Investigation of Fiber-Reinforced Modified Epoxy Resin Composites

2012 ◽  
Vol 510-511 ◽  
pp. 577-584 ◽  
Author(s):  
A. Quddos ◽  
Mohammad Bilal Khan ◽  
R.N. Khan ◽  
M.K.K. Ghauri

The impregnation of the fiber with a resin system, the polymeric matrix with the interface needs to be properly cured so that the dimensional stability of the matrix and the composite is ensured. A modified epoxy resin matrix was obtained with a reactive toughening agent and anhydride as a curing agent. The mechanical properties of the modified epoxy matrix and its fiber reinforced composites were investigated systematically. The polymeric matrix possessed many good properties, including high strength, high elongation at break, low viscosity, long pot life at room temperature, and good water resistance. The special attentions are given to the matrix due to its low out gassing, low water absorption and radiation resistance. In addition, the fiber-reinforced composites showed a high strength conversion ratio of the fiber and good fatigue resistance. The dynamic and static of the composite material were studied by thermo gravimetric analysis (TGA), Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM) with EDX. The influences of processing technique such as curing and proper mixing on the mechanical and interfacial properties were determined. The results demonstrated that the modified epoxy resin matrix is very suitable for applications in products fabricated with fiber-reinforced composites.

2020 ◽  
Vol 10 (3) ◽  
pp. 1159 ◽  
Author(s):  
Yingmei Xie ◽  
Hiroki Kurita ◽  
Ryugo Ishigami ◽  
Fumio Narita

Epoxy resins are a widely used common polymer due to their excellent mechanical properties. On the other hand, cellulose nanofiber (CNF) is one of the new generation of fibers, and recent test results show that CNF reinforced polymers have high mechanical properties. It has also been reported that an extremely low CNF addition increases the mechanical properties of the matrix resin. In this study, we prepared extremely-low CNF (~1 wt.%) reinforced epoxy resin matrix (epoxy-CNF) composites, and tried to understand the strengthening mechanism of the epoxy-CNF composite through the three-point flexural test, finite element analysis (FEA), and discussion based on organic chemistry. The flexural modulus and strength were significantly increased by the extremely low CNF addition (less than 0.2 wt.%), although the theories for short-fiber-reinforced composites cannot explain the strengthening mechanism of the epoxy-CNF composite. Hence, we propose the possibility that CNF behaves as an auxiliary agent to enhance the structure of the epoxy molecule, and not as a reinforcing fiber in the epoxy resin matrix.


2015 ◽  
Vol 466 ◽  
pp. 100-107 ◽  
Author(s):  
Ran Li ◽  
Yizhuo Gu ◽  
Zhongjia Yang ◽  
Min Li ◽  
Shaokai Wang ◽  
...  

Author(s):  
Vijay Kumar Mahakur ◽  
Sumit Bhowmik ◽  
Promod Kumar Patowari

Nowadays, the utilization of natural fiber reinforced composite has increased frequently. These natural fibers have significant features like low cost, renewable, and, more importantly, biodegradable in nature, making them to be utilized for various industrial sectors. However, the massive demand for natural fiber reinforced composites (NFRC), forces them to be machined and operated, which is required for countless areas in multiple industries like automotive, marine, aerospace and constructions. But before obtaining the final shape of any specimen, this specimen should come across numerous machining processes to get the desired shape and structure. Therefore, the present review paper focused on the various aspects during conventional and unconventional machining of the NFRC. It covers the work by exploring the influence of all input variables on the outcome produced after machining the NFRC. Various methodologies and tools are also discussed in this article for reducing the machining defects. The machining of the NFRC is found as a challenging task due to insufficient interlocking between the matrix and fibers, and minimum knowledge in machining characteristics and appropriate input parameters. Thus, this review is trying to assist the readers to grasp a basic understanding and information during the machining of the NFRC in every aspect.


Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 842 ◽  
Author(s):  
Weiwei Zhang ◽  
Jin Gu ◽  
Dengyun Tu ◽  
Litao Guan ◽  
Chuanshuang Hu

Paper fibers have gained broad attention in natural fiber reinforced composites in recent years. The specific problem in preparing paper fiber reinforced composites is that paper fibers easily become flocculent after pulverization, which increases difficulties during melt-compounding with polymer matrix and results in non-uniform dispersion of paper fibers in the matrix. In this study, old newspaper (ONP) was treated with a low dosage of gaseous methyltrichlorosilane (MTCS) to solve the flocculation. The modified ONP fibers were characterized by Scanning Electron Microscope (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and Thermogravimetric Analysis (TG). Then the modified ONP fibers and high-density polyethylene (HDPE) were extruded and pelletized to prepare ONP/HDPE composites via injection molding. Maleic anhydride-grafted polyethylene (MAPE) was added to enhance the interfacial bonding performance with the ultimate purpose of improving the mechanical strength of the composites. The mechanical properties such as tensile, flexural, and impact strength and the water absorption properties of the composite were tested. The results showed that the formation of hydrogen bonding between ONP fibers was effectively prevented after MTCS treatment due to the reduction of exposed –OH groups at the fiber surface. Excessive dosage of MTCS led to severe fiber degradation and dramatically reduced the aspect ratio of ONP fibers. Composites prepared with ONP fibers modified with 4% (v/w) MTCS showed the best mechanical properties due to reduced polarity between the fibers and the matrix, and the relatively long aspect ratio of treated ONP fibers. The composite with or without MAPE showed satisfactory water resistance properties. MTCS was proven to be a cheap and efficient way to pretreat old newspaper for preparing paper fiber reinforced composites.


Author(s):  
Md. Nizam Uddin ◽  
Louie Le ◽  
Rajeev Nair ◽  
Ramazan Asmatulu

A polymer matrix system of thermoset fiber-reinforced composites helps protect its high modulus and strength fibers from an adverse environment and transfers the load to the reinforced fibers. However, when subjected to a high temperature that exceeds its postcuring-stage temperature, the polymeric matrix will decompose or be charred. To address this issue, various techniques have been developed to improve the flame-retardant property of the polymeric matrix. One of these techniques is to either delay ignition or release moisture to extinguish the flame by combining other chemicals or reactively modifying the epoxy resin. Graphene oxide (GO) nanofilms deposited on top of composite surfaces were compared with the test results of nanocomposite coatings of GO and nanoclay particles on composite surfaces. GO thin film applied to the surface of fiber-reinforced composites acts as a heat shield to quickly dissipate heat and eliminate local heat formation. Thermal tests, such as thermogravimetric analysis (TGA), 45-deg burn tests, vertical burn tests, and surface paint adhesion tests were accomplished. Average burn lengths and the average burn areas were reduced with nanoparticle inclusion to the nanoclay samples and graphene samples. TGA analysis indicated that the nanoclay inclusion samples, as well as the graphene inclusion samples, have a higher percentage weight loss than that of the base sample. GO inclusion samples were less affected than nanoclay inclusion samples during the vertical as well as 45-deg burn tests. In addition, there were no signs of damage to the GO thin film that was secondarily bonded to the surface of composite panels for the burn test.


2019 ◽  
Vol 54 (8) ◽  
pp. 1031-1048 ◽  
Author(s):  
Yang Yang ◽  
Qi He ◽  
Hong-Liang Dai ◽  
Jian Pang ◽  
Liang Yang ◽  
...  

A micromechanical model for short fiber-reinforced composites (SFRCs) with functionally graded interphases and a systematic prediction scheme to determine the effective properties are presented. The matrix and the fibers are regarded to be linear elastic, isotropic, and homogeneous. Fibers are assumed to be ellipsoids coated perfectly by functionally graded interphases, which is supposed to be formed chemically or physically by the constituents near the interface. First, to analyze the grading interphase effect, layer-wise concept is followed to divide the functionally graded interphases into multi-homogeneous sub-layers. Next, to take the effect of functionally graded interphases into account, a combination of multi-inclusion method and Mori–Tanaka method is applied to predict effective elastic properties of this unidirectional SFRCs with respect to the content and aspect ratio of the inclusions. By employing coordinate transformation, spatially elastic moduli are obtained. Finally, Voigt homogenization scheme is used to obtain the overall, averaged, symmetrical elastic properties of the SFRCs. Numerical examples and analyses demonstrate the applicability of the proposed method and indicate the influences of graded interphase, orientation, and aspect ratio of inclusions as well as properties and contents of the constituents on the overall properties of SFRCs.


Author(s):  
Xiaochun Wang

There are many methods on computation of transverse elastic properties of unidirectional fiber-reinforced composites when using the finite element method, such as three-dimension model, two-dimension plane strain model, unit cell model, etc[1]. But unit cell models could be used only when the fibers are arrayed regularly. The computations of three- and two-dimension plane strain models are tremendous when many fine fibers are spread randomly in the matrix so that the properties of block of composite must be computed. The paper proposes a new embedded-zone method to compute the transverse elastic properties for a block of fiber-reinforced composites containing a great amount of fibers embedded in the matrix stochastically while using very little computational work compared with three- and two-dimension plane strain model. The transverse elastic modulus and shear modulus of unidirectional fiber-reinforced composites are computed.


1989 ◽  
Vol 170 ◽  
Author(s):  
King H. Lo ◽  
Robert W. Schmitz ◽  
William G. Gottenberg

AbstractThe influence of flexible interlayers/interphases on the performance of unidirectional fiber reinforced composites is studied. Micromechanical analysis based on the embedded composite cylinders model is used to study the stiffness as well as the internal stress distributions within the matrix phase of composites. Based on the results of the analysis, a criterion is proposed for the selection of optimal interlayer thickness for fiber composites. The proposed criterion gives results which seem to correlate well with the experimental data published in the literature.


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