scholarly journals Aerosol and VOC emission factor measurements for African anthropogenic sources

2017 ◽  
Author(s):  
Sekou Keita ◽  
Cathy Liousse ◽  
Véronique Yoboué ◽  
Pamela Dominutti ◽  
Benjamin Guinot ◽  
...  
Keyword(s):  
Particulate Matter ◽  
Organic Carbon ◽  
West Africa ◽  
Black Carbon ◽  
Emission Factor ◽  
Emission Factors ◽  
Anthropogenic Sources ◽  
Total Particulate Matter ◽  
Wood Burning ◽  
Wheeled Vehicles

Abstract. A number of campaigns have been carried out to establish the emission factors of pollutants from fuel combustion in West Africa, as part of work package 2 (‘Air Pollution and Health’) of the DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) FP7 program. Emission sources considered here include wood and charcoal burning, charcoal making, open waste burning, and vehicles including trucks, cars, buses and two-wheeled vehicles. Emission factors of total particulate matter, black carbon, primary organic carbon and non-methane volatile organic compounds (NMVOC) have been established. In addition, emission factor measurements were performed in combustion chambers in order to reproduce field burning conditions for tropical hardwood, and obtain particulate emission factors by size (PM0.25, PM1, PM2.5 and PM10). Aerosol samples were collected on quartz filters and analysed using gravimetric and thermal methods. The emission factors of 50 NMVOC species were determined using systematic off-line sampling. Emission factors from wood burning for black carbon, organic carbon and total particulate matter were 0.8 ± 0.4 g/kg of dry matter (dm), 9.29 ± 3.82 g/kg dm and 34.54 ± 20.6 g/kg dm, respectively. From traffic sources, the highest emission factors for all particulate species were emitted from two wheeled vehicles with two-stroke engines (2.74 g/kg fuel for black carbon, 65.11 g/kg fuel for organic carbon and 496 g/kg fuel for total particulate matter). The emissions of NMVOCs were lower than those of particles for all sources aside from traffic. The largest NMVOC emissions were observed for two-stroke two-wheeled vehicles, which were up to three times higher than emissions from light-duty and heavy-duty vehicles. Isoprene and monoterpenes, which are usually associated with biogenic emissions, were present in almost all anthropogenic source categories and could be as significant as aromatic emissions in wood burning (1 g/kg dm). Black carbon was primarily emitted in the ultrafine fraction, with 77 % of the total mass being emitted as particles smaller than 0.25 µm. This study observed higher particle and NMVOC emission factors than those in the current literature. This study underlines the important role of in-situ measurements in deriving realistic and representative emission factors.

scholarly journals Particle and VOC emission factor measurements for anthropogenic sources in West Africa

2018 ◽  
Vol 18 (10) ◽  
pp. 7691-7708 ◽  
Author(s):  
Sekou Keita ◽  
Cathy Liousse ◽  
Véronique Yoboué ◽  
Pamela Dominutti ◽  
Benjamin Guinot ◽  
...  
Keyword(s):  
West Africa ◽  
Emission Factor ◽  
Gravimetric Method ◽  
Emission Factors ◽  
Anthropogenic Sources ◽  
Thermal Methods ◽  
Particulate Emission ◽  
Voc Emission ◽  
Tropical Hardwood ◽  
Wheeled Vehicles

Abstract. A number of campaigns have been carried out to establish the emission factors of pollutants from fuel combustion in West Africa, as part of work package 2 (“Air Pollution and Health”) of the DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) FP7 program. Emission sources considered here include wood (hevea and iroko) and charcoal burning, charcoal making, open trash burning, and vehicle emissions, including trucks, cars, buses and two-wheeled vehicles. Emission factors of total particulate matter (TPM), elemental carbon (EC), primary organic carbon (OC) and volatile organic compounds (VOCs) have been established. In addition, emission factor measurements were performed in combustion chambers in order to reproduce field burning conditions for a tropical hardwood (hevea), and obtain particulate emission factors by size (PM0.25, PM1, PM2.5 and PM10). Particle samples were collected on quartz fiber filters and analyzed using gravimetric method for TPM and thermal methods for EC and OC. The emission factors of 58 VOC species were determined using offline sampling on a sorbent tube. Emission factor results for two species of tropical hardwood burning of EC, OC and TPM are 0.98 ± 0.46 g kg−1 of fuel burned (g kg−1), 11.05 ± 4.55 and 41.12 ± 24.62 g kg−1, respectively. For traffic sources, the highest emission factors among particulate species are found for the two-wheeled vehicles with two-stroke engines (2.74 g kg−1 fuel for EC, 65.11 g kg−1 fuel for OC and 496 g kg−1 fuel for TPM). The largest VOC emissions are observed for two-stroke two-wheeled vehicles, which are up to 3 times higher than emissions from light-duty and heavy-duty vehicles. Isoprene and monoterpenes, which are usually associated with biogenic emissions, are present in almost all anthropogenic sources investigated during this work and could be as significant as aromatic emissions in wood burning (1 g kg−1 fuel). EC is primarily emitted in the ultrafine fraction, with 77 % of the total mass being emitted as particles smaller than 0.25 µm. The particles and VOC emission factors obtained in this study are generally higher than those in the literature whose values are discussed in this paper. This study underlines the important role of in situ measurements in deriving realistic and representative emission factors.

scholarly journals Emission Factors for Biofuels and Coal Combustion in a Domestic Boiler of 18 kW

Atmosphere ◽  
2019 ◽  
Vol 10 (12) ◽  
pp. 771
Author(s):  
Marianna Czaplicka ◽  
Ewelina Cieślik ◽  
Bogusław Komosiński ◽  
Tomasz Rachwał
Keyword(s):  
Particulate Matter ◽  
Organic Carbon ◽  
Coal Combustion ◽  
Elemental Carbon ◽  
Emission Factors ◽  
Operating Conditions ◽  
Pollutant Emissions ◽  
Molecular Diagnostic ◽  
Diagnostic Ratios ◽  
Total Particulate Matter

The differences in the pollutant emissions from the combustion of bituminous coal and biofuels (wood, straw, and miscanthus pellets) under real-world boiler operating conditions were investigated. The experiments were performed on an experimental installation that comprised an 18 kW boiler, used in domestic central heating systems, equipped with a retort furnace, an automatic fuel feeder, a combustion air fan, and a fuel storage bin. The emission factors of gaseous pollutants, particulate matter, organic carbon, elemental carbon, and polycyclic aromatic hydrocarbons (PAHs), as well as some PAH concentration ratios for coal and biofuel combustion, were determined. The obtained results indicate that fuel properties have a strong influence on the emission factors of gaseous and carbonaceous pollutants. The total particulate matter (PM) emissions from the biofuel combustion were about 5-fold lower than those from the coal burned in the same boiler. The emission factors of the total carbons from the biofuel combustion were between 10 and 20 times lower than those from the coal combustion. The mean organic carbon (OC) and elemental carbon (EC) emission factors, based on the burned fuel, were 161–232 and 42–221 mg/kg for the biofuels and 1264 and 3410 g/kg for the coal, respectively. The obtained results indicate that molecular diagnostic ratios, based on the concentration of PAHs, vary significantly, depending on the fuel type.

scholarly journals Anthropogenic, biomass burning, and volcanic emissions of black carbon, organic carbon, and SO<sub>2</sub> from 1980 to 2010 for hindcast model experiments

2012 ◽  
Vol 12 (9) ◽  
pp. 24895-24954 ◽  
Author(s):  
T. Diehl ◽  
A. Heil ◽  
M. Chin ◽  
X. Pan ◽  
D. Streets ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Black Carbon ◽  
Biomass Burning ◽  
Sharp Decrease ◽  
Emission Factors ◽  
Horizontal Resolution ◽  
Anthropogenic Sources ◽  
Anthropogenic Emissions ◽  
Volcanic Emissions ◽  
So2 Emissions

Abstract. Two historical emission inventories of black carbon (BC), primary organic carbon (OC), and SO2 emissions from land-based anthropogenic sources, ocean-going vessels, air traffic, biomass burning, and volcanoes are presented and discussed for the period 1980–2010. These gridded inventories are provided to the internationally coordinated AeroCom Phase II multi-model hindcast experiments. The horizontal resolution is 0.5°×0.5° and 1.0°×1.0°, while the temporal resolution varies from daily for volcanoes to monthly for biomass burning and aircraft emissions, and annual averages for land-based and ship emissions. One inventory is based on inter-annually varying activity rates of land-based anthropogenic emissions and shows strong variability within a decade, while the other one is derived from interpolation between decadal endpoints and thus exhibits linear trends within a decade. Both datasets capture the major trends of decreasing anthropogenic emissions over the USA and Western Europe since 1980, a sharp decrease around 1990 over Eastern Europe and the former USSR, and a steep increase after 2000 over East and South Asia. The inventory differences for the combined anthropogenic and biomass burning emissions in the year 2005 are 34% for BC, 46% for OC, and 13% for SO2. They vary strongly depending on species, year and region, from about 10% to 40% in most cases, but in some cases the inventories differ by 100% or more. Differences in emissions from wild-land fires are caused only by different choices of the emission factors for years after 1996 which vary by a factor of about 1 to 2 for OC depending on region, and by a combination of emission factors and the amount of dry mass burned for years up to 1996. Volcanic SO2 emissions, which are only provided in one inventory, include emissions from explosive, effusive, and quiescent degassing events for 1167 volcanoes.

scholarly journals The EMEP Intensive Measurement Period campaign, 2008–2009: Characterizing the carbonaceous aerosol at nine rural sites in Europe

2018 ◽  
Author(s):  
Karl Espen Yttri ◽  
David Simpson ◽  
Robert Bergström ◽  
Gyula Kiss ◽  
Sönke Szidat ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Biomass Burning ◽  
Fossil Fuel ◽  
Carbonaceous Aerosol ◽  
Anthropogenic Sources ◽  
Anthropogenic Source ◽  
Emission Inventories ◽  
Model Calculations ◽  
Natural Sources ◽  
Wood Burning

Abstract. Source apportionment (SA) of carbonaceous aerosol was performed as part of the EMEP Intensive Measurement Periods (EIMPs), conducted in fall 2008 and winter/spring 2009. Levels of elemental carbon (EC), particulate organic carbon (OCp), particulate total carbon (TCp), levoglucosan and 14C in PM10, observed at nine European rural background sites, were used as input for the SA, whereas Latin Hypercube Sampling (LHS) was used to statistically treat the multitude of possible combinations resulting when ambient concentrations were combined with appropriate emission ratios. Five predefined sources/subcategories of carbonaceous aerosol were apportioned: Elemental and organic carbon from combustion of biomass (ECbb and OCbb) and from fossil fuel (ECff and OCff) sources, as well as remaining non-fossil organic carbon (OCrnf), typically dominated by natural sources. The carbonaceous aerosol concentration decreased from South to North, as did the concentration of the apportioned carbonaceous aerosol. OCrnf was more abundant in fall compared to winter/spring, reflecting the vegetative season, and made a larger contribution to TCp than anthropogenic sources (here: ECbb, OCbb, ECff and OCff) at four of the sites, whereas anthropogenic sources dominated at all but one sites in winter/spring. Levels of OCbb and ECbb were typically higher in winter/spring than in fall, due to larger residential wood burning emissions in the heating season, whereas there was no consistent seasonal pattern for fossil fuel emissions. Biomass burning (OCbb + ECbb) was the major anthropogenic source at the Central European sites in fall, whereas fossil fuel sources dominated at the southernmost and the two northernmost sites. In winter/spring, biomass burning was the major anthropogenic source at all but two sites. Addressing EC in particular, fossil fuel sources dominated at all sites in fall, whereas there was as shift towards biomass burning in winter/spring for the southernmost sites. Influence of residential wood burning emissions was substantial already in the first week of sampling in fall, constituting 30–50 % of TCp at most sites, showing that this source can be dominating even at a time of the year when the ambient temperature in Europe is still rather high. Model calculations were made, attempting to reproduce LHS-derived OCbb and ECbb, using two different residential wood burning emission inventories. Both simulations strongly under-predicted the LHS-derived values at most sites outside Scandinavia. Emissions based on a consistent bottom-up inventory for residential combustion (and including intermediate volatility compounds, IVOC) improved model results at most sites compared to the base-case emissions (based mainly on officially reported national emissions), but at the three southernmost sites the modelled OCbb and ECbb concentrations were still much lower than the LHS source apportioned results. The current study shows that natural sources is a major contributor to the carbonaceous aerosol in Europe even in fall and in winter/spring, and that residential wood burning emissions can be equally large or larger than that of fossil fuel sources, depending on season and region. Our results suggest that residential wood burning emissions are still poorly constrained for large parts of Europe. The need to improve emission inventories is obvious, with harmonization of emission factors between countries likely being the most important step to improve model calculations, not only for biomass burning emissions, but for European PM2.5 concentrations in general.

scholarly journals Black Carbon, Organic Carbon, and Co-Pollutants Emissions and Energy Efficiency from Artisanal Brick Production in Mexico

2017 ◽  
Author(s):  
Miguel Zavala ◽  
Luisa T. Molina ◽  
Pablo Maiz ◽  
Israel Monsivais ◽  
Judith C. Chow ◽  
...  
Keyword(s):  
Energy Efficiency ◽  
Organic Carbon ◽  
Black Carbon ◽  
Emission Factors ◽  
Climate Impacts ◽  
Emission Characteristics ◽  
Probe Technique ◽  
Brick Kilns ◽  
Sampling Probe ◽  
Tracer Ratio

Abstract. In many parts of the developing world and economies in transition, small-scale traditional brick kilns are a notorious source of urban air pollution. Many are both energy inefficient and burn highly polluting fuels that emit significant levels of black carbon (BC), organic carbon (OC) and other atmospheric pollutants into local communities, resulting in severe health and environmental impacts. However, only a very limited number of studies are available on the emission characteristics of brick kilns; thus there is a need to characterize their gaseous and particulate matter (PM) emission factors to better assess their overall contribution to emissions inventories and to quantify their ecological, human health, and climate impacts. In this study, the fuel-, energy-, and brick-based emissions factors and time-based emission ratios of BC, OC, inorganic PM components, CO, SO2, CH4, NOx, and selected volatile organic compounds (VOCs) from two traditional artisanal kilns and one MK2 kiln in Mexico were quantified using the tracer ratio sampling technique. Simultaneous measurements of PM components, CO and CO2 were also obtained using a filter-based sampling probe technique. Additional measurements included the internal temperature of the brick kilns, mechanical resistance of bricks produced, and characteristics of fuels employed. The results show that both techniques capture similar temporal profiles of the brick kiln emissions and produce comparable emission factors, indicating that the tracer ratio technique can be an alternative option to the filter-based sampling probe technique in understanding the temporal profile of the chemical composition of brick kilns emissions. A more integrated inter-comparison of the brick kilns' performances was obtained by simultaneously assessing emissions factors, energy efficiency, fuel consumption, and the quality of the bricks produced. Overall, a well-designed and operated MK2 kiln produced lower PM2.5, BC, OC emission factors and higher energy efficiency than the traditional artisanal brick kilns. Average fuel-based BC emission factors ranged from 0.15–0.58 g/kg-fuel whereas BC / OC mass ratios ranged from 0.9–5.2, depending on the kiln type. The results from this study contribute to the limited number of databases available on the emission characteristics of the informal brick production sector.

Black carbon concentration in the central Himalayas: impact on glacier melt and potential source contribution

2021 ◽  
Author(s):  
Chaman Gul ◽  
Parth Sarathi Mahapatra ◽  
Shichang Kang ◽  
Praveen Kumar Singh ◽  
Xiaokang Wu ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Black Carbon ◽  
Mass Concentration ◽  
Monsoon Season ◽  
Anthropogenic Sources ◽  
Entire Study ◽  
Central Himalayas ◽  
Source Contribution ◽  
Glacier Melt ◽  
Snow Samples

&lt;p&gt;This study discusses year-long (October 2016&amp;#8211;September 2017) observations of atmospheric black carbon (BC) mass concentration, its source and sector contributions using a chemical transport model at a high-altitude (28&amp;#176;12'49.21&quot;N, 85&amp;#176;36'33.77&quot;E, 4900 masl) site located near the Yala Glacier in the central Himalayas, Nepal. During a field campaign, fresh snow samples were collected from the surface of the Yala Glacier in May 2017, which were analysed for BC and water-insoluble organic carbon&lt;strong&gt; &lt;/strong&gt;mass concentration in order to estimate the scavenging ratio and surface albedo reduction. The maximum BC mass concentration in the ambient atmosphere (0.73 &amp;#956;g m&lt;sup&gt;-3&lt;/sup&gt;) was recorded in the pre-monsoon season. The BC and water-insoluble organic carbon analysed from the snow samples were in the range of 96&amp;#8211;542 ng g&lt;sup&gt;-1&lt;/sup&gt; and 152&amp;#8211;827 ng g&lt;sup&gt;-1&lt;/sup&gt;, respectively. The source apportionment study using the absorption &amp;#197;ngstr&amp;#246;m exponent from in situ observations indicated approximately 44% contribution of BC from biomass-burning sources and the remainder from fossil-fuel sources during the entire study period. The source contribution study, using model data sets, indicated ~14% contribution of BC from open-burning and ~77% from anthropogenic sources during the study period. Our analysis of regional contributions of BC indicated that the highest contribution was from both Nepal and India combined, followed by China, while the rest was distributed among the nearby countries. The surface snow albedo reduction, estimated by an online model &amp;#8211; Snow, Ice, and Aerosol Radiation &amp;#8211; was in the range of 0.8&amp;#8211;3.8% during the pre-monsoon season. The glacier melt analysis suggested that BC contributed to approximately 28% of the total melting in the pre-monsoon season.&amp;#160;&lt;/p&gt;

scholarly journals Biomass burning emissions estimated with a global fire assimilation system based on observed fire radiative power

2012 ◽  
Vol 9 (1) ◽  
pp. 527-554 ◽  
Author(s):  
J. W. Kaiser ◽  
A. Heil ◽  
M. O. Andreae ◽  
A. Benedetti ◽  
N. Chubarova ◽  
...  
Keyword(s):  
Organic Matter ◽  
Particulate Matter ◽  
Black Carbon ◽  
Combustion Rate ◽  
Biomass Burning ◽  
Emission Factors ◽  
Modis Aod ◽  
Radiative Power ◽  
Assimilation System ◽  
Fire Radiative Power

Abstract. The Global Fire Assimilation System (GFASv1.0) calculates biomass burning emissions by assimilating Fire Radiative Power (FRP) observations from the MODIS instruments onboard the Terra and Aqua satellites. It corrects for gaps in the observations, which are mostly due to cloud cover, and filters spurious FRP observations of volcanoes, gas flares and other industrial activity. The combustion rate is subsequently calculated with land cover-specific conversion factors. Emission factors for 40 gas-phase and aerosol trace species have been compiled from a literature survey. The corresponding daily emissions have been calculated on a global 0.5° × 0.5° grid from 2003 to the present. General consistency with the Global Fire Emission Database version 3.1 (GFED3.1) within its accuracy is achieved while maintaining the advantages of an FRP-based approach: GFASv1.0 makes use of the quantitative information on the combustion rate that is contained in the FRP observations, and it detects fires in real time at high spatial and temporal resolution. GFASv1.0 indicates omission errors in GFED3.1 due to undetected small fires. It also exhibits slightly longer fire seasons in South America and North Africa and a slightly shorter fire season in Southeast Asia. GFASv1.0 has already been used for atmospheric reactive gas simulations in an independent study, which found good agreement with atmospheric observations. We have performed simulations of the atmospheric aerosol distribution with and without the assimilation of MODIS aerosol optical depth (AOD). They indicate that the emissions of particulate matter need to be boosted by a factor of 2–4 to reproduce the global distribution of organic matter and black carbon. This discrepancy is also evident in the comparison of previously published top-down and bottom-up estimates. For the time being, a global enhancement of the particulate matter emissions by 3.4 is recommended. Validation with independent AOD and PM10 observations recorded during the Russian fires in summer 2010 show that the global Monitoring Atmospheric Composition and Change (MACC) aerosol model with GFASv1.0 aerosol emissions captures the smoke plume evolution well when organic matter and black carbon are enhanced by the recommended factor. In conjunction with the assimilation of MODIS AOD, the use of GFASv1.0 with enhanced emission factors quantitatively improves the forecast of the aerosol load near the surface sufficiently to allow air quality warnings with a lead time of up to four days.

scholarly journals Biomass burning emissions estimated with a global fire assimilation system based on observed fire radiative power

2011 ◽  
Vol 8 (4) ◽  
pp. 7339-7398 ◽  
Author(s):  
J. W. Kaiser ◽  
A. Heil ◽  
M. O. Andreae ◽  
A. Benedetti ◽  
N. Chubarova ◽  
...  
Keyword(s):  
Organic Matter ◽  
Particulate Matter ◽  
Black Carbon ◽  
Combustion Rate ◽  
Biomass Burning ◽  
Emission Factors ◽  
Modis Aod ◽  
Radiative Power ◽  
Assimilation System ◽  
Fire Radiative Power

Abstract. The Global Fire Assimilation System (GFASv1.0) calculates biomass burning emissions by assimilating Fire Radiative Power (FRP) observations from the MODIS instruments onboard the Terra and Aqua satellites. It corrects for gaps in the observations, which are mostly due to cloud cover, and filters spurious FRP observations of volcanoes, gas flares and other industrial activity. The combustion rate is subsequently calculated with land cover-specific conversion factors. Emission factors for 40 gas-phase and aerosol trace species have been compiled from a literature survey. The corresponding daily emissions have been calculated on a global 0.5° × 0.5° grid from 2003 to the present. General consistency with the Global Fire Emission Database version 3.1 (GFED3.1) within its accuracy is achieved while maintaining the advantages of an FRP-based approach: GFASv1.0 makes use of the quantitative information on the combustion rate that is contained in the observations, and it detects fires in real time at high spatial and temporal resolution. GFASv1.0 indicates omission errors in GFED3.1 due to undetected small fires. It also exhibits slightly longer fire seasons in South America and North Africa and a slightly shorter fire season in Southeast Asia. GFASv1.0 has already been used for atmospheric reactive gas simulations in an independent study, which found good agreement with atmospheric observations. We have performed simulations of the atmospheric aerosol distribution with and without the assimilation of MODIS aerosol optical depth (AOD). They indicate that the emissions of particulate matter need to be boosted with a factor of 2–4 to reproduce the global distribution of organic matter and black carbon. This discrepancy is also evident in the comparison of previously published top-down and bottom-up estimates. For the time being, a global enhancement of the particulate matter emissions by 3.4 is recommended. Validation with independent AOD and PM10 observations recorded during the Russian fires in summer 2010 show that the global Monitoring Atmospheric Composition and Change (MACC) aerosol model with GFASv1.0 aerosol emissions captures the smoke plume evolution well when organic matter and black carbon are enhanced by the recommended factor. In conjunction with the assimilation of MODIS AOD, the use of GFASv1.0 with enhanced emission factors quantitatively improves the forecast of the aerosol load near the surface sufficiently to allow air quality warnings with a lead time of up to four days.

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