scholarly journals MYCOREMEDIATION OF HEAVY METALS PRESENT IN CONTAMINATED AGRICULTURAL SOIL

2020 ◽  
Vol 21 (supplement 1) ◽  
Author(s):  
Manisha Shalini Besra ◽  
Prashant Kumar Mishra
Keyword(s):  
Heavy Metals ◽  
Soil Sample ◽  
Agricultural Soil ◽  
Sampling Site ◽  
Control Sample ◽  
Soil Samples ◽  
The Other ◽  
Mushroom Cultivation ◽  
Initial Screening ◽  
Barren Land

In this study, Mycoremediation technique was used to analyse the potential of mushroom in absorbing heavy metals from contaminated soil. A small village Sitagarha located in Hazaribag, Jharkhand was selected as sampling site. Soil sample was collected from two different sites – from field where cow manure was used as fertilizer and the other soil sample where chemical fertilizer was mixed. A control sample was also collected from nearby barren land where no cultivation was carried out since decades. After initial screening, three heavy metals Cu, Cd and Zn were selected to carry out further studies. The soil sample was processed in laboratory and analysed in AAS to detect the concentration of heavy metals. Results showed the presence of heavy metals as – Cd > Cu > Zn. Further these soil samples were mixed along with straw and spawn to prepare a mushroom cultivation bag as mushroom has the property to absorb heavy metals. The result of absorbance of heavy metals by mushroom was somewhere an indication that mycoremediation proofs to be an important tool to fight against heavy metals.

scholarly journals Evaluation of heavy metals in agricultural soils from Katsina state Nigeria

2020 ◽  
Vol 8 (2) ◽  
Author(s):  
Aliyu Ibrahim Yaradua ◽  
Adamu Jibrin Alhassan ◽  
Abdullahi Nasir ◽  
Kabir Ibrahim Matazu ◽  
Aminu Usman ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Enrichment Factor ◽  
Agricultural Soil ◽  
Agricultural Soils ◽  
Sampling Site ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Soil Samples ◽  
Pollution Load

This work contributes to the monitoring of Agricultural soil pollution in Katsina State, North western Nigeria by assessing the degree of heavy metal pollution in Agricultural soil samples. The study was conducted in the year 2017 within some catchment areas located within the 3 senatorial zones that constitute to make up the state (Katsina senatorial zone: Birchi, Dutsinma and Katsina; Daura senatorial zone: Daura, Ingawa and Zango; Funtua senatorial zone: Dabai, Funtua, Kafur, Malunfashi and Matazu).  Analysis for the concentration of these heavy metals; Cr, Cd, Fe, Ni, Mn, Pb and Zn was conducted by the use of AAS (by Atomic Absorption Spectrophotometry) method. . Several indices were used to assess the metal contamination levels in the Agricultural soil samples, namely; Geo-accumulation Index (Igeo), Enrichment Factor (EF), Contamination Factor (CF), Degree of Contamination (Cd) and Pollution Load Index (PLI). The result of this study has shown that generally among the heavy metals evaluated, the highest concentration was observed for Fe (range: 20.195-38.347 ppm), followed by Zn (range: 0.528-1.134 ppm), Pb (range: 0.256-0.627 ppm), Mn (range: 0.261-0.572 ppm) and Cr (range: 0.093-0.344 ppm). While Cd has the lowest concentration (range: 0.022-0.043 ppm). For all the site sampled the heavy metal Ni was below detection level (BDL). From the results of heavy metals I-geo values, according to Muller’s classification,  soil samples from Birchi, Daura, Dutsinma, Kafur and Zango were unpolluted (class 0) while soil samples from Dabai, Funtua, Ingawa, Katsina, Malunfashi and Matazu are moderately polluted (class 1). The result for the enrichment factor has shown that with the exception of the heavy metal Fe, which shows significant enrichment for all the sites sampled all the other heavy metals show deficiency to minimal enrichment. Also based on the contamination factors for all soil samples the heavy metal Fe has a CF values range of 1.2861-2.3240, indicating that the Agricultural soil samples are moderately contaminated with Fe. In contrast, the rest of the heavy metals exhibit low contamination in general. The value of PLI ranges from 0.2408 to 0.4935, indicating unpolluted to moderate pollution, with the sampling site for Katsina displaying the highest PLI value while the sampling site of Ingawa has the lowest PLI. The Eri values for all samples are all < 40, presenting low ecological risk.  The results suggest that the Agricultural soils samples from Katsina state has low contamination by the heavy metals evaluated.Key words: Agricultural soils, Heavy metals, Katsina state, Pollution load index, Contamination factor.

scholarly journals CONCENTRATION OF HEAVY METALS IN THE SOIL AND PLANTS AROUND WASTE DUMPSITES IN ENUGU METROPOLIS, NIGERIA

2019 ◽  
Vol 3 (1) ◽  
pp. 13
Author(s):  
M. N. Okeke ◽  
Paul Chukwuka Eze ◽  
C. N. Eze
Keyword(s):  
Heavy Metals ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Control Sample ◽  
Control Site ◽  
Soil Samples ◽  
Control Measures ◽  
Plant Sample ◽  
Solid Waste Disposal ◽  
Dump Site

<strong>Aims:</strong> The purpose of this project is to find the concentration of heavy metals (Cu, Zn, Pb, As, Cr, Ni, Cd, Fe and Mn) in the top soil and the plant around the waste dumpsite from Enugu municipal solid waste disposal sites. <strong>Methodology and results: </strong>This was done through collection of soil samples from four designated public municipal solid waste dump sites (Ngwo Umueze, Presidential, New-market and Emene) in Enugu metropolis. The soil samples were collected at 10 metres intervals away from the centre location point of each dump site at constant depth (0 - 15 cm were mixed together and sample picked from it). The samples collection design are as follows: centre (0m) of the dump sites, 10 metres, 20 metres, 30 metres and the control sample which measured 65 metres away from the centre of dumpsites at the same depth. Plant samples were taken just at the centre (0m) and control measures which is at 65 meters distance away from each dump sites. The Goat grasses harvested were taken to the lab to check and analyse its heavy metals intake from the soil. These samples were analysed using atomic absorption spectrophotometer (AA320N) model. On the average, high concentrations of Zn, Fe, Mn, Cu, and Pb were found in the soil samples collected at the centre of the dump sites as 141.70, 121.5, 75.53, 70.33 and 64.53mg/kg respectively. The lower concentrations were obtained in the soil samples taken at the control site which 65 metres distance away from the centre of the four dump sites as 12.00, 81.55, 8.70, 9.56 and 6.51mg/kg for Zn, Fe, Mn, Cu, and Pb respectively. In the plant sample, concentration of Fe (98.00 mg/kg) was found to be the highest in the root at New market dumpsites, while Nil concentration of as (Nil mg/kg) was the least value at Emene from the control distance. <strong>Conclusion, significance and impact study:</strong> SPSS statistical package was used to find out the significant differences between the treatments mean (heavy metals). The result shows that the heavy metals analyses were within the acceptable or permissible limit by WHO/FAO.

Quantification of heavy metals in agricultural soils: the influence of sieving in standard analytical methods

2020 ◽  
Author(s):  
Anne Karine Boulet ◽  
Adelcia Veiga ◽  
Carla Ferreira ◽  
António Ferreira
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Soil Sample ◽  
Analytical Methods ◽  
Agricultural Soils ◽  
Soil Samples ◽  
Metal Concentrations ◽  
Aqua Regia ◽  
Heavy Metal Concentrations ◽  
Pre Treatment

&lt;p&gt;Conservation of agriculture soils is a topic of major concern, namely through the increase of soil organic matter. SoilCare project (https://www.soilcare-project.eu/) aims to enhance the quality of agricultural soils in Europe, through the implementation and testing of Soil Improving Cropping Systems in 16 study sites. In Portugal, the application of urban sewage sludge amendments in agriculture soils has been investigated. However, this application is a sensitive topic, due to the risk of long term accumulation of heavy metals and consequent contamination of the soil. The recent Portuguese legislation (Decret-Law 103/2015) is more restrictive than the precedent one (Decret-Law 276/2009) in terms of maximum concentrations of heavy metals in agricultural soils. The analytical quantification of heavy metals, however, raises some methodological questions associated with soil sample pre-treatment, due to some imprecisions in standard analytical methods. For example, the ISO 11466 regarding the extraction in Aqua Regia provides two pre-treatment options: (i) sieve the soil sample with a 2 mm mesh (but if mass for analyses is &lt;2g, mill and sieve the sample &lt;250&amp;#181;m is required), or (ii) mill and sieve the soil sample through a 150&amp;#181;m mesh. On the other hand, the EN 13650 requests soil samples to be sieved at 500&amp;#181;m. Since heavy metals in the soil are usually associated with finer particles, the mesh size used during the pre-treatment of soil samples may affect their quantification.&lt;/p&gt;&lt;p&gt;This study aims to assess the impact of soil particle size on total heavy metal concentrations in the soil. Soil samples were collected at 0-30cm depth in an agricultural field with sandy loam texture, fertilized with urban sludge amendment for 3 years. These samples were then divided in four subsamples and sieved with 2mm, 500&amp;#181;m, 250&amp;#181;m and 106&amp;#181;m meshes (soil aggregates were broken softly but soil wasn&amp;#8217;t milled). Finer and coarser fractions were weighted and analyzed separately. Heavy metals were extracted with Aqua Regia method, using a mass for analyze of 3g, and quantified by atomic absorption spectrophotometer with graphite furnace (Cd) and flame (Cu, Ni, Pb, Zn and Cr).&lt;/p&gt;&lt;p&gt;Except for Cu, heavy metals concentrations increase linearly with the decline of the coarser fraction. This means that analyzing heavy metals content only in the finest fractions of the soil leads to an over estimation of their concentrations in the total soil. Results also show that coarser fractions of soil comprise lower, but not negligible, concentrations of heavy metals. Calculating heavy metal concentrations in the soil based on the weighted average of both fine and coarse fractions and associated concentrations, provide similar results to those driven by the analyses of heavy metals in the &lt;2mm fraction. This indicates that milling and analyzing finer fractions of the soil did not influence the quantification of heavy metals in total soil. Clearer indications on analytical procedures should be provided in analytical standards, in order to properly assess heavy metal concentrations and compare the results with soil quality standards legislated. &amp;#160;&lt;/p&gt;

scholarly journals Ecological Risk Assessment of Heavy Metals in Soil of Lagos State University, Epe, Lagos State, Nigeria

2021 ◽  
pp. 52-58
Author(s):  
L. Salami ◽  
J. G. Akinbomi ◽  
R. J. Patinvoh
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Risk Index ◽  
Control Sample ◽  
Potential Ecological Risk ◽  
Soil Samples ◽  
State University ◽  
Ecological Risk Index ◽  
Sampling Locations ◽  
Lagos State

Soil contaminated with heavy metals poses an ecological risk especially to public health. The aim of this work is to assess the ecological risk of heavy metals in soil of Lagos State University (LASU), Epe, Lagos State, Nigeria. Soil samples were collected from 8 different points in LASU which were stored in various polythene bags labeled SS1 – SS8. A control sample was taken 1 km away from LASU and was labeled SC9. All the sampling locations were identified using handheld Global Positioning System (GPS) for the purpose of universal identification. The soil samples were analysed for nickel (Ni), lead (Pb), copper (Cu), Zinc (Zn), chromium (Cr), cadmium (Cd) and Iron (Fe) using Atomic Absorption Spectrophotometer. Enrichment factor (EF), potential ecological risk (Ei) and ecological risk index (RI) were carried out using the data from the analysis. The results revealed that all the EF values were less than 2 except that of lead in SS1. The Ei values were less than 40 except that of lead in SS1. Moreover RI values of all the soil samples investigated were less than 150. It was obvious from this work that the soil of LASU, Epe, Lagos State, were not enriched with heavy metals and have a low potential ecological risk.

scholarly journals INDUCED DEGRADATION OF CRUDE OIL POLLUTED SOIL BY MICROBIAL AUGMENTATION

2017 ◽  
Vol 23 (4) ◽  
pp. 37-44
Author(s):  
SYLVESTER UWADIAE ◽  
EMIKE OMOAYENA
Keyword(s):  
Crude Oil ◽  
Soil Sample ◽  
Contaminated Soil ◽  
Polluted Soil ◽  
Soil Samples ◽  
The Other ◽  
Pseudomonas Sp ◽  
Hydrocarbon Content ◽  
Percentage Removal

This study was aimed at assessing the effectiveness of indigenous microbes for remediation of hydrocarbon contaminated soil by first increasing the population of the indigenous microbes via bioaugmentation. Soil samples were treated using a consortium of bacteria: Bacillus substilis and Pseudomonas sp. which were isolated and cultured from the contaminated soil. The non-bacteria injected soil sample had the highest hydrocarbon content (THC) of 271.021 in comparison with the other soil samples. The THC percentage removal of B1 (96.885 %), B2 (97.562 %), B3 (98.835 %), B4 (99.594 %) and B5 (99.540 %) were higher than that of the control; indicating that biodegradation actually took place.

scholarly journals Evaluation of Heavy Metals Contamination in Agricultural Soils

2021 ◽  
Author(s):  
Jyoti Rani ◽  
Sudesh Chaudhary ◽  
Tripti Agarwal
Keyword(s):  
Heavy Metals ◽  
Organic Carbon ◽  
Agricultural Soil ◽  
Agricultural Soils ◽  
Contamination Factor ◽  
Soil Samples ◽  
National Capital Region ◽  
Residential Areas ◽  
Heavy Metals Contamination ◽  
Irrigated Soils

Abstract The present study was conducted to assess heavy metals contamination in agricultural soils in the National Capital Region, Delhi. A total of 84 soil samples were collected from selected agricultural areas located near industries, national highways, state highways, Yamuna floodplain, residential complexes, and wastewater irrigated soils. Heavy metal concentrations (Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn), pH, and organic carbon (%) were analyzed in the collected soil samples. The average value of pH and organic carbon in the soil samples collected were 7.79±0.49 and 0.53±0.17 percent. Average concentrations of heavy metals in soils were found to be in the order of Fe> Al>Mn> Zn> Ni>Cr> Cu>Pb> Co> Cd with value as 14916.92 mg kg -1 , 13538.87 mg kg -1 , 277.16 mg kg -1 , 74.53 mg kg -1 , 35.34 mg kg -1 , 33.68 mg kg -1 , 22.94 mg kg -1 , 18.45 mg kg -1 , 1.88 mg kg -1 , and 0.92 mg kg -1 . A very high concentration of Fe (6640.09-32650.23 mg kg -1 ), Al (5631-27209.99 mg kg -1 ), Mn (73.8-735.72 mg kg -1 ), Zn (16.45-221.88 mg kg -1 ), Ni (7.63-192.63 mg kg -1 ), and Cr (9.65-127.21 mg kg -1 ) were recorded in agricultural soil samples. The average concentrations of Mn, Ni, and Zn in the soil samples were several times higher than their concentration in Indian natural background soils. A significant potential ecological risk has been noticed in nearly all the agricultural soil samples except for the samples collected nearby residential areas. The contamination factor has shown that most of the soil samples were moderately contaminated with Mn, Ni, Fe, and Cr and some soil samples were considerably to strongly contaminated with Cd, Zn, Pb, and Ni. Wastewater irrigated soils showed a moderate to a strong degree of accumulation of heavy metals (Cd, Ni, and Zn).

scholarly journals HEAVY METAL (Cu, Zn, Fe, Mn, Pb, Cd) CONCENTRATION IN SOILS OF TYUMEN

2020 ◽  
pp. 127-134
Author(s):  
A. S. Petukhov ◽  
T. A. Kremleva ◽  
N. A. Khritokhin ◽  
G. A. Petukhova ◽  
P. I. Kaidunova
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metallurgical Plant ◽  
Urban Areas ◽  
Limit Of Detection ◽  
Control Sample ◽  
Atomic Absorption Spectrophotometry ◽  
Soil Samples ◽  
Oil Refining ◽  
Toxic Heavy Metals

Toxic heavy metals contaminating soil get accumulated by plants, cause degradation of plant communities, and eventually penetrate human bodies with food. Therefore, it is urgent to investigate the content of heavy metal in soils in urban areas. The aim of this study was to investigate the concentration of Cu, Fe, Mn, Pb and Cd in soils of Tyumen. Top soil was sampled at the semi-clean control site near a highway, and at sites near metallurgical, motor-building, oil-refining and battery-manufacturing facilities in Tyumen, Russia. The concentration of active and acid-soluble forms of heavy metals was determined by atomic-absorption spectrophotometry. All the soil samples from urban areas were polluted with Fe. The samples collected near the battery manufactory and the metallurgical plant were contaminated with Pb and Zn, respectively, with maximum allowable concentration exceeded. The Cu, Mn and Zn content in most soil samples was higher than that in the control sample. The Cd content in all samples was at the lower limit of detection. The average percentages of active forms of Mn and Zn in soils were the highest among all the studied metals. The most intense accumulation of all heavy metals was observed near the battery manufactory and the metallurgical plant. The obtained results can be useful for environmental monitoring in Tyumen.

Diversity of Penicillium species isolated from heavy metal polluted soil in Guizhou Province, China

Phytotaxa ◽  
2016 ◽  
Vol 273 (3) ◽  
pp. 167 ◽  
Author(s):  
QING-XIN ZHOU ◽  
JOS HOUBRAKEN ◽  
QI-RUI LI ◽  
YING XU ◽  
KEVIN D. HYDE ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Internal Transcribed Spacer ◽  
Polluted Soil ◽  
Soil Samples ◽  
The Other ◽  
Guizhou Province ◽  
Internal Transcribed Spacer Region ◽  
Penicillium Species ◽  
A New Species ◽  
Β Tubulin

Seven Penicillium strains were isolated from soil samples polluted by heavy metals in different zones of Guizhou Province, China. Phenotypic identification proved to be difficult and this data was therefore supplemented with ribosomal internal transcribed spacer region and partial β-tubulin sequences. Comparison of the obtained sequences with references sequences showed that six strain belonged to Penicillium section Lanata-divaricata and one strain to section Sclerotiora. Three of the seven isolates belonged to a new species and were named here P. terrarumae sp. nov. The other four isolates were identified as P. cremeogriseum, P. guanacastense, P. griseopurpureum and P. oxalicum.

scholarly journals EFFECTS OF GAS FLARING ON THE MICROBIAL AND PHYSICOCHEMICAL PROPERTIES OF SOILS IN DELTA STATE

2021 ◽  
pp. e309
Author(s):  
Joseph Enuenwemba ◽  
Nduka Uraih ◽  
William Tanimowo ◽  
Hilda Emmanuel-Akerele
Keyword(s):  
Heavy Metals ◽  
Local Government ◽  
Physicochemical Properties ◽  
Ph Value ◽  
Soil Samples ◽  
Local Government Area ◽  
The Other ◽  
Gas Flaring ◽  
Significant Difference ◽  
The Impact

This study was carried out to determine the impact of gas flaring on microbial and physicochemical characteristics of soil around Ebedei and Kwale Flow Stations in Delta State, Nigeria. Soil samples were collected around Ebedei, in Ukwuani local government area, and Kwale, in Ndokwe West local government area both in Delta State, as well as in their environs. While the soil samples were collected for the analysis of physical, chemical and biological properties of the soil. The highest concentration of the heavy metals was obtained at 10m away from the flaring sites (P < 0.05). In both Ebedei and Kwale, the Fe concentration is significantly higher (1080.33 and 1080.68 mg/kg, respectively) that the other two heavy metals. However, there was a significant difference in the concentration of Zn between Ebedei and Kwale (P < 0.05). In both Ebedei and Kwale, the ECEC concentration is significantly higher (8.16 and 6.57 meq/100g, respectively) that the other chemical parameters. The physicochemical properties were similar at the different distances away from gas flaring sites (P> 0.05). EC decreased from 119.12µs/cm (at 10m) to 50.4 (at 100m) and then to 44.37 (at 200m). pH value remained acidic ranging from 4.97 (at 10m) to 5.9 (at 200m); moisture content ranged from 3.25% (at 10m) to 5.89% (at 200m); organic matter ranged from 1.07% (at 10m) to 1.61 % (at 200m); NO3 reduced sharply from 10.35 mg/kg (at 10m) to 3.92mg/kg (at 100m) and then to 2.4mg/kg (at 200m); phosphate dropped from 0.91mg/kg at (at 10m) to 0.95mg/kg (at 100m) to 0.42mg/kg (at 200m). There was a significant difference in the amount of some physicochemical properties in the soil samples collected from the gas flaring areas in Ebedei and Kwale (P<0.05). Ebedei, Kwale and environs constitute part of the most vegetative and productive areas of the Niger Delta region, these areas are also rich in several pharmacological properties and water resources. The Government should ensure the enforcement of laws aimed at minimizing the amount of gas flared into the atmosphere. Urgent efforts should be geared at cushioning the effect of gas flaring on the communities affected, probably by compensating them or, by relocating them to a more environmental friendly settlement with compensations.

scholarly journals Heavy Metals Content of Two Red Soils in Samar, Philippines

2011 ◽  
pp. 162-173 ◽  
Author(s):  
Ian Navarrete ◽  
Victor Asio
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Agricultural Soils ◽  
Soil Samples ◽  
Mining Activity ◽  
The Other ◽  
Mining Site ◽  
Aqua Regia ◽  
Red Soils ◽  
Heavy Metal Cd

The study evaluated the total and available heavy metal (Cd, Cu, Cr, Pb, Ni, and Zn) contents of two red soils in Samar, Philippines, one developed from slate near a mining site (Bagacay soil) and the other from serpentinite (Salcedo soil), a well-known source of heavy metals. Soil samples were collected from every horizon in each profile and samples were digested using aqua regia and NH4NO3 to determine total and available heavy metals content, respectively. Results revealed that Salcedo soil had high contents of total Cr (average: 1353 mg kg-1), total Ni (average: 610 mg kg-1), and available Cr (average: 0.19 mg kg-1) that exceeded the maximum allowable contents in agricultural soils but it had low amounts of the available form of the heavy metals. Bagacay soil showed very low contents of both total and available heavy metals due to their low amounts in the parent rock. The red Bagacay soil showed no effect of the nearby mining activity.

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