Effect of Colloidal Nano-Silica on the Mechanical and Durability Performances of Mortar

2014 ◽  
Vol 629-630 ◽  
pp. 443-448 ◽  
Author(s):  
Hong Jian Du ◽  
Sze Dai Pang

s. The mechanical and durability properties of cement mortars with colloidal nanosilica (CNS) were investigated experimentally. Reference mortar with a low water-to-cement ratio of 0.30 was used in this study. The influence of CNS was evaluated by adding 0.5, 1.0, 1.5 and 2.0% of CNS by weight of cement. CNS was first stirred in the mixing water for 2 minutes before added to cement and sand. Superplasticizer was used to maintain the same flowability. Results showed that the compressive strength consistently increases with higher dosage of CNS at all the curing ages, due to both hydration acceleration and pozzolanic reaction. With the increase in CNS, the migration coefficient and water sorptivity consistently decreased; with 2% of CNS, the migration coefficient and water sorptivity were reduced by 45% and 30% respectively in comparison with the reference mortar. The improved durability could be explained by the reduction and refinement in the porosity, which can be attributed to nanofiller effect and pozzolanic reaction of nanosilica. Furthermore, the addition of CNS could reduce the drying shrinkage by densifying the microstructure in the cement paste, which has not been reported previously.

2019 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
N. SCHWANTES-CEZARIO ◽  
M. F. PORTO ◽  
G. F. B. SANDOVAL ◽  
G. F. N. NOGUEIRA ◽  
A. F. COUTO ◽  
...  

Abstract This study aims to evaluate the influence of B. subtilis AP91 spores addition on the mechanical properties of mortars. B. subtilis strain AP91, isolated from rice leaves of the needle variety, which has an early cycle of production, was used at the concentration of 105 spores/mL in mortars with cement-to-sand ratio of 1:3 (by weight) and water-to-cement ratio (w/c) of 0.63. These spores were added in two different ways: in the mixing water and by immersion in a solution containing bacterial spores. Scanning Electron Microscope (SEM) analysis showed crystals with calcium peaks on the EDS, which possibly indicates the presence of bioprecipitated calcium carbonate. The results obtained in the mechanical analysis showed that the bioprecipitation of CaCO3 by B. subtilis strain AP91 was satisfactory, particularly when the spores were added in the mixing water, increasing the compressive strength up to 31%. Thus, it was concluded that the addition of B. subtilis AP91 spores in the mixing water of cement mortars induced biocementation, which increased the compressive strength. This bioprecipitation of calcium carbonate may very well have other advantageous consequences, such as the closure of pores and cracks in cementitious materials that could improve durability properties, although more research is still needed on this matter.


2010 ◽  
Vol 168-170 ◽  
pp. 190-194 ◽  
Author(s):  
Zhen Jun Wang ◽  
Rui Wang ◽  
Yu Bin Cheng

In this paper, styrene-butadiene polymer emulsion SD622S was adopted to modify cement mortar; mechanical properties of cement mortars were studied and microstructures was analyzed by means of Scanning Electron Microscope (SEM) and Specific Surface Area & Pore Distribution Analyzer. The results show that in contrast to ordinary cement mortar, if water to cement ratio (W/C) is constant, compressive strength of modified cement mortar can decrease, while flexural strength and toughness, ratio of compressive strength to flexural strength, increase with the increase of polymer to cement ratio in mass (P/C) at 7 and 28 curing days. With the increase of P/C, net structure made from polymer and cement hydration products is developed and pore whose size is smaller than 200Å begins to increase, which indicates pore diameters in modified cement mortar change to be finer. So microstructures of modified cement mortar become denser and display higher toughness.


Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1619 ◽  
Author(s):  
Yawen Tan ◽  
Huaxin Chen ◽  
Zhendi Wang ◽  
Cheng Xue ◽  
Rui He

Modified cement mortar was prepared by incorporating a superabsorbent polymer (SAP) with two kinds of dosing state, dry powdery SAP and swelled SAP (where the SAP has been pre-wetted in tap water), respectively. The mechanical properties, drying shrinkage and freeze–thaw resistance of the mortars were compared and analyzed with the variation of SAP content and entrained water-to-cement ratios. Additionally, the effect of SAP on the microstructure of mortar was characterized by scanning electron microscopy (SEM). The results indicate that agglomerative accumulation is formed in the voids of mortar after water desorption from SAP and there are abundant hydration products, most of which are C-S-H gels, around the SAP voids. The incorporation of the powdery SAP increases the 28 d compressive strength of the mortars by about 10% to 50%, while for the incorporation of swelled SAP, the 28 d compressive strength of the mortar can be increased by about −26% to 6%. At a dosage of 0.1% SAP and an entrained water–cement ratio of 0.06, the powdery SAP and the swelled SAP can reduce the mortar shrinkage rate by about 32.2% and 14.5%, respectively. Both the incorporation of powdery and swelled SAP has a positive effect on the freeze–thaw resistance of cement mortar. In particular, for powdery SAP with an entrained water-to-cement ratio of 0.06, the mass loss rate after 300 cycles is still lower than 5%.


2015 ◽  
Vol 95 ◽  
pp. 636-646 ◽  
Author(s):  
Nima Farzadnia ◽  
Hossein Noorvand ◽  
Abdirahman Mohamed Yasin ◽  
Farah Nora A. Aziz

2021 ◽  
Vol 888 ◽  
pp. 67-75
Author(s):  
Ariel Verzosa Melendres ◽  
Napoleon Solo Dela Cruz ◽  
Araceli Magsino Monsada ◽  
Rolan Pepito Vera Cruz

Chloride ingress into concrete from the surrounding environment can result in the corrosion of the embedded steel reinforcement and cause damage to the concrete. Superabsorbent polymer (SAP) with fine particle size was incorporated into the structure of concrete for controlling the chloride ingress and improving its compressive strength via promotion of internal curing. The SAP used in this study was evaluated for its absorbency property when exposed to cementitious environment such as aqueous solution of Ca (OH)2 and cement slurry. The results were compared to that in sodium chloride solution, the environment where absorbency of most of the SAP found in the market are well studied. Results showed that although SAP absorbency decreased with increasing concentration of Ca (OH)2 and cement, the results suggest that water containing cementitious materials are able to be absorbed by SAP. Chloride ingress into 28-day cured concrete specimens were determined using Rapid Chloride Penetration Test (RCPT) method employing 60V DC driving force. Concrete samples with size of 50 mm height x 100 mm diameter were prepared using a M25 mix design with 0.4 and 0.45 water to cement ratios and different percentages of SAP such as 0.05%, 0.1% and 0.15% with respect to cement mass. Results showed that concrete with 0.15% SAP gave the best result with 14% less chloride permeability than concrete with no SAP for a 0.4 water to cement ratio. Concrete samples for compressive strength tests with size of 200 mm height x 100 mm diameter were prepared using the same mix design and percentages of SAP and cured for 28 days. Results showed that the best results for compressive strength was found at 0.1% SAP at a 0.4 water to cement ratio which can be attributed to internal curing provided by SAP.


2018 ◽  
Vol 203 ◽  
pp. 06001
Author(s):  
Muhammad Bilal Waris ◽  
Hussain Najwani ◽  
Khalifa Al-Jabri ◽  
Abdullah Al-Saidy

To manage tyre waste and conserve natural aggregate resource, this research investigates the use of waste tyre rubber as partial replacement of fine aggregates in non-structural concrete. The research used Taguchi method to study the influence of mix proportion, water-to-cement ratio and tyre rubber replacement percentage on concrete. Nine mixes were prepared with mix proportion of 1:2:4, 1:5:4 and 1:2.5:3; water-to-cement ratio of 0.25, 0.35 and 0.40 and rubber to fine aggregate replacement of 20%, 30% and 40%. Compressive strength and water absorption tests were carried out on 100 mm cubes. Compressive strength was directly proportional to the amount of coarse aggregate in the mix. Water-to-cement ratio increased the strength within the range used in the study. Strength was found to be more sensitive to the overall rubber content than the replacement ratio. Seven out of the nine mixes satisfied the minimum strength requirement for concrete blocks set by ASTM. Water absorption and density for all mixes satisfied the limits applicable for concrete blocks. The study indicates that mix proportions with fine to coarse aggregate ratio of less than 1.0 and w/c ratio around 0.40 can be used with tyre rubber replacements of up to 30 % to satisfy requirements for non-structural concrete.


2013 ◽  
Vol 795 ◽  
pp. 664-668 ◽  
Author(s):  
Roshasmawi Abdul Wahab ◽  
Mohd Noor Mazlee ◽  
Shamsul Baharin Jamaludin ◽  
Khairul Nizar Ismail

In this study, the mixing of polystyrene (PS) beads and fly ash as a sand replacement material in foamed cement composites (FCC) has been investigated. Specifically, the mechanical properties such as compressive strength and flexural strength were measured. Different proportions of fly ash were added in cement composites to replace the sand proportion at 3 wt. %, 6 wt. %, 9 wt. % and 12 wt. % respectively. The water to cement ratio was fixed at 0.65 meanwhile ratios of PS beads used was 0.25 volume percent of samples as a foaming agent. All samples at different mixed were cured at 7 and 28 days respectively. Based on the results of compressive strength, it was found that the compressive strength was increased with the increasing addition of fly ash. Meanwhile, flexural strength was decreased with the increasing addition of fly ash up to 9 wt. %. The foamed cement composites with 12 wt. % of fly ash produced the highest strength of compressive strength meanwhile 3 wt. % of fly ash produced the highest strength of flexural strength.


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