Effect of CS2 Flow Rate on the Formation of Aligned Carbon Microcoils
The formation of aligned carbon microcoils could be achieved using C2H2 as a source gas and CS2 as an incorporated additive gas under thermal chemical vapor deposition system. To elucidate the ratio of C2H2/CS2 for the formation of the aligned carbon microcoils, the CS2 flow rate was first manipulated under the identical C2H2 flow rate (500sccm) condition. The formation and the alignment of carbon microcoils could be only achieved under the ratio of C2H2/CS2 = 33.3 condition, namely the flow rates of CS2 = 15sccm and C2H2= 500sccm. The total flow rate of the used gases was varied under the identical C2H2/CS2 flow rate ratio (33.3) condition. The C2H2 flow rate was manipulated under the identical CS2 flow rate (15sccm) condition. It was found that the formation and the alignment of carbon microcoils could be only achieved under the condition of 15sccm of CS2 flow rate in the range of 200 ~ 500sccm of C2H2 flow rate, regardless of the flow rate ratio of C2H2/CS2 and the total flow rate. The crystal structure of the well-aligned CMCs reveals the increase in the (002) peak in XRD spectrum for the aligned carbon microcoils, indicating the existence of the more regular structure in the aligned carbon microcoils. Based on these results, the cause for the formation of the aligned carbon microcoils only in the case of the CS2 flow rate = 15sccm with the imaginary pictures for the flow rate ratio of C2H2/CS2 just above the substrate were proposed.