Continuous flow analysis of the Mount Brown South ice core

2021 ◽  
Author(s):  
Margaret Harlan ◽  
Helle Astrid Kjær ◽  
Tessa Vance ◽  
Paul Vallelonga ◽  
Vasileios Gkinis ◽  
...  
Keyword(s):  
Indian Ocean ◽  
Size Distribution ◽  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
East Antarctica ◽  
Southern Indian Ocean ◽  
Indian Ocean Region ◽  
Continuous Flow Analysis ◽  
Ocean Region

<p>The Mount Brown South (MBS) ice core is an approximately 300-meter-long ice core, drilled in 2016-2017 to the south of Mount Brown, Wilhelm II Land, East Antarctica. This location in East Antarctica was chosen as it produces an ice core with well-preserved sub-annual records of both chemistry and isotope concentrations, spanning back over 1000 years. MBS is particularly well suited to represent climate variations of the Indian Ocean sector of Antarctica, and to provide information about regional volcanism in the Southern Indian Ocean region.</p><p>A section of ice spanning the length of the MBS core was melted as part of the autumn 2019 continuous flow analysis (CFA) campaign at the Physics of Ice, Climate, and Earth (PICE) group at the University of Copenhagen. During this campaign, measurements were conducted for chemistry and impurities contained in the ice, in addition to water isotopes. The data measured in Copenhagen include measurements of H<sub>2</sub>O<sub>2,</sub> pH, electrolytic conductivity, and NH<sub>4</sub><sup>+</sup>, Ca<sup>2+</sup>, and Na<sup>+</sup> ions, in addition to insoluble particulate concentrations and size distribution measured using an Abakus laser particle counter.</p><p>Here, we present an overview of the CFA chemistry and impurity data, as well as preliminary investigations into the size distribution of insoluble particles and the presence of volcanic material within the ice. These initial chemistry and particulate size distribution data sets are useful in order to identify sections of the MBS core to subject to further analysis to increase our understanding of volcanic activity in the Southern Indian Ocean region.</p>

scholarly journals Calculating uncertainty for the RICE ice core continuous flow analysis water isotope record

2018 ◽  
Vol 11 (8) ◽  
pp. 4725-4736 ◽  
Author(s):  
Elizabeth D. Keller ◽  
W. Troy Baisden ◽  
Nancy A. N. Bertler ◽  
B. Daniel Emanuelsson ◽  
Silvia Canessa ◽  
...  
Keyword(s):  
High Resolution ◽  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
Calibration Error ◽  
Data Set ◽  
Total Uncertainty ◽  
Continuous Flow Analysis ◽  
Uncertainty Estimates ◽  
Water Isotope

Abstract. We describe a systematic approach to the calibration and uncertainty estimation of a high-resolution continuous flow analysis (CFA) water isotope (δ2H, δ18O) record from the Roosevelt Island Climate Evolution (RICE) Antarctic ice core. Our method establishes robust uncertainty estimates for CFA δ2H and δ18O measurements, comparable to those reported for discrete sample δ2H and δ18O analysis. Data were calibrated using a time-weighted two-point linear calibration with two standards measured both before and after continuously melting 3 or 4 m of ice core. The error at each data point was calculated as the quadrature sum of three factors: Allan variance error, scatter over our averaging interval (error of the variance) and calibration error (error of the mean). Final mean total uncertainty for the entire record is δ2H=0.74 ‰ and δ18O=0.21 ‰. Uncertainties vary through the data set and were exacerbated by a range of factors, which typically could not be isolated due to the requirements of the multi-instrument CFA campaign. These factors likely occurred in combination and included ice quality, ice breaks, upstream equipment failure, contamination with drill fluid and leaks or valve degradation. We demonstrate that our methodology for documenting uncertainty was effective across periods of uneven system performance and delivered a significant achievement in the precision of high-resolution CFA water isotope measurements.

Synoptic climatology of southern Indian Ocean and paleoclimate proxy interpretation

2021 ◽  
Author(s):  
Danielle Udy ◽  
Tessa Vance ◽  
Anthony Kiem ◽  
Neil Holbrook ◽  
Mark Curran
Keyword(s):  
Indian Ocean ◽  
Climate Variability ◽  
Large Scale ◽  
Ice Core ◽  
East Antarctica ◽  
Synoptic Climatology ◽  
Southern Indian Ocean ◽  
Westerly Wind ◽  
Weather Patterns ◽  
Modes Of Climate Variability

<p>Weather systems in the southern Indian Ocean drive synoptic-scale precipitation, temperature and wind variability in East Antarctica, sub-Antarctic islands and southern Australia.  Over seasonal to decadal timescales, the mean condition associated with combinations of these synoptic weather patterns (e.g., extratropical cyclones, fronts and regions of high pressure) is often referred to as variability in the westerly wind belt or the Southern Annular Mode (SAM). The westerly wind belt is generally considered to be zonally symmetric around Antarctica however, on a daily timescale this is not the case. To capture the daily variability of regional weather systems, we used synoptic typing (Self-Organising Maps) to group weather patterns based on similar features, which are often lost when using monthly or seasonal mean fields. We identified nine key regional weather types based on anomaly pattern and strength. These include four meridional nodes, three mixed nodes, one zonal node and one transitional node. The meridional nodes are favourable for transporting warm, moist air masses to the subantarctic and Antarctic region, and are associated with increased precipitation and temperature where the systems interact with the Antarctic coastline.  These nodes have limited association with the SAM, especially during austral spring.  In contrast, the zonal and mixed nodes were strongly correlated with the SAM however, the regional synoptic representation of SAM positive conditions is not zonally symmetric and is represented by three separate nodes.  These different types of SAM positive conditions mean that the commonly used hemispheric Marshall index often fails to capture the regional variability in surface weather conditions in the southern Indian Ocean. Our results show the importance of considering different synoptic set ups of SAM conditions, particularly SAM positive, and identify conditions that are potentially missed by SAM variability (e.g., extreme precipitation events). Our results are particularly important to consider when interpreting SAM or westerly wind belt reconstructions in the study region (from ice cores, tree rings, or lake sediments).  Here we present a case study using the synoptic typing results to enhance our understanding of the Law Dome (East Antarctica) ice core record, focussing on links to large scale modes of climate variability and Australian hydroclimate.  These results enhance the usefulness of ice core proxies in coastal East Antarctica and assist with determining where and how it is appropriate to use coastal East Antarctic ice core records for reconstructions of large scale modes of climate variability (e.g. SAM and ENSO) and remote hydroclimate conditions.</p>

scholarly journals Improved methodologies for continuous-flow analysis of stable water isotopes in ice cores

2017 ◽  
Vol 10 (2) ◽  
pp. 617-632 ◽  
Author(s):  
Tyler R. Jones ◽  
James W. C. White ◽  
Eric J. Steig ◽  
Bruce H. Vaughn ◽  
Valerie Morris ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Isotope Ratio Mass Spectrometry ◽  
Absorption Spectrometry ◽  
Isotopic Analysis ◽  
Water Isotopes ◽  
Stable Water Isotopes ◽  
Continuous Flow Analysis

Abstract. Water isotopes in ice cores are used as a climate proxy for local temperature and regional atmospheric circulation as well as evaporative conditions in moisture source regions. Traditional measurements of water isotopes have been achieved using magnetic sector isotope ratio mass spectrometry (IRMS). However, a number of recent studies have shown that laser absorption spectrometry (LAS) performs as well or better than IRMS. The new LAS technology has been combined with continuous-flow analysis (CFA) to improve data density and sample throughput in numerous prior ice coring projects. Here, we present a comparable semi-automated LAS-CFA system for measuring high-resolution water isotopes of ice cores. We outline new methods for partitioning both system precision and mixing length into liquid and vapor components – useful measures for defining and improving the overall performance of the system. Critically, these methods take into account the uncertainty of depth registration that is not present in IRMS nor fully accounted for in other CFA studies. These analyses are achieved using samples from a South Pole firn core, a Greenland ice core, and the West Antarctic Ice Sheet (WAIS) Divide ice core. The measurement system utilizes a 16-position carousel contained in a freezer to consecutively deliver  ∼  1 m  ×  1.3 cm2 ice sticks to a temperature-controlled melt head, where the ice is converted to a continuous liquid stream and eventually vaporized using a concentric nebulizer for isotopic analysis. An integrated delivery system for water isotope standards is used for calibration to the Vienna Standard Mean Ocean Water (VSMOW) scale, and depth registration is achieved using a precise overhead laser distance device with an uncertainty of ±0.2  mm. As an added check on the system, we perform inter-lab LAS comparisons using WAIS Divide ice samples, a corroboratory step not taken in prior CFA studies. The overall results are important for substantiating data obtained from LAS-CFA systems, including optimizing liquid and vapor mixing lengths, determining melt rates for ice cores with different accumulation and thinning histories, and removing system-wide mixing effects that are convolved with the natural diffusional signal that results primarily from water molecule diffusion in the firn column.

scholarly journals Sulphate record from a northeast Greenland ice core over the last 1200 years based on continuous flow analysis

2002 ◽  
Vol 35 ◽  
pp. 250-256 ◽  
Author(s):  
Matthias Bigler ◽  
Dietmar Wagenbach ◽  
Hubertus Fischer ◽  
Josef Kipfstuhl ◽  
Heinrich Miller ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
Depth Resolution ◽  
The Novel ◽  
Small Shift ◽  
Annual Layer ◽  
Continuous Flow Analysis ◽  
Clear Identification ◽  
Relative Errors

AbstractA 150 m deep ice core from the low-accumulation area of northeast Greenland was analyzed for sulphate, calcium, sodium and electrolytical meltwater conductivity at a depth resolution of approximately 1 cm by continuous flow analysis (CFA). the calcium and sodium profiles are used to establish a relatively precise ice-core chronology by annual-layer counting back to AD 830. Inspection of the novel CFA method for sulphate revealed relative errors typically around 15%, but at least ±20 ng g–1, for concentrations 5130 ng g–1, and a current detection limit for routine ice-core analyses of 40 ng g–1. Annual sulphate peaks are shown to occur over almost the entire core, with only a small shift in seasonality between the modern and pre-industrial sections. Inspection of volcanic horizons allowed more accurate timing of these peaks and clear identification of calcium-rich events. Disregarding clear volcanic peaks, significant long-term changes of sulphate are only seen over the industrial period. However, a higher frequency of important volcanic inputs was identified around AD 1200.

scholarly journals Improved Methodologies for Continuous Flow Analysis of Stable Water Isotopes in Ice Cores

2016 ◽  
Author(s):  
Tyler R. Jones ◽  
James W. C. White ◽  
Eric J. Steig ◽  
Bruce H. Vaughn ◽  
Valerie Morris ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Isotope Ratio Mass Spectrometry ◽  
Isotopic Analysis ◽  
Water Isotopes ◽  
Mixing Length ◽  
Stable Water Isotopes ◽  
Continuous Flow Analysis

Abstract. Water isotopes in ice cores are used as a climate proxy for local temperature and regional atmospheric circulation as well as evaporative conditions in moisture source regions. Traditional measurements of water isotopes have been achieved using magnetic sector isotope ratio mass spectrometry (IRMS). However, a number of recent studies have shown that laser absorption spectrometers (LAS) perform as well or better than IRMS. The new LAS technology has been combined with continuous flow analysis (CFA) to improve data density and sample throughput in numerous prior ice coring projects. Here, we present a comparable semi-automated LAS-CFA system for measuring high-resolution water isotopes of ice cores. We outline new methods for partitioning both system uncertainty and system mixing length into liquid and vapor components – useful measures for defining and improving the overall performance of the system. Critically, our methods take into account the uncertainty of depth registration that is not present in IRMS nor fully accounted for in other CFA studies. We also explain a method for introducing consecutive sections of isotopically distinct ice at the melt head to define the system-wide mixing length. These analyses are achieved using samples from a South Pole firn core, a Greenland ice core, and the WAIS Divide ice core. The measurement system utilizes a 16-position carousel contained in a freezer to consecutively deliver ~ 1 m × 1.3 cm2 ice sticks to a temperature controlled melt head, where the ice is converted to a continuous liquid stream, and eventually vaporized using a concentric nebulizer for isotopic analysis. An integrated delivery system for water isotope standards is used for calibration to the VSMOW-SLAP scale and depth registration is achieved using a precise overhead laser distance device with an uncertainty of ±0.2 mm. As an added check on our system, we perform inter-lab LAS comparisons using WAIS Divide ice samples, a corroboratory step not taken in prior CFA studies. The overall results are important for substantiating data obtained from LAS-CFA systems, including optimizing liquid and vapor mixing lengths, determining melt rates for ice cores with different accumulation and thinning histories, and removing system-wide mixing effects that are convolved with the natural diffusional signal that results primarily from water molecule diffusion in the firn column.

Forty years later: High resolution continuous flow analysis of the Dye3 ice core

2021 ◽  
Author(s):  
Helle Astrid Kjær ◽  
Margaret Harlan ◽  
Paul Vallelonga ◽  
Anders Svensson ◽  
Thomas Blunier ◽  
...  
Keyword(s):  
High Resolution ◽  
Forest Fires ◽  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Sheet ◽  
Greenland Ice Sheet ◽  
Ice Cores ◽  
The Core ◽  
Continuous Flow Analysis

<div><span><span>The Dye-3 ice core was drilled to bedrock at the Southern part of the central Greenland ice sheet (65°11'N, 43°50'W) in 1979-1981. The southern location is characterized by high accumulation rates compared to more central locations of the ice sheet. Since its drilling, numerous analyses of the core have been performed, and the ice has since been in freezer storage both in the USA and in Denmark.</span></span></div><div><span>In October and November 2019, the remaining ice, two mostly complete sections covering the depths of 1753–1820m and 1865–1918m of the Dye-3 core, were melted during a continuous flow analysis (CFA) campaign at the Physics of Ice, Climate, and Earth (PICE) group at the University of Copenhagen. The data represents both Holocene, Younger Dryas and Glacial sections (GS 5 to 12).</span></div><div> </div><div><span><span>The measured data consist chemistry and impurities contained in the ice, isotopes, as well as analysis of methane and other atmospheric gases. </span></span></div><div><span><span>The chemistry measurements include NH</span></span><span><span><sub>4</sub></span></span><span><span><sup>+</sup></span></span><span><span>, Ca</span></span><span><span><sup>2+</sup></span></span><span><span>, and Na</span></span><span><span><sup>+</sup></span></span><span><span> ions, which besides being influenced by transport, provide information about forest fires, wind-blown dust, and sea ice, respectively, as well as acidity, which aids in the identification of volcanic events contained in the core. The quantity and grain size distribution of insoluble particles was analyzed by means of an Abakus laser particle counter.</span></span></div><div> </div><div><span>We compare the new high-resolution CFA record of dye3 with previous analysis and thus evaluate the progress made over 40 years. Further we compare overlapping time periods with other central Greenland ice cores and discuss spatial patterns in relation to the presented climate proxies.</span></div>

scholarly journals High-resolution continuous flow analysis setup for water isotopic measurement from ice cores using laser spectroscopy

2014 ◽  
Vol 7 (12) ◽  
pp. 12081-12124 ◽  
Author(s):  
B. D. Emanuelsson ◽  
W. T. Baisden ◽  
N. A. N. Bertler ◽  
E. D. Keller ◽  
V. Gkinis
Keyword(s):  
Response Time ◽  
Laser Spectroscopy ◽  
Temporal Resolution ◽  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Flow Measurements ◽  
Continuous Flow Analysis ◽  
Δ18o And Δd

Abstract. Here we present an experimental setup for water stable isotopes (δ18O and δD) continuous flow measurements. It is the first continuous flow laser spectroscopy system that is using Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS; analyzer manufactured by Los Gatos Research – LGR) in combination with an evaporation unit to continuously analyze sample from an ice core. A Water Vapor Isotopic Standard Source (WVISS) calibration unit, manufactured by LGR, was modified to: (1) increase the temporal resolution by reducing the response time (2) enable measurements on several water standards, and (3) to reduce the influence from memory effects. While this setup was designed for the Continuous Flow Analysis (CFA) of ice cores, it can also continuously analyze other liquid or vapor sources. The modified setup provides a shorter response time (~54 and 18 s for 2013 and 2014 setup, respectively) compared to the original WVISS unit (~62 s), which is an improvement in measurement resolution. Another improvement compared to the original WVISS is that the modified setup has a reduced memory effect. Stability tests comparing the modified WVISS and WVISS setups were performed and Allan deviations (σAllan) were calculated to determine precision at different averaging times. For the 2013 modified setup the precision after integration times of 103 s are 0.060 and 0.070‰ for δ18O and δD, respectively. For the WVISS setup the corresponding σAllan values are 0.030, 0.060 and 0.043‰ for δ18O, δD and δ17O, respectively. For the WVISS setup the precision is 0.035, 0.070 and 0.042‰ after 103 s for δ18O, δD and δ17O, respectively. Both the modified setups and WVISS setup are influenced by instrumental drift with δ18O being more drift sensitive than δD. The σAllan values for δ18O of 0.30 and 0.18‰ for the modified (2013) and WVISS setup, respectively after averaging times of 104 s (2.78 h). The Isotopic Water Analyzer (IWA)-modified WVISS setup used during the 2013 Roosevelt Island Climate Evolution (RICE) ice core processing campaign achieved high precision measurements, in particular for δD, with high temporal resolution for the upper part of the core, where a seasonally resolved isotopic signal is preserved.

scholarly journals Continuous-Flow Analysis of δ17O, δ18O, and δD of H2O on an Ice Core from the South Pole

2021 ◽  
Vol 9 ◽  
Author(s):  
Eric J. Steig ◽  
Tyler R. Jones ◽  
Andrew J. Schauer ◽  
Emma C. Kahle ◽  
Valerie A. Morris ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Ice Core ◽  
Flow Analysis ◽  
South Pole ◽  
Deuterium Excess ◽  
The South ◽  
Continuous Flow Analysis ◽  
Hydrogen Isotope Ratios ◽  
Δ18o And Δd ◽  
Replicate Measurements

The δD and δ18O values of water are key measurements in polar ice-core research, owing to their strong and well-understood relationship with local temperature. Deuterium excess, d, the deviation from the average linear relationship between δD and δ18O, is also commonly used to provide information about the oceanic moisture sources where polar precipitation originates. Measurements of δ17O and “17O excess” (Δ17O) are also of interest because of their potential to provide information complementary to d. Such measurements are challenging because of the greater precision required, particularly for Δ17O. Here, high-precision measurements are reported for δ17O, δ18O, and δD on a new ice core from the South Pole, using a continuous-flow measurement system coupled to two cavity ring-down laser spectroscopy instruments. Replicate measurements show that at 0.5 cm resolution, external precision is ∼0.2‰ for δ17O and δ18O, and ∼1‰ for δD. For Δ17O, achieving external precision of <0.01‰ requires depth averages of ∼50 cm. The resulting ∼54,000-year record of the complete oxygen and hydrogen isotope ratios from the South Pole ice core is discussed. The time series of Δ17O variations from the South Pole shows significant millennial-scale variability, and is correlated with the logarithmic formulation of deuterium excess (dln), but not the traditional linear formulation (d).

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