Potential Application Zn-MOF/MnO2 Composite as Methanol Gas Sensor

2019 ◽  
Vol 811 ◽  
pp. 113-119
Author(s):  
Aep Patah ◽  
Wandi Kasim ◽  
Brian Yuliarto

Methanol is a simple alcohol compound which is known very volatile and to be toxic inside of human’s body. Therefore, it is necessary to develop a sensor that is capable to detect the methanol vapor in indoor air. Zn-based MOF is a polymeric coordination compound made up of ZnxOyCz inorganic cluster as the secondary building unit (SBU) and benzene dicarboxylate as the bridging ligand and formed bulky and porous material. In this research, composites of manganese oxide (MnO2) and Zn-based MOF are synthesized and characterized as material sensor for its capability towards sensing of methanol gas. Diffractogram of PXRD reveals that the synthesized Zn-MOF is crystalline and become more amorphous due to MnO2 addition. The composite was made into pellets and measured of its resistivity. The addition of MnO2 to the Zn-MOF lowered the resistivity of the Zn-MOF and the composite was found to be sensitive towards methanol vapor.

Atmosphere ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 647
Author(s):  
Tobias Baur ◽  
Johannes Amann ◽  
Caroline Schultealbert ◽  
Andreas Schütze

More and more metal oxide semiconductor (MOS) gas sensors with digital interfaces are entering the market for indoor air quality (IAQ) monitoring. These sensors are intended to measure volatile organic compounds (VOCs) in indoor air, an important air quality factor. However, their standard operating mode often does not make full use of their true capabilities. More sophisticated operation modes, extensive calibration and advanced data evaluation can significantly improve VOC measurements and, furthermore, achieve selective measurements of single gases or at least types of VOCs. This study provides an overview of the potential and limits of MOS gas sensors for IAQ monitoring using temperature cycled operation (TCO), calibration with randomized exposure and data-based models trained with advanced machine learning. After lab calibration, a commercial digital gas sensor with four different gas-sensitive layers was tested in the field over several weeks. In addition to monitoring normal ambient air, release tests were performed with compounds that were included in the lab calibration, but also with additional VOCs. The tests were accompanied by different analytical systems (GC-MS with Tenax sampling, mobile GC-PID and GC-RCP). The results show quantitative agreement between analytical systems and the MOS gas sensor system. The study shows that MOS sensors are highly suitable for determining the overall VOC concentrations with high temporal resolution and, with some restrictions, also for selective measurements of individual components.


2021 ◽  
Vol 16 (3) ◽  
pp. 363-367
Author(s):  
Gaoqi Zhang ◽  
Fan Zhang ◽  
Kaifang Wang ◽  
Tao Tian ◽  
Shanyu Liu ◽  
...  

Accurate and real-time detection of formaldehyde (HCHO) in indoor air is urgently needed for human health. In this work, a ceramic material (WO3·H2O) with unique structure was successfully prepared using an efficient hydrothermal method. The crystallinity, morphology and microstructure of the as-prepared sensing material were analyzed by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) as well as transmission electron microscope (TEM). The characterization results suggest that the as-prepared sample is composed of square-like nanoplates with uneven surface. Formaldehyde vapor is utilized as the target gas to investigate gas sensing properties of the synthesized novel nanoplates. The testing results indicate that the as-fabricated gas sensor exhibit high gas response and excellent repeatability to HCHO gas. The response value (Ra/Rg) is 24.5 towards 70 ppm HCHO gas at 350 °C. Besides, the gas sensing mechanism was described.


2012 ◽  
Vol 57 (23) ◽  
pp. 3059-3064 ◽  
Author(s):  
Ding Zhou ◽  
Qing Liu ◽  
QianYi Cheng ◽  
YanChao Zhao ◽  
Yi Cui ◽  
...  

2012 ◽  
Vol 165 (1) ◽  
pp. 24-33 ◽  
Author(s):  
Yuteng Wan ◽  
Huihua Li ◽  
Jinyun Liu ◽  
Fanli Meng ◽  
Zhen Jin ◽  
...  

1998 ◽  
Vol 34 (8) ◽  
pp. 913-921 ◽  
Author(s):  
Shigeki HIROBAYASHI ◽  
Haruhiko KIMURA ◽  
Hidetaka NAMBO ◽  
Satoshi SAKAMORI ◽  
Takashi OYABU

2020 ◽  
Vol 34 (1) ◽  
pp. 37-46
Author(s):  
Su-Gil Choi ◽  
Se-Young Jin ◽  
Sang-Min Park ◽  
Yeong-Jae Nam ◽  
Si-Kuk Kim

This is a basic research on potential application of fire detection by measuring fire detection tendency of indoor air quality measurement factors. In this study, operation experiment using smoke detector sensitivity tester and paper fire experiment specified in UL 268 standards were conducted to evaluate the fire detection tendency of indoor air quality measurement factors. Based on the cross-substitution of values measured in the paper fire experiment, PM10 (excluding average) and HCHO (excluding average and maximum) for the indoor air quality meter (IAQ); PM1.0, PM2.5, and PM10 for IAQ S2; and CO (excluding the average and maximum) for combustion gas analyzers showed consistent tendency despite changes in the measured values for smoke generation under all experimental conditions. In particular, PM10 and CO are considered the most applicable fire detection factors among the factors measured in the experiment.


2019 ◽  
Vol 1 (2) ◽  
pp. 772-780 ◽  
Author(s):  
Hao Cui ◽  
Guozhi Zhang ◽  
Xiaoxing Zhang ◽  
Ju Tang

Using first-principles theory, we investigated the most stable configuration for the Rh dopant on a MoSe2 monolayer, and the interaction of the Rh-doped MoSe2 (Rh-MoSe2) monolayer with four toxic gases (CO, NO, NO2 and SO2) to exploit the potential application of the Rh-MoS2 monolayer as a gas sensor or adsorbent.


Nanomaterials ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 977
Author(s):  
Wang ◽  
Tang ◽  
Cao ◽  
Chen ◽  
Rong

The release of hazardous gas increases with the development of industry. The research of gas-sensitive materials has attracted attention. Nanoscale iron oxide (α-Fe2O3) is one of the research hotspots of gas-sensitive materials because it is a cheap, non-toxic semiconductor material. In this study, pomegranate-shaped α-Fe2O3 was synthesized using an in situ corrosion method of scorodite. Spherical-shaped α-Fe2O3 nanoparticles were included in the octahedral shells. The forming process of the structure was analyzed by a variety of measurements. The shell was formed first through the deposition of Fe(OH)3, which was produced by hydrolyzing scorodite. Then, the corrosion was continued and Fe(OH)3 precipitation was produced below the shell. The particles aggregated and formed spheres. The pomegranate-shaped α-Fe2O3 was formed when the scorodite was hydrolyzed completely. The gas-sensing properties of α-Fe2O3 were investigated. The results showed that pomegranate-shaped α-Fe2O3 was responsive to a variety of gases, especially xylene. The value of Ra/Rg was 67.29 at 340 °C when the concentration of xylene was 1000 ppm. This indicated the pomegranate-shaped α-Fe2O3 has potential application as a xylene gas sensor.


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