Influence of Agitation Equipment on Reinforcing Effect and Dispersion State of Cellulose Nano-Fibers in Natural Rubber

2017 ◽  
Vol 754 ◽  
pp. 23-26
Author(s):  
Sho Omori ◽  
Takayuki Morita ◽  
Koki Matsumoto ◽  
Asahiro Nagatani ◽  
Tatsuya Tanaka
Keyword(s):  
Carbon Black ◽  
Natural Rubber ◽  
Reinforcing Effect ◽  
X Ray ◽  
Centrifugal Mixer ◽  
Vulcanized Rubber ◽  
Biomass Resource ◽  
Dispersion State ◽  
Biomass Resources ◽  
Internal Mixer

There are many rubber products like tires, and reinforcing agents derived from fossil resources such as carbon black (CB) are used for them. However, in recent years, conversion to biomass resources has been demanded due to problems such as depletion of fossil resources. Therefore, we have studied the composite of natural rubber (NR) reinforced with cellulose nano-fibers (CNF), which has attracted attention as a next-generation biomass resource. It is very difficult to uniformly disperse CNF in the conventional kneading process. Therefore, it is preferable to agitate CNF in NR latex. Then, it is necessary to study the optimum agitation equipment of CNF. In this study, the reinforcing effect by CNF was investigated when the agitation equipment was changed. Agitation of NR latex and CNF was carried out by a hand, a homogenizer, a dispersion mixer, and planetary centrifugal mixer. Thereafter, agitated materials were dried and masterbatches were made. Furthermore, the masterbatch and vulcanizing agents were kneaded using an internal mixer. Tensile test and X-ray CT observation of the prepared vulcanized rubber sheets were carried out to evaluate the reinforcing effect and dispersion state of CNF. As a result, the planetary centrifugal mixer was most useful to uniformly disperse CNF.

The Effect of Thermal Aging on Mechanical Properties and Morphological Properties of Thermoplastic Vulcanizates Based on Natural Rubber and Polystyrene

2020 ◽  
Vol 990 ◽  
pp. 262-266
Author(s):  
Prathumrat Nu-Yang ◽  
Atiwat Wiriya-Amornchai ◽  
Jaehoon Yoon ◽  
Chainat Saechau ◽  
Poom Rattanamusik
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Natural Rubber ◽  
Thermal Aging ◽  
Morphological Properties ◽  
Vulcanized Rubber ◽  
Thermoplastic Vulcanizates ◽  
Internal Mixer ◽  
Processing Properties

Thermoplastic vulcanizates or TPVs is a type of materials exhibiting excellent properties between thermoplastic and elastomer by combining the characteristics of vulcanized rubber with the processing properties of thermoplastics. This research aims to study the effect of thermal aging on the morphology and mechanical properties of thermoplastic vulcanizates (TPVs) based on a mixture of natural rubber (NR) and polystyrene (PS). TPVs samples were prepared using the internal mixer at a mass ratio of NR/PS 70/30, 50/50, 30/70 and 0/100. Tensile properties and impact strength showed that when the amount of NR increased tends of impact strength and elongation at break increased but tends of tensile strength decreased. On the other hand, tends of tensile strength for thermal aging at 70°C for 3 days increased when the amount of PS increase. The blending ratio of NR / PS at 70/30 is the best. It gave a worthy increase from 19.94 MPa to be 25.56 MPa (28.18%).

scholarly journals The Orientation of Strain-Induced Crystallites in Uniaxially-Strained, Thin and Wide Bands Made from Natural Rubber

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 294 ◽  
Author(s):  
Konrad Schneider ◽  
Matthias Schwartzkopf
Keyword(s):  
Natural Rubber ◽  
Pure Shear ◽  
Orientation Distribution ◽  
Thin Strip ◽  
X Ray Diffraction ◽  
Reinforcing Effect ◽  
X Ray ◽  
Crack Tips ◽  
Strain Induced Crystallization ◽  
Induced Crystallization

Vulcanized natural rubber (unfilled and filled with 20 phr carbon black) is strained. We suppress the macroscopic formation of fiber symmetry by choosing strip-shaped samples ("pure-shear geometry") and investigate the orientation of the resulting crystallites by two-dimensional wide-angle X-ray diffraction (WAXD), additionally rotating the sample tape about the straining direction. Indications of a directed reinforcing effect of the strain-induced crystallization (SIC) in the thin strip are found. In the filled material fewer crystallites are oriented and the orientation distribution of the oriented crystallites is less perfect. The results confirm, that it is important for the evaluation of crystallinity under deformation to check, whether fiber symmetry can be assumed. This has consequences in particular on the quantitative interpretation of space-resolved scanning experiments in the vicinity of crack tips. Furthermore it raises the question, whether there is an asymmetric reinforcing effect of the SIC in the vicinity of crack tips inside natural rubber.

Processing Characteristics of Synthetic Rubbers and Their Use in the Manufacture of Extruded Products

1944 ◽  
Vol 17 (4) ◽  
pp. 932-940 ◽  
Author(s):  
A. E. Juve
Keyword(s):  
Natural Rubber ◽  
Present Situation ◽  
General Purpose ◽  
High Dispersion ◽  
High Recovery ◽  
Vulcanized Rubber ◽  
Roll Mill ◽  
The Difference ◽  
Extruded Products ◽  
Internal Mixer

Abstract The difference in processing behavior between synthetic rubbers and natural rubber becomes evident when production facilities designed for processing natural rubber are used for synthetic rubbers. All the synthetic rubbers in one respect or another are harder to process than natural rubber. Under circumstances other than the present emergency, processing equipment suitable for handling the synthetic rubbers would gradually be evolved. In the present situation, synthetic rubbers must be processed with equipment already available. In this discussion natural rubber and the general purpose synthetic rubbers, GR-S, GR-M and GR-I, will be considered. The processing of dry rubber consists essentially of the incorporation of vulcanizing agents, pigments, oils, and other ingredients by a process of kneading, followed by the forming of the mix by extrusion or calendering into shapes suitable for fabrication preparatory to final cure. The mixing step, which is accomplished on a two-roll mill or in an internal mixer, requires that the rubber be within a plasticity range that will permit satisfactory dispersion of the ingredients. If the plasticity is too low the rubber tends to crumble, and if it is too high dispersion is poor. Crude natural rubber is quite tough, and before breakdown has some of the properties of vulcanized rubber, such as high recovery after moderate distortion. In the crude state it is extremely difficult to obtain satisfactory dispersion of pigments. It is therefore necessary to soften it by mastication or other means so that the pigments are more readily incorporated and power requirements are lowered. In addition, its nerve or tendency to recover after distortion is greatly reduced. Synthetic rubbers, in general, differ from natural rubber in their susceptibility to softening by mastication, and they show different relationships between nerve and plasticity than does natural rubber.

Some Properties of Vulcanized Rubber under Strain. Degree of Crystallization as Calculated from Temperature Coefficient of Elastic Tension

1951 ◽  
Vol 24 (4) ◽  
pp. 845-852
Author(s):  
B. B. S. T. Boonstra
Keyword(s):  
Natural Rubber ◽  
Temperature Coefficient ◽  
Thermodynamic Calculation ◽  
Energy Change ◽  
Thermodynamic Evaluation ◽  
X Ray ◽  
Vulcanized Rubber ◽  
Calorimetric Measurements ◽  
Degree Of Crystallization

Abstract To elucidate the crystallization phenomenon in natural rubber and to investigate the applicability of thermodynamic calculation to measurements of the elastic tension as a function of temperature, it seemed necessary to check whether crystallization determined by x-ray analysis (and combined with density) lined up reasonably with the percentage of crystallization computed from the energy change found by applying thermodynamics to stretched vulcanized rubber) on stretching. Calorimetric measurements were desirable, as no accurate figures are available for the heat of crystallization of rubber crystallites. The heat of melting of rubber crystallites was determined to about 66 joules per gram, which is of the same order as that of isoprene. The spreading in the results was large; the determination is based on the degree of crystallization found by x-ray analysis of raw rubber. The heat of crystallization on stretching, found by thermodynamic evaluation of the elastic tension and its temperature coefficient, is combined with the value of 66 joules for the heat of melting of the pure rubber crystallites. The degree of crystallization calculated in this way agrees reasonably well with the direct x-ray measurements of Goppel and Arlman. Crystallization as determined by x-ray analysis and that responsible for the energy change on stretching are much the same. This also means that thermodynamic evaluation of the change of stress with temperature is justified if pufficient relaxation of stress has taken place.

The Degree of Crystallinity in Natural Rubber. IV. The Degree of Crystallization in Frozen Raw Rubber and Stretched Vulcanized Rubber

1950 ◽  
Vol 23 (2) ◽  
pp. 310-319 ◽  
Author(s):  
J. M. Goppel ◽  
J. J. Arlman
Keyword(s):  
Natural Rubber ◽  
Experimental Evidence ◽  
Theoretical Investigation ◽  
Degree Of Crystallinity ◽  
X Ray ◽  
Crystallization Point ◽  
Vulcanized Rubber ◽  
Degree Of Crystallization ◽  
The Degree Of Crystallinity

Abstract An improved x-ray technique has been worked out to determine the degree of crystallinity in natural rubber. Inaccuracies which sometimes occur in quantitative x-ray measurements were eliminated, and it has been shown that the amount of crystalline rubber, both in frozen samples of raw rubber and in stretched vulcanized rubber, could be determined fairly accurately. More experiments were carried out and the results are described. These results, which confirm the current views on the problem of crystallization, point to relatively low degress of crystallization, even in highly stretched rubber, and they agree with some other experimental evidence and with a recent theoretical investigation.

Heats of Vulcanization of Synthetic Rubbers

1944 ◽  
Vol 17 (2) ◽  
pp. 404-411 ◽  
Author(s):  
P. L. Bruce ◽  
R. Lyle ◽  
J. T. Blake
Keyword(s):  
Carbon Black ◽  
Natural Rubber ◽  
Chemical Reactions ◽  
Side Reaction ◽  
Heat Evolution ◽  
Butyl Rubber ◽  
Vulcanized Rubber ◽  
Principal Reaction ◽  
Low Sulfur ◽  
Quantity Of Heat

Abstract 1. The heats of vulcanization for natural rubber and Buna-S are nearly equal. The data for both materials indicate two different chemical reactions during vulcanization. At low sulfur percentages, the principal reaction forms soft vulcanized rubber and is accompanied by little or no heat evolution. Above the 2 per cent sulfur region, a second reaction predominates, forming hard rubber and producing a relatively large quantity of heat. 2. The presence of an accelerator (Santocure) in Buna-S has little, if any, effect on heat of vulcanization. 3. The addition of carbon black to Buna-S lowers the heat of vulcanization in the region above 4 per cent sulfur. The calories evolved in a 10 per cent sulfur compound decrease linearly with percentage of carbon black. 4. The heats of vulcanization of Buna-N (Hycar OR-15) indicate the presence of two chemical reactions. Unlike natural rubber and Buna-S, the ebonite reaction does not predominate until the sulfur concentration is raised above 10 per cent. 5. The heat of vulcanization of Butyl rubber with sulfur is equal to the heat evolved with natural rubber containing 0.6 per cent sulfur. If one sulfur atom reacts per double bond, the maximum amount combining would be 0.72 per cent sulfur. During the vulcanization of Butyl rubber with p-quinone dioxime and lead peroxide, a large amount of heat is evolved by a side reaction between the vulcanizing agents. The reaction involving the Butyl rubber produces about 6 calories per gram, a considerably higher value than the 1 calorie produced by sulfur vulcanization. 6. The heat of vulcanization of Neoprene-GN without added agents corresponds to a value for smoked sheet rubber containing 4.5 per cent sulfur. The addition of zinc oxide and magnesia decreases the heat of vulcanization.

Preparation and Properties Investigation of Gadolinium Arylate/Hydrogenated Nitrile-Butadiene Rubber Composites

2013 ◽  
Vol 750-752 ◽  
pp. 1109-1112
Author(s):  
Ya He Hou ◽  
Xiao Ping Zhang
Keyword(s):  
Butadiene Rubber ◽  
Interface Bonding ◽  
Rubber Composites ◽  
X Ray ◽  
In Situ Reaction ◽  
Nitrile Butadiene Rubber ◽  
Vulcanized Rubber ◽  
Dispersion State ◽  
Scanning Electron

The gadolinium acrylate Gd (AA)3/hydrogenated nitrile-butadiene rubber (HNBR) composites have been prepared by in-situ reaction with dicumyl peroxide (DCP) as vulcanizing agent. The original morphology of Gd (AA)3 and its dispersion state in un-vulcanized and vulcanized rubber compound have been analyzed by scanning electron microscopy (SEM). The results demonstrated that Gd (AA)3 dispersed uniform in the composite with smaller size and better interface bonding because of the in-situ reaction. The mechanical properties of Gd (AA)3/HNBR reached the best when filled with 40 phr Gd (AA)3 and the X-ray shielding property increased with the increasing filling amount of Gd (AA)3.

X-Ray Study of the Crystallization of Vulcanized Rubber during Stretching. II.

1951 ◽  
Vol 24 (3) ◽  
pp. 541-549 ◽  
Author(s):  
V. I. Kasotochkin ◽  
B. V. Lukin
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Crystal Formation ◽  
Oxidative Destruction ◽  
Ray Method ◽  
X Ray ◽  
Vulcanized Rubber ◽  
Crystal Content

Abstract 1. The relation between the crystal content of stretched vulcanizates to the time of vulcanization for different mixtures of natural rubber was studied by the x-ray method. 2. It was shown that the tensile strength is a function of the crystal content of the stretched vulcanizate and of the total time of vulcanization. 3. The nature of crystal formation depends on the following factors: changes of density of the network of sulfur bridges, their distribution, the degree of oxidative destruction, and the quantity of bound sulfur which has not formed bridges between the molecular chains.

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