wastewater by the Iron Scurf and Flue Dust Internal Electrolysis Method

2011 ◽  
Vol 415-417 ◽  
pp. 438-441
Author(s):  
Jin Xia Yan ◽  
Dong Fang Li ◽  
Shao Feng Dong
Keyword(s):  
Reaction Time ◽  
Electric Conductivity ◽  
Removal Rate ◽  
Dyeing Wastewater ◽  
Optimum Conditions ◽  
Printing And Dyeing Wastewater ◽  
Flue Dust ◽  
Internal Electrolysis ◽  
Electrolysis Method ◽  
Cod Removal Rate

The printing and dyeing wastewater was treated by internal electrolysis method. The results show the chromaticity removal rate was up to 98.53 percent and COD removal rate 85.98 percent under the optimum conditions of wastewater pH 4, reaction time 30 minutes, the electric conductivity 1450μm/cm, the value BOD5/COD increases from 0.34 to 0.51. Moreover, the pH, Fe2+ concentration and absorbance of wastewater changed in the process, the mechanism of that was also analyzed.

Characterization and Application in Pretreatment of Landfill Leachate on Modified Bentonites

2011 ◽  
Vol 287-290 ◽  
pp. 1675-1679
Author(s):  
Hong Shao ◽  
Ning Cao
Keyword(s):  
Landfill Leachate ◽  
Raw Materials ◽  
Removal Rate ◽  
Ammonium Bromide ◽  
X Ray Diffraction ◽  
Reaction Conditions ◽  
Cod Removal Rate ◽  
Organic Bentonite ◽  
Better Than

A series of sodium bentonites and cetyl tri methyl ammonium bromide as raw materials were prepared to the modified organic composite montmorillonites. The performance characterization of the modified organic bentonite was observed by means of IR spectroscopy, X-ray diffraction, scanning electron microscopy. And the modified organic bentonite was applied into the pretreatment of landfill leachate, which was with the COD as high as 20000-37000 mg/L. The COD removal rate was invested as index. The optimum dosage and the best reaction conditions of bentonite have also been studied. The results indicated that the treatment effect of COD on the modified bentonite was better than the natural bentonite. Under the optimum conditions, the removal rate of COD reached 67.85% and the load of biological treatment was reduced on the next step.

Study on Treatment of Polytetrahydrofuran Wastewater by Iron-Carbon Micro Electrolysis

2013 ◽  
Vol 295-298 ◽  
pp. 1307-1310
Author(s):  
Xi Tian ◽  
Ming Xin Huo ◽  
De Jun Bian ◽  
Sheng Shu Ai ◽  
Qing Kai Ren
Keyword(s):  
Reaction Time ◽  
Removal Efficiency ◽  
Contact Time ◽  
Ph Value ◽  
Removal Rate ◽  
Volume Ratio ◽  
Cod Removal ◽  
Electrolysis Process ◽  
Cod Removal Efficiency ◽  
Cod Removal Rate

The wastewater produced from the polytetrahydrofuran (PolyTHF) was treated with iron-carbon micro electrolysis process. This paper had studied the COD removal efficiency influences of primary PH value, reaction time, the quality ratio of the iron-carbon, the quality and volume ratio of Fe-wastewater. The results show that when pH value is 3, the quality ratio of the iron-carbon is 11 and the quality and volume ratio of Fe and wastewater is 17 with contact time of 90 min, the wastewater COD removal rate can reach as high as 95.0%.

Study on the Kitchen Residues and Cattle Manure Anaerobic Co-Digestion in Bench-Scale Laboratory Test

2012 ◽  
Vol 260-261 ◽  
pp. 621-626
Author(s):  
Xin Ke ◽  
Xin Zhao ◽  
Ying Sun ◽  
Yun Zhang
Keyword(s):  
Comparative Research ◽  
Anaerobic Fermentation ◽  
Raw Materials ◽  
Removal Rate ◽  
Gas Production ◽  
Cod Removal ◽  
Cattle Manure ◽  
Batch Type ◽  
Cod Removal Rate ◽  
Optimal Effect

With kitchen residues and cattle manure as raw materials, in temperature (36±1°C) adopt the way of the batch type fermented for kitchen residues and cattle manure, we will have a comparative research between independent anaerobic fermentation and mixed anaerobic fermentation. The results of the experiments show that the gas production and COD removal rate by the anaerobic fermentation of cattle manure independent would be superior to kitchen residues, the optimal effect is the anaerobic fermentation of kitchen residues mixed with cattle manure in all aspects .In this experiment all the kitchen residues are rice, vegetables, meat, eggs and other food all that have been after cooked, containing a large number of fat and salt, such condition is not suitable for the growth of microorganism. The time of gas production is only nine days and gas production rate is extremely low, only 1500ml accumulative gas production, But cattle manure’s accumulative gas production is 3028ml, COD removal rate was 21%, COD removal rate by mixed anaerobic fermentation of kitchen residues and cattle manure can achieve 60.92%.

Study on the Advanced Treatment of Dyeing Wastewater by Photocatalytic-H2O2

2014 ◽  
Vol 1048 ◽  
pp. 503-506
Author(s):  
Hui Xia Lan ◽  
Ping Ma ◽  
Jian Zhang ◽  
Hui Jie Li ◽  
Heng Zhang ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Reaction Time ◽  
Removal Rate ◽  
Cod Removal ◽  
Advanced Treatment ◽  
Dyeing Wastewater ◽  
Biochemical Treatment ◽  
Emission Standard ◽  
Effect Of Ph ◽  
Cod Removal Rate

The composition of dyeing wastewater is complicated, after biochemical treatment, the effluent COD is still unable to meet the emission standard. To achieve discharge standard that often require advanced treatment after biochemical. This paper investigated effect of pH, reaction time, ZnO dosage, dosage of H2O2on the effect of dyeing wastewater treatment by photocatalytic-H2O2, the results showed that the reaction time of 15 min, pH of 4, dosage of ZnO was 4 g/L, 30% H2O2dosage was 1 ml/L, the COD removal rate was highest, can reach more than 55%.

Performance of anode materials in electrochemical treatment system for indigo dyeing wastewater

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Wei Zhang ◽  
Mengdi Zhang ◽  
Zhijie Huangfu ◽  
Jiming Yao ◽  
Yuan Xie
Keyword(s):  
Anode Materials ◽  
Electrolyte Concentration ◽  
Removal Rate ◽  
Electrochemical Treatment ◽  
Cod Removal ◽  
Aluminum Electrode ◽  
Dyeing Wastewater ◽  
Content Type ◽  
Indigo Dyeing ◽  
Cod Removal Rate

Purpose This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances. Design/methodology/approach The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out. Findings Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%. Research limitations/implications In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched. Practical implications It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater. Originality/value Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.

scholarly journals Pretreatment of printing and dyeing wastewater by Fe/C micro-electrolysis combined with H2O2 process

2018 ◽  
Vol 2017 (3) ◽  
pp. 707-717 ◽  
Author(s):  
Yan Wang ◽  
Xianwei Wu ◽  
Ju Yi ◽  
Lijun Chen ◽  
Tianxiang Lan ◽  
...  
Keyword(s):  
Removal Rate ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Coefficient Of Determination ◽  
H2o2 Concentration ◽  
Dyeing Wastewater ◽  
Spectra Analysis ◽  
Printing And Dyeing Wastewater ◽  
Initial Ph ◽  
Cod Removal Rate

Abstract A novel iron-carbon (Fe/C) micro-electrolysis combined with H2O2 (ICMH) process was proposed to pretreat the printing and dyeing wastewater (PDW), using a micro-electrolysis filling. The effects of H2O2 concentration, reaction time, initial pH, and Fe/C dosage on chemical oxygen demand (COD) removal rate of PDW were optimized by response surface methodology (RSM). The maximum COD removal rate was approximately 77.65% after 186 min treatment, when the concentration of H2O2, initial pH and the dosage of Fe/C were 8.88 g/L, 1.5 and 837 g/L, respectively. Analysis of variance (ANOVA) showed a high coefficient of determination value (R2 = 0.9780). And H2O2 concentration and initial pH were the key factors to improve the treatment effect. UV-Vis spectra indicated that a significant blue shift at 220 nm, attributing that fused aromatic hydrocarbons were degraded effectively. 3D-EEM spectra analysis showed that the water samples of PDW mainly contained three kinds of organic matter: refractory fulvic acid, soluble microbial metabolites and aromatic proteins, and the degradation rate of these was 81.76%, 53.78% and 70.83%, respectively.

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