scholarly journals Fast NO<sub>2</sub> retrievals from Odin-OSIRIS limb scatter measurements

2010 ◽  
Vol 3 (6) ◽  
pp. 5499-5519
Author(s):  
A. E. Bourassa ◽  
C. A. McLinden ◽  
C. E. Sioris ◽  
S. Brohede ◽  
E. J. Llewellyn ◽  
...  

Abstract. The feasibility of retrieving vertical profiles of NO2 from space-based measurements of limb scattered sunlight has been demonstrated using several different data sets since the 1980's. The NO2 data product routinely retrieved from measurements made by the Optical Spectrograph and InfraRed Imaging System (OSIRIS) instrument onboard the Odin satellite uses a spectral fitting technique over the 437 to 451 nm range, over which there are 36 individual wavelength measurements. In this work we present a proof of concept technique for the retrieval of NO2 using only 4 of the 36 OSIRIS measurements in this wavelength range, which reduces the computational cost by almost an order of magnitude. The method is an adaptation of a triplet analysis technique that is currently used for the OSIRIS retrievals of ozone at Chappuis band wavelengths. The results obtained are shown to be in very good agreement with the spectral fit method, and provide an important alternative for two dimensional tomographic algorithms where the computational burden is very high. Additionally this provides a baseline for future instrument design in terms of cost effectiveness and boosting signal to noise by reducing spectral resolution requirements.

2011 ◽  
Vol 4 (5) ◽  
pp. 965-972 ◽  
Author(s):  
A. E. Bourassa ◽  
C. A. McLinden ◽  
C. E. Sioris ◽  
S. Brohede ◽  
A. F. Bathgate ◽  
...  

Abstract. The feasibility of retrieving vertical profiles of NO2 from space-based measurements of limb scattered sunlight has been demonstrated using several different data sets since the 1980's. The NO2 data product routinely retrieved from measurements made by the Optical Spectrograph and InfraRed Imaging System (OSIRIS) instrument onboard the Odin satellite uses a spectral fitting technique over the 437 to 451 nm range, over which there are 36 individual wavelength measurements. In this work we present a proof of concept technique for the retrieval of NO2 using only 4 of the 36 OSIRIS measurements in this wavelength range, which reduces the computational cost by almost an order of magnitude. The method is an adaptation of a triplet analysis technique that is currently used for the OSIRIS retrievals of ozone at Chappuis band wavelengths. The results obtained are shown to be in very good agreement with the spectral fit method, and provide an important alternative for applications where the computational burden is very high. Additionally this provides a baseline for future instrument design in terms of cost effectiveness and reducing spectral range requirements.


2008 ◽  
Vol 86 (7) ◽  
pp. 857-862 ◽  
Author(s):  
R L Gattinger ◽  
D A Degenstein ◽  
E J Llewellyn ◽  
M H Stevens

In this study, we present spectra of the mesospheric OH A2Σ+ –X2Π band system, including the 0–0, 1–1, and 1–0 bands, as observed by OSIRIS (Optical Spectrograph and Infrared Imaging System). Spectral components due to Rayleigh-scattered sunlight, lower thermospheric dayglow emission features, and baffle scatter have been removed to isolate the OH emission signature. The observed spectra are compared with model spectra assembled using rotational emission rate factors for solar resonance fluorescence (g-factors) plus prompt emission of the OH A2Σ+ –X2Π band system from solar Lyman-α photodissociation of water. The observed band ratios are in good agreement with the model values. The altitude variation of the 0–0 band, relative to the 1–1 band, is in agreement with model predictions based on vibrational energy transfer from OH A2Σ+ ν′ = 1 to OH A2Σ+ ν′ = 0. This detailed understanding of the OH A2Σ+ –X2Π system is critical for the successful application of OH observations to the determination of mesospheric OH densities and water vapor concentrations.PACS Nos.: 33.20.Lg, 33.20.Tp, 33.70.Fd, 92.60.hc, 92.60.hw


2007 ◽  
Vol 85 (11) ◽  
pp. 1275-1285 ◽  
Author(s):  
S Brohede ◽  
A Jones ◽  
F Jégou

The two independent instruments on the Odin satellite, the Optical Spectrograph and Infrared Imaging System (OSIRIS) and the Sub-Millimetre Radiometer (SMR) produce atmospheric profiles of various atmospheric species including stratospheric ozone. Comparisons are made between OSIRIS version 3.0 and SMR version 2.1 ozone data to evaluate the consistency of the Odin ozone data sets. Results show good agreement between OSIRIS and SMR in the range 25–40 km, where systematic differences are less than 15% for all latitudes and seasons. Larger systematic differences are seen below 25 km, which can be explained by the increase of various error sources and lower signals. The random differences are between 20–30% in the middle stratosphere. Differences between Odin up-scans and down-scans or AM and PM are insignificant in the middle stratosphere. Furthermore, there is little variation from year to year, but a slight positive trend in the differences (OSIRIS minus SMR) of 0.045 ppmv/year at 30 km over validation period (2002–2006). The fact that the two fundamentally different measurement techniques, (absorption spectroscopy of scattering sunlight and emission measurements in the sub-millimetre region) agree so well, provides confidence in the robustness of both techniques.PACS Nos.: 92.60.Hd, 92.75.Rs, 95.55.Fw, 95.55.Jz


2013 ◽  
Vol 6 (2) ◽  
pp. 3819-3857 ◽  
Author(s):  
C. Adams ◽  
A. E. Bourassa ◽  
V. Sofieva ◽  
L. Froidevaux ◽  
C. A. McLinden ◽  
...  

Abstract. The Optical Spectrograph and InfraRed Imaging System (OSIRIS) was launched aboard the Odin satellite in 2001 and is continuing to take limb-scattered sunlight measurements of the atmosphere. This work aims to characterize and assess the stability of the OSIRIS 11 yr v5.0x ozone data set. Three validation data sets were used: the v2.2 Microwave Limb Sounder (MLS) and v6 Global Ozone Monitoring of Occultation on Stars (GOMOS) satellite data records, and ozone sonde measurements. Global mean percent differences between coincident OSIRIS and validation measurements are within 5% of zero at all altitude layers above 18.5 km for MLS, above 21.5 km for GOMOS, and above 17.5 km for ozone sondes. Below 17.5 km, OSIRIS measurements agree with ozone sondes within 5% and are well-correlated (R > 0.75) with them. For low OSIRIS optics temperatures (< 16 °C), OSIRIS ozone measurements are biased low by up 6% compared with the validation data sets for 25.5–40.5 km. Biases between OSIRIS ascending and descending node measurements were investigated and were found to be related to aerosol retrievals below 27.5 km. Above 30 km, agreement between OSIRIS and the validation data sets was related to the OSIRIS retrieved albedo, which measures apparent upwelling, with a high bias for in OSIRIS data with large albedos. In order to assess the long-term stability of OSIRIS measurements, global average drifts relative to the validation data sets were calculated and were found to be < 3% per decade for comparisons against MLS for 19.5–36.5 km, GOMOS for 18.5–54.5 km, and ozone sondes for 12.5–22.5 km, and within error of 3% per decade at most altitudes. Above 36.5 km, the relative drift for OSIRIS versus MLS ranged from ~ 0–6%, depending on the data set used to convert MLS data to the OSIRIS altitude versus number density grid. Overall, this work demonstrates that the OSIRIS 11 yr ozone data set from 2001 to the present is suitable for trend studies.


2016 ◽  
Author(s):  
Cristen Adams ◽  
Elise N. Normand ◽  
Chris A. McLinden ◽  
Adam E. Bourassa ◽  
Nicholas D. Lloyd ◽  
...  

Abstract. A variant of the limb-nadir matching technique for deriving tropospheric NO2 columns is presented in which the stratospheric component of the NO2 slant column density (SCD) measured by the Ozone Monitoring Instrument (OMI) is removed using non-coincident profiles from the Optical Spectrograph and InfraRed Imaging System (OSIRIS). In order to correct their mismatch in local time and the diurnal variation of stratospheric NO2, OSIRIS profiles, which were measured just after sunrise, were mapped to the local time of OMI observations using a photochemical box model. Following the profile time adjustment, OSIRIS NO2 stratospheric vertical columns densities (VCDs) were calculated. For profiles that did not reach down to the tropopause, VCDs were adjusted using the photochemical model. Using air mass factors from the OMI Standard Product (SP), a new tropospheric NO2 VCD product – referred to as OMI-minus-OSIRIS (OmO) – was generated through limb-nadir matching. To accomplish this, the OMI total SCDs were scaled using correction factors derived from the next-generation SCDs that improve upon the spectral fitting used for the current operational products. One year, 2008, of OmO was generated for 60°S to 60°N and a cursory evaluation was performed. The OmO product was found to capture the main features of tropospheric NO2 including a background value of about 0.3 × 1015 molecules/cm2 over the tropical Pacific and values comparable to the OMI operational products over anthropogenic source areas. While additional study is required, these results suggest that a limb-nadir matching approach is feasible for the removal of stratospheric NO2 measured by a polar orbiter from a nadir-viewing instrument in a geostationary orbit such as Tropospheric Emissions: Monitoring of Pollution (TEMPO) or Sentinel-4.


2014 ◽  
Vol 7 (1) ◽  
pp. 49-64 ◽  
Author(s):  
C. Adams ◽  
A. E. Bourassa ◽  
V. Sofieva ◽  
L. Froidevaux ◽  
C. A. McLinden ◽  
...  

Abstract. The Optical Spectrograph and InfraRed Imaging System (OSIRIS) was launched aboard the Odin satellite in 2001 and is continuing to take limb-scattered sunlight measurements of the atmosphere. This work aims to characterize and assess the stability of the OSIRIS 11 yr v5.0x ozone data set. Three validation data sets were used: the v2.2 Microwave Limb Sounder (MLS) and v6 Global Ozone Monitoring by Occultation of Stars (GOMOS) satellite data records, and ozonesonde measurements. Global mean percent differences between coincident OSIRIS and validation measurements are within 5% at all altitudes above 18.5 km for MLS, above 21.5 km for GOMOS, and above 17.5 km for ozonesondes. Below 17.5 km, OSIRIS measurements agree with ozonesondes within 5% and are well-correlated (R > 0.75) with them. For low OSIRIS optics temperatures (< 16 °C), OSIRIS ozone measurements have a negative bias of 1–6% compared with the validation data sets for 25.5–40.5 km. Biases between OSIRIS ascending and descending node measurements were investigated and found to be related to aerosol retrievals below 27.5 km. Above 30 km, agreement between OSIRIS and the validation data sets was related to the OSIRIS retrieved albedo, which measures apparent upwelling, with a positive bias in OSIRIS data with large albedos. In order to assess the long-term stability of OSIRIS measurements, global average drifts relative to the validation data sets were calculated and were found to be < 3% per decade for comparisons with MLS for 19.5–36.5 km, GOMOS for 18.5–54.5 km, and ozonesondes for 12.5–22.5 km. Above 36.5 km, the relative drift for OSIRIS versus MLS ranged from ~ 0 to 6% per decade, depending on the data set used to convert MLS data to the OSIRIS altitude versus number density grid. Overall, this work demonstrates that the OSIRIS 11 yr ozone data set from 2001 to the present is suitable for trend studies.


2015 ◽  
Author(s):  
Halit Ongen ◽  
Alfonso Buil ◽  
Andrew Brown ◽  
Emmanouil Dermitzakis ◽  
Olivier Delaneau

Motivation: In order to discover quantitative trait loci (QTLs), multi-dimensional genomic data sets combining DNA-seq and ChiP-/RNA-seq require methods that rapidly correlate tens of thousands of molecular phenotypes with millions of genetic variants while appropriately controlling for multiple testing. Results: We have developed FastQTL, a method that implements a popular cis-QTL mapping strategy in a user- and cluster-friendly tool. FastQTL also proposes an efficient permutation procedure to control for multiple testing. The outcome of permutations is modeled using beta distributions trained from a few permutations and from which adjusted p-values can be estimated at any level of significance with little computational cost. The Geuvadis & GTEx pilot data sets can be now easily analyzed an order of magnitude faster than previous approaches. Availability: Source code, binaries and comprehensive documentation of FastQTL are freely available to download at http://fastqtl.sourceforge.net/


2012 ◽  
Vol 5 (4) ◽  
pp. 5493-5526 ◽  
Author(s):  
P. E. Sheese ◽  
K. Strong ◽  
E. J. Llewellyn ◽  
R. L. Gattinger ◽  
J. M. Russell III ◽  
...  

Abstract. The Optical Spectrograph and InfraRed Imaging System (OSIRIS) on the Odin satellite is currently in its 12th year of observing the Earth's limb. For the first time, continuous temperature profiles extending from the stratopause to the upper mesosphere have been derived from OSIRIS observations of Rayleigh-scattered sunlight. OSIRIS temperatures are in good agreement with coincident temperature profiles derived from other satellite and ground-based measurements. In the altitude region of 55–80 km, OSIRIS temperatures are typically within 4–5 K of those from the SABER, ACE-FTS, and SOFIE instruments on the TIMED, SciSat-I, and AIM satellites, respectively. OSIRIS temperatures are typically within 2 K of those from the University of Western Ontario's Purple Crow Lidar in the altitude region of 50–79 km.


Author(s):  
N.J. Long ◽  
M.H. Loretto ◽  
C.H. Lloyd

IntroductionThere have been several t.e.m. studies (1,2,3,4) of the dislocation arrangements in the matrix and around the particles in dispersion strengthened single crystals deformed in single slip. Good agreement has been obtained in general between the observed structures and the various theories for the flow stress and work hardening of this class of alloy. There has been though some difficulty in obtaining an accurate picture of these arrangements in the case when the obstacles are large (of the order of several 1000's Å). This is due to both the physical loss of dislocations from the thin foil in its preparation and to rearrangement of the structure on unloading and standing at room temperature under the influence of the very high localised stresses in the vicinity of the particles (2,3).This contribution presents part of a study of the Cu-Cr-SiO2 system where age hardening from the Cu-Cr and dispersion strengthening from Cu-Sio2 is combined.


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