Kinetic and isotherm study of Cr(VI) biosorption from industrial effluents by biomass of dried sludge

2021 ◽  
Vol 209 ◽  
pp. 91-104
Author(s):  
Fatemeh Kariminejad ◽  
Samira Baghchevan Ghadimi ◽  
Farhad Rahmini ◽  
Mohsen Haghighi ◽  
Rojiar Akbari Sene ◽  
...  
1996 ◽  
Vol 34 (9) ◽  
pp. 9-15 ◽  
Author(s):  
B. W. Atkinson ◽  
F. Bux ◽  
H. C. Kasan

Metal contaminated industrial effluent, from a metal plating company, was exposed to waste activated sludge to optimise the biosorption process at laboratory scale. Metals assessed were Zn2+, Cu2+, Cd2+, Ni2+, Cr3+ and Cr6+, of which, Zn2+ was most prevalent. Biosorption rates of up to 96% were recorded for Zn2+ within the first 15 min., of the reaction, at initial concentrations of 110mg.1−1. Biomass displayed an average adsorptive capacity of 80% at metal concentrations of 50mg.1−1 and above. Both fully mixed and upflow column bioreactors were employed during experimentation, using wet and dried sludge. The findings of this study show that wet sludge, utilised as biosorbent in a fully mixed process, has superior potential for metal ion biosorption from an industrial effluent.


2021 ◽  
Author(s):  
Vandana Gupta ◽  
Athira Nair ◽  
Saurabh Pandey

Since the last few decades, environmental remediation through a sustainable approach is gaining importance. One such attempt has been made in the present work to remove heavy metals from industrial effluents using one of the most prominent animal wastes, the chicken feathers. Biosorption has been a promising technique to remove heavy metals from industrial effluents. In the present work, cleaned but untreated chicken feathers were used to remove Cu(II) ions from electroplating industry wastewater. The physicochemical characteristics like colour, pH, ash content, iodine number and bulk density of chicken feathers were also determined. The FT-IR spectrum of chicken feathers did not show a recognizable difference after biosorption which indicated physical adsorption. The adsorption isotherm study showed that the Freundich isotherm model was the best fit as compared to Langmuir isotherm model. The results obtained were supported statistically by using Chi-square test. In the desorption study, EDTA was found to be a most effective desorbing agent in comparison with acid, alkali and deionized water. Thus, the present work explores the efficiency of chicken feathers to act as biosrbent as remove heavy metals from industrial effluents in a simple, economic and sustainable manner


1985 ◽  
Vol 6 (2) ◽  
pp. 52-58 ◽  
Author(s):  
Susan T. Bagley

AbstractThe genus Klebsiella is seemingly ubiquitous in terms of its habitat associations. Klebsiella is a common opportunistic pathogen for humans and other animals, as well as being resident or transient flora (particularly in the gastrointestinal tract). Other habitats include sewage, drinking water, soils, surface waters, industrial effluents, and vegetation. Until recently, almost all these Klebsiella have been identified as one species, ie, K. pneumoniae. However, phenotypic and genotypic studies have shown that “K. pneumoniae” actually consists of at least four species, all with distinct characteristics and habitats. General habitat associations of Klebsiella species are as follows: K. pneumoniae—humans, animals, sewage, and polluted waters and soils; K. oxytoca—frequent association with most habitats; K. terrigena— unpolluted surface waters and soils, drinking water, and vegetation; K. planticola—sewage, polluted surface waters, soils, and vegetation; and K. ozaenae/K. rhinoscleromatis—infrequently detected (primarily with humans).


2018 ◽  
Vol 2 (1) ◽  
pp. 18-20 ◽  
Author(s):  
Muhammad Usman ◽  
Mian Bilal Khalid ◽  
Hafsa Yasin ◽  
Abdul Nasir, ◽  
Ch Arslan

2014 ◽  
Vol 13 (1) ◽  
pp. 15-20 ◽  
Author(s):  
Marcela Muntean ◽  
Anna-Maria Szoke ◽  
Ovidiu Dumitrescu ◽  
Sandor Meszaros
Keyword(s):  

Author(s):  
S Motaung ◽  
Jannie Maree ◽  
L Bologo ◽  
M de Beer ◽  
V Radebe
Keyword(s):  

2019 ◽  
pp. 1-8
Author(s):  
F. S. Nworie ◽  
S. O. Ngele ◽  
J. C. Onah

Metal ions present in waste samples, industrial effluents, acid mines and other aqueous media constitute a serious challenge in different human activities. Solvent extraction a technique for preconcentration, separation and identification of trace amount of metal ions coupled with multivariate chemometric technique was used for the determination of Fe(II) and Cr(III) from solutions in the presence of bis(salicylidene)ethylenediamine (SALEN). The influence of main extraction variables affecting the extraction efficiency was simultaneously studied and regression model equations illustrating the relationship between variables predicted. The extraction parameters (time of extraction, acid concentration, ligand concentration, temperature and metal concentration) were optimized using experimental designs with the contributions of the various parameters to extraction of the metal ions bound to the complexone evaluated using SPSS19.0 software. The statistically determined simulated models for the parameters were R2 = 0.946, 0.727, 0.793, 0.53, 0.53, 1.000 and F- values of 70.400, 13. 285, 15.348, 4.646 and 2.569×105 respectively for time of extraction, acid concentration, ligand concentration, temperature and metal concentration for Cr (III). For Fe (II), R2 = 0.243, 0.371, 0.519, 0.446, 1.000 and F-values of 0.964, 2.953, 4.310, 3.216 and 2.516×105 for time of extraction, acid concentration, ligand concentration, temperature and metal concentration respectively. The level of significance of the models as predicted was both lower than 5% making it feasible, efficient, reproducible and accurate. This means that metal ions at the conditions stated could be removed from waste samples, industrial effluents, acid mines and other aqueous media with extension in industrial scale application.


Author(s):  
Yukio Komai ◽  
Yukio Komai ◽  
Mana Sakata ◽  
Mana Sakata ◽  
Masaki Nakajima ◽  
...  

Osaka Bay is the most polluted enclosed sea area, in which is located the eastern part of the Seto Inland Sea, Japan. There are four kinds of sources on loadings of nutrients to Osaka Bay, which are land including rivers and industrial effluents beside coast, ocean sea water, release from bottom sediment to sea water, and wet and dry deposition from air. The pollutant loadings inflowing from the land to Osaka Bay have been cut by various policies since 1970’s. The concentrations of nutrients in the inner part of Osaka Bay have showed an obvious decreasing tendency. However, the water quality in offshore sea has not satisfied the environmental standard on nutrients. We investigated the amount of nutrients released from bottom sediments. The core samples were taken at two stations in the inner part of Osaka Bay once a month from February to November, 2015. The core incubation experiment in laboratory was conducted for 24 hours according to Tada et.al. The concentrations of ammonium nitrogen (NH4-N) and phosphate phosphorus (PO4-P) were measured by an automatic analyzer. The flux showed similar range with the values investigated in 1986. The results suggested that the flux of nutrients from bottom sediments in the inner part of Osaka Bay has not decreased during summer season at least since 1985. Therefore, the contribution of release from bottom sediment on the nutrients budget would relatively become larger in inner part of Osaka Bay.


1977 ◽  
Vol 12 (1) ◽  
pp. 191-212
Author(s):  
B. Volesky ◽  
Q. Samak ◽  
P. Waller

Abstract Review of the available results appearing in the recent literature is presented focusing particularly upon the effects of metallic ions such as Cr, Cu, Zn, Cd, Hg, V, Zn, Ni and Co. Some original data involving the effects of Na are presented and discussed. Development of parameters used in evaluating the influence of toxic or inhibitory species on the mixed microbial population of an activated sludge system is of crucial importance and different techniques employed such as BOD-COD-TOC-removal rates, Oxygen Uptake Rate, and others are discussed, showing relative inadequacy of currently applied assays. From the data available, certain trends can be discerned. There is a definite threshold concentration for each metallic ion, depending on the organic load of the feed. In the order of increasing toxicity to activated sludge systems reflected in lower BOD removals the following metals have been listed as inhibiting factors at concentrations starting from 1 ppm applied on a continuous basis: hexavalent chromium, cobalt, zinc, cadmium, trivalent chromium, copper and nickel. Metals in combination have not been reported to exhibit any significantly different effects as compared to those observed with individually introduced metallic ions. Tolerance of some activated sludge systems to shock loadings by various inorganic ions and metals is reviewed. The conclusions are of particular importance for estimating the performance of biox systems handling industrial effluents which are likely to contain toxic components of inorganic or metallic nature.


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