Morphometric Parameters and Biochemical Status of Oilseed Rape Exposed to Fine-Dispersed Metallurgical Sludge, PHMB-Stabilized Silver Nanoparticles and Multi-Wall Carbon Nanotubes

2014 ◽  
Vol 880 ◽  
pp. 212-218 ◽  
Author(s):  
Alexander A. Gusev ◽  
Olga A. Akimova ◽  
Olga V. Zakharova ◽  
Anna Yu. Godymchuk ◽  
Yury A. Krutyakov ◽  
...  

Thepaper Presents Biological Properties of Threefine-Dispersed Materials, Namely Metallurgical Sludge, Colloidal Silver Andmulti-Wall Carbon Nanotubes (MWCNT) Exposing Oilseed Rape Plants. the Stimulationof Plant’s Growth by Silver Nanoparticles and the Intensification of Plantpigments Synthesis by MWCNT have been Experimentally Demonstrated. A Small Decreasein Energy and Germination Capacity were Noticed Whereby Colloidal Silver Hadthe Lowest Suppressive Effect, MWCN Tubes had the Highest Effect, and Sludge Wasfound in between Two above-Mentioned Materials. According to the Research, the Usageof Sludge is the most Effective at the Concentration of 10 and 100 g/l,colloidal Silver – 10 g/l and 300 g/l, MWCNT – 0,001 g/l and 1 g/l.

NANO ◽  
2008 ◽  
Vol 03 (01) ◽  
pp. 37-44 ◽  
Author(s):  
MOHSEN ADELI ◽  
ALI BAHARI ◽  
HODA HEKMATARA

Novel biodegradable nanocomposites containing multi wall carbon nanotubes (MWCNT) and poly(citric acid) (PCA) were successfully synthesized. For preparation of nanocomposites, MWCNT was opened using a mixture of sulfuric and nitric acid and its derivative containing – COOH and – OH functional groups was obtained. Polycondensation of monohydrate citric acid in the presence of functionalized MWCNT in the melting state was lead to nanotube-graft-poly(citric acid) (CNT-g-PCA) nanocomposites. The degree of polymerization of grafted hyperbranched poly(citric acid) onto the CNTs was controlled using CNT/citric acid ratio. The CNT-g-PCA were soluble in water freely and stirring their water solution and silver nitrate at room temperature lead to the CNT-g-PCA containing encapsulated silver nanoparticles in their polymeric shell. The structure of nanocomposites was characterized by TEM, DLS and spectroscopy methods.


2009 ◽  
Vol 08 (06) ◽  
pp. 533-541 ◽  
Author(s):  
MOHSEN ADELI ◽  
REZA SEPAHVAND ◽  
ALI BAHARI ◽  
BANDAR ASTINCHAP

Polycaprolactone-polylactide block copolymers (PCL-block-PLA) were grafted onto filled multi-wall carbon nanotubes (MWCNT) successfully. In this synthesis, MWCNTs were opened and functionalized, and then they were filled by silver nanoparticles. The filled MWCNT were used as macroinitiator for ring opening polymerization of ε-caprolactone and L-lactide. Then the end hydroxyl functional groups of MWCNT-graft-PCL or MWCNT-graft-PLA were used as initiator for ring opening polymerization of lactide and ε-caprolactone and MWCNT-graft-PCL-block-PLA or MWCNT-graft-PLA-block-PCL were obtained, respectively. Length of grafted copolymer chains onto the MWCNT was controlled using CNT/monomer ratio. Nanocomposites' properties depend on the length of polymer blocks strongly. Structure of nanocomposites was evaluated by TEM and spectroscopy methods.


NANO ◽  
2009 ◽  
Vol 04 (04) ◽  
pp. 217-223 ◽  
Author(s):  
ALI BAHARI ◽  
H. HEKMATARA ◽  
R. SEPAHVAND ◽  
MOHSEN ADELI

A simple method has been developed for decorating multi wall carbon nanotubes (MWCNTs) with palladium and silver nanoparticles. In this method, MWCNT was opened and functionalized using nitric and sulfuric acid mixture. Then citric acid was polymerized in the presence of functionalized MWCNT and MWCNT-graft-poly (citric acid) (MWCNT-g-PCA) was obtained. The mixing of MWCNT-g-PCA with metal salts, such as palladium chloride and silver nitrate, leads to encapsulation of metal nanoparticles in the polymeric shell ( MWCNT/Pd, AgNPs ). The structure of MWCNT/Pd and AgNPs were characterized by usual spectroscopy and microscopy methods. The influence of nanoparticles on the electrical conductivity of MWCNT was also investigated.


2003 ◽  
Vol 772 ◽  
Author(s):  
T. Seeger ◽  
G. de la Fuente ◽  
W.K. Maser ◽  
A.M. Benito ◽  
A. Righi ◽  
...  

AbstractCarbon nanotubes (CNT) are interesting candidates for the reinforcement in robust composites and for conducting fillers in polymers due to their fascinating electronic and mechanical properties. For the first time, we report the incorporation of multi walled carbon nanotubes (MWNTs) into silica-glass surfaces by means of partial surface-melting caused by a continuous wave Nd:YAG laser. MWNTs were detected being well incorporated in the silica-surface. The composites are characterized using scanning electron microscopy (SEM) and Raman-spectroscopy. A model for the composite-formation is proposed based on heatabsorption by MWNTs and a partial melting of the silica-surface.


2011 ◽  
Vol 26 (1) ◽  
pp. 73-77 ◽  
Author(s):  
Meng-Li ZHAO ◽  
Yu-Chen YUE ◽  
Li YUAN ◽  
De-Jun LI ◽  
Xiao-Ying LÜ ◽  
...  

2020 ◽  
Vol 36 (4) ◽  
pp. 87-93
Author(s):  
V.Yu. Reshetova ◽  
A.F. Krivoshchepov ◽  
I.A. Butorova ◽  
N.B. Feldman ◽  
S.V. Lutsenko ◽  
...  

Chitosan beads with colloidal silver nanoparticles inclued in the polymer matrix have been obtained by the introduction of chitosan into an acidified nanosilver sol. Dual interconnection of drops of the resulting solution was then carried out by ionotropic gelation at the first stage and covalent crosslinking of the polymer matrix with adipic acid at the second stage. The surface morphology of the obtained beads was studied by scanning electron microscopy. Data of Fourier transform IR spectroscopy confirmed the formation of covalent bonds between chitosan and adipic acid. The antibacterial activity of obtained beads against S. aureus and E. coli was evaluated using agar diffusion test. It was shown that the сhitosan beads modified with nanostructured silver exhibited an antibacterial effect against the tested strains, and they can be used as a basis for creating biodegradable wound healing dressings with a prolonged antibacterial effect. chitosan, silver nanoparticles, antibacterial activity, wound dressings This work was supported by the "Russian Academic Excellence Project 5-100". The study was carried out with the financial support of the Russian Foundation for Basic Research in the framework of the Scientific Project no. 18-29-18039.


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