The pretreatment of acrylonitrile and styrene with the ozonation process

1997 ◽  
Vol 36 (2-3) ◽  
pp. 263-270 ◽  
Author(s):  
Cheng-Nan Chang ◽  
Jih-Gaw Lin ◽  
Allen C. Chao ◽  
Bo-Chuan Cho ◽  
Ruey-Fang Yu
Keyword(s):  
Organic Nitrogen ◽  
Ph Value ◽  
Raw Materials ◽  
Removal Rate ◽  
Acrylonitrile Butadiene Styrene ◽  
Ozone Treatment ◽  
Oxidation Reduction ◽  
Initial Ph ◽  
Cod Removal Rate ◽  
Ozonation Process

Acrylonitrile and styrene are used as the raw materials for manufacturing acrylic fiber, thus they are often found as pollutants in the petrochemical wastewater. This study utilizes ozone to decompose the organic nitrogen contained in acrylonitrile and styrene, and the oxidation process was monitored using on-line measurements of oxidation-reduction potential (ORP) and pH. The efficiency of organic nitrogen decomposition was also estimated based on the COD, organic nitrogen, TOC, ammonia-N, nitrite, and nitrate measurements. Both the initial pH and alkalinity are observed to affect the degradation rate of organic nitrogen. The acrylonitrile sample with the lowest initial pH value (i.e., 4.0) has a shorter t1/2 of 18.9 min and that for samples of the highest initial pH (i.e., 11) was 34 min. The alkalinity of one acrylonitrile sample was boosted by adding 500 mg/l CaCO3, to simulate the field ABS (Acrylonitrile-Butadiene-Styrene) wastewater effluent. It was observed that within a short ozone contact time, the acrylonitrile sample spiked with 500 mg/l CaCO3 had the highest COD decomposition rate of 0.411 min−1, or 1.3 times more than that for samples without addition of CaCO3. Results of the ozonation process can be fitted with a modified Nernst equation for the various pH conditions. Additionally, the ozone treated synthetic ABS sample shows a faster COD removal rate in the subsequent biological process than those samples without ozone treatment.

Catalytic Wet Peroxide Oxidation of Dye Wastewater Using Fe2O3-CeO2/γ-Al2O3 as Catalyst

2014 ◽  
Vol 884-885 ◽  
pp. 29-32
Author(s):  
Hong Ya Li ◽  
Biao Yan ◽  
Bin Xia Zhao ◽  
Xiao Li Zhang
Keyword(s):  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Dye Wastewater ◽  
Peroxide Oxidation ◽  
Oxidation Method ◽  
Wet Peroxide Oxidation ◽  
Initial Ph ◽  
Catalytic Wet Peroxide Oxidation ◽  
Cod Removal Rate

Fe2O3-CeO2/γ-Al2O3 was used as catalyst for treating the dye wastewater by catalytic wet peroxide oxidation method, the effect of reaction temperature, initial pH value of the wastewater, dosage of catalyst and hydrogen peroxide on the COD removal were studied. Results showed that 90.3% of COD removal rate can be obtained under the condition of 90°C, pH=7, 0.8g catalyst/100 mL wasterwater, and 6mL H2O2 /100 mL wasterwater.

Advanced Treatment of Biochemical Treated Coking Wastewater by Ozonation Process

2013 ◽  
Vol 726-731 ◽  
pp. 2515-2520 ◽  
Author(s):  
De Min Yang ◽  
Jian Mei Yuan
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Ozone Concentration ◽  
Ph Value ◽  
Removal Rate ◽  
Color Removal ◽  
Advanced Treatment ◽  
Coking Wastewater ◽  
Initial Ph ◽  
Ozonation Process

Advanced treatment of biochemical treated coking wastewater was studied experimentally with ozonation process. The effects of initial pH value, ozone concentration, reaction temperature, and reaction time on the COD and color removal rate were investigated. The results showed that ozonation was an effective method for advanced treatment of biochemical treated coking wastewater. The increasing of initial pH value, ozone concentration, reaction temperature, and reaction time has enhanced the removal rate of COD and color. Meanwhile, the results also revealed that the maximal COD and color removal rate of 69.65% and 92.27% could be reached under the optimal conditions of the initial pH value is 10.5, ozone concentration is 150 mg/L, reaction temperature is 298 K, and reaction time is 30 min.

scholarly journals Ti/RuO2-IrO2-SnO2 Anode for Electrochemical Degradation of Pollutants in Pharmaceutical Wastewater: Optimization and Degradation Performances

2020 ◽  
Vol 13 (1) ◽  
pp. 126
Author(s):  
Guozhen Zhang ◽  
Xingxing Huang ◽  
Jinye Ma ◽  
Fuping Wu ◽  
Tianhong Zhou
Keyword(s):  
Removal Rate ◽  
Inorganic Compounds ◽  
Oxide Coating ◽  
X Ray Diffraction ◽  
Pharmaceutical Wastewater ◽  
High Concentration ◽  
Dimensionally Stable Anodes ◽  
X Ray ◽  
Initial Ph ◽  
Cod Removal Rate

Electrochemical oxidation technology is an effective technique to treat high-concentration wastewater, which can directly oxidize refractory pollutants into simple inorganic compounds such as H2O and CO2. In this work, two-dimensionally stable anodes, Ti/RuO2-IrO2-SnO2, have been developed in order to degrade organic pollutants from pharmaceutical wastewater. Characterization by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) showed that the oxide coating was successfully fabricated on the Ti plate surface. Electrocatalytic oxidation conditions of high concentration pharmaceutical wastewater was discussed and optimized, and the best results showed that the COD removal rate was 95.92% with the energy consumption was 58.09 kW·h/kgCOD under the electrode distance of 3 cm, current density of 8 mA/cm2, initial pH of 2, and air flow of 18 L/min.

A Study of Fenton’s Oxidation Pretreatment on Dye Wastewater Containing Acetic Acid

2014 ◽  
Vol 1044-1045 ◽  
pp. 215-218
Author(s):  
Xian Huan Qiu ◽  
Hai Yu ◽  
Peng Fei Deng
Keyword(s):  
Acetic Acid ◽  
Processing Time ◽  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Dye Wastewater ◽  
Fenton’S Oxidation ◽  
Effects Of Ph ◽  
Cod Removal Rate ◽  
Fenton's Oxidation

In the presence of acetic acid, the effects of pH, processing time, addition of Fe2+ and H2O2 on dye wastewater treatment were studied. Experimental results showed that in the presence of acetic acid, when the pH value was 4, the processing time was 30.0min, addition of ferrous sulfate was 4.8g/L, and addition of hydrogen peroxide was 56mL/L, the treatment effect was the best, COD removal rate reached 51.0%. Further studied of the effect of the presence of acetic acid on Fenton’s oxidation of dye wastewater, the results showed that without of acetic acid, the COD removal rate was higher than that with acetic acid. And the effect of Fenton's reagent on oxidation of dye substances was interfered by the presence of acetic acid.

Synergetic Degradation of Zidovudine Wastewater by Ultrasonic and Iron-Carbon Micro-Electrolysis

2011 ◽  
Vol 347-353 ◽  
pp. 1949-1952 ◽  
Author(s):  
Liang Li ◽  
Bing Zhe Xu ◽  
Chang Yu Lin ◽  
Xiao Min Hu
Keyword(s):  
Reaction Time ◽  
Degradation Rate ◽  
Removal Rate ◽  
Cod Removal ◽  
Mass Ratio ◽  
Initial Ph ◽  
Cod Removal Rate

Zidovudine wastewater is difficult to biodegradation due to high COD and toxicity. The synergetic treatment of Zidovudine wastewater by Ultrasonic and iron-carbon micro-electrolysis technology was studied. The influence of initial pH, reaction time, mass ratio of iron and carbon and mass ratio of iron and water on degradation rate of COD was researched. The result showed that the COD removal rate was only about 54.3% and the degradation speed is very slow when iron-carbon micro-electrolysis treated Zidovudine wastewater　separately. However, when ultrasonic synergy micro-electrolysis to treat Zidovudine wastewater, the COD removal rate could was up to 85% and the reaction time was also decreased. Moreover, the BOD5 / COD rose from 0.15 to 0.35, which meant the wastewater became easily biodegradable.

Effect of Environment Factors on Phosphorus Removal Efficiency of Phosphate Reduction System

2011 ◽  
Vol 255-260 ◽  
pp. 2797-2801
Author(s):  
Chen Yao ◽  
Chun Juan Gan ◽  
Jian Zhou
Keyword(s):  
Removal Efficiency ◽  
Phosphorus Removal ◽  
Ph Value ◽  
Removal Rate ◽  
Mass Rearing ◽  
Phosphate Removal ◽  
Environment Factors ◽  
Reduction System ◽  
Initial Ph ◽  
The Impact

Effect of environment factors such as initial pH value, dissolved oxygen (DO) and temperature on phosphorus removal efficiency of phosphate reduction system was discussed in treating pickled mustard tube wastewater. Results indicate that environment factors have significant influence on dephosphorization efficiency. And, the impact of DO on phosphate reduction is mainly by affecting the distribution of micro-environment inner biofilm, manifest as phosphate removal rate decreased with a fall in DO concentration, while overhigh DO can lead to detachment of biofilm, thus causing the increase of effluent COD concentration, and so DO need to be controlled in the range of 6 mg/L. Moreover, a higher temperature is more beneficial to phosphorus removal by PRB. Unfortunately, exorbitant temperature can result in mass rearing of Leuconostoc characterized with poor flocculability in reactor, and that cause turbidity in effluent appeared as a rise in COD of effluent. Hence, the optimal temperature is found to be about 30°C.

Research on Waste Materials with Decentralized White Spirit Wastewater Pretreatment by Fe-C Micro-Electrolysis

2014 ◽  
Vol 644-650 ◽  
pp. 5419-5422
Author(s):  
Jin Xiang Fu ◽  
Hong Mei Li ◽  
Peng Fei Yu ◽  
Kai Zhao
Keyword(s):  
Phosphorus Removal ◽  
Ph Value ◽  
Removal Rate ◽  
Temperature Response ◽  
Brewery Wastewater ◽  
Electrochemical Test ◽  
Optimal Processing ◽  
Water Ph ◽  
Cod Removal Rate ◽  
Iron Electrolysis

This research adopts the important iron electrolysis, removal of the wastewater of high COD, SS, phosphorus pretreatment experiment. Discusses the different iron dosing quantity, iron carbon ratio, and pH value, reaction time on the COD and turbidity, the influence of the phosphorus removal effect. Studies show that iron important electrochemical test in brewery wastewater treatment static optimal processing conditions for: water pH value is 4, 5% dosage of iron filings, 60 min temperature response, COD removal rate was 52.31%. When the iron carbon ratio of 2:1, removing effect is good, can reach 54.53%.

Preparation of Xonotlite Whiskers from Carbide Slag

2010 ◽  
Vol 434-435 ◽  
pp. 787-789
Author(s):  
Fei Liu ◽  
Ling Ke Zeng ◽  
Jian Xin Cao ◽  
Qian Lin ◽  
Jing Li
Keyword(s):  
Ph Value ◽  
Raw Materials ◽  
Removal Rate ◽  
Hydrothermal Conditions ◽  
Hydrothermal Route ◽  
Synthesis Conditions ◽  
Ph Values ◽  
Carbide Slag ◽  
Xrd Techniques ◽  
First Time

Carbide slag was used as raw materials for the first time to prepare xonontlite whiskers via a hydrothermal route without special instruments and synthesis conditions. And the effect of pH value of emulsion of carbide slag and hydrothermal conditions on removal rate of impurities, morphology and crystallinity of synthesized xonotlite whiskers were explored using ICP, SEM and XRD techniques. The results indicated that the carbide slag after purification could be used to prepare xonotlite whiskers, and different pH values of emulsion of carbide slag had great impact on the removal rate of impurities and morphology of xonotlite whiskers. Xonotlite whiskers with 20-40 μm in length and 100-500 nm in diameter were hydrothermally synthesized at 230 °C for 15 h with using silicic acid as kiesel material.

Synthesis and Characterization of Zeolite X Obtained from Coal Gangue for Adsorption of Cu2+

2021 ◽  
Vol 13 (8) ◽  
pp. 1512-1520
Author(s):  
MiaoSen Zhang ◽  
SiYang Wang ◽  
Zheng Hu ◽  
RunZe Zhang ◽  
XiaoLi Wang
Keyword(s):  
Adsorption Capacity ◽  
Adsorption Kinetics ◽  
Ph Value ◽  
Copper Ions ◽  
Removal Rate ◽  
Coal Gangue ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Zeolite X ◽  
Initial Ph

China is a big coal producing country, there are a lot of coal gangue piled up. The zeolite X was synthesized by alkali melting and hydrothermal method based on the coal gangue from Chifeng city, Inner Mongolia. The obtained zeolite X sample is characterized by X-ray diffraction, SEM, EDS spectrum and IR which showed the X zeolite is an octahedral structure with complete crystal shape and uniform grain size. The results of BET showed the specific surface area of zeolite X is 354.8 m2/g and the minimum pore size is 3.8 nm which indicated that the zeolite X belongs to mesoporous materials. The adsorption conditions of the zeolite X adsorbent on copper ions were optimized. A solution containing Cu2+ ions with an initial concentration of 300 mg/L was added to the zeolite X with a dosage of 0.1 g and the initial pH value of the solution was adjusted to 6. Then the solution was oscillated for 120 min at 225 r/min. The maximum adsorption capacity and removal rate were 148.6 mg/g and 99.1%, respectively. The adsorption mechanism was discussed by adsorption kinetics and thermodynamics. The quasi-second order kinetic equation can be well used to describe the adsorption kinetics of zeolite X to Cu2+ (R2 = 0.9994) and Langmuir can well describe the adsorption behavior of zeolite X to Cu2+ (R2 = 0.9995) which showed the adsorption is a monolayer of chemical adsorption. The adsorption capacity of zeolite X to Cu2+ is about 4.0 times that of coal gangue, indicating that the zeolite X has good adsorption capacity.

Characterization and Application in Pretreatment of Landfill Leachate on Modified Bentonites

2011 ◽  
Vol 287-290 ◽  
pp. 1675-1679
Author(s):  
Hong Shao ◽  
Ning Cao
Keyword(s):  
Landfill Leachate ◽  
Raw Materials ◽  
Removal Rate ◽  
Ammonium Bromide ◽  
X Ray Diffraction ◽  
Reaction Conditions ◽  
Cod Removal Rate ◽  
Organic Bentonite ◽  
Better Than

A series of sodium bentonites and cetyl tri methyl ammonium bromide as raw materials were prepared to the modified organic composite montmorillonites. The performance characterization of the modified organic bentonite was observed by means of IR spectroscopy, X-ray diffraction, scanning electron microscopy. And the modified organic bentonite was applied into the pretreatment of landfill leachate, which was with the COD as high as 20000-37000 mg/L. The COD removal rate was invested as index. The optimum dosage and the best reaction conditions of bentonite have also been studied. The results indicated that the treatment effect of COD on the modified bentonite was better than the natural bentonite. Under the optimum conditions, the removal rate of COD reached 67.85% and the load of biological treatment was reduced on the next step.

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