Retrieval of nitric oxide in the mesosphere from SCIAMACHY
nominal limb spectra
Abstract. We retrieve nitric monoxide (NO) number densities from measurements from the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY, on Envisat) nominal limb mode (0–91 km). We derive the NO number densities from atmospheric emissions in the gamma bands in the range 230–300 nm, measured by the SCIAMACHY ultra-violet (UV) channel 1. We adapt the NO retrieval from the mesosphere and lower thermosphere mode (MLT, 50–150 km) (Bender et al., 2013), including the same 3-D ray tracing, 2-D retrieval grid, and regularisations with respect to altitude and latitude. Since the nominal mode limb scans extend only to about 91 km, we use NO densities in the lower thermosphere (above 92 km) derived from empirical models as a priori input. As priors we use the NOEM model (Marsh et al., 2004) and a regression model derived from the MLT NO data comparison (Bender et al., 2015). Our algorithm yields meaningful NO number densities from 60 km to 85 km from the SCIAMACHY nominal limb mode scans. Using a priori input substantially reduces the misidentification of NO from the lower thermosphere, where no direct limb measurements are available. We achieve a vertical resolution of 5–10 km in the altitude range 65–80 km. Analysing all SCIAMACHY nominal limb scans provides almost ten years (from August 2002 to April 2012) of daily NO measurements in this altitude range. This provides a unique data record of NO in the upper atmosphere and is invaluable to constrain NO in the mesosphere, in particular for testing and validating chemistry climate models during this period.