Desulfation of Pd-based Oxidation Catalysts for Lean-burn Natural Gas and Dual-fuel Applications

2015 ◽  
Vol 8 (4) ◽  
pp. 1472-1477 ◽  
Author(s):  
Nathan Ottinger ◽  
Rebecca Veele ◽  
Yuanzhou Xi ◽  
Z. Gerald Liu
Keyword(s):  
Natural Gas ◽  
Dual Fuel ◽  
Oxidation Catalysts ◽  
Lean Burn

scholarly journals Characterization and Evaluation of Methane Oxidation Catalysts for Dual-Fuel Diesel and Natural Gas Engines

2016 ◽  
Vol 2 (4) ◽  
pp. 204-214 ◽  
Author(s):  
Donnie J. Worth ◽  
Marc E. J. Stettler ◽  
Paul Dickinson ◽  
Kieran Hegarty ◽  
Adam M. Boies
Keyword(s):  
Natural Gas ◽  
Methane Oxidation ◽  
Dual Fuel ◽  
Oxidation Catalysts ◽  
Natural Gas Engines

scholarly journals A Numerical Study on the Pilot Injection Conditions of a Marine 2-Stroke Lean-Burn Dual Fuel Engine

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1396
Author(s):  
Hao Guo ◽  
Song Zhou ◽  
Jiaxuan Zou ◽  
Majed Shreka
Keyword(s):  
Natural Gas ◽  
Fuel Injection ◽  
Numerical Study ◽  
Pollutant Emissions ◽  
Dual Fuel ◽  
Injection Timing ◽  
Pilot Injection ◽  
Lean Burn ◽  
Injection Duration ◽  
Pilot Fuel

The global demand for clean fuels is increasing in order to meet the requirements of the International Maritime Organization (IMO) of 0.5% global Sulphur cap and Tier III emission limits. Natural gas has begun to be popularized on liquefied natural gas (LNG) ships because of its low cost and environment friendly. In large-bore marine engines, ignition with pilot fuel in the prechamber is a good way to reduce combustion variability and extend the lean-burn limit. However, the occurrence of knock limits the increase in power. Therefore, this paper investigates the effect of pilot fuel injection conditions on performance and knocking of a marine 2-stroke low-pressure dual-fuel (LP-DF) engine. The engine simulations were performed under different pilot fuel parameters. The results showed that the average in-cylinder temperature, the average in-cylinder pressure, and the NOx emissions gradually decreased with the delay of the pilot injection timing. Furthermore, the combustion situation gradually deteriorated as the pilot injection duration increased. A shorter pilot injection duration was beneficial to reduce NOx pollutant emissions. Moreover, the number of pilot injector orifices affected the ignition of pilot fuel and the flame propagation speed inside the combustion chamber.

Rapid Deactivation of Lean-Burn Natural Gas Engine Exhaust Oxidation Catalysts

1996 ◽  
Author(s):  
Robert L. McCormick ◽  
Anthony W. Newlin ◽  
Deborah Mowery ◽  
Michael S. Graboski ◽  
T. R. Ohno
Keyword(s):  
Natural Gas ◽  
Oxidation Catalysts ◽  
Lean Burn ◽  
Engine Exhaust ◽  
Gas Engine ◽  
Natural Gas Engine

scholarly journals Investigation of Effect on Environmental Performance of Using LNG as Fuel for Engines in Seaport Tugboats

2021 ◽  
Vol 9 (2) ◽  
pp. 123
Author(s):  
Sergejus Lebedevas ◽  
Lukas Norkevičius ◽  
Peilin Zhou
Keyword(s):  
Diesel Engine ◽  
Natural Gas ◽  
Baltic Sea ◽  
Impact Assessment ◽  
Fuel Consumption ◽  
Dual Fuel ◽  
Nox Emissions ◽  
The Baltic Sea ◽  
Emission Analysis ◽  
The Baltic

Decarbonization of ship power plants and reduction of harmful emissions has become a priority in the technological development of maritime transport, including ships operating in seaports. Engines fueled by diesel without using secondary emission reduction technologies cannot meet MARPOL 73/78 Tier III regulations. The MEPC.203 (62) EEDI directive of the IMO also stipulates a standard for CO2 emissions. This study presents the results of research on ecological parameters when a CAT 3516C diesel engine is replaced by a dual-fuel (diesel-liquefied natural gas) powered Wartsila 9L20DF engine on an existing seaport tugboat. CO2, SO2 and NOx emission reductions were estimated using data from the actual engine load cycle, the fuel consumption of the KLASCO-3 tugboat, and engine-prototype experimental data. Emission analysis was performed to verify the efficiency of the dual-fuel engine in reducing CO2, SO2 and NOx emissions of seaport tugboats. The study found that replacing a diesel engine with a dual-fuel-powered engine led to a reduction in annual emissions of 10% for CO2, 91% for SO2, and 65% for NOx. Based on today’s fuel price market data an economic impact assessment was conducted based on the estimated annual fuel consumption of the existing KLASCO-3 seaport tugboat when a diesel-powered engine is replaced by a dual-fuel (diesel-natural gas)-powered engine. The study showed that a 33% fuel costs savings can be achieved each year. Based on the approved methodology, an ecological impact assessment was conducted for the entire fleet of tugboats operating in the Baltic Sea ports if the fuel type was changed from diesel to natural gas. The results of the assessment showed that replacing diesel fuel with natural gas achieved 78% environmental impact in terms of NOx emissions according to MARPOL 73/78 Tier III regulations. The research concludes that new-generation engines on the market powered by environmentally friendly fuels such as LNG can modernise a large number of existing seaport tugboats, significantly reducing their emissions in ECA regions such as the Baltic Sea.

A phenomenological model for the description of unburned hydrocarbons emission in ultra-lean engines

2021 ◽  
pp. 146808742110050
Author(s):  
Enrica Malfi ◽  
Vincenzo De Bellis ◽  
Fabio Bozza ◽  
Alberto Cafari ◽  
Gennaro Caputo ◽  
...  
Keyword(s):  
Natural Gas ◽  
Internal Combustion Engines ◽  
Pollutant Emissions ◽  
Average Error ◽  
Combustion Engines ◽  
Nitric Oxides ◽  
Lean Burn ◽  
Fuel Charge ◽  
Unburned Hydrocarbons ◽  
Model Reliability

The adoption of lean-burn concepts for internal combustion engines working with a homogenous air/fuel charge is under development as a path to simultaneously improve thermal efficiency, fuel consumption, nitric oxides, and carbon monoxide emissions. This technology may lead to a relevant emission of unburned hydrocarbons (uHC) compared to a stoichiometric engine. The uHC sources are various and the relative importance varies according to fuel characteristics, engine operating point, and some geometrical details of the combustion chamber. This concern becomes even more relevant in the case of engines supplied with natural gas since the methane has a global warming potential much greater than the other major pollutant emissions. In this work, a simulation model describing the main mechanisms for uHC formation is proposed. The model describes uHC production from crevices and flame wall quenching, also considering the post-oxidation. The uHC model is implemented in commercial software (GT-Power) under the form of “user routine”. It is validated with reference to two large bore engines, whose bores are 31 and 46 cm (engines named accordingly W31 and W46). Both engines are fueled with natural gas and operated with lean mixtures (λ > 2), but with different ignition modalities (pre-chamber device or dual fuel mode). The engines under study are preliminarily schematized in the 1D simulation tool. The consistency of 1D engine schematizations is verified against the experimental data of BMEP, air flow rate, and turbocharger rotational speed over a load sweep. Then, the uHC model is validated against the engine-out measurements. The averaged uHC predictions highlight an average error of 7% and 10 % for W31 and W46 engines, respectively. The uHC model reliability is evidenced by the lack of need for a case-dependent adjustment of its tuning constants, also in presence of relevant variations of both engine load and ring pack design.

scholarly journals CFD Study and Experimental Validation of a Dual Fuel Engine: Effect of Engine Speed

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4307
Author(s):  
Roberta De Robbio ◽  
Maria Cristina Cameretti ◽  
Ezio Mancaruso ◽  
Raffaele Tuccillo ◽  
Bianca Maria Vaglieco
Keyword(s):  
Natural Gas ◽  
High Performance ◽  
Engine Speed ◽  
Pollutant Emissions ◽  
Dual Fuel ◽  
Automotive Market ◽  
Light Duty ◽  
Viable Solution ◽  
Dual Fuel Engines ◽  
Gas Ratio

Dual fuel engines induce benefits in terms of pollutant emissions of PM and NOx together with carbon dioxide reduction and being powered by natural gas (mainly methane) characterized by a low C/H ratio. Therefore, using natural gas (NG) in diesel engines can be a viable solution to reevaluate this type of engine and to prevent its disappearance from the automotive market, as it is a well-established technology in both energy and transportation fields. It is characterized by high performance and reliability. Nevertheless, further improvements are needed in terms of the optimization of combustion development, a more efficient oxidation, and a more efficient exploitation of gaseous fuel energy. To this aim, in this work, a CFD numerical methodology is described to simulate the processes that characterize combustion in a light-duty diesel engine in dual fuel mode by analyzing the effects of the changes in engine speed on the interaction between fluid-dynamics and chemistry as well as when the diesel/natural gas ratio changes at constant injected diesel amount. With the aid of experimental data obtained at the engine test bench on an optically accessible research engine, models of a 3D code, i.e., KIVA-3V, were validated. The ability to view images of OH distribution inside the cylinder allowed us to better model the complex combustion phenomenon of two fuels with very different burning characteristics. The numerical results also defined the importance of this free radical that characterizes the areas with the greatest combustion activity.

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