Identifying possible Stratification phenomenon in ionospheric F2 Layer using the data observed by the Demeter satellite: Method and Results

Abstract. Many studies have revealed the stratification phenomenon of the topside ionospheric F2 layer using ground-based or satellite-based ionograms, which can show direct signs of this phenomenon. However, it is difficult to identify this phenomenon using the satellite-based in situ electron density data. Therefore, a statistical method, using the shuffle resampling skill, is adopted in this paper. For the first time, in situ electron density data, recorded by the same Langmuir probe onboard the Demeter satellite at different altitudes, are analyzed and a possible stratification phenomenon is identified using the proposed method. Our results show that the nighttime stratification, possibly a permanent phenomenon, can cover most longitudes near the geomagnetic equator, which is not found from the daytime data. The arch-like nighttime stratification decreases slowly on the summer hemisphere and thus extends a larger latitudinal distance from the geomagnetic equator. All results, obtained by the proposed method, indicate that the stratification phenomenon is more complex than what has previously been found. The proposed method thus is an effective one, which can also be used on similar studies of comparing fluctuated data.

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Identifying a possible stratification phenomenon in ionospheric F2 layer using the data observed by the DEMETER satellite: method and results

Annales Geophysicae ◽

10.5194/angeo-37-645-2019 ◽

2019 ◽

Vol 37 (4) ◽

pp. 645-655 ◽

Cited By ~ 1

Author(s):

Xiuying Wang ◽

Dehe Yang ◽

Dapeng Liu ◽

Wei Chu

Keyword(s):

Electron Density ◽

Langmuir Probe ◽

Geomagnetic Equator ◽

Density Data ◽

Demeter Satellite ◽

Summer Hemisphere ◽

Electro Magnetic ◽

First Time ◽

Different Altitudes

Abstract. Many studies have revealed the stratification phenomenon of the topside ionospheric F2 layer using ground-based or satellite-based ionograms, which can show direct signs of this phenomenon. However, it is difficult to identify this phenomenon using the satellite-based in situ electron density data. Therefore, a statistical method, using the shuffle resampling skill, is adopted in this paper. For the first time, in situ electron density data, recorded by the same Langmuir probe aboard the DEMETER (Detection of Electro-Magnetic Emission Transmitted from Earthquake Regions) satellite at different altitudes, are analyzed, and a possible stratification phenomenon is identified using the proposed method. Our results show that the nighttime stratification, possibly a permanent phenomenon, can cover most longitudes near the geomagnetic equator, which is not found from the daytime data. The arch-like nighttime stratification decreases slowly on the summer hemisphere and thus extends a larger latitudinal distance from the geomagnetic equator. All results, obtained by the proposed method, indicate that the stratification phenomenon is more complex than what has previously been found. The proposed method is thus an effective one, which can also be used in similar studies of comparing fluctuated data.

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Stratification observed by the in situ measurements from the Swarm satellites

10.5194/angeo-2019-161 ◽

2020 ◽

Author(s):

Xiuying Wang ◽

Wanli Cheng ◽

Zihan Zhou ◽

Dehe Yang ◽

Jing Cui ◽

...

Keyword(s):

Unsolved Problem ◽

Continuous Distribution ◽

Density Measurements ◽

Equatorial Ionization Anomaly ◽

Swarm Satellites ◽

Plasma Peak ◽

First Time ◽

Different Altitudes ◽

New Discovery

Abstract. Stratification phenomenon is investigated using the simultaneous in situ plasma density measurements obtained by the Swarm satellites orbiting at different altitudes above F2 peak. For the first time, the continuous distribution morphology and the exact locations are obtained for the nighttime stratification, which show that the stratification events are centered at the EIA (equatorial ionization anomaly) trough and extend towards the two EIA crests with the most significant part being located at the EIA trough. Another new discovery is the stratification in southern mid-latitudes; stratification events in this region are located on a local plasma peak sandwiched by two lower density strips covering all the longitudes. The formation mechanism of the stratification for the two latitudinal regions is discussed, but the stratification mechanism in southern mid-latitudes remains an unsolved problem.

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A Langmuir Probe – fluxgate magnetometer combination for Comet Interceptor

10.5194/epsc2021-285 ◽

2021 ◽

Author(s):

Johan De Keyser ◽

Sylvain Ranvier ◽

Jeroen Maes ◽

Jordan Pawlak ◽

Eddy Neefs ◽

...

Keyword(s):

Electric Fields ◽

Langmuir Probe ◽

Fluxgate Magnetometer ◽

Magnetic Field Direction ◽

Strong Activity ◽

Plasma Environment ◽

Spacecraft Potential ◽

First Time

ESA&#8217;s Comet Interceptor mission is a low budget, fast track mission to a dynamically new comet (DNC). As a DNC enters the inner solar system for the first time, it is expected to feature strong activity and to display a fluid-scale plasma environment, rather than the kinetic-scale environment encountered at weakly active objects such as 67P. &#160;In situ characterization of this plasma environment is therefore one of the main mission objectives and is the object of the Dust-Fields-Plasma instrument, a suite of sensors for the measurement of the dust, the plasma populations, and the magnetic and electric fields and waves, with the field sensors being mounted on booms, all within strict mass, power, and budget constraints. In this context a sensor has been developed that harbors a fluxgate magnetometer at the center of a hollow spherical Langmuir probe. Precautions have been taken to minimize the possible interference between both, while at the same time being very lightweight. An engineering model has been built, tested and characterized in detail. Together with a companion Langmuir probe and an additional magnetometer in gradiometer configuration, the probe-magnetometer combination (COMPLIMENT + FGM) provides data regarding magnetic and electric fields and waves, total ion and electron densities and electron temperature, as well as the ambient nanodust population. It also offers reference data for the other sensors, such as magnetic field direction, spacecraft potential and total plasma density at high cadence, and integrated EUV flux.

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Probing the Dynamic Self-Assembly Behaviour of Photoswitchable Wormlike Micelles in Real Time

10.26434/chemrxiv.7098695 ◽

2018 ◽

Author(s):

Elaine A. Kelly ◽

Judith E. Houston ◽

Rachel Evans

Keyword(s):

Real Time ◽

Absorption Spectroscopy ◽

Self Assembly ◽

Uv Light ◽

Wormlike Micelles ◽

Tetraethylene Glycol ◽

Light Illumination ◽

First Time ◽

Dependent Processes

Understanding the dynamic self-assembly behaviour of azobenzene photosurfactants (AzoPS) is crucial to advance their use in controlled release applications such asdrug delivery and micellar catalysis. Currently, their behaviour in the equilibrium cis-and trans-photostationary states is more widely understood than during the photoisomerisation process itself. Here, we investigate the time-dependent self-assembly of the different photoisomers of a model neutral AzoPS, <a>tetraethylene glycol mono(4′,4-octyloxy,octyl-azobenzene) </a>(C8AzoOC8E4) using small-angle neutron scattering (SANS). We show that the incorporation of in-situUV-Vis absorption spectroscopy with SANS allows the scattering profile, and hence micelle shape, to be correlated with the extent of photoisomerisation in real-time. It was observed that C8AzoOC8E4could switch between wormlike micelles (transnative state) and fractal aggregates (under UV light), with changes in the self-assembled structure arising concurrently with changes in the absorption spectrum. Wormlike micelles could be recovered within 60 seconds of blue light illumination. To the best of our knowledge, this is the first time the degree of AzoPS photoisomerisation has been tracked in-situthrough combined UV-Vis absorption spectroscopy-SANS measurements. This technique could be widely used to gain mechanistic and kinetic insights into light-dependent processes that are reliant on self-assembly.

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The Total Synthesis of Rhabdastrellic Acid A

10.26434/chemrxiv.7479944 ◽

2018 ◽

Author(s):

Yaroslav Boyko ◽

Christopher Huck ◽

David Sarlah

Keyword(s):

Total Synthesis ◽

Late Stage ◽

Cross Coupling ◽

Side Chains ◽

General Strategy ◽

Modular Approach ◽

Linear Sequence ◽

Generating Sequence ◽

First Time

<div>The first total synthesis of rhabdastrellic acid A, a highly cytotoxic isomalabaricane triterpenoid, has been accomplished in a linear sequence of 14 steps from commercial geranylacetone. The prominently strained trans-syn-trans-perhydrobenz[e]indene core characteristic of the isomalabaricanes is efficiently accessed in a selective manner for the first time through a rapid, complexity-generating sequence incorporating a reductive radical polyene cyclization, an unprecedented oxidative Rautenstrauch cycloisomerization, and umpolung 𝛼-substitution of a p-toluenesulfonylhydrazone with in situ reductive transposition. A late-stage cross-coupling in concert with a modular approach to polyunsaturated side chains renders this a general strategy for the synthesis of numerous family members of these synthetically challenging and hitherto inaccessible marine triterpenoids.</div>

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Catalytic activity of rhodium(I) complexes containing (ω-trimethylsilylalkyl)diphenylphosphines

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19802219 ◽

1980 ◽

Vol 45 (8) ◽

pp. 2219-2223 ◽

Cited By ~ 6

Author(s):

Marie Jakoubková ◽

Martin Čapka

Keyword(s):

Catalytic Activity ◽

Nmr Spectroscopy ◽

Ir Spectroscopy ◽

Electron Density ◽

Phosphorus Atom ◽

Proton Acceptor ◽

Trimethylsilyl Group ◽

Kinetics Of

Kinetics of homogenous hydrogenation of 1-heptene catalysed by rhodium(I) complexes prepared in situ from μ,μ'-dichloro-bis(cyclooctenerhodium) and phosphines of the type RP(C6H5)2 (R = -CH3, -(CH2)nSi(CH3)3; n = 1-4) have been studied. The substitution of the ligands by the trimethylsilyl group was found to increase significantly the catalytic activity of the complexes. The results are discussed in relation to the electron density on the phosphorus atom determined by 31P NMR spectroscopy and to its proton acceptor ability determined by IR spectroscopy.

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Engineered Phage Endolysin Eliminates Gardnerella Biofilm without Damaging Beneficial Bacteria in Bacterial Vaginosis Ex Vivo

Pathogens ◽

10.3390/pathogens10010054 ◽

2021 ◽

Vol 10 (1) ◽

pp. 54

Author(s):

Christine Landlinger ◽

Lenka Tisakova ◽

Vera Oberbauer ◽

Timo Schwebs ◽

Abbas Muhammad ◽

...

Keyword(s):

Bacterial Vaginosis ◽

Bactericidal Activity ◽

High Selectivity ◽

Ex Vivo ◽

Vaginal Microbiome ◽

Wild Type ◽

Wild Type Enzyme ◽

Promising Alternative ◽

First Time

Bacterial vaginosis is characterized by an imbalance of the vaginal microbiome and a characteristic biofilm formed on the vaginal epithelium, which is initiated and dominated by Gardnerella bacteria, and is frequently refractory to antibiotic treatment. We investigated endolysins of the type 1,4-beta-N-acetylmuramidase encoded on Gardnerella prophages as an alternative treatment. When recombinantly expressed, these proteins demonstrated strong bactericidal activity against four different Gardnerella species. By domain shuffling, we generated several engineered endolysins with 10-fold higher bactericidal activity than any wild-type enzyme. When tested against a panel of 20 Gardnerella strains, the most active endolysin, called PM-477, showed minimum inhibitory concentrations of 0.13–8 µg/mL. PM-477 had no effect on beneficial lactobacilli or other species of vaginal bacteria. Furthermore, the efficacy of PM-477 was tested by fluorescence in situ hybridization on vaginal samples of fifteen patients with either first time or recurring bacterial vaginosis. In thirteen cases, PM-477 killed the Gardnerella bacteria and physically dissolved the biofilms without affecting the remaining vaginal microbiome. The high selectivity and effectiveness in eliminating Gardnerella, both in cultures of isolated strains as well as in clinically derived samples of natural polymicrobial biofilms, makes PM-477 a promising alternative to antibiotics for the treatment of bacterial vaginosis, especially in patients with frequent recurrence.

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Chromosomal painting of the sandpiper (Actitis macularius) detects several fissions for the Scolopacidae family (Charadriiformes)

BMC Ecology and Evolution ◽

10.1186/s12862-020-01737-x ◽

2021 ◽

Vol 21 (1) ◽

Author(s):

Melquizedec Luiz Silva Pinheiro ◽

Cleusa Yoshiko Nagamachi ◽

Talita Fernanda Augusto Ribas ◽

Cristovam Guerreiro Diniz ◽

Patricia Caroline Mary O´Brien ◽

...

Keyword(s):

Chromosome Painting ◽

Diploid Number ◽

Chromosomal Evolution ◽

Long Distance ◽

Chromosomal Painting ◽

Cytogenetic Studies ◽

Burhinus Oedicnemus ◽

Clear Idea ◽

First Time

Abstract Background The Scolopacidae family (Suborder Scolopaci, Charadriiformes) is composed of sandpipers and snipes; these birds are long-distance migrants that show great diversity in their behavior and habitat use. Cytogenetic studies in the Scolopacidae family show the highest diploid numbers for order Charadriiformes. This work analyzes for the first time the karyotype of Actitis macularius by classic cytogenetics and chromosome painting. Results The species has a diploid number of 92, composed mostly of telocentric pairs. This high 2n is greater than the proposed 80 for the avian ancestral putative karyotype (a common feature among Scolopaci), suggesting that fission rearrangements have formed smaller macrochromosomes and microchromosomes. Fluorescence in situ hybridization using Burhinus oedicnemus whole chromosome probes confirmed the fissions in pairs 1, 2, 3, 4 and 6 of macrochromosomes. Conclusion Comparative analysis with other species of Charadriiformes studied by chromosome painting together with the molecular phylogenies for the order allowed us to raise hypotheses about the chromosomal evolution in suborder Scolopaci. From this, we can establish a clear idea of how chromosomal evolution occurred in this suborder.

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Stretchable supercapacitor at −30 °C

Energy & Environmental Science ◽

10.1039/d0ee04066e ◽

2021 ◽

Author(s):

Xuting Jin ◽

Li Song ◽

Hongsheng Yang ◽

Chunlong Dai ◽

Yukun Xiao ◽

...

Keyword(s):

First Time

A stretchable supercapacitor at −30 °C was developed for the first time by in situ growth of polyaniline onto the newly-designed anti-freezing organohydrogel polyelectrolyte.

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Direct TEM observation of the “acanthite α-Ag2S–argentite β-Ag2S” phase transition in a silver sulfide nanoparticle

Nanoscale Advances ◽

10.1039/c8na00347e ◽

2019 ◽

Vol 1 (4) ◽

pp. 1581-1588 ◽

Cited By ~ 6

Author(s):

S. I. Sadovnikov ◽

E. Yu. Gerasimov

Keyword(s):

Electron Microscopy ◽

Phase Transition ◽

Transmission Electron Microscopy ◽

Silver Sulfide ◽

Transmission Electron ◽

Silver Sulfide Nanoparticles ◽

Microscopy Method ◽

Electron Microscopy Method ◽

First Time

For the first time, the α-Ag2S (acanthite)–β-Ag2S (argentite) phase transition in a single silver sulfide nanoparticles has been observed in situ using a high-resolution transmission electron microscopy method in real time.

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