scholarly journals Model calculations of the age of firn air across the Antarctic continent

2004 ◽  
Vol 4 (2) ◽  
pp. 1817-1853 ◽  
Author(s):  
K. A. Kaspers ◽  
R. S. W. van de Wal ◽  
M. R. van de Broeke ◽  
J. Schwander ◽  
N. P. M. van Lipzig ◽  
...  
Keyword(s):  
Climate Model ◽  
Accumulation Rate ◽  
Methyl Chloride ◽  
Trace Gas ◽  
Model Calculations ◽  
Antarctic Plateau ◽  
Input Surface ◽  
Antarctic Continent ◽  
High Level ◽  
Air Diffusion

Abstract. The age of firn air in Antarctica at pore close-off depth is only known for a few specific sites where firn air has been sampled for analyses. We present a model that calculates the age of firn air at pore close-off depth for the entire Antarctic continent. The model basically uses four meteorological parameters as input (surface temperature, pressure, accumulation rate and wind speed). Using parameterisations for surface snow density, pore close-off density and tortuosity, in combination with a density-depth model and data of a regional atmospheric climate model, distribution of pore close-off depth for the entire Antarctic continent is determined. The deepest pore close-off depth was found for the East Antarctic Plateau near 72° E, 82° S, at 150±15 m (2σ). A firn air diffusion model was applied to calculate the age of CO2 at pore close-off depth. The results predict that the oldest firn gas (CO2 age) is located between Dome Fuji, Dome Argos and Vostok at 43° E, 78° S being 148±23 (1σ or 38 for 2σ) years old. At this location an atmospheric trace gas record should be obtained. In this study we show that methyl chloride could be recorded with a predicted length of 125 years as an example for trace gas records at this location. The longest record currently available from firn air is derived at South Pole, being 80 years. Sensitivity tests reveal that the locations with old firn air (East Antarctic Plateau) have an estimated uncertainty (2σ) for the modelled CO2 age at pore close-off depth of 30% and of about 40% for locations with younger firn air (CO2 age typically 40 years). Comparing the modelled age of CO2 at pore close-off depth with directly determined ages at seven sites yielded a correlation coefficient of 0.90 and a slope close to 1, suggesting a high level of confidence for the modelled results in spite of considerable remaining uncertainties.

scholarly journals Model calculations of the age of firn air across the Antarctic continent

2004 ◽  
Vol 4 (5) ◽  
pp. 1365-1380 ◽  
Author(s):  
K. A. Kaspers ◽  
R. S. W. van de Wal ◽  
M. R. van den Broeke ◽  
J. Schwander ◽  
N. P. M. van Lipzig ◽  
...  
Keyword(s):  
Climate Model ◽  
Accumulation Rate ◽  
Methyl Chloride ◽  
Trace Gas ◽  
Model Calculations ◽  
Antarctic Plateau ◽  
Input Surface ◽  
Antarctic Continent ◽  
High Level ◽  
Air Diffusion

Abstract. The age of firn air in Antarctica at pore close-off depth is only known for a few specific sites where firn air has been sampled for analyses. We present a model that calculates the age of firn air at pore close-off depth for the entire Antarctic continent. The model basically uses four meteorological parameters as input (surface temperature, pressure, accumulation rate and wind speed). Using parameterisations for surface snow density, pore close-off density and tortuosity, in combination with a density-depth model and data of a regional atmospheric climate model, distribution of pore close-off depth for the entire Antarctic continent is determined. The deepest pore close-off depth was found for the East Antarctic Plateau near 72° E, 82° S, at 150±15 m (2σ). A firn air diffusion model was applied to calculate the age of CO2 at pore close-off depth. The results predict that the oldest firn gas (CO2 age) is located between Dome Fuji, Dome Argos and Vostok at 43° E, 78° S being 148±23 (1σ or 38 for 2σ) years old. At this location an atmospheric trace gas record should be obtained. In this study we show that methyl chloride could be recorded with a predicted length of 125 years as an example for trace gas records at this location. The longest record currently available from firn air is derived at South Pole, being 80 years. Sensitivity tests reveal that the locations with old firn air (East Antarctic Plateau) have an estimated uncertainty (2σ) for the modelled CO2 age at pore close-off depth of 30% and of about 40% for locations with younger firn air (CO2 age typically 40 years). Comparing the modelled age of CO2 at pore close-off depth with directly determined ages at seven sites yielded a correlation coefficient of 0.90 and a slope close to 1, suggesting a high level of confidence for the modelled results in spite of considerable remaining uncertainties.

scholarly journals The Community Firn Model (CFM) v1.0

2020 ◽  
Author(s):  
C. Max Stevens ◽  
Vincent Verjans ◽  
Jessica M.D. Lundin ◽  
Emma C. Kahle ◽  
Annika N. Horlings ◽  
...  
Keyword(s):  
Climate Model ◽  
Noble Gas ◽  
Regional Climate ◽  
Ice Core ◽  
Ice Cores ◽  
Elevation Change ◽  
Model Framework ◽  
Modular Model ◽  
Surface Elevation Change ◽  
Air Diffusion

Abstract. Models that simulate evolution of polar firn are important for several applications in glaciology, including converting ice-sheet elevation-change measurements to mass change and interpreting climate records in ice cores. We have developed the Community Firn Model (CFM), an open-source, modular model framework designed to simulate numerous physical processes in firn. The modules include firn densification, heat transport, meltwater percolation and refreezing, water-isotope diffusion, and firn-air diffusion. The CFM is designed so that new modules can be added with ease. In this paper, we first describe the CFM and its modules. We then demonstrate the CFM's usefulness in two model applications that utilize two of its novel aspects. The CFM currently has the ability to run any of 13 previously published firn-densification models, and in the first application we compare those models' results when they are forced with regional climate model outputs for Summit, Greenland. The results show that the models do not agree well (spread greater than 10 %) when predicting depth-integrated porosity, firn age, or trend in surface-elevation change trend. In the second application, we show that the CFM's coupled firn-air and firn-densification models can simulate noble-gas records from an ice core better than a firn-air model alone.

scholarly journals A Comprehensive Assessment of Tropical Stratospheric Upwelling in Specified Dynamics CESM1.2.2 (WACCM)

2019 ◽  
Author(s):  
Nicholas A. Davis ◽  
Sean M. Davis ◽  
Robert W. Portmann ◽  
Eric Ray ◽  
Karen H. Rosenlof ◽  
...  
Keyword(s):  
Best Practices ◽  
Climate Models ◽  
Climate Model ◽  
Meridional Circulation ◽  
Trace Gas ◽  
Mean Meridional Circulation ◽  
Community Earth System Model ◽  
Free Running ◽  
The Mean ◽  
Wave Momentum

Abstract. Specified dynamics (SD) schemes relax the circulation in climate models toward a reference meteorology to simulate historical variability. These simulations are widely used to isolate the dynamical contributions to variability and trends in trace gas species. However, it is not clear if trends in the stratospheric overturning circulation are properly reproduced by SD schemes. This study assesses numerous SD schemes and modeling choices in the Community Earth System Model (CESM) Whole Atmosphere Chemistry Climate Model (WACCM) to determine a set of best practices for reproducing interannual variability and trends in tropical stratospheric upwelling estimated by reanalyses. Nudging toward the reanalysis meteorology as is typically done in SD simulations expectedly changes the model’s mean upwelling compared to its free-running state, but does not accurately reproduce upwelling trends present in the underlying reanalysis. In contrast, nudging to anomalies from the climatological winds or from the zonal mean winds and temperatures preserves WACCM’s climatology and better reproduces trends in stratospheric upwelling. An SD scheme’s performance in simulating the acceleration of the shallow branch of the mean meridional circulation from 1980–2017 hinges on its ability to simulate the downward shift of subtropical lower stratospheric wave momentum forcing. Key to this is not nudging the zonal-mean temperature field. Gravity wave momentum forcing, which drives a substantial fraction of the upwelling in WACCM, cannot be constrained by nudging and presents an upper-limit on the performance of these schemes.

scholarly journals Air–snow transfer of nitrate on the East Antarctic Plateau – Part 1: Isotopic evidence for a photolytically driven dynamic equilibrium in summer

2013 ◽  
Vol 13 (13) ◽  
pp. 6403-6419 ◽  
Author(s):  
J. Erbland ◽  
W. C. Vicars ◽  
J. Savarino ◽  
S. Morin ◽  
M. M. Frey ◽  
...  
Keyword(s):  
Nitrogen Isotopes ◽  
Dynamic Equilibrium ◽  
Accumulation Rate ◽  
Strong Relationship ◽  
Skin Layer ◽  
Snow Accumulation ◽  
Oxygen Isotope Exchange ◽  
Nitrate Loss ◽  
Antarctic Plateau ◽  
Atmospheric Nitrate

Abstract. Here we report the measurement of the comprehensive isotopic composition (δ15N, Δ17O and δ18O) of nitrate at the air–snow interface at Dome C, Antarctica (DC, 75°06' S, 123°19' E), and in snow pits along a transect across the East Antarctic Ice Sheet (EAIS) between 66° S and 78° S. In most of the snow pits, nitrate loss (either by physical release or UV photolysis of nitrate) is observed and fractionation constants associated are calculated. Nitrate collected from snow pits on the plateau (snow accumulation rate below 50 kg m−2 a−1) displays average fractionation constants of (−59±10) ‰, (+2.0±1.0) ‰ and (+8.7±2.4)‰ for δ15N, Δ17O and δ18O, respectively. In contrast, snow pits sampled on the coast show distinct isotopic signatures with average fractionation constants of (−16±14) ‰, (−0.2±1.5) ‰ and (+3.1±5.8) ‰, for δ15N, Δ17O and δ18O, respectively. Our observations corroborate that photolysis (associated with a 15N / 14N fractionation constant of the order of –48 ‰ according to Frey et al. (2009) is the dominant nitrate loss process on the East Antarctic Plateau, while on the coast the loss is less pronounced and could involve both physical release and photochemical processes. Year-round isotopic measurements at DC show a~close relationship between the Δ17O of atmospheric nitrate and Δ17O of nitrate in skin layer snow, suggesting a photolytically driven isotopic equilibrium imposed by nitrate recycling at this interface. Atmospheric nitrate deposition may lead to fractionation of the nitrogen isotopes and explain the almost constant shift of the order of 25 ‰ between the δ15N values in the atmospheric and skin layer nitrate at DC. Asymptotic δ15N(NO3−) values calculated for each snow pit are found to be correlated with the inverse of the snow accumulation rate (ln(δ15N as. + 1) = (5.76±0.47) ċ (kg m−2 a−1/ A) + (0.01±0.02)), confirming the strong relationship between the snow accumulation rate and the degree of isotopic fractionation, consistent with previous observations by Freyer et al. (1996). Asymptotic Δ17O(NO3−) values on the plateau are smaller than the values found in the skin layer most likely due to oxygen isotope exchange between the nitrate photoproducts and water molecules from the surrounding ice. However, the apparent fractionation in Δ17O is small, thus allowing the preservation of a portion of the atmospheric signal.

Radiation Damage in NaCI: Calculations with an Extended Jain-Lidiard Model

1992 ◽  
Vol 294 ◽  
Author(s):  
Wim J. Soppe ◽  
J. Prij
Keyword(s):  
Rock Salt ◽  
Extended Version ◽  
Salt Formation ◽  
Mole Percent ◽  
Model Calculations ◽  
Nucleation Stage ◽  
Defect Centers ◽  
Waste Repository ◽  
High Level

ABSTRACTThe colloid growth due to irradiation in a rock salt formation is calculated with an extended version of the Jain-Lidiard model. The extensions of the model comprise a description of the nucleation stage of the colloids and the role of impurities on the formation of defect centers. Results of model calculations are shown for a representative design for a high-level radioactive waste repository in a rock salt formation. It is concluded that it is unlikely that, near the waste containers, the fraction of NaCl that will be converted to metallic Na and molecular Cl centers will exceed a few mole percent.

scholarly journals A comprehensive assessment of tropical stratospheric upwelling in the specified dynamics Community Earth System Model 1.2.2 – Whole Atmosphere Community Climate Model (CESM (WACCM))

2020 ◽  
Vol 13 (2) ◽  
pp. 717-734 ◽  
Author(s):  
Nicholas A. Davis ◽  
Sean M. Davis ◽  
Robert W. Portmann ◽  
Eric Ray ◽  
Karen H. Rosenlof ◽  
...  
Keyword(s):  
Climate Models ◽  
Climate Model ◽  
Earth System Model ◽  
System Model ◽  
Trace Gas ◽  
Earth System ◽  
Mean Meridional Circulation ◽  
Community Earth System Model ◽  
The Mean ◽  
Wave Momentum

Abstract. Specified dynamics (SD) schemes relax the circulation in climate models toward a reference meteorology to simulate historical variability. These simulations are widely used to isolate the dynamical contributions to variability and trends in trace gas species. However, it is not clear if trends in the stratospheric overturning circulation are properly reproduced by SD schemes. This study assesses numerous SD schemes and modeling choices in the Community Earth System Model (CESM) Whole Atmosphere Chemistry Climate Model (WACCM) to determine a set of best practices for reproducing interannual variability and trends in tropical stratospheric upwelling estimated by reanalyses. Nudging toward the reanalysis meteorology as is typically done in SD simulations does not accurately reproduce lower-stratospheric upwelling trends present in the underlying reanalysis. In contrast, nudging to anomalies from the climatological winds or anomalies from the zonal-mean winds and temperatures better reproduces trends in lower-stratospheric upwelling, possibly because these schemes do not disrupt WACCM's climatology. None of the schemes substantially alter the structure of upwelling trends – instead, they make the trends more or less AMIP-like. An SD scheme's performance in simulating the acceleration of the shallow branch of the mean meridional circulation from 1980 to 2017 hinges on its ability to simulate the downward shift of subtropical lower-stratospheric wave momentum forcing. Key to this is not nudging the zonal-mean temperature field. Gravity wave momentum forcing, which drives a substantial fraction of the upwelling in WACCM, cannot be constrained by nudging and presents an upper limit on the performance of these schemes.

Extratropical Cyclone Clouds in the GFDL Climate Model: Diagnosing Biases and the Associated Causes

2019 ◽  
Vol 32 (20) ◽  
pp. 6685-6701 ◽  
Author(s):  
Catherine M. Naud ◽  
James F. Booth ◽  
Jeyavinoth Jeyaratnam ◽  
Leo J. Donner ◽  
Charles J. Seman ◽  
...  
Keyword(s):  
Cloud Cover ◽  
Climate Model ◽  
Extratropical Cyclones ◽  
Moist Convection ◽  
Radiative Balance ◽  
Tuning Parameters ◽  
Model Cloud ◽  
Low Levels ◽  
Cloud Parameterization ◽  
High Level

Abstract The clouds in Southern Hemisphere extratropical cyclones generated by the GFDL climate model are analyzed against MODIS, CloudSat, and CALIPSO cloud and precipitation observations. Two model versions are used: one is a developmental version of “AM4,” a model GFDL that will utilize for CMIP6, and the other is the same model with a different parameterization of moist convection. Both model versions predict a realistic top-of-atmosphere cloud cover in the southern oceans, within 5% of the observations. However, an examination of cloud cover transects in extratropical cyclones reveals a tendency in the models to overestimate high-level clouds (by differing amounts) and underestimate cloud cover at low levels (again by differing amounts), especially in the post–cold frontal (PCF) region, when compared with observations. In focusing only on the models, it is seen that their differences in high and midlevel clouds are consistent with their differences in convective activity and relative humidity (RH), but the same is not true for the PCF region. In this region, RH is higher in the model with less cloud fraction. These seemingly contradictory cloud and RH differences can be explained by differences in the cloud-parameterization tuning parameters that ensure radiative balance. In the PCF region, the model cloud differences are smaller than either of the model biases with respect to observations, suggesting that other physics changes are needed to address the bias. The process-oriented analysis used to assess these model differences will soon be automated and shared.

scholarly journals Bifurcation of potential vorticity gradients across the Southern Hemisphere stratospheric polar vortex

2018 ◽  
Vol 18 (11) ◽  
pp. 8065-8077 ◽  
Author(s):  
Jonathan Conway ◽  
Greg Bodeker ◽  
Chris Cameron
Keyword(s):  
Southern Hemisphere ◽  
Potential Vorticity ◽  
Polar Vortex ◽  
Trace Gas ◽  
Stratospheric Polar Vortex ◽  
Distinct Structure ◽  
Barrier Region ◽  
Westerly Winds ◽  
Antarctic Continent ◽  
The Antarctic

Abstract. The wintertime stratospheric westerly winds circling the Antarctic continent, also known as the Southern Hemisphere polar vortex, create a barrier to mixing of air between middle and high latitudes. This dynamical isolation has important consequences for export of ozone-depleted air from the Antarctic stratosphere to lower latitudes. The prevailing view of this dynamical barrier has been an annulus compromising steep gradients of potential vorticity (PV) that create a single semi-permeable barrier to mixing. Analyses presented here show that this barrier often displays a bifurcated structure where a double-walled barrier exists. The bifurcated structure manifests as enhanced gradients of PV at two distinct latitudes – usually on the inside and outside flanks of the region of highest wind speed. Metrics that quantify the bifurcated nature of the vortex have been developed and their variation in space and time has been analysed. At most isentropic levels between 395 and 850 K, bifurcation is strongest in mid-winter and decreases dramatically during spring. From August onwards a distinct structure emerges, where elevated bifurcation remains between 475 and 600 K, and a mostly single-walled barrier occurs at other levels. While bifurcation at a given level evolves from month to month, and does not always persist through a season, interannual variations in the strength of bifurcation display coherence across multiple levels in any given month. Accounting for bifurcation allows the region of reduced mixing to be better characterised. These results suggest that improved understanding of cross-vortex mixing requires consideration of the polar vortex not as a single mixing barrier but as a barrier with internal structure that is likely to manifest as more complex gradients in trace gas concentrations across the vortex barrier region.

scholarly journals Parameterizing radiative transfer to convert MAX-DOAS dSCDs into near-surface box averaged mixing ratios and vertical profiles

2012 ◽  
Vol 5 (5) ◽  
pp. 7641-7673 ◽  
Author(s):  
R. Sinreich ◽  
A. Merten ◽  
L. Molina ◽  
R. Volkamer
Keyword(s):  
Boundary Layer ◽  
Radiative Transfer ◽  
Mexico City ◽  
Vertical Gradient ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Transfer Model ◽  
Model Calculations ◽  
Near Surface ◽  
Mixing Ratios

Abstract. We present a novel parameterization method to convert Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) differential Slant Column Densities (dSCDs) into near-surface box averaged volume mixing ratios. The approach is applicable inside the planetary boundary layer under conditions with significant aerosol load, does not require a-priori assumptions about the trace gas vertical distribution and builds on the increased sensitivity of MAX-DOAS near the instrument altitude. It parameterizes radiative transfer model calculations and significantly reduces the computational effort. The biggest benefit of this method is that the retrieval of an aerosol profile, which usually is necessary for deriving a trace gas concentration from MAX-DOAS dSCDs, is not needed. The method is applied to NO2 MAX-DOAS dSCDs recorded during the Mexico City Metropolitan Area 2006 (MCMA-2006) measurement campaign. The retrieved volume mixing ratios of two elevation angles (1° and 3°) are compared to volume mixing ratios measured by two long-path (LP)-DOAS instruments located at the same site. Measurements are found to agree well during times when vertical mixing is expected to be strong. However, inhomogeneities in the air mass above Mexico City can be detected by exploiting the different horizontal and vertical dimensions probed by MAX-DOAS measurements at different elevation angles, and by LP-DOAS. In particular, a vertical gradient in NO2 close to the ground can be observed in the afternoon, and is attributed to reduced mixing coupled with near surface emission. The existence of a vertical gradient in the lower 250 m during parts of the day shows the general challenge of sampling the boundary layer in a representative way and emphasizes the need of vertically resolved measurements.

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