scholarly journals A comparison of measured HONO uptake and release with calculated source strengths in a heterogeneous forest environment

2015 ◽  
Vol 15 (16) ◽  
pp. 9237-9251 ◽  
Author(s):  
M. Sörgel ◽  
I. Trebs ◽  
D. Wu ◽  
A. Held
Keyword(s):  
Cross Sections ◽  
Forest Floor ◽  
Kinetic Data ◽  
Reaction Pathway ◽  
Vertical Mixing ◽  
Early Morning ◽  
Alternative Mechanism ◽  
Forest Environment ◽  
Emission Fluxes ◽  
Order Of Magnitude

Abstract. Vertical mixing ratio profiles of nitrous acid (HONO) were measured in a clearing and on the forest floor in a rural forest environment. For the forest floor, HONO was found to predominantly deposit, whereas for the clearing, net deposition dominated only during nighttime and net emissions were observed during daytime. For selected days, net fluxes of HONO were calculated from the measured profiles using the aerodynamic gradient method. The emission fluxes were in the range of 0.02 to 0.07 nmol m−2 s−1 and thus were in the lower range of previous observations. These fluxes were compared to the strengths of postulated HONO sources. Laboratory measurements of different soil samples from both sites revealed an upper limit for soil biogenic HONO emission fluxes of 0.025 nmol m−2 s−1. HONO formation by light-induced NO2 conversion was calculated to be below 0.03 nmol m−2 s−1 for the investigated days, which is comparable to the potential soil fluxes. Due to light saturation at low irradiance, this reaction pathway was largely found to be independent of light intensity, i.e. it was only dependent on ambient NO2. We used three different approaches based on measured leaf nitrate loadings for calculating HONO formation from HNO3 photolysis. While the first two approaches based on empirical HONO formation rates yielded values in the same order of magnitude as the estimated fluxes, the third approach based on available kinetic data of the postulated pathway failed to produce noticeable amounts of HONO. Estimates based on reported cross sections of adsorbed HNO3 indicate that the lifetime of adsorbed HNO3 was only about 15 min, which would imply a substantial renoxification. Although the photolysis of HNO3 was significantly enhanced at the surface, the subsequent light-induced conversion of the photolysis product NO2 did not produce considerable amounts of HONO. Consequently, this reaction might occur via an alternative mechanism. By explicitly calculating HONO formation based on available kinetic data and simple parameterizations, we showed that (a) for low NOx the light-induced conversion of NO2 on humic acids is already light saturated by the early morning, (b) HONO formation from photolysis of adsorbed HNO3 appears to proceed via an alternative mechanism and (c) estimates of HONO emissions from soil are very sensitive to mass transfer and acidic soils do not necessarily favour HONO emissions.

scholarly journals A comparison of measured HONO uptake and release with calculated source strengths in a heterogeneous forest environment

2015 ◽  
Vol 15 (2) ◽  
pp. 2119-2155 ◽  
Author(s):  
M. Sörgel ◽  
I. Trebs ◽  
D. Wu ◽  
A. Held
Keyword(s):  
Cross Sections ◽  
Forest Floor ◽  
Reaction Pathway ◽  
Vertical Mixing ◽  
Alternative Mechanism ◽  
Forest Environment ◽  
Emission Fluxes ◽  
Order Of Magnitude ◽  
Net Fluxes ◽  
Leaf Nitrate

Abstract. Vertical mixing ratio profiles of nitrous acid (HONO) were measured in a clearing and on the forest floor in a rural forest environment. For the forest floor, HONO was found to be predominantly deposited, whereas net deposition was dominating in the clearing only during nighttime and net emissions were observed during daytime. For selected days, net fluxes of HONO were calculated from the measured profiles using the aerodynamic gradient method. The emission fluxes were in the range of 0.02 to 0.07 nmol m−2 s−1, and, thus were in the lower range of previous observations. These fluxes were compared to the strengths of postulated HONO sources. Laboratory measurements of different soil samples from both sites revealed an upper limit for soil biogenic HONO emission fluxes of 0.025 nmol m−2 s−1. HONO formation by light induced NO2 conversion was calculated to be below 0.03 nmol m−2 s−1 for the investigated days, which is comparable to the potential soil fluxes. Due to light saturation at low irradiance, this reaction pathway was largely found to be independent of light intensity, i.e. it was only dependent on ambient NO2. We used three different approaches based on measured leaf nitrate loadings for calculating HONO formation from HNO3 photolysis. While the first two approaches based on empirical HONO formation rates yielded values in the same order of magnitude as the estimated fluxes, the third approach based on available kinetic data of the postulated pathway failed to produce noticeable amounts of HONO. Estimates based on reported cross sections of adsorbed HNO3 indicate that the lifetime of adsorbed HNO3 was only about 15 min, which would imply a substantial renoxification. Although the photolysis of HNO3 was significantly enhanced at the surface, the subsequent light induced conversion of the photolysis product NO2 did not produce considerable amounts of HONO. Consequently, this reaction might occur via an alternative mechanism.

Anonymized Firm Data under Test: Evidence from a Replication Study

2005 ◽  
Vol 225 (5) ◽  
Author(s):  
Joachim Wagner
Keyword(s):  
Cross Sections ◽  
Statistical Significance ◽  
Original Data ◽  
Replication Study ◽  
Firm Level ◽  
Level Data ◽  
Practical Usefulness ◽  
Order Of Magnitude ◽  
Anonymized Data ◽  
Firm Data

SummaryThis paper contributes to the literature on the use of anonymized firm level data by reporting results from a replication study. To test for the practical usefulness of anonymized data I selected two of my published papers based on different cross sections of firm data. The data used there were anonymized by micro aggregation. I replicated the analyses reported in the papers with the anonymized data, and then compared the results to those produced with the original data. Frequently, the reported levels of statistical significance differ. Furthermore, statistically significant coefficients sometimes differ by order of magnitude. Therefore, at least for the moderate sample sizes used here micro-aggregated firm data should not be considered as a tool for empirical research.

ISOSPIN DECOMPOSITION OF pp → NNππ CROSS SECTIONS — DO WE SEE A SIGN OF Δ(1600) EXCITATION IN THE nnπ+π+ CHANNEL?

2009 ◽  
Vol 24 (02n03) ◽  
pp. 450-453
Author(s):  
◽  
T. SKORODKO ◽  
M. BASHKANOV ◽  
D. BOGOSLOWSKY ◽  
H. CALÉN ◽  
...  
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Differential Cross ◽  
Pion Production ◽  
Significant Contribution ◽  
Differential Cross Sections ◽  
Pp Collisions ◽  
Theoretical Predictions ◽  
Order Of Magnitude ◽  
The Cross

The two-pion production in pp-collisions has been investigated in exclusive measurements from threshold up to Tp = 1.36 GeV . Total and differential cross sections have been obtained for the channels pnπ+π0, ppπ+π-, ppπ0π0 and also nnπ+π+. For intermediate incident energies Tp > 1 GeV , i.e. in the region, which is beyond the Roper excitation but at the onset of ΔΔ excitation the total ppπ0π0 cross section falls behind theoretical predictions by as much as an order of magnitude near 1.2 GeV, whereas the nnπ+π+ cross section is a factor of five larger than predicted. A model-unconstrained isospin decompostion of the cross section points to a significant contribution of an isospin 3/2 resonance other than the Δ(1232). As a possible candidate the Δ(1600) is discussed.

Theoretical studies on the one- and two-photon absorption of tetrabenzoporphyrins and phthalocyanines

2004 ◽  
Vol 82 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Xin Zhou ◽  
Ai-Min Ren ◽  
Ji-Kang Feng ◽  
Xiao-Juan Liu
Keyword(s):  
Dipole Moment ◽  
Cross Sections ◽  
Density Functional ◽  
Transition Dipole Moment ◽  
Photon Absorption ◽  
Transition Dipole ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Order Of Magnitude ◽  
The One

The one-photon absorption (OPA) properties of tetrabenzoporphyrins (TBPs) and phthalocyanines (Pcs) were studied using the semiempirical ZINDO method and time-dependent density functional theory (TDDFT), respectively. The compared results confirmed that the semiempirical ZINDO method was reasonably reliable when calculating the OPA of tetrabenzoporphyrins and phthalocyanines. On the basis of the OPA properties obtained from the ZINDO method, two-photon absorption (TPA) properties of two series of molecules were investigated, using ZINDO and sum-over-states (SOS) methods. The results showed that the TPA cross-sections of all molecules were in the range of 220.6 × 10–50 – 345.9 × 10–50 cm4·s·photon–1, which were in the same order of magnitude as the values reported in the literature. The relatively larger δ(ω) value for Pcs with respect to that for corresponding TBPs originates from larger intramolecular charge transfer, which can be characterized by the difference of dipole moment between S0 and S1 and the transition dipole moment between S1 and S5.Key words: two-photon absorption, ZINDO, sum-over-states, tetrabenzoporphyrin, phthalocyanines.

scholarly journals Submesoscale Cold Filaments in the Gulf Stream

2014 ◽  
Vol 44 (10) ◽  
pp. 2617-2643 ◽  
Author(s):  
Jonathan Gula ◽  
M. Jeroen Molemaker ◽  
James C. McWilliams
Keyword(s):  
Life Cycle ◽  
Gulf Stream ◽  
Baroclinic Instability ◽  
Vertical Mixing ◽  
Thermal Wind ◽  
Filament Dynamics ◽  
Oceanic Surface ◽  
Secondary Circulations ◽  
Order Of Magnitude ◽  
Surface Buoyancy

Abstract A set of realistic, very high-resolution simulations is made for the Gulf Stream region using the oceanic model Regional Oceanic Modeling System (ROMS) to study the life cycle of the intense submesoscale cold filaments that form on the subtropical gyre, interior wall of the Gulf Stream. The surface buoyancy gradients and ageostrophic secondary circulations intensify in response to the mesoscale strain field as predicted by the theory of filamentogenesis. It can be understood in terms of a dual frontogenetic process, along the lines understood for a single front. There is, however, a stronger secondary circulation due to the amplification at the center of a cold filament. Filament dynamics in the presence of a mixed layer are not adequately described by the classical thermal wind balance. The effect of vertical mixing of momentum due to turbulence in the surface layer is of the same order of magnitude as the pressure gradient and Coriolis force and contributes equally to a so-called turbulent thermal wind balance. Filamentogenesis is disrupted by vigorous submesoscale instabilities. The cause of the instability is the lateral shear as energy production by the horizontal Reynolds stress is the primary fluctuation source during the process; this contrasts with the usual baroclinic instability of submesoscale surface fronts. The filaments are lines of strong oceanic surface convergence as illustrated by the release of Lagrangian parcels in the Gulf Stream. Diabatic mixing is strong as parcels move across the filaments and downwell into the pycnocline. The life cycle of a filament is typically a few days in duration, from intensification to quasi stationarity to instability to dissipation.

Nucleon-antinucleon interaction in the new Tamm-Dancoff approximation

1960 ◽  
Vol 257 (1288) ◽  
pp. 59-73
Keyword(s):  
Integral Equation ◽  
Wave Function ◽  
Cross Sections ◽  
Nucleon Nucleon ◽  
Phase Shifts ◽  
Exchange Term ◽  
Total Cross Sections ◽  
Nucleon Wave Function ◽  
Usual Manner ◽  
Order Of Magnitude

The nucleon-antinucleon ( N-N ) problem is formulated in the new Tamm-Dancoff (NTD) approximation in the lowest order, and the integral equation for N-N̅ scattering derived, taking account of both the exchange and annihilation interactions. It is found convenient to represent the N-N̅ wave-function as a 4 x 4 matrix, rather than the usual 16 x 1 matrix for the nucleon-nucleon wave-function, and a complete correspondence is established between these two representations. The divergences associated with the annihilation interaction and their renormalization are discussed in detail in the following paper (Mitra & Saxena 1960; referred to as II). The integral equation with the exchange interaction alone, is then separated into eigenstates of T, J, L and S in the usual manner and the various phase shifts obtained. The results of II for the contribution of the annihilation term are then used to calculate the complete phase shifts from which the various cross-sections (scattering and charge exchange) are derived. The results indicate that while the exchange term alone gives too small values for the total cross-sections versus energy, inclusion of the annihilation interaction without renormalization effects makes the cross-sections nearly three times larger than those observed. On the other hand, inclusion of the finite effects of renormalization (which manifest themselves essentially as a suppression of the virtual meson propagator) brings down these cross-sections to the order of magnitude of the observed ones.

Charge moderated preplanetary growth from single grains to giant aggregates

2021 ◽  
Author(s):  
Felix Jungmann ◽  
Jens Teiser ◽  
Maximilian Kruss ◽  
Tobias Steinpilz ◽  
Kolja Joeris ◽  
...  
Keyword(s):  
Cross Sections ◽  
Planet Formation ◽  
Dipole Moments ◽  
Copper Plate ◽  
Net Charge ◽  
Electrostatic Charges ◽  
Ongoing Work ◽  
Astrophysical Journal ◽  
Stable Clusters ◽  
Order Of Magnitude

<p>In early phases of planet formation, bouncing and fragmentation barriers still represent major obstacles. Beginning at micrometer, dust can readily grow to sub-millimeter size in collisions due to cohesion before bouncing prevails. Later, streaming instabilities trigger further growth which might finally results into planetesimal formation by gravitational collapse. However, for streaming instabilities sub-millimeter grains might be too small, therefore there is gap of at least 1 order of magnitude in size which needs to be bridged.</p> <p>Here, we present our ongoing work how to bridge this gap by charge moderated aggregation [1]. When two (dielectric) grains collide they charge. This tribocharging or collisional charging is omnipresent in nature. We designed drop tower experiments in which we generated charges on glass and basalt grains by collisions in a shaker. In microgravity, the particle trajectories and collisions were observed, and charges were measured by applying an electric field.</p> <p>In early work, we analyzed millimeter-sized glass grain collisions with a copper plate. The coefficient of restitution increased with the charge on a single grain due to mirror charge forces. That means highly charged grains tend to stick more easily to surfaces than uncharged grains. The velocity where sticking is possible was increased by a factor of 100 up to several dm/s [2].<br /> <br />More recently, we used half millimeter basalt spheres and observed sticking events at several cm/s among grains themselves [3]. This is also way higher than predicted by adhesion. In a number of cases, we could observe the sequential formation of aggregates of up to ten single grains. During approach the grains are accelerated due to net charge Coulomb forces but likely also due to higher order charges on the surfaces in agreement to earlier measurements of strong permanent dipole moments [4]. Attraction increases collision cross-sections and the growth is sped up. Growth only stopped by the end of microgravity [3]. </p> <p>To observe the formation of still larger aggregates we developed a new setup, in which a dense cloud of 150 µm diameter basalt grains was continuously agitated slightly under microgravity and in vacuum. Here, the growth of a giant aggregate of centimeter size was observed collecting nearly all material in one cluster [5].</p> <p>To conclude, in experiments under various conditions, we see strong evidence that electrostatic charges on grains are able to conquer the bouncing barrier. We observed the bottom-up growth tracking individual particles, stable clusters emerging from dense regions and the formation of giant clusters during agitation. These are all bricks in the wall giving evidence that collisional charging might play a crucial role in planet formation.</p> <p><strong>References:</strong></p> <p>[1] Steinpilz, T.; Joeris, K.; Jungmann, F.; Wolf, D.; Brendel, L.; Teiser, J.; Shinbrot, T.; Wurm, G. Nature Physics 2020a, 16, 225-229.</p> <p>[2] Jungmann, F.; Steinpilz, T.; Teiser, J.; Wurm, G. Journal of Physics Communications 2018, 2 095009, 095009.</p> <p>[3] Jungmann, F.;Wurm, G. Astronomy and Astrophysics 2021, DOI: https://doi.org/10.1051/0004-6361/202039430.</p> <p>[4] Steinpilz, T.; Jungmann, F.; Joeris, K.; Teiser, J.; Wurm, G. New Journal of Physics 2020b, 22, 093025.</p> <p>[5] Teiser, J.; Kruss, M.; Jungmann, F.; Wurm, G. The Astrophysical Journal Letters 2021, 908, L22.</p>

scholarly journals Impact of Cyclonic Ocean Eddies on Upper Ocean Thermodynamic Response to Typhoon Soudelor

2019 ◽  
Vol 11 (8) ◽  
pp. 938 ◽  
Author(s):  
Jue Ning ◽  
Qing Xu ◽  
Han Zhang ◽  
Tao Wang ◽  
Kaiguo Fan
Keyword(s):  
Vertical Mixing ◽  
Heat Content ◽  
Mesoscale Eddies ◽  
Upper Ocean ◽  
Surface Cooling ◽  
Ocean Eddies ◽  
Horizontal Advection ◽  
Content Change ◽  
Order Of Magnitude ◽  
The Impact

By using multiplatform satellite datasets, Argo observations and numerical model data, the upper ocean thermodynamic responses to Super Typhoon Soudelor are investigated with a focus on the impact of an ocean cyclonic eddy (CE). In addition to the significant surface cooling inside the CE region, an abnormally large rising in subsurface temperature is observed. The maximum warming and heat content change (HCC) reach up to 4.37 °C and 1.73 GJ/m2, respectively. Moreover, the HCC is an order of magnitude larger than that calculated from statistical analysis of Argo profile data in the previous study which only considered the effects caused by typhoons. Meanwhile, the subsurface warming outside the CE is merely 1.74 °C with HCC of 0.39 GJ/m2. Previous studies suggested that typhoon-induced vertical mixing is the primary factor causing subsurface warming but these studies ignored an important mechanism related to the horizontal advection caused by the rotation and movement of mesoscale eddies. This study documents that the eddy-induced horizontal advection has a great impact on the upper ocean responses to typhoons. Therefore, the influence of eddies should be considered when studying the responses of upper ocean to typhoons with pre-existing mesoscale eddies.

scholarly journals Numerical Simulations of Encounters of Hard Binaries

1985 ◽  
Vol 113 ◽  
pp. 335-338
Author(s):  
Seppo Mikkola
Keyword(s):  
Cross Sections ◽  
Transfer Rate ◽  
Binding Energies ◽  
Body System ◽  
Energy Transfer Rate ◽  
Orbital Elements ◽  
Numerical Integrations ◽  
Order Of Magnitude ◽  
Three Body ◽  
Theory And Experiments

Results from numerical integrations of random binary-binary encounters have been used to obtain various cross-sections and outcome distributions for the four-body scattering. The initial orbital elements were chosen randomly except the Kepler-energies for which various selected values were used. Rough estimates for mass effects were obtained by simulating encounters of binaries with unequal component masses.We developed a semi-analytical theory for obtaining the types and energies of the outcome configurations. The theory contains some adjustable parameters, the values of which we deduced by comparing the theory and experiments.The energy transfer rate by collisions (=outcome is not two binaries) dominates over that due to fly-by's by an order of magnitude, provided that the binaries are hard. The formation of a hierarchical three-body system is fairly common. In a collision of energetically similar very hard binaries the probability is about 20 percent, while it is greater than 50 percent if the binding energies differ by a factor of more than four.

Collision excitation of sodium cyanide molecule by helium at low temperature

2019 ◽  
Vol 489 (3) ◽  
pp. 4322-4328
Author(s):  
C Gharbi ◽  
Y Ajili ◽  
D Ben Abdallah ◽  
M Mogren Al Mogren ◽  
M Hochlaf
Keyword(s):  
Electronic Structure ◽  
Cross Sections ◽  
Energy Surface ◽  
Three Dimensional ◽  
Sodium Cyanide ◽  
Rate Coefficients ◽  
Quantum Scattering ◽  
Stable Form ◽  
Excitation Cross Sections ◽  
Order Of Magnitude

ABSTRACT Cyanides/isocyanides are the most common metal-containing molecules in interstellar medium. In this work, quantum scattering calculations were carried out to determine the rotational (de-)excitation cross-sections of the most stable form of the sodium cyanide molecule, t-NaCN, in collision with the helium atom. Rate coefficients for the first 43 rotational levels (up to ${j_{{K_a}{K_c}}}$ = 63,3) of NaCN were determined for kinetic temperatures ranging from 1 to 30 K. Prior to that, we constructed a new three-dimensional potential energy surface (3D-PES) for the t-NaCN–He interacting system. These electronic structure computations are done at the CCSD(T)-F12/aug-cc-pVTZ level of theory. Computations show the dominance of Δj = ΔKc = −1 transitions, which is related to the dissymmetric shape of the t-NaCN–He 3D-PES. The NaCN–He rate coefficients are of the same order of magnitude (∼10−11 cm3.s−1) as those of other metal CN-containing molecules such as MgCN and AlCN in collision with He. This work is a contribution for understanding and modelling the abundances and chemistry of nitriles in astrophysical media.

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