Effect of rare earth nucleating agent on supercritical CO2 foaming behavior of block copolymerized polypropylene

The rare earth nucleating agent was used to modify block copolymerized polypropylene (PPB) in foaming process. The results show that the crystallization of PPB and the melting temperature of β-crystal increased gradually with increased β-crystal nucleating agent content. The total crystallinity decreased with amount of addition increasing, and the relative content of β-crystal increased first and then decreased. When β-crystal nucleating agent content was 0.4 wt%, the relative β-crystal content reached the maximum value of 95.27%, and the final crystal grain refinement significantly. The addition of rare earth β-crystal nucleating agent has a good effect on improving the uniformity of foam cells. Under the same content of β-crystal nucleating agent and pressure, the average cell diameter and expansion ratio increased with the saturation temperature increasing. After the foaming temperature reaches 155°C, the expansion ratio began to decrease, which was also consistent with the changed trend of relative β-crystal content. At the same content of temperature and relative β-crystal, as the foaming pressure increased, the cell diameter decreased gradually, and the expansion ratio increased first, and then decreased.

Sensitivity of Tropical Tropopause Layer Cirrus Prediction in GRAPES Global Forecast System

A warm bias with a maximum value of over 4 K in the tropical tropopause layer (TTL) is detected in day-5 operational forecasts of the Global/Regional Assimilation and Prediction System (GRAPES) for global medium-range numerical weather prediction (GRAPES_GFS). In this study, the predicted temperature changes caused by different processes are examined, and the predicted cloud fractions are compared with the European Centre for Medium-Range Weather Forecasts ERA5 reanalysis data. It is found that the overprediction of the TTL cirrus fraction contributes to the warm bias due to cloud-radiative heating. The interactions among the ice nucleation, deposition/sublimation, and the large-scale condensation together determine the results of the TTL ice crystal content prediction. Moreover, a range of sensitivity experiments show that the TTL ice crystal content prediction is sensitive to the threshold relative humidity over ice (RHi) in the ice nucleation process. Then the uncertainties of the formulas for saturation vapor pressure over ice at very low temperatures are discussed. The RHi calculated based on the Magnus–Tetens formula is up to 10% higher than that based on the Goff–Gratch formula. As the Goff–Gratch formula is applicable over a broader range of 184–273 K, it is more suitable for the cold TTL. When the Goff–Gratch formula rather than the Magnus–Tetens formula is used in the microphysics scheme, the TTL cirrus forecasts are improved greatly, and the warm bias disappears completely. After investigating the interplay of the dynamical, microphysical, and radiative processes, we find a positive feedback mechanism that exacerbates the TTL cirrus prediction error.

ОСОБЕННОСТИХРУСТАЛЕНОСНОСТИУЛЫТАУСКОГОРАЙОНА

The Ulytau crystal-bearing region is located in the western part of the Kazakh folded country, distinguished by a significant complexity of the geological structure. The latter is due to the heterogeneity and varying degrees of dislocation of its constituent rocks.In connection with the manifestation of two stages of tectogenesis, two structural stages are distinguished in the folded base of the Ulytau zone.The purpose of this article is to study the features of the crystal content of the region.On the territory of the Ulytau district, 140 vein fields were identified, numbering up to 6,000 quartz veins, of which 1,700 with signs of crystallinity. Of the total number of crystal-bearing veins, 1100 were explored, located within 75 vein fields. Quartz veins, including crystal-bearing ones, are found in almost all rocks, including deposits of the Middle Carboniferous, which determine the upper age limit of the veins in the region.Productive (industrially -crystal-bearing) mineralization is manifested in the contours of the region more locally. Of the 110 identified fields and areas, industrial mineralization is associated with vein formations only 18 objects.

Lava dome morphology inferred from numerical modelling

SUMMARY Lava domes form when highly viscous magmas erupt on the surface. Several types of lava dome morphology can be distinguished depending on the flow rate and the rheology of magma. Here, we develop a 2-D axisymmetric model of magma extrusion on the surface and lava dome evolution and analyse the dome morphology using a finite-volume method implemented in Ansys Fluent software. The magma/lava viscosity depends on the volume fraction of crystals and temperature. We show that the morphology of domes is influenced by two parameters: the characteristic time of crystal content growth (CCGT) and the discharge rate (DR). At smaller values of the CCGTs, that is, at rapid lava crystallization, obelisk-shaped structures develop at low DRs and pancake-shaped structures at high DRs; at longer CCGTs, lava domes feature lobe- to pancake-shaped structures. A thick carapace of about 70 per cent crystal content evolves at smaller CCGTs. We demonstrate that cooling does not play the essential role during a lava dome emplacement, because the thermal thickness of the evolving carapace remains small in comparison with the dome's height. A transition from the endogenic to exogenic regime of the lava dome growth occurs after a rapid increase in the DR. A strain-rate-dependent lava viscosity leads to a more confined dome, but the influence of this viscosity on the dome morphology is not well pronounced. The model results can be used in assessments of the rates of magma extrusion, the lava viscosity and the morphology of active lava domes..

Zinc oxide nanorod as effective reinforcing material for enhancing β phase crystal in poly(vinylidene fluoride) filaments

The present work is an attempt to demonstrate that incorporation of small amount of zinc oxide nanorods enhances the β crystal percentage, which is essential for improvement in piezo-electric performance of the poly(vinylidene fluoride) (PVDF) fiber. The zinc oxide nanorods were synthesized with aspect ratio of 26 and uniformly dispersed in PVDF by melt compounding process. Those compounded polymers were melt spun and subsequently cold drawn to obtain composite filaments. The effect of nanostructure, loading amount, melt draw ratio, cold draw ratio, and drawing temperature was investigated. The incorporation of nanorods resulted in 14% increase in β phase crystal content compared to control PVDF filaments. The β phase crystal content has been analyzed using the wide-angle X ray diffraction and FTIR spectroscopy. This increase in β phase crystal content was 10% more compared to circular zinc oxide nanoparticle reinforced PVDF composite filament. There was no significant change in mechanical properties of the composite filaments compared to the control PVDF filament.

Thermal Stability of Shear-Induced Precursors and Their Effect on the Crystalline Structure of β-Nucleated Isotactic Polypropylene

The thermal stability and lifetime of shear-induced precursors under various annealing temperatures, as well as the influence of their relaxation on the crystalline modification in β-nucleated isotactic polypropylene (iPP), are investigated using an ARES rheometer. The wide-angle X-ray diffraction results show that the β-crystal content of sheared β-nucleated iPP samples gradually increases with thermal treatments. The relaxation of shear-induced precursors during annealing which caused the decrease of shear nuclei may restrain the counteraction effect between the shear flow and β-nucleation agent as well as result in the increase of β-crystal content. At the early stage of relaxation, the relaxation degree is closely related to the increase of β-crystals, for which the deeper relaxed shear-induced precursors result in the more restoration of β-crystals. However, when the relaxation degree exceeded a certain limitation, where the β-crystals reached the maximum, the relaxation of shear-induced precursors will no longer influence the crystal structure of β-nucleated iPP.

Deformation-driven emplacement-differentiation in the Closepet pluton, Dharwar Craton, South India: an alternate view

In the Late Archean north-trending Closepet pluton, trains of euhedral K-feldspar phenocrysts and matrix-supported idiomorphic K-feldspar crystals in the central part of the pluton define oblique-to-pluton margin steep-dipping east/ENE-trending magmatic fabrics. The magmatic fabric is defined by phenocryst-rich and phenocryst-poor layers, with the euhedral porphyries continuous across the layers. The fabrics are near-orthogonal to the gently-dipping gneissic layers in the host gneisses. The fabrics curve adjacent to locally-developed north/NNE-trending melt-hosted dislocations parallel to the axial planes of horizontal/gently-plunging north-trending upright folds in the host gneisses. In the pluton interior, both fabrics in the intrusives formed at supra-solidus conditions, although the volume fraction of melts diminished drastically due to cooling/melt expulsion. At the pluton margin, the north-trending fabric is penetrative and post-dates magma solidification. Within the pluton, the major element oxides, rare earth elements, anorthite contents in plagioclase, and (Mg/Fe + Mg) ratios in biotite decrease with increasing SiO2 from phenocryst-rich (up to 75% by volume) granodiorite to phenocryst-poor (<15 vol%) granite that broadly correspond to minimum melt composition. The chemical-mineralogical variations in the pluton is attributed to deformation-driven ascent of magma with heterogeneous crystal content, ascending at variable velocities (highest in crystal-poor magma) along oblique-to-pluton margin east/ENE-trending extensional fractures induced by dextral shearing.