scholarly journals A high ozone episode in winter 2013 in the Uinta Basin oil and gas region characterized by aircraft measurements

2014 ◽  
Vol 14 (14) ◽  
pp. 20117-20157 ◽  
Author(s):  
S. J. Oltmans ◽  
A. Karion ◽  
R. C. Schnell ◽  
G. Pétron ◽  
C. Sweeney ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Power Plant ◽  
Surface Ozone ◽  
Inversion Layer ◽  
Temperature Inversion ◽  
Gas Production ◽  
Point Sources ◽  
Uinta Basin ◽  
Gas Field ◽  
Near Surface

Abstract. During the winter of 2012–2013 atmospheric surface ozone mole fractions exceeded the US 8 h standard of 75 ppb on 39 days in the Uinta Basin of Utah. As part of the Uinta Basin Winter Ozone Study (UBWOS) aircraft flights were conducted throughout the basin with continuous measurements of ozone (O3), methane (CH4), carbon dioxide (CO2), carbon monoxide (CO), nitrogen dioxide (NO2), and discrete whole air flask samples for determination of ∼50 trace gases including a number of non-methane hydrocarbons (NMHCs). During the course of seven flights conducted between 31 January and 7 February 2013, coinciding with strong, multi-day temperature inversions, O3 levels gradually built up in the shallow boundary layer from ∼45 ppb to ∼140 ppb. Near-surface CH4 mole fractions increased during the episode from near background levels of ∼2 ppm to over 10 ppm. Based on elevated levels of CH4 across the basin and high correlations of CH4 with NMHCs from the discrete air samples, O3 precursor NMHCs were also inferred to be elevated throughout the basin. Discrete plumes of high NO2 were observed in the gas production region of the basin suggesting that gas processing plants and compressor facilities were important point sources of reactive nitrogen oxides (NOx). Vertical profiles obtained during the flights showed that the high O3 mole fractions (as well as other elevated constituents) were confined to a shallow layer from near the ground to 300–400 m above ground level (m a.g.l.) capped by a strong temperature inversion. The highest mole fractions of the measured constituents during the study period were in an isothermal cold layer that varied from ∼300 m depth on 4 February to ∼150 m on 5 February. A gradient layer with declining mole fractions with altitude extended above the isothermal layer to ∼1900 m a.s.l. (300–400 m a.g.l.) indicative of some mixing of air out of the boundary layer. O3 mole fractions continued to increase within the basin as the high O3 episode developed over the course of a week. CH4 mole fractions, on the other hand, leveled off after several days. On several flights, the aircraft sampled the plume of a coal-fired power plant (located east of the main gas field) flowing above the inversion layer. These measurements ruled out the effluents of the power plant as a significant source of NOx for O3 production beneath the temperature inversion in the basin. The presence of elevated O3 precursors within the basin and the rapid daytime production of O3 in the atmosphere beneath the temperature inversion both indicated that O3 was being produced from precursors emitted within the basin beneath the temperature inversion. Although observations show that horizontal winds in the surface layer were relatively light during the high ozone event, they were sufficient to disperse precursors up to 80 km from primary sources in the main gas field in the southeast quadrant to the balance of the Uinta Basin.

scholarly journals O3, CH4, CO2, CO, NO2 and NMHC aircraft measurements in the Uinta Basin oil and gas region under low and high ozone conditions in winter 2012 and 2013

Elem Sci Anth ◽  
2016 ◽  
Vol 4 ◽  
Author(s):  
S. J. Oltmans ◽  
A. Karion ◽  
R. C. Schnell ◽  
G. Pétron ◽  
D. Helmig ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Oil And Gas ◽  
Primary Source ◽  
Combustion Products ◽  
Gas Production ◽  
Cold Pool ◽  
Strong Positive Correlation ◽  
Uinta Basin ◽  
Gas Field ◽  
Oil And Gas Production

Abstract Instrumented aircraft measuring air composition in the Uinta Basin, Utah, during February 2012 and January-February 2013 documented dramatically different atmospheric ozone (O3) mole fractions. In 2012 O3 remained near levels of ∼40 ppb in a well-mixed 500–1000 m deep boundary layer while in 2013, O3 mole fractions >140 ppb were measured in a shallow (∼200 m) boundary layer. In contrast to 2012 when mole fractions of emissions from oil and gas production such as methane (CH4), non-methane hydrocarbons (NMHCs) and combustion products such as carbon dioxide (CO2) were moderately elevated, in winter 2013 very high mole fractions were observed. Snow cover in 2013 helped produce and maintain strong temperature inversions that capped a shallow cold pool layer. In 2012, O3 and CH4 and associated NMHCs mole fractions were not closely related. In 2013, O3 mole fractions were correlated with CH4 and a suite of NMHCs identifying the gas field as the primary source of the O3 precursor NMHC emissions. In 2013 there was a strong positive correlation between CH4 and CO2 suggesting combustion from oil and natural gas processing activities. The presence of O3 precursor NMHCs through the depth of the boundary layer in 2013 led to O3 production throughout the layer. In 2013, O3 mole fractions increased over the course of the week-long episodes indicating O3 photochemical production was larger than dilution and deposition rates, while CH4 mole fractions began to level off after 3 days indicative of some air being mixed out of the boundary layer. The plume of a coal-fired power plant located east of the main gas field was not an important contributor to O3 or O3 precursors in the boundary layer in 2013.

Idealized large-eddy simulations of stratocumulus advecting over cold water. Part 1: Boundary layer decoupling

2021 ◽  
Author(s):  
Youtong Zheng ◽  
Haipeng Zhang ◽  
Daniel Rosenfeld ◽  
Seoung-Soo Lee ◽  
Tianning Su ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Surface Temperature ◽  
Cold Water ◽  
Temperature Inversion ◽  
Atmospheric Modeling ◽  
Sea Surface ◽  
Entrainment Rate ◽  
Surface Cooling ◽  
Near Surface ◽  
Large Eddy

AbstractWe explore the decoupling physics of a stratocumulus-topped boundary layer (STBL) moving over cooler water, a situation mimicking the warm air advection (WADV). We simulate an initially well-mixed STBL over a doubly periodic domain with the sea surface temperature decreasing linearly over time using the System for Atmospheric Modeling large-eddy model. Due to the surface cooling, the STBL becomes increasingly stably stratified, manifested as a near-surface temperature inversion topped by a well-mixed cloud-containing layer. Unlike the stably stratified STBL in cold air advection (CADV) that is characterized by cumulus coupling, the stratocumulus deck in the WADV is unambiguously decoupled from the sea surface, manifested as weakly negative buoyancy flux throughout the sub-cloud layer. Without the influxes of buoyancy from the surface, the convective circulation in the well-mixed cloud-containing layer is driven by cloud-top radiative cooling. In such a regime, the downdrafts propel the circulation, in contrast to that in CADV regime for which the cumulus updrafts play a more determinant role. Such a contrast in convection regime explains the difference in many aspects of the STBLs including the entrainment rate, cloud homogeneity, vertical exchanges of heat and moisture, and lifetime of the stratocumulus deck, with the last being subject to a more thorough investigation in part 2. Finally, we investigate under what conditions a secondary stratus near the surface (or fog) can form in the WADV. We found that weaker subsidence favors the formation of fog whereas a more rapid surface cooling rate doesn’t.

scholarly journals The role of open lead interactions in atmospheric ozone variability between Arctic coastal and inland sites

Elem Sci Anth ◽  
2016 ◽  
Vol 4 ◽  
Author(s):  
Peter K. Peterson ◽  
Kerri A. Pratt ◽  
William R. Simpson ◽  
Son V. Nghiem ◽  
Lemuel X. Pérez Pérez ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Ozone Depletion ◽  
Surface Ozone ◽  
Optical Absorption Spectroscopy ◽  
Atmospheric Ozone ◽  
Vertical Profiles ◽  
Large Spatial Scale ◽  
Near Surface ◽  
Air Masses

Abstract Boundary layer atmospheric ozone depletion events (ODEs) are commonly observed across polar sea ice regions following polar sunrise. During March-April 2005 in Alaska, the coastal site of Barrow and inland site of Atqasuk experienced ODEs (O3< 10 nmol mol-1) concurrently for 31% of the observations, consistent with large spatial scale ozone depletion. However, 7% of the time ODEs were exclusively observed inland at Atqasuk. This phenomenon also occurred during one of nine flights during the BRomine, Ozone, and Mercury EXperiment (BROMEX), when atmospheric vertical profiles at both sites showed near-surface ozone depletion only at Atqasuk on 28 March 2012. Concurrent in-flight BrO measurements made using nadir scanning differential optical absorption spectroscopy (DOAS) showed the differences in ozone vertical profiles at these two sites could not be attributed to differences in locally occurring halogen chemistry. During both studies, backward air mass trajectories showed that the Barrow air masses observed had interacted with open sea ice leads, causing increased vertical mixing and recovery of ozone at Barrow and not Atqasuk, where the air masses only interacted with tundra and consolidated sea ice. These observations suggest that, while it is typical for coastal and inland sites to have similar ozone conditions, open leads may cause heterogeneity in the chemical composition of the springtime Arctic boundary layer over coastal and inland areas adjacent to sea ice regions.

scholarly journals Simulations of a cold-air pool associated with elevated wintertime ozone in the Uintah Basin, Utah

2014 ◽  
Vol 14 (11) ◽  
pp. 15953-16000 ◽  
Author(s):  
E. M. Neemann ◽  
E. T. Crosman ◽  
J. D. Horel ◽  
L. Avey
Keyword(s):  
Boundary Layer ◽  
Snow Cover ◽  
Layer Structure ◽  
Inversion Layer ◽  
Cloud Microphysics ◽  
Photochemical Reactions ◽  
Near Surface ◽  
Cold Air ◽  
Air Temperatures ◽  
Uintah Basin

Abstract. Numerical simulations are used to investigate the meteorological characteristics of the 1–6 February 2013 cold-air pool in the Uintah Basin, Utah, and the resulting high ozone concentrations. Flow features affecting cold-air pools and air quality in the Uintah Basin are studied, including: penetration of clean air into the basin from across the surrounding mountains, elevated easterlies within the inversion layer, and thermally-driven slope and valley flows. The sensitivity of the boundary layer structure to cloud microphysics and snow cover variations are also examined. Ice-dominant clouds enhance cold-air pool strength compared to liquid-dominant clouds by increasing nocturnal cooling and decreasing longwave cloud forcing. Snow cover increases boundary layer stability by enhancing the surface albedo, reducing the absorbed solar insolation at the surface, and lowering near-surface air temperatures. Snow cover also increases ozone levels by enhancing solar radiation available for photochemical reactions.

scholarly journals A numerical process study on the rapid transport of stratospheric air down to the surface over western North America and the Tibetan Plateau

2019 ◽  
Vol 19 (9) ◽  
pp. 6535-6549 ◽  
Author(s):  
Bojan Škerlak ◽  
Stephan Pfahl ◽  
Michael Sprenger ◽  
Heini Wernli
Keyword(s):  
Boundary Layer ◽  
Tibetan Plateau ◽  
Surface Ozone ◽  
Vertical Transport ◽  
The Tibetan Plateau ◽  
Near Surface ◽  
Air Mass ◽  
Ozone Concentrations ◽  
Rapid Transport ◽  
Upper Level

Abstract. Upper-level fronts are often associated with the rapid transport of stratospheric air along tilted isentropes to the middle or lower troposphere, where this air leads to significantly enhanced ozone concentrations. These plumes of originally stratospheric air can only occasionally be observed at the surface because (i) stable boundary layers prevent an efficient vertical transport down to the surface, and (ii) even if boundary layer turbulence were strong enough to enable this transport, the originally stratospheric air mass can be diluted by mixing, such that only a weak stratospheric signal can be recorded at the surface. Most documented examples of stratospheric air reaching the surface occurred in mountainous regions. This study investigates two such events, using a passive stratospheric air mass tracer in a mesoscale model to explore the processes that enable the transport down to the surface. The events occurred in early May 2006 in the Rocky Mountains and in mid-June 2006 on the Tibetan Plateau. In both cases, a tropopause fold associated with an upper-level front enabled stratospheric air to enter the troposphere. In our model simulation of the North American case, the strong frontal zone reaches down to 700 hPa and leads to a fairly direct vertical transport of the stratospheric tracer along the tilted isentropes to the surface. In the Tibetan Plateau case, however, no near-surface front exists and a reservoir of high stratospheric tracer concentrations initially forms at 300–400 hPa, without further isentropic descent. However, entrainment at the top of the very deep boundary layer (reaching to 300 hPa over the Tibetan Plateau) and turbulence within the boundary layer allows for downward transport of stratospheric air to the surface. Despite the strongly differing dynamical processes, stratospheric tracer concentrations at the surface reach peak values of 10 %–20 % of the imposed stratospheric value in both cases, corroborating the potential of deep stratosphere-to-troposphere transport events to significantly influence surface ozone concentrations in these regions.

scholarly journals Ambient Mercury Observations near a Coal-Fired Power Plant in a Western U.S. Urban Area

Atmosphere ◽  
2019 ◽  
Vol 10 (4) ◽  
pp. 176 ◽  
Author(s):  
Lynne Gratz ◽  
Chris Eckley ◽  
Story Schwantes ◽  
Erick Mattson
Keyword(s):  
Power Plant ◽  
Urban Area ◽  
Quality Parameters ◽  
Point Sources ◽  
Urban Site ◽  
Front Range ◽  
Near Surface ◽  
Surface Emission ◽  
Mixing Ratios ◽  
The City

We report on the continuous ambient measurements of total gaseous mercury (TGM) and several ancillary air quality parameters that were collected in Colorado Springs, CO. This urban area, which is located adjacent to the Front Range of the Rocky Mountains, is the second largest metropolitan area in Colorado and has a centrally located coal-fired power plant that installed mercury (Hg) emission controls the year prior to our study. There are few other Hg point sources within the city. Our results, which were obtained from a measurement site < 1 km from the power plant, show a distinct diel pattern in TGM, with peak concentrations occurring during the night (1.7 ± 0.3 ng m−3) and minimum concentrations mid-day (1.5 ± 0.2 ng m−3). The TGM concentrations were not correlated with wind originating from the direction of the plant or with sulfur dioxide (SO2) mixing ratios, and they were not elevated when the atmospheric mixing height was above the effective stack height. These findings suggest that the current Hg emissions from the CFPP did not significantly influence local TGM, and they are consistent with the facility’s relatively low reported annual emissions of 0.20 kg Hg per year. Instead, variability in the regional signal, diurnal meteorological conditions, and/or near-surface emission sources appears to more greatly influence TGM at this urban site.

scholarly journals Evaluation of Polar WRF from Modeling the Atmospheric Boundary Layer over Antarctic Sea Ice in Autumn and Winter

2012 ◽  
Vol 140 (12) ◽  
pp. 3919-3935 ◽  
Author(s):  
Esa-Matti Tastula ◽  
Timo Vihma ◽  
Edgar L Andreas
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Surface Temperature ◽  
Atmospheric Boundary Layer ◽  
Inversion Layer ◽  
Temperature Inversion ◽  
Heat Fluxes ◽  
Poor Correlation ◽  
Antarctic Sea Ice ◽  
Autumn And Winter

Abstract Regional simulations of the atmospheric boundary layer over Antarctic sea ice that have been adequately validated are rare. To address this gap, the authors use the doubly nested Polar Weather Research and Forecasting (Polar WRF) mesoscale model to simulate conditions during Ice Station Weddell (ISW) in the austral autumn and winter of 1992. The WRF simulations test two boundary layer schemes: Mellor–Yamada–Janjic and the Asymmetric Convective Model. Validation is against surface-layer and sounding observations from ISW. Simulated latent and sensible heat fluxes for both boundary layer schemes had poor correlation with the observed fluxes. Simulated surface temperature had better correlation with the observations, with a typical bias of 0–2 K and a root-mean-square error of 6–7 K. For surface temperature and wind speed, the Polar WRF yielded better results than the ECMWF Re-Analysis Interim (ERA-Interim). A more challenging test of the simulations is to reproduce features of the low-level jet and the temperature inversion, which were observed, respectively, in 80% and 96% of the ISW radiosoundings. Both boundary layer schemes produce only about half as many jets as were observed. Moreover, the simulated jet coincided with an observed jet only about 30% of the time. The number of temperature inversions and the height at the inversion base were better reproduced, although this was not the case with the depth of the inversion layer. Simulations of the temperature inversion improved when forecasts of cloud fraction agreed to within 0.3 with observations. The modeled inversions were strongest when the incoming longwave radiation was smallest, but this relationship was not observed at ISW.

scholarly journals Detecting Regime Transitions of the Nocturnal and Polar Near-Surface Temperature Inversion

2020 ◽  
Vol 77 (8) ◽  
pp. 2921-2940
Author(s):  
Amandine Kaiser ◽  
Davide Faranda ◽  
Sebastian Krumscheid ◽  
Danijel Belušić ◽  
Nikki Vercauteren
Keyword(s):  
Boundary Layer ◽  
Atmospheric Boundary Layer ◽  
Time Series Data ◽  
Temperature Inversion ◽  
Series Data ◽  
Small Scale ◽  
Dynamical Regime ◽  
Near Surface ◽  
Nonstationary Field ◽  
Regime Transitions

Abstract Many natural systems undergo critical transitions, i.e., sudden shifts from one dynamical regime to another. In the climate system, the atmospheric boundary layer can experience sudden transitions between fully turbulent states and quiescent, quasi-laminar states. Such rapid transitions are observed in polar regions or at night when the atmospheric boundary layer is stably stratified, and they have important consequences in the strength of mixing with the higher levels of the atmosphere. To analyze the stable boundary layer, many approaches rely on the identification of regimes that are commonly denoted as weakly and very stable regimes. Detecting transitions between the regimes is crucial for modeling purposes. In this work a combination of methods from dynamical systems and statistical modeling is applied to study these regime transitions and to develop an early warning signal that can be applied to nonstationary field data. The presented metric aims to detect nearing transitions by statistically quantifying the deviation from the dynamics expected when the system is close to a stable equilibrium. An idealized stochastic model of near-surface inversions is used to evaluate the potential of the metric as an indicator of regime transitions. In this stochastic system, small-scale perturbations can be amplified due to the nonlinearity, resulting in transitions between two possible equilibria of the temperature inversion. The simulations show such noise-induced regime transitions, successfully identified by the indicator. The indicator is further applied to time series data from nocturnal and polar meteorological measurements.

scholarly journals The relationship between anticyclonic anomalies in northeastern Asia and severe haze in the Beijing–Tianjin–Hebei region

2019 ◽  
Vol 19 (9) ◽  
pp. 5941-5957 ◽  
Author(s):  
Wogu Zhong ◽  
Zhicong Yin ◽  
Huijun Wang
Keyword(s):  
Boundary Layer ◽  
Inversion Layer ◽  
Temperature Inversion ◽  
Fine Particulates ◽  
Northeastern Asia ◽  
Haze Pollution ◽  
Clean Air ◽  
Accumulation Of Pollutants ◽  
Surrounding Areas ◽  
Bth Region

Abstract. Haze pollution in the Beijing–Tianjin–Hebei (BTH) region has become increasingly more severe and persistent in recent years. To better understand the formation of severe haze and its relationship with anticyclonic anomalies over northeastern Asia (AANA), this research focused on severe haze over the BTH region occurring in December during 2014–2016 and examined the impacts of AANA. The results indicated that local meteorological conditions were conducive to severe haze (such as weaker surface winds, a stronger temperature inversion, a shallower boundary layer, and higher relative humidity) and were all closely related to AANA. During severe haze episodes, AANA remained strong in the middle upper troposphere, generating anomalous southeasterly winds near the surface. This effect not only promoted the accumulation of pollutants due to the unique topographical conditions in the BTH region but also caused warm advection in lower levels, which was the main cause of the formation and development of a temperature inversion layer. As a synoptic-scale circulation, AANA were accompanied by anomalous vertical motions in the surrounding areas, which weakened the meridional circulation over the BTH region. Intrusions of clean air from upper levels to the surface and downward transport of westerly momentum at mid-levels and upper levels were suppressed, resulting in weaker northerly winds near the surface and a shallower boundary layer. The thermally indirect zonal circulation between the BTH region and western Pacific triggered by AANA provided a persistent source of moisture for the BTH region, which strengthened the development of severe haze by promoting the growth of fine particulates. The advance and retreat of AANA often corresponded with the emergence and dissipation of severe haze, illustrating that AANA could be effective forecast indicators for air quality.

scholarly journals Simulations of a cold-air pool associated with elevated wintertime ozone in the Uintah Basin, Utah

2015 ◽  
Vol 15 (1) ◽  
pp. 135-151 ◽  
Author(s):  
E. M. Neemann ◽  
E. T. Crosman ◽  
J. D. Horel ◽  
L. Avey
Keyword(s):  
Boundary Layer ◽  
Snow Cover ◽  
Layer Structure ◽  
Inversion Layer ◽  
Cloud Microphysics ◽  
Photochemical Reactions ◽  
Near Surface ◽  
Cold Air ◽  
Air Temperatures ◽  
Uintah Basin

Abstract. Numerical simulations are used to investigate the meteorological characteristics of the 31 January–6 February 2013 cold-air pool in the Uintah Basin, Utah, and the resulting high ozone concentrations. Flow features affecting cold-air pools and air quality in the Uintah Basin are studied, including the following: penetration of clean air into the basin from across the surrounding mountains, elevated easterlies within the inversion layer, and thermally driven slope and valley flows. The sensitivity of the boundary layer structure to snow cover variations and cloud microphysics are also examined. Snow cover increases boundary layer stability by enhancing the surface albedo, reducing the absorbed solar insolation at the surface, and lowering near-surface air temperatures. Snow cover also increases ozone levels by enhancing solar radiation available for photochemical reactions. Ice-dominant clouds enhance cold-air pool strength compared to liquid-dominant clouds by increasing nocturnal cooling and decreasing longwave cloud forcing.

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