Influence of Hot Corrosion on Local Mechanical Properties of HVOF Sprayed Coating Based on NiCrBSi Alloy

2015 ◽  
Vol 662 ◽  
pp. 123-126
Author(s):  
Jan Schubert ◽  
Zdeněk Česánek ◽  
Olga Bláhová

Ongoing increase in demands on efficiency of power plants and other facilities leads to increased interest of new progressive materials and technologies. One of the modern methods which lead to enhancement of surface properties is application of coatings on surface of components composed of less quality materials. Commonly used methods protecting components are based on some form of heat treatment. The current pressure on increasing operating temperatures for enhanced performance of steam turbines caused elevation of operating temperature at limit of the applicability of commonly used protections. From this reasons the demand for using an alternative technologies which would provide such a desired protection rises rapidly. One of the key areas of protection in such environment is protection against hot temperature corrosion. Possible solution can be found in application of coatings based on alloys and cermets prepared by HVOF technology. This paper examines local mechanical and microstructural properties of NiCrBSi coating after exposition to extremely severe hot corrosion environment. Furthermore, the nanoindentation measurements of NiCrBSi coating were performed before and after the corrosion test. In this case the mixture of salts composed from 59% Na2(SO)4 with 34.5% KCl and 6.5% NaCl was used. Temperature of test was set on 525°C and 575°C. Duration of exposition to hot corrosion environment was 168 hours in autoclave.

2018 ◽  
Vol 784 ◽  
pp. 141-146
Author(s):  
Jan Schubert ◽  
Zdeněk Česánek ◽  
Olga Bláhová

Current development in power generation industry leads to search of new technologies and ways how to protect surface against aggressive corrosion environment. Suitable method leading to enhancement of surface properties is application of protective coatings on surface. This approach allows to use components composed from less quality materials. The current development in steam turbines leads to increasing operating temperatures for the purpose to enhance performance. This process results in elevation of operating temperature reaching the potential limits of commonly used materials. One of the key areas of protection in such environment is protection against hot temperature corrosion. Possible solution can be found in application of coatings based on alloys and cermets prepared by HVOF (High Velocity Oxygen Fuel) technology. This paper examines local mechanical and microstructural properties of Cr3C2-25%NiCr coating after exposition to extremely severe hot corrosion environment. Furthermore, the nanoindentation measurements of this coating were performed before and after the corrosion test. The test environment composition was based on mixture of salts 59% Na2SO4 with 34.5% KCl and 6.5% NaCl. Test temperature was 525°C and 575°C. Duration of the exposition to hot corrosion environment was 168 hours in autoclave. The results confirmed that the coating matrix is deteriorated during the exposition to such aggressive environment. The deterioration is localized at surface of coating and is characterized by creation of oxide layer which decreases the speed further speed of matrix dissolution and stabilizes the coating.


2021 ◽  
Vol 11 (9) ◽  
pp. 3910
Author(s):  
Saba Shirin ◽  
Aarif Jamal ◽  
Christina Emmanouil ◽  
Akhilesh Kumar Yadav

Acid mine drainage (AMD) occurs naturally in abandoned coal mines, and it contains hazardous toxic elements in varying concentrations. In the present research, AMD samples collected from an abandoned mine were treated with fly ash samples from four thermal power plants in Singrauli Coalfield in the proximate area, at optimized concentrations. The AMD samples were analyzed for physicochemical parameters and metal content before and after fly ash treatment. Morphological, geochemical and mineralogical characterization of the fly ash was performed using SEM, XRF and XRD. This laboratory-scale investigation indicated that fly ash had appreciable neutralization potential, increasing AMD pH and decreasing elemental and sulfate concentrations. Therefore, fly ash may be effectively used for AMD neutralization, and its suitability for the management of coalfield AMD pits should be assessed further.


Author(s):  
Yifan Wu ◽  
Wei Li ◽  
Deren Sheng ◽  
Jianhong Chen ◽  
Zitao Yu

Clean energy is now developing rapidly, especially in the United States, China, the Britain and the European Union. To ensure the stability of power production and consumption, and to give higher priority to clean energy, it is essential for large power plants to implement peak shaving operation, which means that even the 1000 MW steam turbines in large plants will undertake peak shaving tasks for a long period of time. However, with the peak load regulation, the steam turbines operating in low capacity may be much more likely to cause faults. In this paper, aiming at peak load shaving, a fault diagnosis method of steam turbine vibration has been presented. The major models, namely hierarchy-KNN model on the basis of improved principal component analysis (Improved PCA-HKNN) has been discussed in detail. Additionally, a new fault diagnosis method has been proposed. By applying the PCA improved by information entropy, the vibration and thermal original data are decomposed and classified into a finite number of characteristic parameters and factor matrices. For the peak shaving power plants, the peak load shaving state involving their methods of operation and results of vibration would be elaborated further. Combined with the data and the operation state, the HKNN model is established to carry out the fault diagnosis. Finally, the efficiency and reliability of the improved PCA-HKNN model is discussed. It’s indicated that compared with the traditional method, especially handling the large data, this model enhances the convergence speed and the anti-interference ability of the neural network, reduces the training time and diagnosis time by more than 50%, improving the reliability of the diagnosis from 76% to 97%.


2016 ◽  
Vol 254 ◽  
pp. 231-236 ◽  
Author(s):  
Ion Dragoş Uţu ◽  
Gabriela Marginean ◽  
Iosif Hulka ◽  
Viorel Aurel Şerban

Microstructure and wear properties of the Al2O3-13.wt% TiO2 thermally sprayed coatings before and after remelting were investigated in this study. The coatings were deposited on a pure titanium substrate using the atmospheric plasma spraying (APS) process. The as-sprayed coatings were electron beam (EB) modified in order to improve their compactness and bonding strength.The effect of EB remelting on the microstructure, phase constituents and wear properties was investigated using scanning electron microscopy (SEM), X-Ray diffraction technique and hardness measurements. The sliding wear behavior was tested using a pin on disk method.The results showed that the remelting process had a positive effect removing the lamellar defect of the as-sprayed coating and improving the compactness, hardness and wear behavior.


2009 ◽  
Vol 289-292 ◽  
pp. 413-420 ◽  
Author(s):  
F.J. Bolívar ◽  
L. Sánchez ◽  
M.P. Hierro ◽  
F.J. Pérez

The development of new power generation plants firing fossil fuel is aiming at achieving higher thermal efficiencies of the energy conversion process. The major factors affecting the efficiency of the conventional steam power plants are the temperature and, to a lesser extent, the pressure of the steam entering the turbine. The increased operating temperature and pressure require new materials that have major oxidation resistance. Due to this problem, in the last years numerous studies have been conducted in order to develop new coatings to enhance the resistance of steels with chromium contents between 9 and 12% wt against steam oxidation in order to allow operation of steam turbines at 650 0C. In this study, Si protective coatings were deposited by CVD-FBR on ferritic steel P-91. These type of coatings have shown to be protective at 650 0C under steam for at least 3000 hours of laboratory steam exposure under atmospheric pressure. Morphology and composition of coatings were characterized by different techniques, such as scanning electron microscopy (SEM), electron probe microanalysis, and X-ray diffraction (XRD). The results show a substantial increase of steam oxidation protection afforded by Si coating by CVD-FBR process.


Author(s):  
Andreas Pickard

At the start of this new century, environmental regulations and free-market economics are becoming the key drivers for the electricity generating industry. Advances in Gas Turbine (GT) technology, allied with integration and refinement of Heat Recovery Steam Generators (HRSG) and Steam Turbine (ST) plant, have made Combined Cycle installations the most efficient of the new power station types. This potential can also be realized, to equal effect, by adding GT’s and HRSG’s to existing conventional steam power plants in a so-called ‘repowering’ process. This paper presents the economical and environmental considerations of retrofitting the steam turbine within repowering schemes. Changing the thermal cycle parameters of the plant, for example by deletion of the feed heating steambleeds or by modified live and reheat steam conditions to suit the combined cycle process, can result in off-design operation of the existing steam turbine. Retrofitting the steam turbine to match the combined cycle unit can significantly increase the overall cycle efficiency compared to repowering without the ST upgrade. The paper illustrates that repowering, including ST retrofitting, when considered as a whole at the project planning stage, has the potential for greater gain by allowing proper plant optimization. Much of the repowering in the past has been carried out without due regard to the benefits of re-matching the steam turbine. Retrospective ST upgrade of such cases can still give benefit to the plant owner, especially when it is realized that most repowering to date has retained an unmodified steam turbine (that first went into operation some decades before). The old equipment will have suffered deterioration due to aging and the steam path will be to an archaic design of poor efficiency. Retrofitting older generation plant with modern leading-edge steam-path technology has the potential for realizing those substantial advances made over the last 20 to 30 years. Some examples, given in the paper, of successfully retrofitted steam turbines applied in repowered plants will show, by specific solution, the optimization of the economics and benefit to the environment of the converted plant as a whole.


Author(s):  
Kevin Cremanns ◽  
Dirk Roos ◽  
Simon Hecker ◽  
Peter Dumstorff ◽  
Henning Almstedt ◽  
...  

The demand for energy is increasingly covered through renewable energy sources. As a consequence, conventional power plants need to respond to power fluctuations in the grid much more frequently than in the past. Additionally, steam turbine components are expected to deal with high loads due to this new kind of energy management. Changes in steam temperature caused by rapid load changes or fast starts lead to high levels of thermal stress in the turbine components. Therefore, todays energy market requires highly efficient power plants which can be operated under flexible conditions. In order to meet the current and future market requirements, turbine components are optimized with respect to multi-dimensional target functions. The development of steam turbine components is a complex process involving different engineering disciplines and time-consuming calculations. Currently, optimization is used most frequently for subtasks within the individual discipline. For a holistic approach, highly efficient calculation methods, which are able to deal with high dimensional and multidisciplinary systems, are needed. One approach to solve this problem is the usage of surrogate models using mathematical methods e.g. polynomial regression or the more sophisticated Kriging. With proper training, these methods can deliver results which are nearly as accurate as the full model calculations themselves in a fraction of time. Surrogate models have to face different requirements: the underlying outputs can be, for example, highly non-linear, noisy or discontinuous. In addition, the surrogate models need to be constructed out of a large number of variables, where often only a few parameters are important. In order to achieve good prognosis quality only the most important parameters should be used to create the surrogate models. Unimportant parameters do not improve the prognosis quality but generate additional noise to the approximation result. Another challenge is to achieve good results with as little design information as possible. This is important because in practice the necessary information is usually only obtained by very time-consuming simulations. This paper presents an efficient optimization procedure using a self-developed hybrid surrogate model consisting of moving least squares and anisotropic Kriging. With its maximized prognosis quality, it is capable of handling the challenges mentioned above. This enables time-efficient optimization. Additionally, a preceding sensitivity analysis identifies the most important parameters regarding the objectives. This leads to a fast convergence of the optimization and a more accurate surrogate model. An example of this method is shown for the optimization of a labyrinth shaft seal used in steam turbines. Within the optimization the opposed objectives of minimizing leakage mass flow and decreasing total enthalpy increase due to friction are considered.


Author(s):  
Deqi Yu ◽  
Jiandao Yang ◽  
Wei Lu ◽  
Daiwei Zhou ◽  
Kai Cheng ◽  
...  

The 1500-r/min 1905mm (75inch) ultra-long last three stage blades for half-speed large-scale nuclear steam turbines of 3rd generation nuclear power plants have been developed with the application of new design features and Computer-Aided-Engineering (CAE) technologies. The last stage rotating blade was designed with an integral shroud, snubber and fir-tree root. During operation, the adjacent blades are continuously coupled by the centrifugal force. It is designed that the adjacent shrouds and snubbers of each blade can provide additional structural damping to minimize the dynamic stress of the blade. In order to meet the blade development requirements, the quasi-3D aerodynamic method was used to obtain the preliminary flow path design for the last three stages in LP (Low-pressure) casing and the airfoil of last stage rotating blade was optimized as well to minimize its centrifugal stress. The latest CAE technologies and approaches of Computational Fluid Dynamics (CFD), Finite Element Analysis (FEA) and Fatigue Lifetime Analysis (FLA) were applied to analyze and optimize the aerodynamic performance and reliability behavior of the blade structure. The blade was well tuned to avoid any possible excitation and resonant vibration. The blades and test rotor have been manufactured and the rotating vibration test with the vibration monitoring had been carried out in the verification tests.


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