scholarly journals Electrochemical Treatment of High Concentration Ammonia using RuO2/Ti Anode and TiO2 Nanotube Cathode

2020 ◽  
Vol 42 (7) ◽  
pp. 339-348
Author(s):  
Sumin Lee ◽  
Daewon Pak
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Current Density ◽  
Ammonia Oxidation ◽  
Tio2 Nanotube ◽  
Ion Concentration ◽  
Oxidizing Agent ◽  
Hydroxyl Ion ◽  
Total Nitrogen Removal ◽  
Chlorine Ion

Objectives:In this study, the treatment potential of ammonia in wastewater generated by S company odor removal process was tested by using electrochemical reactor with RuO2/Ti anode and TiO2 nanotube cathode. The effect of chlorine ion concentration and current density on ammonia oxidation were investigated by comparing the treatment efficiencies.Methods:380 mL of wastewater was electrolyzed for 3 h using 4 anodes and 5 cathodes and pH, NH3-N, NO3--N, and TN were measured and analyzed every 30 minutes.Results and Discussion:As the addition of chlorine ion increases, about 1,700 mg/L of ammonia in the wastewater was found to increase in oxidation reaction rate due to an increase in chlorine based oxidizing agent. An increase in chlorine based oxidizing agent leads to an increase in indirect oxidation. As a result, total nitrogen removal was increased. Ammonia oxidation rate was increased as the current density increased. Nitrate, ammonia oxidation byproduct, was accumulated at a current density from 20 to 40 mA/cm2. At higher than 50 mA/cm2, nitrate was accumulated for a while and then decreased. Total nitrogen removal rate increased as the current density increased. During electrochemical oxidation of ammonia to nitrate, hydroxyl ions were consumed by the reaction. The hydroxyl ion consumed during ammonia oxidation was less than that produced from nitrate reduction.Conclusions:Thus, ammonia in actual wastewater was completely removed using RuO2/Ti anode and TiO2 nanotube cathode and the possibility of reducing nitrate was confirmed. We confirmed the applicability of the two electrodes to the real industry.

scholarly journals Treatment performance, nitrous oxide production and microbial community under low-ammonium wastewater in a CANON process

2017 ◽  
Vol 76 (12) ◽  
pp. 3468-3477 ◽  
Author(s):  
Weixing Mi ◽  
Jianqiang Zhao ◽  
Xiaoqian Ding ◽  
Guanghuan Ge ◽  
Rixiang Zhao
Keyword(s):  
Nitrous Oxide ◽  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Ammonia Oxidation ◽  
Removal Rate ◽  
Biofilm Reactor ◽  
Ammonium Concentration ◽  
Nitrous Oxide Production ◽  
Total Nitrogen Removal ◽  
Canon Process

Abstract To investigate the characteristics of anaerobic ammonia oxidation for treating low-ammonium wastewater, a continuous-flow completely autotrophic nitrogen removal over nitrite (CANON) biofilm reactor was studied. At a temperature of 32 ± 1 °C and a pH between 7.5 and 8.2, two operational experiments were performed: the first one fixed the hydraulic retention time (HRT) at 10 h and gradually reduced the influent ammonium concentrations from 210 to 50 mg L−1; the second one fixed the influent ammonium concentration at 30 mg L−1 and gradually decreased the HRT from 10 to 3 h. The results revealed that the total nitrogen removal efficiency exceeded 80%, with a corresponding total nitrogen removal rate of 0.26 ± 0.01 kg N m−3 d−1 at the final low ammonium concentration of 30 mg L−1. Small amounts of nitrous oxide (N2O) up to 0.015 ± 0.004 kg m−3 d−1 at the ammonium concentration of 210 mg L−1 were produced in the CANON process and decreased with the decrease in the influent ammonium loads. High-throughput pyrosequencing analysis indicated that the dominant functional bacteria ‘Candidatus Kuenenia’ under high influent ammonium levels were gradually succeeded by Armatimonadetes_gp5 under low influent ammonium levels.

scholarly journals Nitrogen removal via a single-stage PN–Anammox process in a novel combined biofilm reactor

2017 ◽  
Vol 77 (6) ◽  
pp. 1483-1492 ◽  
Author(s):  
Yue-mei Han ◽  
Feng-xia Liu ◽  
Xiao-fei Xu ◽  
Zhuo Yan ◽  
Zhi-jun Liu
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Ammonia Oxidation ◽  
Biofilm Reactor ◽  
Nitrifying Bacteria ◽  
Anammox Bacteria ◽  
Ammonia Oxidizing Bacteria ◽  
High Ammonia ◽  
Total Nitrogen Removal ◽  
Anammox Process

Abstract This study developed a partial nitrification (PN) and anaerobic ammonia oxidation (Anammox) process for treating high-ammonia wastewater using an innovative biofilm system in which ammonia oxidizing bacteria grew on fluidized Kaldnes (K1) carriers and Anammox bacteria grew on fixed acryl resin carriers. The airlift loop biofilm reactor (ALBR) was stably operated for more than 4 months under the following conditions: 35 ± 2 °C, pH 7.5–8.0 and dissolved oxygen (DO) of 0.5–3.5 mg/L. The results showed that the total nitrogen removal efficiency reached a maximum of 75% and the total nitrogen removal loading rate was above 0.4 kg/(d·m3). DO was the most efficient control parameter in the mixed biofilm system, and values below 1.5 mg/L were observed in the riser zone for the PN reaction, while values below 0.8 mg/L were observed in the downer zone for the Anammox reaction. Scanning electron microscopy and Fluorescence In Situ Hybridization images showed that most of the nitrifying bacteria were distributed on the K1 carriers and most of the Anammox bacteria were distributed within the acryl resin carriers. Therefore, the results indicate that the proposed combined biofilm system is easy to operate and efficient for the treatment of high-ammonia wastewater.

Effect of Ca2+ and Fe3+ Addition on Nitrification-Denitrification Process in a Membrane Bioreactor

2012 ◽  
Vol 610-613 ◽  
pp. 422-427 ◽  
Author(s):  
Mo Jie Sun ◽  
Hong Hong Wang ◽  
Hai Feng Zhang
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Membrane Bioreactor ◽  
Removal Rate ◽  
Ammonia Nitrogen ◽  
Ion Concentration ◽  
Ferric Ion ◽  
Submerged Membrane Bioreactor ◽  
Total Nitrogen Removal ◽  
Denitrification Process

Study on the effect of Ca2+and Fe3+addition on nitrification-denitrification process in a submerged membrane bioreactor was conducted. The removal rate of total nitrogen and ammonia nitrogen was investigated. The result indicated that the ammonia nitrogen and total nitrogen removal rate increased from 75% to 85% and 55% to 75%, respectively, as the calcium concentration ranging from 0 to 150 mg/L, which indicated that the nitrification and denitrification process were promoted. Ferric ion of 50 mg/L obtained a considerable increase in TN removal from 55% to 70% ,with an increase of ammonia nitrogen removal rate from 75% to 83%. However, ferric ion concentration ranging between 100 mg/L and 150mg/L caused a decrease of both total nitrogen and ammonia nitrogen removal efficiency, indicating that the activity of nitrifying and denitrifying bacteria was inhibited.

scholarly journals Modeling granule-based completely autotrophic nitrogen removal over the nitrite (CANON) process in an SBR

2021 ◽  
Author(s):  
Qing Cai ◽  
Qiang He ◽  
Sheng Zhang ◽  
Jiajia Ding
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Ammonia Oxidation ◽  
Heterotrophic Bacteria ◽  
Removal Rate ◽  
Operation Condition ◽  
N Concentration ◽  
Heterotrophic Microorganisms ◽  
Simulation Results ◽  
Total Nitrogen Removal

Abstract Based on the simplified activated sludge model No. 1 (ASM1), a 1D biofilm model containing autotrophic microorganisms and heterotrophic microorganisms was developed to describe the microbial population dynamics and reactor dynamics of CANON SBR. After sensitivity analysis and calibration for parameters, the simulation results of NH4+-N concentration and NO2−-N concentration were consistent with the measured results, while the simulated NO3−-N concentration was slightly lower than the measured. The simulation results showed that the soluble microbial products had an extremely low concentration. The aerobic ammonia oxidation bacteria and anaerobic ammonia oxidation bacteria were the dominant microbial populations of the CANON system, while nitrite oxidization bacteria and heterotrophic bacteria were eliminated completely. The optimal ratio of air aeration load to influent NH4+-N load was about 0.18 L air/mgN. The operation condition of the reactor was optimized according to the simulation results, and the total nitrogen removal rate and the total nitrogen removal efficiency increased from 0.312 ± 0.015 to 0.485 ± 0.013 kg N/m3/d and from 71.2 ± 4.3 to 85.7 ± 1.4%, respectively.

Effects of tetracycline on simultaneous biological wastewater nitrogen and phosphorus removal

RSC Advances ◽  
2015 ◽  
Vol 5 (73) ◽  
pp. 59326-59334 ◽  
Author(s):  
A. Chen ◽  
Y. Chen ◽  
C. Ding ◽  
H. Liang ◽  
B. Yang
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Phosphorus Removal ◽  
Protective Role ◽  
Nitrogen And Phosphorus ◽  
Nitrogen And Phosphorus Removal ◽  
Total Nitrogen Removal

The presence of 2 and 5 mg L−1of tetracycline decreased total nitrogen removal. Tetracycline induced EPS release and decreased its protective role on cells. Denitrifiers instead of nitrifiers were negatively affected by tetracycline.

Intermittent feeding of wastewater in combination with alternating aeration for complete denitrification and control of filaments

2010 ◽  
Vol 61 (9) ◽  
pp. 2259-2266 ◽  
Author(s):  
Styliani Kantartzi ◽  
Paraschos Melidis ◽  
Alexander Aivasidis
Keyword(s):  
Wastewater Treatment ◽  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Wastewater Treatment Plant ◽  
Municipal Wastewater ◽  
Settling Tank ◽  
Treatment Plant ◽  
Operating Conditions ◽  
Anoxic Conditions ◽  
Total Nitrogen Removal

In the present study, a laboratory scale system, consisting of a primary settling tank, a continuous stirred tank reactor and a clarifier were constructed and operated, using wastewater from the municipal wastewater treatment plant in Xanthi, Greece. The system operated under intermittent aeration in aerobic/anoxic conditions and feeding of the wastewater once in every cycle. The unit was inoculated with sludge, which originated from the recirculation stream of the local wastewater treatment plant. The wastewater was processed with hydraulic retention time (HRT) of 12 h, in which various experimental states were studied regarding the combination of aerobic and anoxic intervals. The wastewater was fed in limited time once in every cycle of aerobic/anoxic conditions at the beginning of the anoxic period. The two states that exhibited highest performance in nitrification and total nitrogen removal were, then, repeated with HRT of 10 h. The results show that, regarding the nitrification stage and the organic load removal, the intermittent system achieved optimum efficiency, with an overall removal of biological oxygen demand (BOD5) and ammonium nitrogen in the range of 93–96% and 91–95% respectively. As far as the total nitrogen removal is concerned, and if the stage of the denitrification is taken into account, the performance of the intermittent system surpassed other methods, as it is shown by the total Kjeldahl nitrogen (TKN) removal efficiency of 85–87%. These operating conditions suppressed the growth of filamentous organisms, a fact reflected at the SVI values, which were lower than 150 ml/g.

Total nitrogen removal from high-strength ammonia recycle stream using a single submerged attached growth bioreactor

2007 ◽  
Vol 55 (8-9) ◽  
pp. 59-65 ◽  
Author(s):  
A. Onnis-Hayden ◽  
P.B. Pedros ◽  
J. Reade
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Removal Rate ◽  
Treatment Plant ◽  
High Strength ◽  
Nitrogen Loading ◽  
Digested Sludge ◽  
Attached Growth ◽  
Anaerobically Digested Sludge ◽  
Total Nitrogen Removal

An experimental study investigating the nitrogen removal efficiency from the recycle stream generated in the dewatering facility of the anaerobically digested sludge at the Deer Island wastewater treatment plant (WWTP) in Boston was conducted using a single submerged attached growth bioreactor (SAGB), designed for simultaneous nitrification and denitrification. The applied nitrogen loading to the reactor ranged from 0.7 to 2.27 kg-N/m3·d, and the corresponding total nitrogen (TN) removal rate ranged from 0.38 to 1.8 kg-N/m3·d. The observed nitrification rates varied from 0.42 kg-N/m3·d to 1.45 kg-N/m3·d with an ammonia load of 0.5 kg-N/m3·d and 1.8 kg-N/m3·d, respectively. An average nitrification efficiency of 91% was achieved throughout the experiment. Denitrification efficiency varied from 55%, obtained without any addition of carbon source, to 95% when methanol was added in order to obtain a methanol/nitrate ratio of about 3 kg methanol/kg NO3−-N.

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