Modeling of Shape-Memory Recovery in Crosslinked Semicrystalline Polymers

2012 ◽  
Vol 77 ◽  
pp. 319-324 ◽  
Author(s):  
Igor Kolesov ◽  
Oleksandr Dolynchuk ◽  
Hans Joachim Radusch
Keyword(s):  
Shape Memory ◽  
Crosslink Density ◽  
Polymer Network ◽  
Thermally Induced ◽  
Crosslinked Polymer ◽  
Memory Recovery ◽  
Recovery Strain ◽  
Crystallizable Polymer ◽  
Temperature Dependences ◽  
Constant Heating

In present work a new theoretical approach based on the modified three-element Eyring-Halsey mechanical model was used for the derivation of an equation, which describes the thermally-induced recovery of preloaded covalently crosslinked polymer. This approach takes into account the influence of crystallizable polymer network as well as of entangled slipped molecular chains. Modeling of the temperature dependences of shape-memory (SM) recovery strain and SM recovery rate detected at constant heating rate has been performed for three types of polyethylene with sufficiently different crystallinity and crosslink density at programming strain of 100%. The results of modeling agree well with the experimental data. The values of material parameters determined by fitting correspond satisfactorily to the estimations existing in literature. It is shown that the contribution of the entangled slipped molecules to the total stored SM strain increases with increasing degree of branching and crosslink density. The physical sense of main fitting parameters and their dependences on the material constants such as crystallinity are discussed.

Freeze-etch TEM of aqueous polymer gel network morphology

1986 ◽  
Vol 44 ◽  
pp. 796-797
Author(s):  
J. A. N. Zasadzinski ◽  
R. K. Prud'homme
Keyword(s):  
Metal Ion ◽  
Polymer Network ◽  
Polymer Gels ◽  
Polymer Gel ◽  
Deformation History ◽  
Crosslinked Polymer ◽  
Aqueous Polymer ◽  
History Of ◽  
Gel Network ◽  
Network Morphology

The rheological and mechanical properties of crosslinked polymer gels arise from the structure of the gel network. In turn, the structure of the gel network results from: thermodynamically determined interactions between the polymer chain segments, the interactions of the crosslinking metal ion with the polymer, and the deformation history of the network. Interpretations of mechanical and rheological measurements on polymer gels invariably begin with a conceptual model of,the microstructure of the gel network derived from polymer kinetic theory. In the present work, we use freeze-etch replication TEM to image the polymer network morphology of titanium crosslinked hydroxypropyl guars in an attempt to directly relate macroscopic phenomena with network structure.

scholarly journals Thermally-Induced Shape-Memory Behavior of Degradable Gelatin-Based Networks

2021 ◽  
Vol 22 (11) ◽  
pp. 5892
Author(s):  
Axel T. Neffe ◽  
Candy Löwenberg ◽  
Konstanze K. Julich-Gruner ◽  
Marc Behl ◽  
Andreas Lendlein
Keyword(s):  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Shape Recovery ◽  
Polymer Networks ◽  
Water Soluble ◽  
Compression Tests ◽  
Thermally Induced ◽  
Thermomechanical Process ◽  
Triple Helices

Shape-memory hydrogels (SMH) are multifunctional, actively-moving polymers of interest in biomedicine. In loosely crosslinked polymer networks, gelatin chains may form triple helices, which can act as temporary net points in SMH, depending on the presence of salts. Here, we show programming and initiation of the shape-memory effect of such networks based on a thermomechanical process compatible with the physiological environment. The SMH were synthesized by reaction of glycidylmethacrylated gelatin with oligo(ethylene glycol) (OEG) α,ω-dithiols of varying crosslinker length and amount. Triple helicalization of gelatin chains is shown directly by wide-angle X-ray scattering and indirectly via the mechanical behavior at different temperatures. The ability to form triple helices increased with the molar mass of the crosslinker. Hydrogels had storage moduli of 0.27–23 kPa and Young’s moduli of 215–360 kPa at 4 °C. The hydrogels were hydrolytically degradable, with full degradation to water-soluble products within one week at 37 °C and pH = 7.4. A thermally-induced shape-memory effect is demonstrated in bending as well as in compression tests, in which shape recovery with excellent shape-recovery rates Rr close to 100% were observed. In the future, the material presented here could be applied, e.g., as self-anchoring devices mechanically resembling the extracellular matrix.

New star-shape memory polyurethanes capable of thermally induced recovery and hydrogen bond-self-healing

2021 ◽  
Author(s):  
Zonghui Huang ◽  
Jianfeng Ban ◽  
Lulu Pan ◽  
Shuqing Cai ◽  
Junqiu Liao
Keyword(s):  
Hydrogen Bond ◽  
Shape Memory ◽  
Self Healing ◽  
Thermally Induced ◽  
Thermally Responsive

Star-shape memory polyurethanes that combine thermally responsive and self-healing properties.

scholarly journals Shape memory polymer network with thermally distinct elasticity and plasticity

2016 ◽  
Vol 2 (1) ◽  
pp. e1501297 ◽  
Author(s):  
Qian Zhao ◽  
Weike Zou ◽  
Yingwu Luo ◽  
Tao Xie
Keyword(s):  
Shape Memory ◽  
Molecular Design ◽  
Shape Change ◽  
Shape Memory Polymer ◽  
Polymer Network ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Device Applications ◽  
Temperature Ranges ◽  
Rational Molecular Design

Stimuli-responsive materials with sophisticated yet controllable shape-changing behaviors are highly desirable for real-world device applications. Among various shape-changing materials, the elastic nature of shape memory polymers allows fixation of temporary shapes that can recover on demand, whereas polymers with exchangeable bonds can undergo permanent shape change via plasticity. We integrate the elasticity and plasticity into a single polymer network. Rational molecular design allows these two opposite behaviors to be realized at different temperature ranges without any overlap. By exploring the cumulative nature of the plasticity, we demonstrate easy manipulation of highly complex shapes that is otherwise extremely challenging. The dynamic shape-changing behavior paves a new way for fabricating geometrically complex multifunctional devices.

Polymer design for high temperature shape memory: Low crosslink density polyimides

Polymer ◽  
2013 ◽  
Vol 54 (1) ◽  
pp. 391-402 ◽  
Author(s):  
Hilmar Koerner ◽  
Robert J. Strong ◽  
Matthew L. Smith ◽  
David H. Wang ◽  
Loon-Seng Tan ◽  
...  
Keyword(s):  
High Temperature ◽  
Shape Memory ◽  
Crosslink Density

A phenomenological model for thermally-induced hysteresis in polycrystalline shape memory alloys with internal loops

2021 ◽  
pp. 1045389X2110482
Author(s):  
Yuxiang Han ◽  
Haoyuan Du ◽  
Linxiang Wang ◽  
Roderick Melnik
Keyword(s):  
Shape Memory Alloys ◽  
Single Crystal ◽  
Shape Memory ◽  
Phenomenological Model ◽  
Landau Theory ◽  
Thermally Induced ◽  
First Order ◽  
Proposed Model ◽  
Crystal Model ◽  
Hysteretic Response

In the current study, a 1-D phenomenological model is constructed to capture the temperature-induced hysteretic response in polycrystalline shape memory alloys (SMAs). The martensitic and austenitic transformations are regarded as the first-order transitions. A differential single-crystal model is formulated on the basis of Landau theory. It is assumed that the transformation temperatures follow the normal distribution among the grains due to the anisotropic stress field developed in the material. The polycrystalline hysteretic response is expressed as the integration of single-crystal responses. Besides, the prediction strategy for incomplete transitions is presented, and the first-order reversal curves are obtained via density reassignment. The proposed model is numerically implemented for validation. Comparisons between the modeling results and the experimental ones demonstrate the capability of the proposed model in addressing the hysteresis in thermally-induced phase transformations.

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