Examination of the Elemental Composition of Hair in Cholelithiasis, Kidney Stone, Hypertension and Diabetes by Scanning Electron Microscopy and Energy Dispersive Spectrometry SEM/EDS

Author(s):  
Blicharska (Grushka) El
2014 ◽  
Vol 20 (5) ◽  
pp. 1534-1543 ◽  
Author(s):  
Annalaura Restivo ◽  
Ilaria Degano ◽  
Erika Ribechini ◽  
Josefina Pérez-Arantegui ◽  
Maria Perla Colombini

Abstract:An innovative approach, combining field-emission scanning electron microscopy (FESEM) with energy dispersive X-ray spectroscopy (EDX) analysis, is presented to investigate the degradation mechanisms affecting tannin-dyed wool. In fact, tannin-dyed textiles are more sensitive to degradation then those dyed with other dyestuffs, even in the same conservation conditions.FESEM-EDX was first used to study a set of 48 wool specimens (artificially aged) dyed with several raw materials and mordants, and prepared according to historical dyeing recipes. EDX analysis was performed on the surface of wool threads and on their cross-sections. In addition, in order to validate the model formulated by the analysis of reference materials, several samples collected from historical and archaeological textiles were subjected to FESEM-EDX analysis.FESEM-EDX investigations enabled us to reveal the correlation between elemental composition and morphological changes. In addition, aging processes were clarified by studying changes in the elemental composition of wool from the protective cuticle to the fiber core in cross-sections. Morphological and elemental analysis of wool specimens and of archaeological and historical textiles showed that the presence of tannins increases wool damage, primarily by causing a sulfur decrease and fiber oxidation.


1989 ◽  
Vol 169 ◽  
Author(s):  
Alexis S. Nash ◽  
K. C. Goretta ◽  
Philip Nash ◽  
R. B. Poeppel ◽  
Donglu Shi

AbstractA series of 4336 Bi‐Sr‐Ca‐Cu oxide samples doped with 1 to 5% metallic Ag was prepared by solid state reaction. The distribution of Ag, the microstructure and the crystal structure of the samples were studied using energy dispersive spectrometry, EDS, scanning electron microscopy, SEM, and x‐ray diffractometry, XRD. Addition of Ag leads to a marked increase in preferred orientation with (001) planes perpendicular to the pressing direction in sintered pellets. The resistivity‐temperature data show an enhanced Tc in Ag‐doped samples under certain conditions. Energy dispersive spectrometry indicates that the dopant mostly segregates to the grain boundaries.


2017 ◽  
Vol 32 (S2) ◽  
pp. S95-S100 ◽  
Author(s):  
Christopher E. Marjo ◽  
Gillan Davis ◽  
Bin Gong ◽  
Damian B. Gore

Archaeometrists use a variety of analytical methods to determine trace elements in ancient Greek silver coins, for provenance studies, understanding social and technological change, and authentication. One analytical problem which is little documented is understanding the horizontal spatial heterogeneity of coin elemental composition in micro-sampled areas, which are usually assumed to be uniform. This study analysed ten ancient Greek coins representative of silver circulating in the Aegean region in the sixth to third centuries BC. Scanning electron microscopy with energy dispersive spectrometry was used to map the spatial distribution of elements on coins that were abraded to remove the patina. Time of flight-secondary ion mass spectrometry was then conducted on selected coins, mapping an area ~100 × 100 µm and depth profiling from 0 to 10 µm. These data revealed the three-dimensional elemental complexity of the coins, in particular, the heterogeneity both in the patina and beneath it. These data will guide future authentication and provenance studies of larger sample sets of ancient Greek coins including the use of line scanning for laser ablation inductively coupled plasma mass spectrometry data collection rather than spot analyses, and non-destructive analytical techniques such as X-ray fluorescence spectrometry.


2018 ◽  
Vol 83 (3) ◽  
pp. 536-551 ◽  
Author(s):  
Jenny L. Adams ◽  
Mary F. Ownby

Recent examinations of more than 13,000 disk beads from mortuary contexts determined that macroscopic examination was not always enough to distinguish shell, stone, and fired-clay beads. Using replication experiments and scanning electron microscopy energy dispersive spectrometry (SEM-EDS), we update the 80-year-old conclusions of Emil Haury, who defined features distinctive to bead manufacture. With this renewed confidence in materials identification, we analyzed the distributions of disk beads made from shell, stone, and fired clay among Hohokam inhumations and cremations at the Yuma Wash, Honey Bee Village, and Wetlands sites in the Tucson Basin. Not everyone was buried with disk beads, but all age groups were represented among those who were buried with beads. Some people were buried with only stone, or only shell, or only fired-clay beads, although more were buried with beads of some combination of these three materials. In this article, we consider why fired-clay beads were added to the mix and conclude that they were made as acceptable substitutes for stone beads, not for deceptive reasons concerning wealth or status, but rather in imitation of stone to honor a tradition that could not otherwise be efficiently met.


2004 ◽  
Vol 852 ◽  
Author(s):  
Barbara H. Berrie ◽  
Louisa C. Matthew

ABSTRACTIn the light of new documentary information regarding the range of materials available to sixteenth century artists, cross sections from paintings were re-examined using scanning electron microscopy - energy dispersive spectrometry. Among a variety of new materials, colored glassy pigments were found including diverse yellow glassy particles, specifically lead silicate and a glass colored by lead antimonate. These are the “yellow smalts” described in Renaissance writings on artists’ materials.


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