scholarly journals Concentrations of Ground-Level Ozone on Petroleum Filling Stations in Urban West Region- Zanzibar

2021 ◽  
pp. 37-44
Author(s):  
Saadat Soud Mohamed ◽  
Abdul Ali Juma Mohamed ◽  
Chukwuma J. Okafor
Keyword(s):  
Ground Level ◽  
Spatial Variations ◽  
Mean Values ◽  
Ground Level Ozone ◽  
Environment And Health ◽  
West Region ◽  
Ambient Concentration ◽  
Gas Detector ◽  
The Mean

Ambient concentration of ground-level ozone was quantified from 14 petroleum filling stations in Urban and West districts allocated in urban west region Zanzibar between August and November 2019. In situ measurement was conducted for two separate sessions that involved before noon and afternoon in each day in the field using BH-4S Portable multi-gas detector. The analyzed data revealed both temporary and spatial variations of measured parameters. During phase1, the range of ozone was 4.8- 0.6 ppm. During phase2, the range of ozone was 14.2 - 4.5 ppm. The mean values recorded for ozone ranged from 0.6 ppm to 4.8 ppm for phase1, and from 4.5 ppm to 14.2 ppm for phase2. This study revealed that, ground-level ozone is at a point that calls attention tothe environment and health sectors.

scholarly journals High-precision quasi-continuous atmospheric greenhouse gas measurements at Trainou tower (Orléans forest, France)

2014 ◽  
Vol 7 (7) ◽  
pp. 2283-2296 ◽  
Author(s):  
M. Schmidt ◽  
M. Lopez ◽  
C. Yver Kwok ◽  
C. Messager ◽  
M. Ramonet ◽  
...  
Keyword(s):  
In Situ Measurements ◽  
Atmospheric Measurements ◽  
Flame Ionization ◽  
Gas Detector ◽  
Sampling Height ◽  
The Mean ◽  
Drying System ◽  
Gas Measurements ◽  
Television Tower

Abstract. Results from the Trainou tall tower measurement station installed in 2006 are presented for atmospheric measurements of CO2, CH4, N2O, SF6, CO, H2 mole fractions and radon-222 activity. Air is sampled from four sampling heights (180, 100, 50 and 5 m) of the Trainou 200 m television tower in the Orléans forest in France (47°57'53" N, 2°06'45" E, 131 m a.s.l.). The station is equipped with a custom-built CO2 analyser (CARIBOU), which is based on a commercial non-dispersive, infrared (NDIR) analyser (Licor 6252), and a coupled gas chromatography (GC) system equipped with an electron capture detector (ECD) and a flame ionization detector (FID) (HP6890N, Agilent) and a reduction gas detector (PP1, Peak Performer). Air intakes, pumping and air drying system are shared between the CARIBOU and the GC systems. The ultimately achieved short-term repeatability (1 sigma, over several days) for the GC system is 0.05 ppm for CO2, 1.4 ppb for CH4, 0.25 ppb for N2O, 0.08 ppb for SF6, 0.88 ppb for CO and 3.8 for H2. The repeatability of the CARIBOU CO2 analyser is 0.06 ppm. In addition to the in situ measurements, weekly flask sampling is performed, and flask air samples are analysed at the Laboratoire des Sciences du Climat et de l'Environnement (LSCE) central laboratory for the same species as well for stable isotopes of CO2. The comparison between in situ measurements and the flask sampling showed averaged differences of 0.08 ± 1.40 ppm for CO2, 0.7 ± 7.3 ppb for CH4, 0.6 ± 0.6 ppb for N2O, 0.01 ± 0.10 ppt for SF6, 1.5± 5.3 ppb for CO and 4.8± 6.9 ppb for H2 for the years 2008–2012. At Trainou station, the mean annual increase rates from 2007 to 2011 at the 180 m sampling height were 2.2 ppm yr−1 for CO2, 4 ppb yr−1 for CH4, 0.78 ppb yr−1 for N2O and 0.29 ppt yr−1 for SF6. For all species, the 180 m sampling level showed the smallest diurnal variation. Mean diurnal gradients between the 50 m and the 180 m sampling level reached up to 30 ppm CO2, 15 ppm CH4 or 0.5 ppb N2O during nighttime whereas the mean gradients are smaller than 0.5 ppm for CO2 and 1.5 ppb for CH4 during afternoon.

scholarly journals Vectors of subsurface stormflow in a layered hillslope during runoff initiation

2006 ◽  
Vol 10 (3) ◽  
pp. 309-320 ◽  
Author(s):  
M. Retter ◽  
P. Kienzler ◽  
P. F. Germann
Keyword(s):  
Three Dimensional ◽  
Volume Flux ◽  
Wetting Front ◽  
Experimental Assessment ◽  
Mean Values ◽  
Top Soil ◽  
Wave Guides ◽  
The Mean ◽  
Vector Approach

Abstract. The focus is the experimental assessment of in-situ flow vectors in a hillslope soil. We selected a 100 m2 trenched hillslope study site. During prescribed sprinkling an obliquely installed TDR wave-guide provides for the velocity of the wetting front in its direction. A triplet of wave-guides mounted along the sides of an hypothetical tetrahedron, with its peak pointing down, produces a three-dimensional vector of the wetting front. The method is based on the passing of wetting fronts. We analysed 34 vectors along the hillslope at distributed locations and at soil depths from 11 cm (representing top soil) to 40 cm (close to bedrock interface). The mean values resulted as follows vx=16.1 mm min-1, vy=-0.2 mm min-1, and vz=11.9 mm min-1. The velocity vectors of the wetting fronts were generally gravity dominated and downslope orientated. Downslope direction (x-axis) dominated close to bedrock, whereas no preference between vertical and downslope direction was found in vectors close to the surface. The velocities along the contours (y-axis) varied widely. The Kruskal-Wallis tests indicated that the different upslope sprinkling areas had no influence on the orientation of the vectors. Vectors of volume flux density were also calculated for each triplet. The lateral velocities of the vector approach are compared with subsurface stromflow collected at the downhill end of the slope. Velocities were 25-140 times slower than lateral saturated tracer movements on top of the bedrock. Beside other points, we conclude that this method is restricted to non-complex substrate (skeleton or portion of big stones).

scholarly journals Six years of high-precision quasi-continuous atmospheric greenhouse gas measurements at Trainou Tower (Orléans Forest, France)

2014 ◽  
Vol 7 (1) ◽  
pp. 569-604 ◽  
Author(s):  
M. Schmidt ◽  
M. Lopez ◽  
C. Yver Kwok ◽  
C. Messager ◽  
M. Ramonet ◽  
...  
Keyword(s):  
In Situ Measurements ◽  
Atmospheric Measurements ◽  
Short Term ◽  
Gas Detector ◽  
Sampling Height ◽  
The Mean ◽  
Drying System ◽  
Gas Measurements ◽  
Television Tower

Abstract. Results from the Trainou tall tower measurement station installed in 2006, are presented for atmospheric measurements of CO2, CH4, N2O, SF6, CO, H2 mole fractions and Radon-222 activity. Air is sampled from four sampling heights (180 m, 100 m, 50 m and 5 m) of the Trainou 200 m television tower in the Orléans forest in France (47°57'53'' N, 2°06'45'' E, 131 m a.s.l.). The station is equipped with a custom-build CO2 analyzer (CARIBOU), which is based on a commercial NDIR analyser (Licor 6252), and a coupled gas chromatographic GC system equipped with ECD and FID (HP6890N, Agilent) and a reduction gas detector (PP1, Peak Performer). Air intakes, pumping and air drying system are shared between the CARIBOU and the GC systems. After some initial problems, we achieved short-term repeatability (1 sigma, over several days) for the GC system of of 0.05 ppm for CO2, 1.4 ppb for CH4, 0.25 ppb for N2O, 0.08 ppb for SF6, 0.88 ppb for CO and 3.8 for H2. The repeatability of the CARIBOU CO2 analyser is 0.06 ppm. In addition to the in-situ measurements, weekly flask sampling is performed, and flask air samples are analysed at the LSCE central laboratory for the same species as well for stable isotopes of CO2. The comparison between in-situ measurements and the flask sampling showed averaged differences of 0.08 ± 1.4 ppm CO2, 0.69 ± 7.3 ppb CH4, 0.64 ± 0.62 ppb N2O, 0.01 ± 0.1 ppt SF6 and 1.5 ± 5.3 ppb CO for the years 2008–2012. At Trainou station, the mean annual increase rates from 2007 to 2011 at the 180 m sampling height were 2.2 ppm yr−1 for CO2, 4 ppb yr−1 for CH4, 0.78 ppb yr−1 for N2O and 0.29 ppt yr−1 for SF6 respectively. For all species the 180 m sampling level showed the smallest diurnal variation. Mean diurnal gradients between the 50 m and the 180 m sampling level reached up to 30 ppm CO2, 15 ppm CH4 or 0.5 ppb N2O during night whereas the mean gradients are smaller than 0.5 ppm for CO2 and 1.5 ppb for CH4 during afternoon.

scholarly journals Spatial variations of ground level ozone concentrations in areas of different scales

2001 ◽  
Vol 35 (33) ◽  
pp. 5799-5807 ◽  
Author(s):  
Tsai-Yin Lin ◽  
Li-Hao Young ◽  
Chiu-Sen Wang
Keyword(s):  
Ground Level ◽  
Spatial Variations ◽  
Ground Level Ozone ◽  
Ozone Concentrations

scholarly journals Aerosol optical properties in the North China Plain during HaChi campaign: an in-situ optical closure study

2011 ◽  
Vol 11 (12) ◽  
pp. 5959-5973 ◽  
Author(s):  
N. Ma ◽  
C. S. Zhao ◽  
A. Nowak ◽  
T. Müller ◽  
S. Pfeifer ◽  
...  
Keyword(s):  
Optical Properties ◽  
North China Plain ◽  
North China ◽  
Scattering Coefficient ◽  
Aerosol Optical Properties ◽  
Mean Values ◽  
The North ◽  
The North China Plain ◽  
The Mean

Abstract. The largest uncertainty in the estimation of climate forcing stems from atmospheric aerosols. In early spring and summer of 2009, two periods of in-situ measurements on aerosol physical and chemical properties were conducted within the HaChi (Haze in China) project at Wuqing, a town between Beijing and Tianjin in the North China Plain (NCP). Aerosol optical properties, including the scattering coefficient (σsp), the hemispheric back scattering coefficient (σbsp), the absorption coefficient (σap), as well as the single scattering albedo (ω), are presented. The diurnal and seasonal variations are analyzed together with meteorology and satellite data. The mean values of σsp, 550 nm of the dry aerosol in spring and summer are 280±253 and 379±251 Mm−1, respectively. The average σap for the two periods is respectively 47±38 and 43±27 Mm−1. The mean values of ω at the wavelength of 637 nm are 0.82±0.05 and 0.86±0.05 for spring and summer, respectively. The relative high levels of σsp and σbsp are representative of the regional aerosol pollution in the NCP. Pronounced diurnal cycle of $σsp, σap and ω are found, mainly influenced by the evolution of boundary layer and the accumulation of local emissions during nighttime. The pollutants transported from the southwest of the NCP are more significant than that from the two megacities, Beijing and Tianjin, in both spring and summer. An optical closure experiment is conducted to better understand the uncertainties of the measurements. Good correlations (R>0.98) are found between the values measured by the nephelometer and the values calculated with a modified Mie model. The Monte Carlo simulation shows an uncertainty of about 30 % for the calculations. Considering all possible uncertainties of measurements, calculated σsp and σbsp agree well with the measured values, indicating a stable performance of instruments and thus reliable aerosol optical data.

scholarly journals Aerosol optical properties in the North China Plain during HaChi campaign: an in-situ optical closure study

2011 ◽  
Vol 11 (3) ◽  
pp. 9567-9605 ◽  
Author(s):  
N. Ma ◽  
C. S. Zhao ◽  
A. Nowak ◽  
T. Müller ◽  
S. Pfeifer ◽  
...  
Keyword(s):  
Optical Properties ◽  
North China Plain ◽  
North China ◽  
Aerosol Optical Properties ◽  
Mean Values ◽  
The North ◽  
The North China Plain ◽  
The Mean ◽  
Local Emissions

Abstract. The largest uncertainty in the estimation of radiative forcings on climate stems from atmospheric aerosols. In winter and summer of 2009, two periods of in-situ measurements on aerosol physical and chemical properties were conducted within the HaChi project at Wuqing, a town between Beijing and Tianjin in the North China Plain (NCP). Aerosol optical properties including scattering coefficient (σsp), hemispheric back scattering coefficient (σbsp), absorption coefficient (σap, as well as single scattering albedo (ω) are presented. The characteristics of diurnal and seasonal variations are analyzed together with the meteorological and satellite data. The mean values of σsp, 550 nm of the dry aerosol in winter and summer are 280 ± 253 and 379 ± 251 Mm−1, respectively. The average σap for the two periods are respectively 47 ± 38 and 43 ± 27 Mm−1. The mean values of ω are 0.83 ± 0.05 and 0.87 ± 0.05 for winter and summer, respectively. The relative high levels of σsp and σbsp are representative of the regional polluted aerosol of the North China Plain. Pronounced diurnal cycle of σsp, σap and ω are found, mainly influenced by the evolution of boundary layer and accumulation of local emissions during night-time. Regional transport of pollutants from southwest in the NCP is significant both in winter and summer, while high values of σsp and σap correlate with calm winds in winter, which indicating the significant contribution of local emissions. An optical closure experiment is conducted to better understand uncertainties of the measurements. Good correlations (R>0.98) are found between values measured by nephelometer and values calculated with a modified Mie model. Monte Carlo simulations show an uncertainty of about 30% for the calculations. Considering all possible uncertainties of measurements, calculated σsp and σbsp agree well with measured values, indicating a stable performance of instruments and thus a reliable aerosol optical data.

scholarly journals Polarization Measurements and Evaluation Based on Multidimensional Polarization Indices Applied in Analyzing Atmospheric Particulates

2021 ◽  
Vol 11 (13) ◽  
pp. 5992
Author(s):  
Riwei Liao ◽  
Wei Guo ◽  
Nan Zeng ◽  
Jun Guo ◽  
Yonghong He ◽  
...  
Keyword(s):  
Scientific Basis ◽  
Mean Values ◽  
Atmospheric Particulates ◽  
Online Identification ◽  
The Mean ◽  
Scattering Index ◽  
Aerosol Types ◽  
Identification And Characterization

Online identification and characterization of suspended aerosols can provide a scientific basis for understanding aerosol transformations, quantitatively evaluating the impacts on air quality, public health, and the source apportionment of different atmospheric particulate matters. In this study, we confirm the validity of our developed high-throughput multi-angle polarized scattering vector detection of aerosols and multidimensional polarization scattering index systems. By observation of the mean values, variance, and Wilk’s Lambda of multidimensional polarization indices for different aerosol types, the polarization index shows unique characterization abilities for aerosol properties, and the optimal combination of polarization indices can always be found for a specific aerosol category with a high resolution and discrimination. Clearly, the multidimensional polarization indices of individual aerosols are more suitable for online and real-time aerosol identification and even help to explain the in situ microphysical characteristics of aerosols or evaluate the dynamic evolution of aerosols.

Cigarette smoke-induced ‘chronic bronchitis’: A study in situ of laryngo–tracheal hypersecretion in the rat

1987 ◽  
Vol 72 (5) ◽  
pp. 629-637 ◽  
Author(s):  
D. F. Rogers ◽  
N. C. Turner ◽  
C. Marriott ◽  
P. K. Jeffery
Keyword(s):  
Chronic Bronchitis ◽  
Cigarette Smoke ◽  
Specific Marker ◽  
Tissue Fluid ◽  
Mucous Secretion ◽  
Basal Secretion ◽  
Mucosal Permeability ◽  
Mean Values ◽  
The Mean

1. Mucous secretion and mucosal permeability by the larynx and trachea, isolated in situ, was investigated in normal rats and in those in which ‘chronic bronchitis' was induced by daily exposure to cigarette smoke for 2 weeks. Fucose was used as a specific marker for the secretion of mucus glycoprotein, and hexose and protein were markers both for mucus and plasma-type glycoproteins present in tissue fluid transudate. Albumin was used as an indicator of the contribution of serum to the secretions. 2. After equilibration, the mean basal secretion of fucose (μg/30 min collection) was significantly higher in ‘bronchitic’ rats than in the controls (P < 0.01). Mean values for controls were: fucose 3 (sem 1; n = 9), hexose 41 (sem 9; n = 8), protein 1082 (sem 385; n = 8), albumin <2 (n = 8); for ‘bronchitic’ rats the values were: 24 (sem 6; n = 7), 101 (sem 26; n = 8), 2000 (sem 520; n = 8) and <2 μg (n = 7) respectively. 3. In control and bronchitic animals acute administrations of cigarette smoke, blown directly through the laryngo-tracheal segment after equilibration, caused significant (P < 0.05) transient increases in the secretion of fucose, hexose and protein, but not of albumin.

Distensibility of small arteries of the dog lung

1991 ◽  
Vol 71 (5) ◽  
pp. 1714-1722 ◽  
Author(s):  
A. al-Tinawi ◽  
J. A. Madden ◽  
C. A. Dawson ◽  
J. H. Linehan ◽  
D. R. Harder ◽  
...  
Keyword(s):  
Transmural Pressure ◽  
Mean Values ◽  
Small Arteries ◽  
X Ray ◽  
Isolated Lung ◽  
Significant Difference ◽  
Pulmonary Arterial ◽  
The Mean ◽  
Lung Lobes

To obtain in situ measurements of the distensibility of small (100- to 1,000-microns-diam) pulmonary arterial vessels of the dog lung, X-ray angiograms were obtained from isolated lung lobes with the vascular pressure adjusted to various levels. The in situ diameter-pressure relationships were compared with the diameter-pressure relationships for small arteries that were dissected free from the lungs and cannulated with small glass pipettes for the measurement of diameter and transmural pressure. The diameter-vascular or diameter-transmural pressure curves from both in situ and cannulated vessels were sufficiently linear in the pressure range studied (0–30 Torr) that they could be characterized by linear regression to obtain estimates of D0, the diameter at zero vascular pressure, and beta, the change in diameter (micron) per Torr change in pressure. The vessel distensibility coefficient (alpha) was defined as alpha = beta/D0. The mean values of alpha were approximately 2.0 +/- 0.8%/Torr (SD) for the in situ vessels and 1.7 +/- 0.6%/Torr for the cannulated vessels, with no statistically significant difference between the two methods. The influence of vasoconstriction elicited by serotonin was evaluated in the in situ vessels. Serotonin-induced vasoconstriction caused a decrease in D0 and little change in alpha.

scholarly journals In Situ Synchrotron X-Ray Micro-Diffraction Investigation of Elastic Strains in Laminated Ti-Al Composites

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 668
Author(s):  
Tianbo Yu ◽  
Yan Du ◽  
Guohua Fan ◽  
Rozaliya Barabash ◽  
Dorte Juul Jensen ◽  
...  
Keyword(s):  
Compressive Strain ◽  
Spatial Variations ◽  
External Loading ◽  
Metal Composite ◽  
Tensile Direction ◽  
Mean Values ◽  
X Ray ◽  
Lattice Strains ◽  
Elastic Strains

Spatially resolved elastic strains in the bulk interior of a laminated Ti-Al metal composite were studied during in situ tensile loading at strains up to 1.66% by a synchrotron-based micro-diffraction technique, namely differential aperture X-ray microscopy (DAXM). For both Al and Ti grains, deviatoric elastic strains were estimated based on polychromatic X-ray microbeam diffraction, while lattice strains along the normal direction of the tensile sample were directly measured using monochromatic X-ray microbeam diffraction. The estimated deviatoric strains show large spatial variations, and the mean values are consistent with the external loading conditions, i.e., increasing tensile strain along the tensile direction and increasing compressive strain along the sample normal with increasing loading. The directly measured lattice strains also show large spatial variations, although the magnitude of this variation is smaller than that for the estimated deviatoric strain. The directly measured lattice strains in Ti grains are largely consistent with the external loading, whereas those in Al grains are in contradiction with the external loading. The causes of the experimental results are discussed and related to both the laminated microstructure of the composite material and the limitations of the techniques.

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